cooperating with them were developing a type of ground sound-ranging
apparatus which it was hoped could be utilized to give troops warning
of the firing of heavy artillery shells in their general direction.
Preliminary experiments show that at a distance of 4.1 miles this
mechanism could record the firing of a gun some 19 seconds before the
arrival of the shell. Under proper circumstances this elapsed time
would enable troops properly warned to seek cover from the explosion
of the projectile. This development of sound-ranging apparatus and its
application to the protection of personnel was made possible by the
far greater speed with which shock vibrations travel through a dense
medium like the earth than through the usual sound-conveying medium,
the atmosphere.
SEARCHLIGHTS.
The searchlight equipment of the United States Army prior to 1914
consisted chiefly of lights located at our coast defenses. In 1916
we began the development of mobile searchlight-and-power units for
field-army work, four horse-drawn equipments, with 36-inch lights,
being ordered first, and later eight other sets, with extensible towers
and gasoline electric generators. When the war was approaching we
ordered 85 sets of the limber-and-caisson type. The caissons of these
sets carried 24-inch lights on extensible towers. In January, 1917,
we ordered 50 high-intensity lights to replace as many low-intensity
lamps at our seacoast fortifications. The first war order was placed in
April, 1917, and consisted of 20 additional searchlights of the 60-inch
dimension, the largest light ordered by the War Department.
After the entrance of America in the war the Engineer Department
began studying the requirements abroad for searchlights used in
defense against hostile aircraft; and in September, 1917, this
investigation resulted in orders for 360 high-intensity searchlights,
693 high-intensity arc mechanisms, and 1,000 glass mirrors of standard
design.
About this time we began looking to the improvement of existing
searchlight equipment. The cooperation of leading scientists,
manufacturers, and Government bureaus was obtained, and the product
of exhaustive experiments was 18 different new kinds of searchlights
either partially or wholly developed.
The first of these were produced, shipped, and were in operation with
the Second Field Army in France on October 1, 1918. This was a new form
of searchlight more powerful than any that had been produced before
that time. It weighed one-eighth as much as lights of former design,
cost only one-third as much, was about one-fourth as large in bulk, and
threw a light 10 per cent stronger than any other portable projector in
existence.
Without going into the details of this mechanism its most striking
innovation, from the standpoint of the nontechnical observer, was the
absence of the front glass through which the beams of the older type
lamps are sent. The absence of the glass, while reducing the weight
and cost of a light, also increased the intensity of the beam of the
searchlight, since any glass, no matter how conducive to rays, absorbs
light to a considerable extent.
In the first part of the war we took the 36-inch lights which the
Government had on hand and mounted them on motor trucks. For generating
power for the lights, motor trucks were equipped with electric
generators operated by the crank-shaft of the truck engine. In moving
about each truck carried not only the light and power unit and
accessories, but provided space for the crew and their equipment.
When we went into the war there was only one firm in the United States
that could make the large searchlight mirrors, but two other concerns
developed the art and the faculties during the hostilities. These
mirrors were of glass and cost about $1,000 at prewar prices. The
maximum output in the United States before the war was three 60-inch
mirrors per week. As the result of governmental encouragement the
production of the 60-inch mirrors increased until it reached the stage
of 15 a week in November, 1918; and the price was reduced to about $900
per mirror, even under war-time conditions with respect to labor and
material. This was equivalent to a price of about $700 per mirror under
normal conditions, or a saving of 30 per cent.
A remarkable contribution of the United States to searchlight science
was the production of a satisfactory metal mirror for projecting the
beam. The metal mirror not only weighed a little less than the glass
mirror, but it cost only one-third as much as the glass one, could be
produced in one-fifth the time, was much less fragile, and extended the
possibility of manufacture to a wide number of industries. The metal
mirror possessed 97 per cent of the reflectivity of the glass mirror.
This slight dullness is inappreciable in searchlight work and more than
compensated for by the other qualities of the metal reflector. This
type of mirror, however, had not yet been put in production when the
war ended.
Our inventors during the 19 months of hostilities succeeded in
reducing the size of carbons used in 200-ampere lamps from 2 inches in
diameter to 1-1/8 inches. This cut the cost of carbons in two, but the
improvements tripled the amount of light developed.
In November, 1918, we were working with assurance of success to develop
a simple system whereby field searchlights could be pointed and
controlled from a distance. Such controls had been used in experimental
work prior to 1917, but the mechanisms were complicated and not
suitable for field service.
The searchlight section of the Corps of Engineers also developed
optical finding devices, which doubled the range of all searchlights
without requiring any modification of the lights themselves. Neither
the ordinary telescope nor night glass is suitable for target finding
by searchlight. The result of our investigation was the development
of a combined observer's chair, eye protector, and searchlight target
finder, the new equipment adding only 10 per cent to the cost of the
searchlight unit.
The range of our modern high-power searchlight, whose target is a ship
at sea, is about 15,000 yards; the range of this searchlight when its
target is an airplane is about 15,000 feet.
BOOK IV.
CHEMICAL WARFARE.
CHAPTER I.
TOXIC GASES.
The first recorded use of suffocating gases in warfare was about 431
B. C., sulphur fumes having been used in besieging the cities of
Platea and Belium in the war between the Athenians and the Spartans.
Similar uses of toxic substances are recorded during the Middle Ages.
In August, 1855, the English Admiral Lord Dundonald, having observed
the deadly character of the fumes of sulphur in Sicily, proposed to
reduce Sebastopol by sulphur fumes, and worked out the details of the
proposition. The English Government disapproved the proposition on the
ground that "the effects were so horrible that no honorable combatant
could use the means required to produce them."
That the probable use of poison gases was still in the minds of
military men is evidenced by the fact that at The Hague conference in
1899 several of the more prominent nations of Europe and Asia pledged
themselves not to use any projectiles whose only object was to give out
suffocating or poisonous gases. Many of the Powers did not sign this
declaration until later. Germany signed and ratified it on September 4,
1900, but the United States never signed it. Further, this declaration
was not to be binding in case of a war in which a non-signatory was or
became a belligerent. Admiral Mahan, a United States delegate, stated
his position in regard to the use of gas in shell, at that time an
untried theory, as follows:
The reproach of cruelty and perfidy addressed against these
supposed shells was equally uttered previously against firearms
and torpedoes, although both are now employed without scruple.
It is illogical and not demonstrably humane to be tender about
asphyxiating men with gas, when all are prepared to admit
that it is allowable to blow the bottom out of an ironclad at
midnight, throwing four or five hundred men into the sea to
be choked by the water, with scarcely the remotest chance to
escape.
The Second Hague Peace Congress in 1907 adopted rules for land warfare,
and among them was article 23 which read as follows: "It is expressly
forbidden to employ poisons or poisonous weapons."
The use of toxic gas in the great war dates back to April 22, 1915, on
which day the Germans employed chlorine, a common and well-known gas,
in an attack against the French and British lines in the northeastern
part of the upper Ypres salient.
The methods of manufacturing toxic gases, the use of such gases, and
the tactics connected with their use were new developments of this war;
yet during the year 1918 from 20 to 30 per cent of all American battle
casualties were due to gas, showing that toxic gas is one of the most
powerful implements of war. The records show, however, that when armies
were supplied with masks and other defensive appliances, only about 3
or 4 per cent of the gas casualties were fatal. This indicates that gas
can be made not only one of the most effective implements of war, but
one of the most humane. It will, of course, be necessary to remove the
noncombatant population from a greater depth of country immediately in
the rear of the fighting lines than formerly, in order that women and
children may not be gassed. This additional sacrifice of territory for
war uses is another element of effectiveness in the weapon.
Since Germany had chosen to utilize toxic gas in warfare, the allied
nations were compelled to adopt like tactics; accordingly England and
France, faced with the desperate situation resulting from advantages
secured by the Germans through the employment of these new weapons,
immediately turned their attention not only to devising methods
for protecting their own troops, but also to securing supplies and
equipment necessary for the utilization of toxic gas as an agent of
warfare against the German Army.
Germany originated thereafter the use of most of the new forms of gas,
but the allied nations and America were actually producing, at the time
of the armistice, gases on a much greater scale than Germany was ever
able to attain. In fact, America itself was producing gases at a rate
several times as great as was possible in Germany.
Prior to the entry of America in the war our overseas observers had
been collecting information bearing upon gas warfare, referring the
facts so obtained to the Ordnance Department in Washington, where the
information was turned over to Lieut. Col. E. J. W. Ragsdale, who was
then in charge of the Trench Warfare Section.
In the early days of our belligerency it was seen that we should need
a plant for filling artillery shell with toxic gases. The Government
in the fall of 1917 bought a large tract of land near Aberdeen, Md.,
to be an artillery proving ground. Approximately 3,400 acres of this
reservation, about one-tenth of it in area, was set aside as the
site for the gas shell-filling plant. This reservation was known as
Edgewood, and the plant erected on the site was called the Edgewood
Arsenal. Work started on the construction of the arsenal on November 1,
1917.
None of the toxic gases in use in Europe, except chlorine and small
amounts of phosgene, had ever been commercially prepared in the
United States. It was the original intention to interest existing
chemical firms in the manufacture of these gases; but there were many
difficulties in the way of such a project, not the least of which was
the ruling of the Director General of Railways that such products as
poison gas be transported only on special trains.
Also we discovered that the private chemical companies were loath to
undertake such manufacture. The exhaustive investigations necessary
before quantity methods of manufacture could be devised would be
uncertain and expensive. There would be great danger to the lives of
those employed in such work. Many of the private concerns were already
crowded with war work. Finally, the new plant equipment which must be
set up would be worth nothing when the war ended, since the manufacture
of such gases would be limited to the period of hostilities. These and
other considerations explain the reluctance of the commercial chemical
industry to undertake the production of war gases.
Consequently the Government was forced to adopt the plan of building
various chemical plants at the Edgewood Arsenal in connection with the
filling plant. By December 1, 1917, it had been decided to build at
Edgewood a chlorpicrin plant and a phosgene plant. The contracts were
immediately let, and the work was pushed through the rigorous winter of
1917-18.
In March, 1918, the Edgewood project was taken from the Trench Warfare
Section of the Ordnance Department and made an independent division
under the command of Col. Wm. H. Walker. In June, 1918, the Chemical
Warfare Service was organized, and the Edgewood Arsenal was transferred
to it. Gen. W. L. Sibert, Director of the Gas Service, took charge of
the activities of the arsenal in May prior to the official transfer.
Chlorine, the raw material for the manufacture of which is common salt,
was one of the principal materials required in the gas-production
program. Although chlorine was a standard product in the United States
prior to the war, it was soon seen that we had an inadequate commercial
supply to meet the requirements of our proposed gas offensive. Chlorine
was used not only by itself, but it was also the active agent in the
manufacture of nearly all the other toxic gases which we required.
Consequently we decided to build a Government chlorine plant with two
50-ton units, giving a daily capacity of 100 tons of liquid chlorine.
The ground for this plant at Edgewood was broken on May 11, 1918, and
the actual production of chlorine begun on September 1.
In July, 1917, the Germans introduced the so-called mustard gas. It
was immediately realized that for certain purposes of fighting this
chemical was the most effective product so far employed, and a large
number of Government experts here at once concentrated their energies
in developing methods for its manufacture on a large scale. Not only
were the uniformed experimenters busy at the Gas Service's American
University Camp, at Washington, D. C., but experimental units were
established at the plant of the Dow Chemical Co., at Midland, Mich.,
at the plant of Zinsser & Co., Hastings-on-Hudson, N. Y., and at the
Government plant which had been started by the Trench Warfare Section,
at Cleveland, Ohio.
Eventually it was decided to erect a large plant at Edgewood for the
manufacture of mustard gas. Not until April, 1918, however, did we
feel that we possessed sufficient knowledge and information to justify
the construction of a mustard-gas plant on a large scale. France
and England also were long in working out satisfactory methods of
mustard-gas production. We began to make mustard in June, and continued
with rapidly increasing output until the signing of the armistice.
It soon became evident that we could not depend upon civilian labor in
the operation of the various chemical plants at Edgewood because of the
danger involved. It was decided, therefore, to utilize enlisted men in
the working crews. As the projects at Edgewood increased in size and
number, the forces at the arsenal grew, until at one time there were
7,400 troops at this point.
Meanwhile the Government had at last been able to persuade a number
of private chemical firms to manufacture toxic gases. The Government
agreed to finance all new construction, but the operation was to be in
the hands of the contracting companies. At each plant the Government
stationed one of its representatives with necessary assistants. In the
spring of 1918, these scattered factories by official order were made
part of the Edgewood Arsenal, each plant being designated by the name
of the city or town where it was located. Thereafter in Army usage the
term "Edgewood Arsenal" embraced not only the group of factories on the
Edgewood reservation, but also included the following projects:
Niagara Falls plant, operated by the Oldbury Electro-Chemical Co.
Project--the manufacture of phosgene.
Midland, Mich., plant, operated by the Dow Chemical Co. Project--the
sinking of 17 brine wells for the purpose of securing adequate supplies
of bromine.
Charleston, W. Va., plant, operated by the Charleston Chemical Co.
Project--the manufacture of sulphur chloride.
Bound Brook, N. J., plant, operated by Frank Hemingway (Inc.).
Project--the manufacture of phosgene.
Buffalo plant, operated by the National Aniline & Chemical Co.
Project--the manufacture of mustard gas.
In addition to these, the Edgewood Arsenal built at points advantageous
to supplies of raw materials four other plants, and operated them as
well. These were as follows:
Stamford, Conn., plant. Project--the manufacture of chlorpicrin.
Hastings-on-Hudson, N. Y., plant. Project--the manufacture of mustard
gas.
Kingsport, Tenn., plant. Project--the manufacture of brombenzylcyanide.
Croyland, Pa., plant. Project--the manufacture of diphenylchlorarsine.
In constructing and equipping the Edgewood Arsenal we laid 21 miles
of standard-gauge railway and 15 miles of narrow-gauge railway, built
nearly 15 miles of improved roadway, and set up two water systems, one
with a capacity of 1,500,000 gallons per day for the manufacturing
purposes of the chemical plants, and the other providing a fresh-water
supply pumped 4 miles with a daily capacity of 2,000,000 gallons. In
all 558 buildings were put up on the grounds of the arsenal. There
were 86 cantonment buildings, with a capacity of 8,400 men, as well
as adequate quarters for officers and civilian employees. Three field
hospitals, a complete base hospital, and separate buildings for Y. M.
C. A. and K. of C. activities indicated the extent of the building
equipment. Three power houses were provided, with a total capacity of
26,500 kilowatts.
In the construction of buildings every precaution was taken to avoid
accidents from the handling of toxic gas, the ventilating systems being
as near perfection as human science could make them. It is notable that
out of the thousands of men employed only four met their death by gas
poisoning. Three of these casualties were due to phosgene and one to
mustard gas.
To show that all of the danger of the war was not confined to the
front, the following table of casualties in 1918 at the Edgewood
Arsenal proper is here given:
-----------------+------+------+-----+------+-----+-----+-----+-------
Toxic agent. |June. |July. |Aug. |Sept. |Oct. |Nov. |Dec. |Total.
-----------------+------+------+-----+------+-----+-----+-----+-------
Mustard gas | 14 | 41 | 190 | 153 | 227 | 47 | 2 | 674
Stannic chloride | | 3 | 8 | 15 | 21 | 3 | | 50
Phosgene | | | 3 | 7 | 2 | 17 | 1 | 50
Chlorpicrin | | 14 | 18 | 9 | 3 | | | 44
Bleach chlorine | | 2 | 39 | 2 | 1 | | | 44
Liquid chlorine | | 1 | 3 | 2 | 7 | 5 | | 18
Sulphur chloride | | | 2 | 1 | 6 | | | 9
Phosphorus | | 2 | 7 | 5 | 1 | | | 15
Caustic soda | | | 3 | | 3 | 4 | | 10
Sulphuric acid | | | 4 | 3 | 1 | | | 8
Picric acid | | | 2 | | | | | 2
Carbon monoxide | | | | | 1 | | | 1
+------+------+-----+------+-----+-----+-----+-------
Totals | 14 | 63 | 279 | 197 | 293 | 76 | 3 | 925
-----------------+------+------+-----+------+-----+-----+-----+-------
As has been noted, chlorine was the only war gas produced on a
commercial scale in America prior to the war. At the ordinary
temperatures chlorine is a greenish-yellow gas of strong, suffocating
odor. Through the combined effects of cold and pressure it is readily
condensed to a liquid and is ordinarily shipped in this form, stored in
strong cylinders.
Chlorine is prepared commercially by the electrolytic process. A
current of electricity is passed through a solution of common salt. The
greenish gas at once arises, leaving behind it a residue of caustic
soda. The apparatus in which the salt is decomposed by the electric
current is known as a cell. The Government plant used Nelson cells,
each with a capacity of 60 pounds of chlorine and 65 pounds of caustic
soda per 24 hours.
The Government chlorine plant at Edgewood was ready for operation in
August, 1918, but was not actually started until September 1. The plant
consisted of (1) a cell house, which had a total capacity of 100 tons
of chlorine per 24 hours; (2) an electric substation for supplying the
current; (3) a brine building, where the salt was mixed with water and
the resulting brine purified; (4) a boiler and evaporation building,
for concentrating the caustic soda from the cells; (5) a caustic fusion
building, for drying the caustic soda and fusing it into solid form for
shipment; and (6) a liquefying plant to condense and liquefy 50 tons of
chlorine per day.
With the exception of chlorine, chlorpicrin was the first war gas to be
manufactured on a large scale in this country. When pure, chlorpicrin
is a colorless liquid which boils at a temperature approximately of
112° C. The compound has been known since 1848. While not so poisonous
as some of the other products used in gas warfare, it is, nevertheless,
an active poison, and has the additional advantage of being a fair
lachrymator, or tear producer.
Chlorpicrin is made by the reaction between picric acid and chlorine.
The chlorine is best supplied in the form of so-called bleaching
powder, which is ordinary chloride of lime. In the manufacturing
process as originally carried out, free picric acid was mixed with
bleaching powder held in suspension with water. Later it was found
advantageous to use calcium picrate instead of picric acid.
Accordingly, the final process was as follows: The bleaching powder
was creamed with water and mixed with a solution of calcium picrate in
large stills holding 5,000 gallons or more. A jet of live steam was
then introduced at the bottom of the still, and the reaction began
at once, the rapidity depending upon the amount of steam introduced.
The resulting chlorpicrin, together with a certain quantity of steam,
passed out of the still and was liquefied in the condenser. The
resulting mixture of chlorpicrin and water was run into tanks, where
the chlorpicrin, being insoluble in water, gradually settled to the
bottom and was run off and used directly in gas shell.
In developing this process the Government was assisted by the Dow
Chemical Co., the Semet-Solvay Co., and the American Synthetic
Color Co., of Stamford, Conn., the principal work being done by
representatives of the Bureau of Mines at the Stamford plant.
[Illustration: AIRPLANE VIEW OF CHLORINE PLANT, EDGEWOOD ARSENAL.]
[Illustration: CHLORINE PLANT, EDGEWOOD ARSENAL.
This is the largest single chlorine and caustic soda plant in
the country. Its capacity, when entirely completed, is 100 tons
of chlorine and 112 tons of fused caustic soda per day.]
[Illustration: CHLORPICRIN PLANT AT EDGEWOOD ARSENAL.
Bleaching powder, lime, and picric acid are received by rail.
In the mixers appearing in the right foreground lime, picric
acid, and water are mixed to form a solution of calcium picric,
and bleach and water are mixed to form a cream. These solutions
are pumped together into any of the several stills, where they
react to form chlorpicrin. This plant was rated at 12½ tons of
chlorpicrin a day, but reached a production as high as 31 tons
on one day.]
[Illustration: MIXER BUILDING OF PHOSGENE PLANT AT EDGEWOOD ARSENAL.
The capacity of this building is 20 tons of liquid phosgene per
day. Dry 98 per cent gaseous chlorine, as obtained directly
from the cells of the chlorine plant, and pure carbon monoxide
obtained from the producers, are mixed in approximate equal
volumes and the mixture passed through catalyzers, where the
two gases combine to form phosgene. The resultant gas is
liquefied in the condensers, appearing in the left.]
[Illustration: CHLORINE PLANT, EDGEWOOD ARSENAL.
One of eight cell rooms, capacity 12½ tons gaseous chlorine per day.
Each cell room consists of six circuits--74 cells per circuit, or a
total of 444 cells per room.]
[Illustration:
IN THE FOREGROUND THE CHLORINE PIPE LINE FROM CHLORINE PLANT
PASSING TO CHEMICAL PLANTS IN RIGHT CENTER OF THE PICTURE. ON
THE EXTREME RIGHT THE MUSTARD GAS PLANT. IN UPPER LEFT AND
CENTER, VIEW OF FILLING PLANTS AND SHELL DUMPS.]
[Illustration: FILLING 1-TON CONTAINERS WITH PHOSGENE.
Each empty cylinder weighs 1,300 pounds and will contain 1,650 pounds
of liquid. The plant shown fills 25 cylinders per day.]
[Illustration: MACHINE FILLING 75-MILLIMETER SHELL WITH MUSTARD GAS.]
[Illustration: FILLING HAND GRENADES WITH WHITE PHOSPHORUS.
Empty grenades are first completely immersed in a shallow
hot-water bath, shown on extreme left in photo. In a tank that
is not shown in picture white phosphorus is melted under water,
and this molten phosphorus is pumped by a small centrifugal
pump into a system of distributing pipes. Through a flexible
tube and by hand, each grenade is completely filled with
molten phosphorus, displacing the water in them. While the
grenades are still immersed in the water bath, a suction tube
is inserted in each grenade to remove the molten phosphorus
to a certain depth below the top of the grenade, this molten
phosphorus being displaced by water in the bath. The operation
shown in the photo depicts the grenades thus filled with molten
phosphorus to a definite heighth and with the remaining heighth
filled with water, having the water removed from the top of the
phosphorus by suction, after being taken out of the bath.]
[Illustration: FILLING MUSTARD GAS SHELL AT EDGEWOOD ARSENAL.
Inspected empty shell, as shown inverted on the left in the
foreground, are placed on small filling trucks, shown in the
right middle ground, and run under filling machine. Filled
shell with boosters screwed down leave the tunnel, as shown
in center of picture, where any possible mustard gas liquid
on them is vaporized by gasoline torch. A draft from this
operation into the tunnel prevents the distribution of mustard
gas vapor throughout the plant. The loaded shell are then
placed on trucks, as shown in foreground of photo.]
[Illustration: FILLING LIVENS DRUMS AT EDGEWOOD ARSENAL.
This photo shows the Livens drums being filled with phosgene.
The range of this special type of projectile, known as the
Livens drum, is about 1,500 yards. Its empty weight is about 30
pounds, and it contains a charge of about 30 pounds of gas.]
[Illustration: PAINTING AND STRIPING FILLED SHELL AT EDGEWOOD ARSENAL.
After leaving the filling plants, shell are classified by
weight into four groups and each group maintained separately.
The shell then are stored in an inverted position to detect
leaks. After testing for 24 hours, the shell are buffed,
painted, and striped by spray painting, as shown on the
endless conveyor, and then are ready for packing. In the left
background will be noted Livens drums being similarly painted.]
[Illustration: SHELL DUMP AT EDGEWOOD ARSENAL.
This picture shows filled shell being stored for leakage test before
being painted.]
[Illustration: FILLED CONTAINERS OF PHOSGENE, READY AT EDGEWOOD ARSENAL
FOR OVERSEAS SHIPMENT.
Each container holds approximately 1 ton of liquid.]
[Illustration: PHOSPHORUS CLOUDS FROM BURSTS OF 75-MILLIMETER SHELL AT
LAKEHURST, N. J., PROVING GROUNDS.]
[Illustration: GAS CLOUD FROM 4.7-INCH GAS SHELL EXPLODING 8,533 YARDS
AWAY FROM THE GUN AT LAKEHURST.] America's whole supply of chlorpicrin
during the war came from the American Synthetic Color Co. and the
Edgewood Arsenal. The Stamford plant was the first to reach large-scale
production.
The contract with the American Synthetic Color Co. was dated December
13, 1917; and the company shipped over 111,853 pounds of the gas to
Edgewood on March 11. This, when mixed with the necessary stannic
chloride, supplies of which were already on the ground, was sufficient
to fill approximately 100,000 75-millimeter shell. In the spring of
1918, due to certain internal troubles at the Stamford plant, it was
agreed that the United States should lease this factory and operate it
as a Government plant. Under Government operation the total production
of chlorpicrin at the Stamford plant amounted to 3,226,000 pounds, of
which 2,703,300 pounds were shipped overseas in 660-pound drums.
The chlorpicrin plant at Edgewood went into entire operation on June
14, 1918. Up to the signing of the armistice this plant had produced
2,320,000 pounds of chlorpicrin.
Phosgene was one of the deadliest gases employed in the war. Numerous
other gases were used to annoy the enemy and force the wearing of
masks, but phosgene was a killer employed to produce as many casualties
as possible. The gas did not persist long in the air or on the ground
after the shell had exploded, so that it was an ideal chemical for use
in an attack. The gas would clear away by the time the troops following
reached the place of gas concentration.
Phosgene at ordinary temperatures is a colorless gas, but it condenses
to a liquid at 8° C. It is formed by the combination of two gases,
chlorine and carbon monoxide, in the presence of a catalyzer. The
reaction is best conducted in iron boxes lined with lead and filled
with charcoal of proper quality, into which boxes a stream of the
reacting gases, mixed in proper proportions, is introduced. The
reaction creates heat, and means must usually be taken to keep the
reaction boxes cooled. The resulting phosgene is condensed to a liquid
by passing the gas through a condenser which is surrounded by brine
kept cold by refrigeration. The liquid is then stored in strong steel
containers or run directly into Livens drums or artillery shell.
Prior to 1917, the Oldbury Electro-Chemical Co., of Niagara Falls, N.
Y., had set up a small experimental phosgene plant in the hope that the
experiments might lead to the commercial utilization of carbon monoxide
which was obtained by this company as a by-product in the manufacture
of phosphorus. When we entered the war the company had developed its
process to such efficiency as to warrant the construction of a large
phosgene plant, and the Government entered into a contract with the
company for the creation of facilities with a capacity of 10 tons of
phosgene per day. Also, because of the great importance of phosgene in
warfare, it was decided at the same time to build a Government phosgene
plant at Edgewood. A little later the Government financed a phosgene
plant at the factory of Frank Hemingway (Inc.), at Bound Brook, N. J.
The total output of the original small experimental plant at Niagara
Falls, which was later leased by the United States, was 83,070 pounds
of phosgene, of which 24,800 pounds were shipped overseas. The contract
with the Oldbury Chemical Co. for its main phosgene plant was signed on
January 15, 1918. Production here began on August 5 and by August 20
had reached a daily average of 5 tons. On November 1 the average daily
production was 7 tons. The total quantity produced at this plant was
435 tons. The plant loaded 18,768 Livens drums with phosgene, each drum
holding about 30 pounds. This plant was operated by enlisted men.
The contract with Frank Hemingway (Inc.) called for a factory producing
5 tons of phosgene per day by a secret process controlled by the
company. The construction of the plant was begun on February 2, 1918,
and phosgene was first manufactured on May 17. This concern reached its
maximum of 5 tons per day by August 1, and produced in all 205 tons of
phosgene.
Construction of the phosgene plant at Edgewood was begun on March 1,
1918. The plant consisted of four catalyzer buildings, each building
having four units, each unit possessing a projected capacity of 5 tons
of phosgene per day. The total capacity, therefore, was designed to be
80 tons per day. The carbon monoxide used in the process was produced
by passing a mixture of oxygen and carbon dioxide over heated coke in
a gas producer, the oxygen being supplied by a Claude machine with a
capacity of 100,000 cubic feet of oxygen every 24 hours. The chlorine
used came partly from the Edgewood chlorine plant and partly from
outside sources.
The actual production of phosgene at Edgewood began on July 5, 1918,
and worked up to an output of 20 tons per day by the date of the
armistice. The total production of phosgene at Edgewood was 935 tons.
The total output of phosgene from all three plants, Edgewood and the
Bound Brook and Niagara Falls operations, at the date of the armistice
was 35 tons per day; and this was increasing to reach 95 tons per day
by May 1, 1919. The total phosgene produced by all the plants before
the armistice was 1,616 tons.
The Germans, in spite of their attainments in chemistry, were never
able to improve their clumsy and expensive methods of producing mustard
gas. The best reports we have show that at the time the fighting ended,
all of Germany's chemical warfare facilities could not produce more
than 6 tons of mustard per day. The United States alone had ten times
that capacity on the same date, while France and England both reached a
heavy output. So concerned was the German high command because of the
fact that Germany was being outdistanced in the production of mustard
gas that the ablest spy of the German Empire was sent into France in
October, 1918, to find out the French method of making mustard. One of
the Chemical Warfare officers who accompanied our forces into German
territory reported that the Germans had decided to adopt the American
method of making mustard gas and to stop their former process.
Mustard gas was by no means a child of the great war, having been
prepared in experimental quantities since 1886. It is a colorless,
slightly oily liquid, boiling at 220° C. with some decomposition. When
perfectly pure it freezes at 14° C.; but, since it usually contains
small percentages of impurities, it usually remains liquid at 0° C, or
even below that. In chemistry the substance is known as dichlorethyl
sulphide.
The first commercial process proposed for the manufacture of mustard
gas depended upon the use of ethylene chlorhydrin; and on April 13,
1918, a contract was made with the Commercial Research Co., Flushing,
Long Island, for the manufacture of 10 tons per day by this process.
In the spring and summer of 1918 a new process was developed both
abroad and in the United States, one which used sulphur monochloride.
Accordingly, the contract with the Commercial Research Co. was
canceled, and efforts were concentrated on the later process.
This process consisted in blowing gaseous ethylene into liquid sulphur
monochloride in large iron reaction vessels. The reaction developed
much heat. Sulphur is set free by this reaction, and the temperature
must be controlled in order to prevent the formation of solid sulphur
in the reaction machine.
At the date of the armistice three mustard gas plants were either
completed or nearing completion. The construction of the Edgewood plant
was begun on May 18, 1918, and the first mustard was produced exactly
a month later. The changing of processes, however, hampered production
somewhat, but by September 20, the arsenal was producing 10 tons per
day, and by November 11 had increased this to 30 tons per day. The
total production of mustard gas at Edgewood during the war period was
711 tons, of which approximately 300 tons went into shell.
On July 8, 1918, the Government began the construction of a mustard gas
plant at Hastings, N. Y. This factory was to have a capacity of 25 tons
per day, afterwards increased to 50 tons per day. The first unit of
this plant was ready to operate when the armistice was signed.
On July 6, 1918, the Government signed a contract with the National
Aniline & Chemical Co., Buffalo, N. Y., calling for a mustard gas plant
with a capacity of 50 tons daily. On November 11 this plant was 80 per
cent complete. The cost of the plant was met by the Government, but
the operation was to be in the hands of the Buffalo concern. The total
daily capacity of all three plants when complete was estimated to be
200 tons.
To insure an adequate supply of sulphur monochloride for its mustard
gas production the Government built a special plant at Edgewood with a
capacity of 300 tons of sulphur monochloride per day.
As soon as toxic gas warfare had developed to a considerable extent,
the perfection of gas-absorbing masks had given almost a complete
protection against this new weapon, if the soldier put on his gas mask
in time. But the mask, especially the earlier forms of it, was not easy
upon the wearer, due to the difficulty of breathing through it and also
because it restricted the soldier's vision. It was soon discovered
that a force compelled to wear its gas masks for any considerable
period lost in efficiency. The employment of gas by both sides for the
purpose of forcing the opposite sides to wear masks continually was an
important element in war at the close of hostilities.
For this purpose the so-called tear gases were produced. Gassing the
enemy with tear gas was much cheaper than with poison gas, yet it
forced him to remain masked. The tear gases were highly effective.
Even a trace of tear gas in the air would in a few moments blind a man
temporarily. A single tear-gas shell could force the wearing of masks
over an area so wide that it would require from 500 to 1,000 phosgene
shell to produce the same effect.
Most of the tear gases had bromine bases; so it was early determined
that we should have to increase the American supply of bromine
considerably if we were to meet our gas-warfare requirements. Bromine
is a deep red liquid which boils at 63° C. The domestic source of
bromine is principally in certain subterranean brines found in the
United States, these solutions containing bromine in its compounds. The
brines obtained in the vicinity of Midland, Mich., are especially rich
in bromine, and by far the largest amount of bromine obtained in this
country comes from that locality.
In December, 1917, at a conference with Mr. Dow, of the Dow Chemical
Co., Midland, Mich., it was decided that the Government should finance
the sinking of 17 brine wells near Midland, the Dow Chemical Co. to
supervise the work and to produce the bromine from the brine. The work
on this project was not begun until March, 1918, but the entire project
was practically completed when the armistice was signed. This plant is
a future war asset of the United States. It is capable of yielding
approximately 650,000 pounds of bromine per year.
The tear gas which we prepared to manufacture was brombenzyl cyanide.
It is a brownish oily liquid which solidifies to white or brownish
crystals at 29° C.
The production of brombenzyl cyanide involves a fairly intricate
chemical process. The first step is to chlorinate ordinary toluol, one
of the coal tar bases, to produce benzyl chloride. This chloride is
then mixed with sodium cyanide in alcoholic solution and distilled,
benzyl cyanide being the result. It is then only necessary to brominate
the benzyl cyanide by treating it with bromine vapor.
The first manufacture of brombenzyl cyanide in the United States was
conducted at an experimental plant at the American University Station
at Washington. After this a large scale plant was authorized at the
plant of the Federal Dye & Chemical Co., at Kingsport, Tenn. The
construction of this factory began on July 8, 1918, and operations
started on October 29, the total production of brombenzyl cyanide being
a trifle over 5 tons. In November the plant reached a capacity of 3
tons per day.
The bromine gases were not poisonous in the sense of being killers,
but were merely highly irritating to the membranes of the eye. The
killing gases were phosgene, chlorpicrin, and chlorine. Mustard gas in
sufficient amount was also fatal, its effect being identical to that
of a deep burn. It attacked the lungs, the eyes, the skin, and even
the intestines if food contaminated with mustard gas were swallowed.
An insidious feature of mustard gas is the fact that its action is
practically always delayed. It might be several hours after a man was
gassed, even fatally, with mustard before he became aware of it, and
then it was too late to administer the treatment that might save his
life. Goggles alone would have been sufficient protection against tear
gas, except for the fact that it was invariably mixed with the deadlier
gases.
The various experiments preliminary to our production of gases were
conducted in provisional laboratories at the Bureau of Standards,
Washington, D. C., Bureau of Mines, Washington, D. C., the Geophysical
Laboratory, Washington, D. C., the Ohio State University, Columbus,
Ohio, and Johns Hopkins University, Baltimore, Md. A control
laboratory for the solution of problems arising in manufacture was
eventually established at Edgewood. A total of 167,092 single chemical
determinations were made at these laboratories under the direction of
20 commissioned officers, 45 noncommissioned officers, and 204 privates.
The production of gases and other chemicals was only part of the work
of the Edgewood Arsenal and its subsidiary plants. The other chief
activity was that of filling artillery shell with the toxic substances.
The description of the plant which filled shell with phosgene will
indicate the scale upon which this operation was conducted.
The empty shell, after being inspected, were loaded on trucks, together
with the proper number of loaded boosters. The booster was the device
which exploded the shell and scattered the gas. Electric locomotives
then pulled the shell trucks to the filling buildings. There were four
of these to a single shell-filling plant, radiating at right angles
from a common center. From the trucks the empty shell were lifted by
hand to a belt conveyor and the conveyor carried the shell slowly
through a room kept cold by artificial refrigeration. Although the
shell moved only 70 feet through this room the conveyor traveled so
slowly that they were 30 minutes in transit, and during this time they
were cooled to a temperature of about 0° F. This chilling was necessary
because phosgene has a low boiling point, and it was necessary to
keep the temperature of the metal of the shell considerably below the
boiling point of phosgene in order that the gas might remain in liquid
form while the filling was going on.
The chilled shell cases were next transferred to small trucks, each
carrying six of them. The loaded truck was then drawn through a filling
tunnel by means of a chain haul. This tunnel was so ingeniously
contrived that the human assistance to the filling and closing
machinery could all be conducted from the outside. The phosgene, kept
liquid by refrigeration, was run into the shell by an automatic filler.
The truck was then moved forward a few feet to a point where the
boosters were inserted into the noses of the shell by the hands of
the operator reaching in through an aperture in the tunnel. The final
closing of the shell was then accomplished by motors. The air in
the filling tunnel was constantly withdrawn by strong ventilation,
the exhaust air being washed in stone towers by chemical agents to
neutralize any gases that might be present. The filled, inclosed shell
were next conveyed to a dump, where they were classified and then stood
nose down for 24 hours to test them for leaks. Then they were painted,
striped, and stenciled by air paint brushes. The final process was to
pack them in boxes and store them for shipment. This was done in large
storage magazines on the grounds of the Edgewood Arsenal.
A similar method was used for filling shell with chlorpicrin, except
that refrigeration was unnecessary. Mustard gas required another sort
of filling machine.
Several filling plants were designed and constructed for filling
grenades with stannic chloride and with white phosphorus, and also one
for filling incendiary drop bombs.
The capacity of each of these plants per day was as follows:
Stannic chloride plant, hand grenades, 25,000. White phosphorus grenade
plant, 30,000. White phosphorus smoke-shell plant, 155 millimeter
shell, 2,000; or 4.7-inch or 5-inch shell, 4,000; or 75-millimeter
shell, 6,000. Incendiary drop-bomb plant, 2,000.
The following sentences summarize the production and expectations of
the Edgewood Arsenal:
(1) The gas program as of March 1918 called for approximately 545 tons
of toxic gas weekly.
(2) The Chemical Warfare Service program of August 12, 1918, called for
a much larger amount, viz, about 4,525 tons per week.
(3) The approximate filling capacity of the Edgewood Arsenal plant from
August to November, 1918, was nearly 1,000 tons per week.
(4) The toxic gas production during this same period increased from 450
to 675 tons per week.
(5) The capacity of all projectiles received, unlimited by boosters,
varied during the same period from 125 to 450 tons per week.
(6) The maximum capacity corresponding to boosters received was less
than 100 tons per week.
In these facts it will be seen that the numbers of empty shell
delivered to the plant was far less than the number required to
accommodate the gas production. Many of the shell received were without
boosters and therefore without value until boosters were provided,
so that the limiting factor was really the supply of boosters. The
booster supply was sufficient to take care of only a relatively small
fraction of the toxic gas actually produced. The filling capacity of
the plant was also in excess of the delivery of shell and boosters. The
75-millimeter shell-filling plant had a capacity of 1,200,000 shell per
month, eventually double that, while delivery of shell was slightly
over 300,000 per month and of boosters less than 200,000.
Because of the nature of toxic gas it is impossible to store it up in
any large quantities. Early in the summer of 1918 large amounts were
shipped in bulk overseas and there loaded into shell. Later we received
instructions to stop all shipments in bulk except a limited amount of
chlorine, and thereafter our production was limited to the number of
shell and boosters available.
In June, 1918, we shipped in bulk 15 tons of mustard gas, 705 tons of
chlorpicrin, and 48 tons of phosgene. This was to be exchanged for
gas shell produced by the French. In late July the French had no more
extra shell to be filled with American gas and this fact terminated
the arrangement. However, we sold excess gas both to England and to
France. England received 900 tons of our chlorpicrin and 368 tons of
American phosgene. France took 300 tons of chlorpicrin and 1,408 tons
of chlorine, equivalent to 1,226 tons of phosgene, since phosgene is
80 per cent chlorine including allowance for wastage in manufacture.
France furnished phosgene shell to us in exchange for chlorine. In
addition 200 tons of mustard gas were shipped to England and utilized
by the English.
We therefore shipped to Europe in bulk 3,662 tons of gas or its
equivalent, which gas was largely loaded in shell and used by the
United States troops or those of the allies. This quantity was
sufficient to load 1,600,000 shell, two-thirds of them being of the
75-millimeter caliber and the other one-third 155-millimeter, the total
number being thought to be at least equal to the total number of gas
shell fired by American troops in action. Thus while American gas was
not actually fired in American shell against the Germans, American gas
was used against the enemy and America furnished at least as much gas
as she fired.
In addition to this we shipped 18,600 Livens drums loaded with
phosgene. These contained 279 tons of gas, and some of them were fired
at the enemy. We began producing loaded gas shell in the summer of 1918
and by August 9 had shipped 75,000 loaded 75-millimeter shell. These
shell were unassembled for firing in the guns, the Ordnance Department
having decided in June to assemble gas shell in their cartridge cases
in France.
The Chemical Warfare production organization developed and manufactured
a large number of special containers for the shipment of toxic gases.
These were of special construction in order to guard against dangers
that would result from leaks, and all had to stand the tests required
by the Bureau of Explosives before they would be received for railroad
shipment. The 1-ton containers, all of which would hold 1 ton of liquid
chlorine, were designed by the Ordnance Department and would withstand
a pressure of 500 pounds per square inch. The 300-pound phosgene
cylinders, designed by the Ordnance Department, were made to withstand
a 500-pound hydrostatic pressure and a 250-pound air test.
We purchased standard 55-gallon acid drums and standard-pattern
cylinders for holding 75 pounds of chlorine.
We constructed chlorine tank cars, each tank with a capacity of 15 tons
and a strength that could withstand a pressure of 500 pounds to the
square inch. We also designed a tank car originally for the shipment of
chlorpicrin and later used it for shipping sulphur monochloride.
CHEMICAL WARFARE PRODUCTION DATA.
_Production of toxic material._
[All figures are for tons of 2,000 pounds.]
---------+-------+-------+-------+-----+--------------+-------+------+-----
| | | | | | | | |Tita-
1918 |Liquid |Gaseous|Chlor- |Phos-|Mus- |Brom- |White | Tin |nium
|chlor- |chlor- |picrin.|gene.|tard |benzyl |phos- |tetra-|tetra-
|ine.[33]ine.[34] | |oil. |cyanide |phorus |chlor-|chlor-
| | | | | | | | ide |ide.
---------+-------+-------+-------+-----+-----+--------+-------+------+------
January | | | 10 | | | | | |
February | | | 27 | | | | 34| |
March | 40| | 59 | | | | 74| 38|
April | 176| | 33 | 15| | | 59| 116|
May | 378| | 130 | 18| | | 70| 51| 50
June | 546| | 263 | 23| 6| | 60| 95|
July | 512| | 499 | 100| 21| | 80| 112| 27
August | 243| | 646 | 314| 36| | 162| 94| 53
September| 438| 191| 564 | 327| 144| | 125| 96| 26
October | 242| 649| 445 | 664| 361| | 265| 75| 25
November | 148| 264| 100 | 155| 143| 5 | 77| 18|
| | | | | | | | |
+-------+-------+-------+-----+-----+--------+-------+------+------
Total | 2,723| 1,104| 2,776 |1,616| 711| 5 | 1,006| 695| 181
| | | | | | | | |
Amount | 1,488| | 1,903| 420| 190| | 171| 106|
shipped | | | | | | | | |
overseas | | | | | | | | |
Total | 895| 1,500| 1,500|1,050| 900| 90| 100| 91| 30
monthly | | | | | | | | |
producing| | | | | | | | |
capacity,| | | | | | | | |
Nov. 1, | | | | | | | | |
1918 | | | | | | | | |
Estimated| 1,100| 2,250| 1,500|1,650|4,000| 90| 100| 91| 30
capacity,| | | | | | | | |
Jan. 1, | | | | | | | | |
1919 | | | | | | | | |
---------+-------+-------+-------+-----+-----+--------+-------+------+------
[33] Procured from commercial agencies.
[34] Manufactured at Edgewood.
_Shell, grenades, Livens drums, and drop bombs filled._
---------+----------------------+-----------------+--------+----------------
| 75-mm. shell. | Grenades. | Livens |Incendiary drop
| | | drums. | bombs.
1918 +-------+-----+--------+-------+---------+--------+-------+--------
|Chloro-|Phos-|Mustard | White | Tin | Phos- | |
|picrin |gene | oil | phos- | tetra- | gene |Mark I |Mark II.
| | | |phorus |chloride | | |
---------+-------+-----+--------+-------+---------+--------+-------+--------
July | 62,866| | | 8,696| 1,639| | |
August |125,951| | |170,160| 56,763| 1,738| 350|
September|110,358|1,988| 75,529| 51,421| 127,319| 6,355| | 1,998
October | 09,704| 12| 79,272|110,928| 147,669| 12,026| 184| 100
November | 15,892| 9| 224| 98,948| 30,386| 5,570| 8| 6
+-------+-----+--------+-------+---------+--------+-------+--------
Total |424,771|2,009| 155,025|440,153| 363,776| 25,689| 542| 2,104
| | | | | | | |
Total |300,000| | 150,000|224,984| 175,080| 18,600| |
number | | | | | | | |
shipped | | | | | | | |
overseas | | | | | | | |
---------+-------+-----+--------+-------+---------+--------+-------+--------
_Total monthly capacity of filling plants on date of armistice
(Stokes shell, drop bombs, and other special containers not
included)._
75-mm. shell (ultimate capacity) 2,400,000
4.7-inch shell 450,000
155-mm. shell 540,000
6-inch shell 180,000
Gas grenades 750,000
Smoke grenades 480,000
Livens drums 30,000
CHAPTER II.
GAS DEFENSE EQUIPMENT.
During the spring and summer of 1917 two marked tendencies were to
be observed in the fighting in France. One of these was the greatly
increased use by both sides of poisonous gases and chemicals, frightful
in their effect; the other the almost complete censorship that hid
the knowledge of this tendency not only from the people of Europe but
particularly from those of the newest belligerent, America. The French
and British Governments, who then controlled all news from the front,
feared, and perhaps with reason, that if the picture of gas warfare, as
it was then developing, should be placed before the American people,
it would result in an unreasonable dread of gases on the part of the
American Nation and its soldiers.
One year later, with tens of thousands of American troops facing the
Germans, there was almost no censorship upon the details of fighting
with chemicals. The mysterious gases of 1917 were then known to almost
every reading individual in the civilized world. The once secret
formulas were published in the technical journals. Non-censored
photographs of defensive equipment were freely published, and masks and
other paraphernalia were exhibited for the public interest. Except for
secret plans for the future and the various surprises being prepared by
one or more of the belligerents, the whole subject of chemical warfare
had become an open book.
What occasioned this change in policy on the part of governing
authorities? The reason was that the American troops brought with
them to France the best and most protective gas masks the world had
seen; and they brought these with them by the millions. Starting a
mask-production effort in May, 1917, America turned out a total of
5,250,000 gas masks before the armistice was signed, and sent more
than 4,000,000 of them overseas. As to the quality of these masks, it
is only necessary to say that they gave twenty times the protection
afforded by the best German gas masks. In other words, we protected our
soldiers against the poisons which Germany had brought into warfare,
and protected them completely. No American soldier was ever gassed due
to the failure of an American gas mask, and such gas casualties as
did occur were due to the fact that the masks were not quickly enough
utilized when gas was thrown over, or because the soldier was unaware
of the presence of gas. With such protection there was no longer
reason to fear that the frightfulness of chemical warfare would reduce
American morale.
The production of gas masks was one of the most picturesque and
successful phases of our entire war preparation. It engaged the
attention of some of the principal chemical engineers of the country,
and millions of men, women, and children in the United States
contributed something to the success of the undertaking, if only to
obey the "Eat More Coconut" slogan or to save peach stones for the
benefit of the production of the charcoal essential to efficient gas
masks.
The problem of making masks in such quantity and under such supreme
demands for perfection was one which might well stagger manufacturers
accustomed to large-scale operations. We started in with practically
no knowledge whatsoever of the fundamental principles of a perfect
mask. Yet the apparatus was as difficult to build as a rifle. It must,
perforce, be made of perishable materials, and this fact brought the
question of durability to the fore at the very start. It was evident
that no chemical substances known in our past commercial life would
give protection against the new poisons which had been developed in
Europe. With the exception of phosgene and chlorine, the various war
gases which had been brought out prior to our entrance in the struggle
were completely unknown in our trade or commerce and had existed only
in our experimental laboratories. Then it was discovered that as these
toxins increased in power they could penetrate the ordinary fabrics
known in commerce, and this necessitated the creation of new types
of materials to be used in the masks. Finally the increasing use of
gases forced the soldiers to wear their masks for much longer periods
than had been necessary at the beginning of gas warfare; so that
the problem of comfort became one of great importance. All of these
basic considerations indicate to some extent the difficulty of the
undertaking.
The chlorine, which floated in a pale greenish-yellow cloud down upon
the defenseless Canadian troops at Ypres, with such terrible effect
upon the men, was, as has been said, the first gas used. Chlorine,
though easy to obtain, the principal source of supply being common
table salt, was, from the standpoint of strategy, far from being the
ideal gas of warfare. Troops could be quickly and easily protected
from it. But even as it was, only lack of faith in their new weapon
prevented the Germans from winning the war with it then and there. Had
they brought into the fighting a sufficient supply of this chlorine,
they might have gassed their way to Paris in short order. In fact, they
brought to the line an almost negligible supply and they themselves
were insufficiently protected to go through their own gas and follow up
the attack. By the time they were able to renew gas warfare the French
and British had equipped themselves with masks which were sufficient
to protect men against chlorine.
Thereafter the tendency was toward new and strange gases which were
heavy in weight and highly toxic in their physiological action. This
development led to new, slightly volatile liquids, the so-called
mustard gas being the best example. Mustard gas (properly called
dichlorethyl sulphide) is similar to lubricating oil in many of its
physical characteristics but smells like ordinary mustard. Ground
soaked with the mustard gas remains impregnated for days, the vapor
rising continually.
A perfect mask is one which will remove completely every trace of gas
or poisonous vapor before the air can reach the eyes, nose, or mouth of
the soldier.
The first masks adopted by the allies were simply gauze pads saturated
with neutralizing chemicals. These became unsuitable as soon as new
varieties of powerful poisons were brought out. The mask development
thereafter progressed to the box respirator type. This consisted
of a mask or helmet connected to a box filled with absorbing and
neutralizing chemicals which purified the air for the mask wearer. This
was the type of respirator in use to the end of the fighting.
It is quite clear to us now that only such a mask could be efficient
in chemical warfare, but in the early part of 1917 the matter was not
clear either to us or to the allies. The first requisitions from the
A. E. F. called for masks of two types, each soldier to be supplied
with one of each. The reserve mask was to be of the gauze type and the
regular mask of the box respirator type, affording protection from
the more powerful poisons that were then just coming into use. We
wasted considerable energy at the beginning in our attempt to produce
both types. Eventually, however, when we were just ready to start
manufacturing the gauze-type mask, orders came to abandon the effort,
since it was even then apparent that our soldiers must be prepared at
all times to withstand all gases.
The box respirator equipment, the general principle of which was
finally adopted by all the nations at war, fell into two classes. In a
single-protection mask the wearer breathed air from inside of the face
piece, so that any leakage around the edges of the face piece would
result in a casualty when the wearer was in a strong concentration of
gas. The other sort, known as the double-protection mask, consisted of
a gas-tight face piece, similar to that of the single-protection mask.
In this type, to guard against any possible leakage around the edges
between the mask and the wearer's skin, the breathing system was sealed
away from the air inside the face piece by means of a rubber mouthpiece
and a nose clip, the wearer inhaling through the mouthpiece.
[Illustration: VARIOUS TYPES OF GAS MASKS.
Top row, left to right.--First type U. S. Navy mask, now
obsolete; U. S. Navy mask as finally developed; U. S. C. E.
respirator (production started October, 1917); U. S. R. F. K.
respirator (production started February, 1918); U. S. A. T.
respirator (production started August, 1918); U. S. K. T. mask
(production started August, 1918); U. S. model 1919 mask (ready
for production when armistice was signed).
Middle row, left to right--British black veil mask (first
mask used after initial gas attack in April, 1915); British
P. H. helmet (stops phosgene but not tear gases); standard
British box respirator used by all British forces after 1916;
French M-2 mask used by the French; French Tissot mask used by
artillerymen; French A. R. S. mask.
Bottom row, left to right.--Late type of German mask;
Experimental mask; Italian mask (similar to French M-2 mask);
British Motor Corps respirator; U.S. rear area emergency
respirator; U. S. Connell mask (never passed the experimental
stage).]
[Illustration: AMERICAN C. E. TYPE OF BOX RESPIRATOR.
This side view shows face piece, harness, hose, flutter valve, and
knapsack. This is the mask most used by our troops.]
The United States and English double-protection masks consisted of 11
principal parts as follows:
1. A knapsack slung from the shoulder or neck. This contained the
canister and a pocket for storing away the mask when not in use.
2. A metal canister in which was contained the absorptive neutralizing
chemicals.
3. A flexible hose reaching from the canister to the face piece.
4. A flutter, or exhalation, valve, which opened when the wearer
exhaled his breath and closed when he inhaled, thus bringing the
inhalation through the canister but allowing the exhalation from the
lungs to pass out without polluting the chemicals of the canister.
5. The face piece, or hood, fitting snugly around the edges and
covering the eyes, cheeks, lower forehead, nose, mouth, and chin.
6. The eyepieces, or lenses, through which vision was maintained.
7. An elastic harness for the head, to hold the face piece in place.
8. A body cord to tie around the chest and hold the knapsack firmly,
so that the mask could be seized in both hands and pulled out of the
knapsack.
9. A metal flange connection or angle tube which carried the hose
through the face piece to the mouthpiece.
10. A rubber mouthpiece through which the wearer breathed and which
helped to hold the mask in place.
11. A wire nose spring and rubber nose pad to hold the nostrils shut
and force breathing through the mouth.
The first order for gas masks was issued on May 16, 1917, when the
Chief of Staff asked the Surgeon General to supply 1,100,000 masks
before June 30, 1918, or within about one year. Meanwhile 25,000 masks
were needed at once in order to equip Gen. Pershing's first division,
then about to sail overseas. There was but one man in the Army who knew
anything at all about the subject and who could even attempt to produce
this quantity in three weeks. This was Maj. (later colonel) L. P.
Williamson, of the Surgeon General's Department, who had been spending
some months at the Army War College at Washington studying as a side
issue such papers on gas warfare as came from abroad. It was due to his
knowledge and the volunteer staff of the Bureau of Mines that we were
able to begin the actual manufacture of masks within a few days after
the requirements were fixed, and actually to turn out 25,000 masks in
but little more than three weeks' time.
Col. Williamson's first step was to consult with Dr. Van. H. Manning,
the Director of the Bureau of Mines, and with his assistant, Mr.
G. A. Burrell. Since February, 1917, the Bureau of Mines had been
experimenting with gas masks and had built up a corps of scientists for
this work. Within this organization was Mr. Bradley Dewey, a chemical
engineer, who, though then director of the research laboratory of the
American Sheet & Tin Plate Co., of Pittsburgh, had been loaned to the
Bureau of Mines. To Mr. Dewey was turned over the job of directing
the production of the first 25,000 masks for the American troops then
sailing.
To produce 25,000 gas masks in three weeks meant to compress England's
two years of experience into 21 days. The military authorities of this
country at that time could plead entire ignorance of the qualifications
of an efficient gas mask. The prevailing idea seemed to be that you
could go out into the market and buy them by the hundreds of thousands,
as you might buy Halloween masks. But this was not any ordinary poison
which we were to fight. These powerful chemicals attacked the human
tissues as would acid. As the result of the effort, we did supply
the first division going overseas in July. However, the masks were
inferior to the British and were quickly replaced in France by British
equipment. It was not until the following January that we developed an
apparatus which we regarded as satisfactory to undergo the supreme test
of battle.
To indicate some of the difficulties overcome between May and December,
1917, there are here set forth some of the features of an effective
mask.
In the first place, the face piece must fit perfectly; it must not leak
gas around the edges. It must fit into the hollows of the temples and
must give the jaws a free space in which to work, and yet not slip back
and press against one's Adam's apple. The pressure of the mask on the
forehead must come above the supraorbital nerves which are just above
the eyebrows, or else intense headaches will result from a few moments'
wear. Moreover, to fit all faces and heads, several graduated sizes of
masks are required. We first attained the gas-tight fit with a padded
band around the edge of a flexible rubber-cloth face piece. Later we
developed a thicker, stiffer face piece, but maintained a gas-tight fit
by the elasticity of the face piece and the head harness.
Then the material of the face piece must be gas-tight in itself. At
first we manufactured a fabric made by spreading rubber on cotton
sailcloth; and, after testing it, we found that the smallest molecule
known, that of hydrogen, would not pass through it in large amounts.
This seemed to be a suitable fabric, until tested by the newer gases.
Then we found that some of these gases were soluble in rubber compounds
and could dissolve their way through thin rubber so quickly that the
face piece cloth offered practically no protection at all. Another
difficulty with the rubber fabric was that it was likely to absorb and
hold certain of the poisons, so that a man might be gassed by the mask
itself. The rubber companies, principally at Akron, Ohio, experimented
continually until they discovered a coating that would not only
withstand gas concentrations for a sufficient time, but would also
aerate promptly and lose as much gas as it had absorbed.
The eyepieces or lenses offered another problem. Celluloid is strong
but it is not so transparent as glass. It ignites easily and is easily
scratched. Glass is ideal in transparency and will not burn, but is
fragile. It was evident that we must provide eyepieces which would not
break easily, since even so slight an accident as the breaking of a
lens might cost a soldier his life by admitting concentrated gas to the
mask. A material known as triplex glass had been experimentally made.
This consisted of a thin celluloid strip sandwiched between two layers
of glass, all three welded together. This glass would not splinter, and
even if cracked or broken, would still be gas-tight. However, this had
never been made in quantity and it was necessary to work out many kinks
and to start a large plant to provide the necessary millions of lenses.
Then there was also to be overcome the tendency of the eyepieces to
dim, particularly in cold weather, as the wearer breathed moist breath
into the mask. The answer to this problem was a soapy compound which
put a slippery surface on the glass and avoided the droplets of mist.
The first masks were also equipped with deep plaits so that the wearer
could wipe off the lens with the interior of the face-piece itself,
though the final development (the invention of a Frenchman by the name
of Tissot) was to bring the cold air into the mask so that it flowed
directly against the lenses and evaporated any condensed moisture. This
kept them clear under all ordinary circumstances.
It was evident that the metal tube passing through the face piece must
not contain pinholes and must be able to stand rough handling without
pulling loose. The harness must maintain a gas-tight connection between
the wearer's face and the face piece, but not at the cost of pain or
chafing of the face or head. The flutter valve must fit with absolute
tightness and must work perfectly and instantaneously at all times.
The flexible hose leading from the canister to the face piece must be
strong and without flaws or leaks, and yet flexible in the extreme.
A stiff hose would be likely to swing and displace the face piece
whenever the wearer moved. The mouthpiece must be comfortable and must
be built along lines to prevent irritation to the gums or lips, yet it
must be reinforced so that in his excitement the soldier can not bite
down and shut off his air supply.
The canister must withstand corrosion and must be gas-tight. Smooth
sided canisters can not be used, for the gas would slip up the sides
without coming in contact with much of the chemical filling. The sides
of the canisters were, therefore, ribbed so that the charcoal and
other ingredients working into these ribs baffled the gas and threw
it out into the body of the chemicals. The canister, moreover, must
be equipped with a perfectly working check valve which will stop
exhalation through the canister and force the air to pass out through
the flutter valve.
The web sling of the knapsack must not curl and chafe the neck or
shoulders of the wearer. The knapsack must be waterproof and must have
easily and quickly workable fastenings.
The canisters were filled with charcoal and with cement granules.
These were crushed into carefully sized small bits about the size of
a pinhead and packed in layers in the canisters. The air could pass
through them easily and the particles of both substances absorbed gas.
The chief quality requirements for the carbon and the cement were that
they must have long life and great activity.
Of the canister ingredients the charcoal offered the more difficult
technical problem. It had long been known that charcoal was highly
absorptive of certain gases, but except in rare instances no thorough
study had ever been made of the subject. It was evident, however, that
the more charcoal or carbon which could be packed into the canister and
still allow the free passage of air the greater the amount of gas that
would be absorbed. Consequently a search was made for carbon existing
in the natural state in the most compact form. This search is described
later.
Each canister also contained concrete granules in a definite proportion
to the carbon pieces. These granules were made of cement mixed with
strong alkalis and oxidizing agents to digest the poisons as they
passed through the canister.
It will be seen that the manufacture of good gas masks was a highly
technical undertaking, one calling for the best talents of eminent men
of science. The mask was not something that could be improvised on the
spur of the moment, but each part of it must be worked out after the
most painstaking research. The Gas Defense Division of the Chemical
Warfare Service never at any time approved a type of mask which
its own officers or men did not themselves wear in the most deadly
concentrations of gas.
To get back to the chronological order of development, on May 21,
1917, the making of the first 25,000 masks was started with frantic
haste; though, as it developed later, there was no need for such an
effort, since there were available in England and France plenty of
masks for the first American troops. Working to produce in the shortest
possible time some sort of protection for the first overseas division,
the officers in charge were forced to adopt methods which, had they
been followed throughout the manufacturing program, would have been
extremely costly. There was no time then to stop and study the problem
either here or abroad. Before the end of June 20,088 masks had been
started overseas, and 5,000 more were ready a little later. The most
that can be said for this effort was that it gave our officers the
experience which was the groundwork of the solid development later on.
The production of these first 25,000 masks called upon the services of
various manufacturers. The assembling of the masks was conducted by the
American Can Co., at Brooklyn, N. Y. The B. F. Goodrich Co., of Akron,
manufactured the face pieces with the eyepieces inserted, also the
connecting hose, the check valve of the canister, the flutter valve,
and the rubber mouthpiece. The American Can Co. produced the canisters.
The Day Chemical Co., of Westline, Pa., gave the charcoal its first
burning. The Ward Baking Co., of Brooklyn, patriotically baked the
charcoal--to activate it--in their bread ovens free of charge. The
General Chemical Co., of New York, supplied the soda-lime granules. The
Doehler Die Casting Co., of Brooklyn, manufactured the angle tubes. The
Simmons Hardware Co., of St. Louis, produced the waterproof knapsacks.
The Seaver Howland Press, of Boston, printed the cards of instructions
that went with the mask outfit; and the Beetle & MacLean Manufacturing
Co., of Boston, printed the record tags.
Though Maj. (now colonel) Williamson was formally in charge of this
emergency work, he requisitioned the masks from the Bureau of Mines,
which took entire charge of the first contract. Following this, on
August 31, 1917, the Gas Defense Service of the Surgeon General's
Department was established by official order, and Mr. Dewey, who had
been working as a volunteer in the Bureau of Mines, was commissioned
major and put in charge.
The next step was to prepare for the permanent development and
manufacture of gas masks. Contracts were let for the manufacture of
320,000 component parts of masks as we then knew them, and a price
was fixed for the assembling of the entire original requirement of
1,100,000 masks. The assembling contract went to the Hero Manufacturing
Co., of Philadelphia, which remained until the end of the war the sole
private contractor assembling our gas masks.
The spirit of cooperation and desire to serve the Government was
evident from the start. The B. F. Goodrich Co. had been the only
producers of the rubber parts of the first 25,000 masks. In this
original contract it had gained valuable technical and cost knowledge;
but in order that the Government might not be limited to one source of
supply for such parts, the Goodrich Co. voluntarily imparted to the
Goodyear Tire & Rubber Co. and to the United States Rubber Co. the
information that would enable them to bid intelligently for portions
of the work. This was a distinct departure from the usual practice in
competitive industry.
All during the fall of 1917 and early winter of 1917-18 the development
of the mask continued, the Government experts working hand in hand with
private contractors. Because of the newness of this sort of manufacture
and because of the wide variety of unusual articles required, entailing
in some instances the actual creation of hitherto unknown commodities,
the Government at all times was required to act as the procurer of raw
materials for the masks. In this period of development America designed
her own typical mask--a gradual evolution, but one which, though based
on the British design, arrived at a perfection which had been unknown
in warfare before.
The triplex glass used in the eyepieces was a patented commodity
produced only in one small factory in Philadelphia. It was necessary to
expand the facilities for the production of this necessary material.
Meanwhile some of the men engaged in the work had improved the eyepiece
by providing it with an aluminum mounting. But this very improvement
brought embarrassment to the work, since the Akron rubber contracts
had provided for eyepieces inserted in the fabric itself, and to apply
the aluminum frame brought about a radical change in the manufacturing
methods at the rubber factories.
There were also many other problems that had to be solved before our
authorities were satisfied to go ahead in quantity production. There
was the matter of rubberizing the face-piece fabric, for instance. Two
methods of rubberizing cloth were in use. The first method was to roll
out a thin sheet of rubber and then press it into the cloth fabric by
running the whole thing under heavy rollers. This was known as the
calender method. The other method, called the spreader method, was
more intricate. In this process the sailcloth, tightly stretched, was
carried around a roller. Above the roller a few thousandths of an inch
was a knife blade extending from edge to edge. The rubber compound in
liquid form was then fed upon the roller in such manner that a thin
film of it pressed under the knife blade and upon the cloth on the
roller. The rubberizing method finally adopted was a combination of
the calender and spreader methods. The rubber was applied green to
the cloth. The curing process thereafter was highly important. If the
curing process were too short, the rubber would be sticky and would
pull off the sailcloth too easily. If the rubber were over-cured, it
would crack and split.
Nothing short of absolute perfection in every part would do, since the
slightest imperfection anywhere was likely to cost a man his life.
Consequently we installed at the various producing plants not only 100
per cent inspection, but we constructed laboratories for putting the
materials through the most elaborate and exhaustive sorts of control
tests, and then reinspected the parts at the assembly plants, both
before and after the assembly.
[Illustration:
CHEMICAL DEVELOPMENT DEPARTMENT OF LONG ISLAND LABORATORY, GAS
DEFENSE DIVISION, SHOWING INTERMITTENT FLOW CANISTER TESTING
MACHINE.]
[Illustration:
PHOTO TAKEN AT PHILADELPHIA CONTROL LABORATORY OF GAS DEFENSE
DIVISION, SHOWING APPARATUS USED IN EXPERIMENTAL WORK ON THE
EFFECT OF RESISTANCE TO INHALATION AND EXHALATION OF MASKS.]
[Illustration: SIDE VIEW OF GAS CHAMBER AT CHEMICAL DEVELOPMENT
LABORATORY, SHOWING SUBJECTS ON OUTSIDE BREATHING TESTS.]
[Illustration: ANOTHER VIEW OF GAS CHAMBER AT CHEMICAL DEVELOPMENT
LABORATORY, SHOWING SUBJECTS INSIDE.]
All the rubber used was continually sampled and analyzed in the
laboratories. The tensile strengths of all fabrics were determined by
standard destructive tests. We also tested the adhesion of the rubber
coating by standard chemical methods and worked out flexibility tests
for the breathing tube.
After all of the factory inspection and material-control tests, the
masks themselves were sampled and worn in highly toxic atmospheres. In
this work thousands of our masks were worn by the officers and men of
the Gas Defense Division in concentrated atmospheres of the most deadly
gases. For such work we constructed testing rooms whose atmosphere
could be completely exhausted and changed in 90 seconds. The efficiency
of canisters was tested either by the lungs of the inspectors or by
mechanical breathing into telltale solutions.
The story of the carbon (charcoal) which went into the American
canister is one of the most interesting phases of the whole
undertaking. Investigations carried on by the research staff of the
National Carbon Co., aided by a clue from the University of Chicago,
led to the selection of coconut shell as a raw material. Any carbon
absorbs a definite number of times its weight of gas. Therefore the
densest carbons will be most efficient, volume for volume, as gas
absorbers in a given space. Coconut shells and other nut shells were
found to be the most compact form in which carbon exists in nature
in commercially practicable quantities, being considerably superior
in this respect to anthracite coal and to such woods as ironwood and
mahogany. Another essential for charcoal used in the canisters was that
it must be so hard that it would not crumble easily and produce dust
that would clog up the air passages and prevent easy breathing through
the canister. Coconut shell fulfilled both of these conditions better
than any other known material.
Further study by the National Carbon Co., backed up by wonderful
large-scale development work, paid for and carried out by the National
Electric Lamp Association under the direction of their Mr. F. N. Dorsey
(who later became Col. Dorsey and chief of the Development Division of
the Chemical Warfare Service), gave us the details of a new process
for treating the charcoal to make it absorptive. After the original
burning of the nut shells, or other carbon materials, the resulting
carbon was given a second highly specialized heat treatment, and this
activated it until it had a powerful affinity for gas. Such carbon,
made from nutshell material, would absorb 150 times its own volume of
chlorpicrin, one of the most deadly of the war gases, the action being
approximately instantaneous.
It must not be supposed, however, that investigation of carbons
stopped with these experiments. In the search for the ideal carbon
we experimented with almost every hard vegetable substance known.
Literally, hundreds of kinds of carbon were tested. Next to coconut
shells, the fruit pits, several common varieties of nuts abundant
in the United States, and several tropical nuts, were found to make
the best carbon. Pecan nuts, and all woods ranging in hardness from
ironwood down to ordinary pine and fir, were found to be in the second
class of efficiency. Among other substances tested were almonds,
Arabian acorns, grape seeds, Brazil-nut husks, balsa, osage oranges,
Chinese velvet beans, synthetic carbons, cocoa bean shells, coffee
grounds, flint corn, corn cobs, cottonseed husks, peanut shells and
oil shale. While many of these substances might have been used in an
emergency, none of them would produce carbon as efficient, volume for
volume, as that of the coconut shells and other hard nuts.
Some idea of the scale of the American mask production may be seen in
our requirements for coconut shells. In our survey of raw materials we
included the entire coconut resources of the world. Such figures were
relatively easy to obtain because the copra, or dried coconut meat,
industry is an important one, particularly in southern Asia and the
South Sea Islands of the Pacific. Ceylon was the greatest single source
of coconuts, 2,300,000,000 nuts being gathered there annually. British
India was next with 1,500,000,000 nuts. Our own Philippine Islands were
third, with an annual production of 900,000,000 nuts. Then followed in
order the Dutch East Indies, British Malaya, French Indo-China, Siam,
and the Pacific archipelagos, the total production of the Orient being
7,450,200,000 nuts annually. This was a supply that would provide 4,000
tons of coconut shells every day. The total production of coconuts
in Central America, the West Indies and the Caribbean coast of South
America amounted to 131,000,000 nuts annually, equal to a supply of 75
tons of shells daily.
When we first began to build masks our demands for carboniferous
material ranged from 40 to 50 tons a day of raw material; but by the
end of the war, due to vastly increased mask requirements, we were in
need of a supply of 400 tons of coconut shells per day. This demand
would absorb the entire coconut production of the tropical Americas
five times over. It was equal to one-tenth of the total coconut
production of the Orient. Since transportation from the oriental
countries was out of the question on the scale demanded by our mask
program, it was evident that we were likely to be seriously embarrassed
by the lack of raw materials; and, indeed, at no time before September,
1918, did we have on hand a reserve supply of shells and other charcoal
materials that would last for more than a few days, though at no time
after the start was the actual output of masks retarded by lack of
these materials.
[Illustration: AIRPLANE PICTURE OF CARBON PLANT AND CANTONMENT OF GAS
DEFENSE DIVISION AT ASTORIA, LONG ISLAND.]
[Illustration: GENERAL VIEW OF CARBON PLANT NO. 3 ON LEFT AT GAS
DEFENSE DIVISION PLANT, ASTORIA, L. I.
Storage bins are in central background, with administration building
and carbon plant No. 2 in the right foreground.]
[Illustration: CARBON PLANT NO. 2 AT ASTORIA, L. I., SHOWING ALSO
OFFICE AND LABORATORY.]
In building up our supply of coconut shells we naturally turned first
to the resources in the United States. America normally consumes fresh
coconuts at a rate sufficient to supply about 50 tons of shells daily.
The war restrictions on the use of sugar had the effect of cutting
down the consumption of coconuts, used largely in candy and cakes,
and consequently one of our efforts was to increase by widespread
propaganda the use of coconut. The "Eat-More-Coconut" campaign more
than doubled the American consumption of coconut in a brief space of
time; and the 50 tons of shells daily, which had been the original
supply, grew in volume until in October, 1918, with the help of
importations of shell, we averaged about 150 tons per day exclusive of
the Orient.
The first heating of coconut shells to make charcoal reduces their
weight 75 per cent. Therefore it was evident that we could most
economically ship our oriental supply in the form of charcoal produced
on the other side of the Pacific Ocean. For this purpose, in August, we
established under the direction of an officer of the Chemical Warfare
Service a charcoal plant in the Philippine Islands. From this plant
agents were sent to Ceylon, India, Siam, and other oriental countries
to purchase enormous supplies of nutshells. This work was only gaining
momentum when the armistice was declared. As it was, the Philippine
charcoal plant actually shipped over 300 tons of coconut shell carbon
to the United States and had 1,000 tons on hand ready for shipment on
November 11.
The method adopted in the Philippines was to burn the shells in long,
shallow trenches. As soon as the smoke had disappeared and the flames
came clear and lambent through the incandescent mass, the bed of
coals was smothered by means of galvanized-iron lids thrown over the
trenches. It is interesting to note that the coolies hired by the
Chemical Warfare Service in the Philippines would not work at charcoal
burning more than a few hours each day, because they declared that the
heat from the pits would give them tuberculosis and other lung troubles.
Meanwhile agents and officers of the Gas Defense Division were
searching the tropical regions of Central and South America for other
nuts valuable for this purpose. The best of these was found to be the
cohune or corozo nut. These nuts are the fruit of the Manaca palm tree.
They grow in clusters, like bananas or dates, one to four clusters to a
tree, each cluster yielding from 60 to 75 pounds of nuts. Cohune nuts
grow principally on the west coast of Central America in low, swampy
regions from Mexico to Panama, but are also found along the Caribbean
coast. Before the war created a demand for cohune nuts none of them
had ever been imported commercially in this country, although it is
understood that France had a prewar commercial use for them.
The chief virtue of the cohune nut from our point of view was its
extreme thickness of shell, the kernel of this large nut, which is 3
inches or more in length and nearly 2 in diameter, being relatively
small. We were importing cohune nuts at the rate of 4,000 tons per
month at the time of the armistice. A disadvantage in the use of cohune
nuts was that their husks contained a considerable amount of acid
which rotted the jute bags and also caused the heaps of nuts to heat
in storage. The fire department at the Chemical Warfare Service nut
storehouse at Astoria, N. Y., was kept busy putting out spontaneous
blazes in the storage piles of cohune nuts. We also sent agents to West
Africa and there arranged for the shipment of some hundred tons of palm
nuts a month.
A third source of tropical material was in the ivory nuts used in
considerable quantities in this country by the makers of buttons. In
the button factories in this country there is considerable waste of
this nut material, amounting to 400 or 500 tons a month, this waste
including the nut dust which was useless to us and had to be screened
out. The price of ivory-nut waste was high, because of the use of this
material in the manufacture of lactic acid. Nevertheless, we used a
considerable quantity of it.
Another great branch of activity in securing carbon supplies was
undertaken in this country. In the search for fruit pits and for
domestic nuts it was found that the quantity of apricot pits, peach
pits, cherry pits (largely from the canning industry), and walnut
shells on the Pacific coast amounted to 23,600 tons annually. We
arranged for the whole Pacific coast supply of these commodities and
converted a part of a San Francisco plant of the Pacific Gas & Electric
Co. into a plant for the preliminary carbonization of 100 tons a day of
these materials.
The next step was to turn to the consumers of the country and ask them
to save their peach and apricot stones, their prune, plum, and olive
pits, their date seeds, cherry pits, butternut shells, Brazil nut
shells, and their walnut and hickory nut shells. The work of securing
these and advertising the Government's need to the public was turned
over to the American Red Cross. There was some question at the start as
to whether the charter of the Red Cross would permit it to undertake
such a war activity; but, since it was determined that this was purely
a defensive operation, the legal forces of the Red Cross decided that
the organization could go into a campaign of this kind.
[Illustration:
BAREFOOTED NEGROES IN SPANISH HONDURAS SHOVELING COROZO NUTS
INTO BASKETS TO BE LOADED INTO BOATS FOR SHIPMENT TO GAS
DEFENSE DIVISION.]
[Illustration: 5,000 TONS OF PEACH PITS PILED UP AT SAN FRANCISCO.
This is enough to produce 1,600 tons of carbon for use in gas mask
canisters.]
[Illustration:
NUT SHELLS STORED ON DOCK OF EAST RIVER WHARF, ASTORIA, L. I.,
AFTER BEING UNLOADED FROM BARGES. SHELL-CRACKING TOWER ALSO
SHOWN.]
[Illustration:
1,200 TONS OF APRICOT PITS AT SAN FRANCISCO READY TO BE REDUCED
TO CARBON FOR GAS MASKS.]
[Illustration: TROOPS IN TRENCH AT LONG ISLAND CITY READY FOR A GAS
ATTACK.]
[Illustration: TROOPS WEARING GAS MASKS CHARGING IN OPEN ORDER AT LONG
ISLAND CITY.]
[Illustration: "GAS!" TROOPS HASTILY DON THEIR MASKS AT THE ALARM.]
[Illustration:
TROOPS WEARING GAS MASKS CUTTING BARBED-WIRE ENTANGLEMENTS IN
TESTS AT LONG ISLAND CITY.]
"Help us to give him the best gas mask." That was the slogan which
was carried on the posters, catching the attention of almost every
person in the United States. More than 1,000,000 pieces of literature
were distributed. The Red Cross established 163 collection points,
and collection barrels appeared on the streets of practically every
community in the United States. The Junior Red Cross, the Food
Administration, and the Department of Agriculture gave valuable
assistance. The Boy Scouts organized nut gathering parties. The
governor of Massachusetts proclaimed November 9, 1918, to be gas mask
day for the collection of carbon material, and 28 other States fixed
gas mask days in November. Two reels of motion pictures were shown
through the country. Journalists aided the campaign in newspapers and
magazines. Frederic J. Haskin sent out a valuable article which was
published in many of the important newspapers of the United States. One
Oklahoma town took a day off en masse and gathered a whole carload of
nuts.
This campaign started September 13, 1918, but was abruptly cut short
on the 11th of November. Thus it is impossible to give exactly the
result of it, since many of the scheduled shipments of nuts and fruit
pits were canceled and found their way into fuel bins. However, at one
time there were on the rails, en route to the carbon plant at Astoria,
100 carloads of materials supplied by the patriotism of the American
people. It was estimated that some 4,000 tons were collected in this
brief period, exclusive of the material from the California canning
industry.
The procurement of the nuts, however, was but the first step in the
production of carbon for use in our mask canisters, for after charcoal
is first burned its pores are still filled with various impurities
which may be summed up by the word "tar." When the charcoal was given
a second heating, under careful temperature regulation, this tar was
burned out, with the result that the charcoal itself became much more
active in its absorption of gas. In fact, properly activated charcoal
is more than absorptive--it is catalytic in its action toward the
gaseous poisons used in the war, not only absorbing them but hastening
their breakdown (digestion) into less injurious substances.
The activating of charcoal offered at the start considerably more
of a problem than the question of making the charcoal itself,
since activating had never before been conducted on a commercial
scale. Two months of experimentation showed us that the best
distillation of shells and pits for charcoal was that conducted in
illuminating-gas-making retorts. The activation thereafter had to be
done in special equipment permitting of fine control of temperature.
The Government eventually spent more than $1,000,000 in a charcoal
activating plant, providing for America the best protection known to
science against the poisons which Germany had introduced into warfare.
The cement granules, which also had to go into the canisters, supplied
another problem. We originally used a special soda-lime for this
material, but only obtained a satisfactory product after Maj. H. W.
Dudley, R.E., came to America as our British advisor and brought to
us the British granule formula. The basis of this cement was lime, to
absorb gases of an acid nature. Portland cement was used, to give
hardness and prevent disintegration and the formation of dust in
the canister. Then infusorial earth was added, to make the compound
porous in texture. A little sodium hydroxide was put in, to increase
the alkalinity of the mixture. Finally there was an infusion of
sodium permanganate, which is a powerful oxidizing agent. This latter
chemical was added as a precaution against arsine. Arsine and arsenical
compounds were difficult to use in warfare, but the Germans had
introduced them to some extent, justifying us in adding this protection.
In making the granules the sodium permanganate solution was mixed with
the cement. The mixture was roughed out into slabs, allowed to set for
three days, dried, ground up, screened to the proper size, and packed
in drums for future use.
As has been noted, the charcoal and cement were packed in the canister
in alternate layers. The cement had the virtue of working while the
carbon slept--that is, the carbon was active when there were gases
present to be absorbed, but the cement kept on thereafter, digesting
the gases which had been absorbed by the charcoal. The cement was not
quick in action, but it had a remarkable capacity for consuming some
poisons.
To return to the chronological development of manufacturing facilities,
after we had placed the contracts for the first 1,000,000 masks in
the early fall of 1917, we began looking around for facilities for
producing carbon and cement in the quantities which we should need in
the near future. We found at Astoria, the district near Hell Gate at
the junction of the East River and Long Island Sound in New York, the
large gas works of the Astoria Light, Heat & Power Co. perhaps the
largest illuminating-gas plant in the world. This was a subsidiary of
the Consolidated Gas Co. of New York, which concern readily agreed
to turn over to the Government some of its retorts and to permit the
construction of a Government-operated plant on its grounds. We might
have been seriously delayed in the production of gas masks except for
the extraordinary and continuing efforts of Mr. W. Cullen Morris, Chief
Construction engineer of the Consolidated Gas Co., and Mr. Addicks, its
vice president. It was due to Mr. Morris that a $150,000 granule plant
was constructed, heavy complicated equipment installed, and operations
started in the short space of 30 days.
Let us now go back to the history of actual mask production. At the
start it was estimated that when the Hero Manufacturing Co. had reached
full capacity it could assemble and turn out 6,000 masks a day. The
fuel shortage and the railroad congestion of the late fall and early
winter of 1917-18 hampered our supplying the Hero Manufacturing Co.
with parts, until the mask production, averaging 2,430 a day as it
had in November, dwindled to 1,500 a day in December. The Goodyear
Co. at Akron had meanwhile established its Akron-Boston motor track
line. This was put at the service of the Gas Defense Division, hauling
various supplies from both Akron and Boston to the assembling plant at
Philadelphia. Sometimes in the mountains of Pennsylvania the trucks
would be blocked in snow and the patriotic citizens of the community
would get out with shovels and work until the supplies again started on
their way.
[Illustration: Slabbing the doughlike mixture of carbon and spreading
it on screen-bottomed trays at carbon plant No. 2.]
[Illustration: Chemical laboratory showing apparatus for testing the
absorbent power of the carbon and gran powder.]
[Illustration: Retort house. Discharging machine drawing out the nearer
half and pushing out the far half of the hot carbon.]
[Illustration: Carbon plant No. 3, showing treater room and west side
batteries of Dorsite treaters.
FOUR VIEWS OF CARBON PLANT AT ASTORIA, L. I.]
[Illustration: Zigzagging and combing work on masks.]
[Illustration: Doping the masks.]
[Illustration: Assembly department.]
[Illustration: Final inspection department.
FOUR INTERIOR VIEWS OF GAS MASK PLANT.]
All of the masks produced in the fall of 1917 were still regarded as
experimental and not yet up to the standard of masks which we were
willing to supply for actual service at the front. Consequently, not
one of them was exported, but the entire 1917 production, after the
first order of 25,000, was sent only to the training camps in this
country. By January 8, 1918, we were producing masks which we were
willing to put into actual service, and on that date the manufacture of
masks for export was started.
In January we exported 54,000 masks, which was 16,000 less than the
schedule which we had set for ourselves. But by February 20 we had
wiped out this deficit with a little over, for our schedule by that
date called for the production of 141,000 gas masks, and we had
produced 142,000.
Late in the fall of 1917 the requirements of the Expeditionary Forces
were reanalyzed in the light of information gathered abroad and in
accordance with the new military program. Requirements were multiplied
almost fourfold. Let us see how these requirements were met, and what
difficulties were solved in the course of the effort.
Experience had already shown that for many reasons the Government
needed its own mask factory, where improvements could be adopted as
soon as made and where inspections and the storage of parts could be
more centralized than in private plants.
With the necessary expansion then confronting us, any other policy
would have meant making face pieces in half a dozen or more private
plants, all starting at once with organizations untrained for this
work. This would have been fatal, for even with the Goodyear and
Goodrich companies manufacturing face pieces in Akron and the Kenyon
Manufacturing Co. making them in Brooklyn, we found it most difficult
to maintain uniform standards in all the plants. As new points came up,
it was constantly necessary to interchange inspection personnel and to
send men from one plant to another to teach manufacturing wrinkles.
Such practices consumed more personnel than we could train in the time
available. Moreover, it was impossible under the conditions that we
were then facing to build up more than barely adequate supplies of gas
mask parts and such raw materials as special fabrics. To have operated
many more face-piece plants would have meant to divide these stocks
of fabrics, elastic, tape, etc., still further. To have kept each of
these plants properly stocked, under the existing traffic conditions,
would have been impossible. A big central gas-defense plant was the
only solution of our difficulties.
The order approving the establishment of the gas-defense plant was
signed by Secretary Baker on November 20, 1917. The officers of the
Gas Defense Division found in Long Island City, not far from the new
chemical plant at Astoria, a group of modern concrete factory buildings
which had been put up in this newly developed section by several
different concerns, among them the Ford Motor Co., the Goodyear Tire
& Rubber Co., and the National Casket Co. One of these buildings,
known as the Stewart Building, was taken over by the Government and
modern machinery was installed. Mr. R. R. Richardson, of Chicago, was
appointed plant manager with a salary of $1 per year. He quickly set
to work organizing the factory and its staff. On January 9, 1918,
the first few factory operators were hired. Five days later the
executive offices at the plant were ready for occupancy. The plant
grew apace. One by one the other buildings were absorbed and added to
the establishment--first the Goodyear Tire & Rubber building, then
the National Casket building. Next a long storage building was built
between the Stewart and the Goodyear buildings. Runways were built
which connected up the various buildings, and, finally, in July, the
Ford Motor building was taken over and connected up to complete the
group.
Thus by the summer of 1918 we occupied five large buildings, with a
total of over 1,000,000 square feet, or 20 acres, of floor space,
connected up to make the gas-defense plant. Of the 12,000 employees in
this plant, 8,600 were women. Endeavors were made as far as possible
to hire those who had near relatives with the American Expeditionary
Forces. The degree of care required in the manufacture of masks was
beyond anything known in normal industry, and we rightly believed
that this personal interest in the work would bring about greater
care in manufacture and inspection. Since the factory was working at
top speed a great deal of attention was paid to welfare work. Women
employees were given 12-minute rest periods both in the morning and
the afternoon, and completely furnished attractive rest and recreation
rooms were set apart for women in the factory.
[Illustration: GAS-DEFENSE PLANT AT LONG ISLAND CITY.]
[Illustration: EMPLOYEES OF GAS-DEFENSE PLANT LONG ISLAND CITY,
NOVEMBER 11, 1918.]
The plant was unique in more than one respect. At the very start it
attempted the supposedly impossible, for it combined in its staff
and in its working organization civilian and military personnel. The
manager was a civilian, the assistant manager was Lieut. Col. Coonley.
Below them on the next tier of the organization were Army officers
in charge of several departments and civilians in charge of others.
Throughout the plant were certain groups of women workers or inspectors
in charge of civilians were others; in charge of sergeants or even
privates. The arrangement worked out well and the whole organization
pulled together as one team, without reference to civilian or military
status. Again, at the start there was laid down a policy of inspection
at every single stage of manufacture. The incoming parts, though
already inspected at their source, were reinspected and retested. After
every operation in the manufacture of the face piece there came an
inspection by specially trained women set apart from the operators.
Then again, there was a special control inspection. After the face
piece was finished, and when assembly was complete, the entire mask
went to a final inspection where it was looked over by several trained
women, who worked in dark closets and inspected the face pieces over
a bright light to make sure that no pin pricks had been made, either
maliciously or otherwise. Furthermore, wherever there was an inspector
there was a system of checking his or her accuracy, for 5 per cent of
every inspector's work was periodically selected at random and checked
over by other inspectors.
Hand in hand with this went many of the latest developments of factory
operation. The best machinery was employed, conveyors were used
wherever possible, and, when changes in the size of the operation
or the design of the mask made it advisable, the factory was at
once rearranged in order that the flow might always be orderly and
continuous.
From all of this the reader might judge that the operation, lasting,
as it did, for only a little more than eight months, was a costly one.
Such, however, was not the case, for a well-ordered and accurate cost
system, kept from the very start in accordance with the best practices
of factory accounting, showed that after charging in all equipment
changes and overhead, the plant made complete masks which cost the
Government about 50 cents per mask less than it cost to get complete
masks by purchasing parts and assembling them under private contracts.
Along with this manufacturing development went the building up of
an elaborate procurement force charged with the responsibility of
providing parts to be assembled at the gas-defense plant and the Hero
Manufacturing Co. This section faced a hard and intricate task, but
though there were instances where a shortage of parts temporarily
slowed down production, these were remarkably few. Many were the
difficulties of buying new parts; many of the parts were the product
of elaborate die work; die makers in the country were overworked.
Specifications had to be written, checked, and approved, and a field
inspection first had to be organized and trained so that the product
from all the different plants could be relied upon as satisfactory for
the assembling plants. But this problem was still further complicated
by ever-recurring changes in design, made necessary as improvement
followed improvement. Officers had to be trained in a day and then sent
out to train inspection corps in manufacturing plants in many parts of
the country. Inspection and procurement detachments were maintained in
most of the eastern industrial centers. There were over 100 enlisted
men and 9 officers in Akron, 30 enlisted men with 6 officers in Boston,
and men and officers in over 60 cities. Here again the civilian and
Army officer worked hand in hand; for Mr. Robert Skemp, a volunteer
civilian from Pittsburgh, was in charge of this procurement, reporting
to Lieut. Col. Besse and directing an organization made up almost
entirely of officers and enlisted men.
The March output of masks was 183,000; that of April, 363,000; May,
slightly less than this figure; that of June, 504,000; that of July,
671,000. In all, between January 1 and November 11, 1918, we built more
than 5,000,000 gas masks.
In February, 1918, shortly before the German drive commenced, we
received requisitions for sample lots of oiled mittens and oiled union
suits as protection against mustard gas and also for chloride of lime
to neutralize poison-impregnated earth. In their March drive the
Germans used gas in much more protracted concentrations than before.
Originally the masks had been worn only during the sporadic gas alarms,
and then only for a brief period at a time.
The double-protection mask which we had been building had been
admirable in its day, but it was no longer adapted to the sort of use
to which it was evident it must now be put. In long-continued wear the
mouthpiece would irritate the gums and lips of the soldier, and the
face-piece band would cause excruciating headaches after a few hours.
It had now become frequently necessary for men to wear their masks for
eight hours at a stretch. The word discomfort is a weak description of
the feelings of a man wearing one of our masks for that period.
Our authorities in France decreed for a single-protection mask and more
comfort, even at the expense of a little safety. The result of these
new conditions together with the establishment of closer relationship
with our Expeditionary Forces, through a visit of Col. Dewey to France,
was the determination to build masks in this country which should give
the protection of the masks which we had been turning out and at the
same time be comparatively comfortable. There had been brought out in
France a single-protection mask, that is, a mask in which the inlet
tube entered directly into the space between the mask and the face,
with the orifices so arranged that the fresh air was drawn across the
eyepieces. This was known as the Tissot mask. The principle of the
Tissot was correct as far as comfort was concerned, since it did away
with the irritating mouthpiece, but the chief danger in this mask arose
from the fact that it was made of thin, pure gum rubber. We took the
Tissot and endeavored to produce a mask of this type which should be
gas-tight and yet rugged. In this work we experimented on hundreds of
subjects to determine face and head sizes and shapes. It is interesting
to note in this connection that the size of a man's face has nothing to
do with the size of his head, as large heads with small faces and small
heads with large faces occur not infrequently.
We made two developments of the mask without mouthpiece or nose clip.
Both were ready for field tests in August, 1918. The one produced in
Akron and assembled at the Philadelphia contracting plant was known as
the Akron Tissot, or Type A-T.
At the start of operations in Long Island City Mr. Waldemar Kops, of
New York, a manufacturer of corsets, came to the Government, asking
an opportunity to do his part in the war. He was assigned to the
gas-defense plant, and later, with the commission of major, took
charge of the gas-defense Long Island laboratories. Maj. Kops had no
experience with gas masks until he came to the gas-defense plant, but
his experiments soon led to an improvement in the design of the Tissot
mask. It was called the Type KT mask--the Kops-Tissot. Only a few
hundred thousand were produced, though the latest model was scheduled
for enormous production beginning in December, 1918. It possessed much
of the protective efficiency of the old uncomfortable mask, the cut of
the face piece insured a gas-tight connection with the head, it was
relatively comfortable, and it was durable.
The call of the allies in the spring of 1918 for American troops in
as great numbers as the ships could carry them to France resulted in
still further increases in our mask requirements. At the height of the
drive we were making over 40,000 masks a day. Approximately 35,000
employees were engaged in the manufacture of various gas-mask parts.
Our carbon requirements were expanding at a rate that would have needed
400 tons of raw materials a day by December, 1918. We built 336,919 KT
masks and approximately 200,000 A-T masks. In exact figures the total
production of masks of all types was 5,692,499. Of these 3,666,683 were
built at the gas-defense plant and 2,025,816 were assembled by the Hero
Manufacturing Co. In addition, we furnished 3,189,357 extra filled
canisters for the replacement of those used up by 40 hours of field
service.
Hand in hand with this procurement and manufacturing achievement went
the development of the technical section of the Gas Defense Division.
This was known as the Long Island laboratories, manned by a personnel
of several hundred men and officers. Here in its laboratories were
solved the knotty problems that bridged the gap between experimental
work and production. Many new designs were worked out, only to be
rejected when tested. Here there were workrooms that could make sample
lots of 1,000 masks, and here were located the chemical laboratories
and the gas chambers in which the product of the gas-defense plant was
tested daily by control chemical analysis and by actual breathing and
wearing tests.