typographic plate. This plate is made as follows:--The form, composed in
ordinary types, and containing one, two, three, or more pages, inversely
as the size of the book, being laid flat upon a slab, with the letters
looking upwards, the faces of the types are brushed over with oil, or
preferably, with plumbago (black lead). A heavy brass rectangular frame
of three sides, with bevelled borders, adapted exactly to the size of
the pages, is then laid down upon the chase,[61] to circumscribe three
sides of its typography; but the fourth side, which is one end of the
rectangle, is formed by placing near the types, and over the hollows of
the chase, a single brass bar, having the same inwards sloping bevel as
the other three sides. The complete frame resembles that of a picture,
and serves to define the area and thickness of the cast, which is made
by pouring the pap of Paris plaster into its interior space, up to a
given line on its edges. The plaster mould, which soon sets, or becomes
concrete, is lifted gently off the types, and immediately placed upright
on its edge in one of the cells of a sheet-iron rack mounted within the
cast-iron oven. An able workman will mould ten sheets octavo in a day,
or 160 pages. The moulds are here exposed to air heated to fully 400°
F., and become perfectly dry in the course of two hours. As they are now
friable and porous, they require to be delicately handled. Each mould,
containing generally two pages octavo, is laid, with the impression
downwards, upon a flat cast-iron plate, called the floating-plate; this
plate being itself laid on the bottom of the dipping-pan, which is a
cast-iron square tray, with its upright edges sloping outwards. A
cast-iron lid is applied to the dipping-pan, and secured in its place by
a screw. The pan having been heated to 400° in a cell of the oven, under
the mould-rack, previous to receiving the hot mould, is ready to be
plunged into the bath of melted alloy contained in an iron pot placed
over a furnace, and it is dipped with a slight deviation from the
horizontal plane, in order to facilitate the escape of the air. As there
is a minute space between the back or top surface of the mould and the
lid of the dipping-pan, the liquid metal, on entering into the pan
through the orifices in its corners, floats up the plaster along with
the iron plate on which it had been laid, thence called the
floating-plate, whereby it flows freely into every line of the mould,
through notches cut in its edge, and forms a layer or lamina upon its
face, of a thickness corresponding to the depth of the border. Only a
thin metal film is left upon the back of the mould. The dipping-pan is
suspended, plunged, and removed by means of a powerful crane,
susceptible of vertical and horizontal motions in all directions. When
lifted out of the bath, it is set in a water-cistern, upon bearers so
placed as to allow its bottom only to touch the surface. Thus the metal
first concretes below, while, by remaining fluid above, it continues to
impart hydrostatic pressure during the shrinkage attendant upon
refrigeration. As it thus progressively contracts in volume, more melted
metal is fed into the corners of the pan by a ladle, in order to keep up
the hydrostatic pressure upon the mould, and to secure a perfect
impression, as well as a solid cast. Were the pan more slowly and
equably cooled, by being left in the air, the thin film of metal upon
the back of the inverted plaster cake would be apt to solidify first,
and intercept the hydrostatic action indispensable to the purpose of
filling all the lines in its face. A skilful workman makes five dips,
containing two pages octavo each, in the course of an hour, or about
nine and a half octavo sheets per day. The pan being taken asunder, the
compound cake of mould and metal is removed, and beat upon its edges
with a wooden mallet, to detach the superfluous metal. The stereotype
plate is then handed over to the picker, who planes its edges truly
square, turns its back flat upon a lathe to a determinate thickness, and
carefully removes the little imperfections occasioned by dirt or air
left among the letters when the mould was cast. Should any of them be
damaged in the course of the operation, they must be cut out, and
replaced by soldering in separate types of the same size and form.
[61] Chase (_chassis_, frame, Fr.), quoin (_coin_, wedge, Fr.), are
terms which show that the art of printing came directly from France to
England.
STILL (_Alambic_, Fr.; _Blase_, Germ.); is a chemical apparatus, for
vaporizing liquids by heat in one part, called the _cucurbit_, and
condensing the vapours into liquids in another part, called the
_refrigeratory_; the general purpose of both combined being to separate
the more volatile fluid particles from the less volatile. In its
simplest form, it consists of a retort and a receiver, or of a
pear-shaped matrass and a capital, furnished with a slanting tube for
conducting away the condensed vapours in drops; whence the term _still_,
from the Latin verb _stillare_, to drop. Its chief employment in this
country being to eliminate alcohol, of greater or less strength, from
fermented wash, I shall devote this article to a description of the
stills best adapted to the manufacture of British spirits, referring to
chemical authors[62] for those fitted for peculiar objects.
[62] The treatises of Le Normand and Dubrunfaut may also be consulted.
The French stills are in general so much complicated with a great many
small pipes and passages, as to be unfit for distilling the glutinous
wash of grains.
In respect of rapidity and extent of work, stills had attained to an
extraordinary pitch of perfection in Scotland about thirty years ago,
when legislative wisdom thought fit to levy the spirits duty, per annum,
from each distiller, according to the capacity of his still. It having
been shown, in a report presented to the House of Commons in 1799, that
an 80-gallon still could be worked off in eight minutes, this fact was
made the basis of a new fiscal law, on the supposition that the maximum
of velocity had been reached. But, instigated by the hopes of enormous
gains at the expense of the revenue, the distillers soon contrived to do
the same thing in three minutes, by means of broad-bottomed shallow
stills, with stirring-chains, and lofty capitals. In the year 1815, that
preposterous law, which encouraged fraud and deteriorated the
manufacture, was repealed. The whiskey duties having been since levied,
independently of the capacity of the still, upon the quantity produced,
such rapid operations have been abandoned, and processes of economy in
fuel, and purity in product, have been sought after.
One of the greatest improvements in modern distilleries, is completing
the analysis of crude spirit at one operation. Chemists had been long
familiar with the contrivance of Woulfe, for impregnating with gaseous
matter, water contained in a range of bottles; but they had not thought
of applying that plan to distillation, when Edouard Adam, an illiterate
workman of Montpellier, after hearing accidentally a chemical lecture
upon that apparatus, bethought himself of converting it into a still. He
caused the boiling-hot vapours to chase the spirits successively out of
one bottle into another, so as to obtain in the successive vessels
alcohol of any desired strength and purity, “_at one and the same
heat_.” He obtained a patent for this invention in 1801, and was soon
afterwards enabled, by his success on the small scale, to set up in his
native city a magnificent distillery, which excited the admiration of
all the practical chemists of that day. In November, 1805, he obtained a
certificate of certain improvements for extracting from wine, at one
process, the whole of its alcohol. Adam was so overjoyed, after making
his first experiments, that he ran about the streets of Montpellier,
telling every body of the surprising results of his invention. Several
competitors soon entered the lists with him, especially Solimani,
professor of chemistry in that city, and Isaac Berard, distiller in the
department of Gard; who, having contrived other forms of continuous
stills, divided the profits with the first inventor.
The principles of spirituous distillation may be stated as follows:--The
boiling point of alcohol varies with its density or strength, in
conformity with the numbers in the following table:--
+--------+-------------------+
|Specific| Boiling point, by |
|gravity.|Fahrenheit’s scale.|
+--------+-------------------+
| 0·7939 | 168·5° |
| 0·8034 | 168·0 |
| 0·8118 | 168·5 |
| 0·8194 | 169·0 |
| 0·8265 | 172·5 |
| 0·8332 | 173·5 |
| 0·8397 | 175·0 |
| 0·8458 | 177·0 |
| 0·8518 | 179·0 |
| 0·8875 | 181·0 |
| 0·8631 | 183·0 |
| 0·8765 | 187·0 |
| 0·8892 | 190·0 |
| 0·9013 | 194·0 |
| 0·9126 | 197·0 |
| 0·9234 | 199·0 |
| 0·9335 | 201·0 |
+--------+-------------------+
See also the table under ALCOHOL, page 16.
Hence, the lower the temperature of the spirituous vapour which enters
the refrigeratory apparatus, the stronger and purer will the condensed
spirit be; because the offensive oils, which are present in the wash or
wine, are less volatile than alcohol, and are brought over chiefly with
the aqueous vapour. A perfect still should, therefore, consist of three
distinct members; first, the cucurbit, or kettle; second, the rectifier,
for intercepting more or less of the watery and oily particles; and
third, the refrigerator, or condenser of the alcoholic vapours.
These principles are illustrated in the construction of the still
represented in _figs._ 1057, 1058, 1059, 1060, 1061.; in which the
resources of the most refined French stills are combined with a
simplicity and solidity suited to the grain distilleries of the United
Kingdom. Three principal objects are obtained by the arrangement here
shown; first, the extraction from fermented wort or wine, at one
operation, of a spirit of any desired cleanness and strength; second,
great economy of time, labour, and fuel; third, freedom from all danger
of blowing up or boiling over, by mismanaged firing. When a combination
of water, alcohol, and essential oil, in the state of vapour, is passed
upwards through a series of winding passages, maintained at a
determinate degree of heat, between 170° and 180°, the alcohol alone, in
any notable proportion, will retain the elastic form, and will proceed
onwards into the refrigeratory tube, in which the said passages
terminate; while the water and the oil will be in a great measure
condensed, arrested, and thrown back into the body of the still, to be
discharged with the effete residuum.
The system of passages or channels, represented in _fig._ 1058., is so
contrived as to bring the mingled vapours which rise from the alembic
_a_, into ample and intimate contact with metallic surfaces, maintained,
in a water-bath, at a temperature self-regulated by a heat-governor. See
THERMOSTAT.
[Illustration: 1057 1058 1059 1060 1061]
The neck of the alembic tapers upwards, as shown at _b_, _fig._ 1057.;
and at _c_, _fig._ 1058., it enters the bottom, or ingress vestibule, of
the rectifier _c_, _f_. _f_ is its top or egress vestibule, which
communicates with the bottom one by parallel cases or rectangular
channels _d_, _d_, _d_, of which the width is small, compared with the
length and height. These cases are open at top and bottom, where they
are soldered or riveted into a general frame within the cavity, enclosed
by the two covers _f_, _c_, which are secured round their edges _e_,
_e_, _e_, _e_, with bolts and packing. Each case is occupied with a
numerous series of shelves or trays, placed at small distances over each
other, in a horizontal or slightly inclined position, of which a side
view is given in _fig._ 1059., and cross sections at _d_, _d_, _d_,
_fig._ 1058. Each shelf is turned up a little at the two edges, and at
one end, but sloped down at the other end, that the liquor admitted at
the top may be made to flow slowly backwards and forwards in its descent
through the system of shelves or trays, as indicated by the darts and
spouts in _fig._ 1059. The shelves of each case are framed together by
two or more vertical metallic rods, which pass down through them, and
are fixed to each shelf by solder, or by screw-nuts. By this means, if
the cover _f_, be removed, the sets of shelves may be readily lifted out
of the cases and cleaned; for which reason they are called _movable_.
The intervals _i_, _i_, _i_, _fig._ 1058., between the cases, are left
for the free circulation of the water contained in the bath-vessel _g_,
_g_; these intervals being considerably narrower than the cases.
_Fig._ 1060. represents in plan the surface of the rectifying cistern,
shown in two different sections in _figs._ 1058. and 1059. _h_, _k_,
_figs._ 1058. and 1060., is the heat-governor, shaped somewhat like a
pair of tongs. Each leg is a compound bar, consisting of a flat bar or
ruler of steel, and one of brass alloy, riveted facewise together,
having their edges up and down. The links, at _k_, are joined to the
free ends of these compound bars, which, receding by increase and
approaching by decrease of temperature, act by a lever on the stopcock
_l_, fixed to the pipe of a cold-water back, and are so adjusted by a
screw-nut, that whenever the water in the bath vessel _g_, _g_, rises
above the desired temperature, cold water will be admitted, through the
stopcock _l_, and pipe _n_, into the bottom of the cistern, and will
displace the over-heated water by the overflow-pipe _m_. Thus a perfect
equilibrium of caloric may be maintained, and alcoholic vapour of
correspondent uniformity transmitted to the refrigeratory.
_Fig._ 1061. is the cold condenser, of similar construction to the
rectifier, _fig._ 1058.; only the water cells should be here larger in
proportion to the vapour channels _d_, _d_. This refrigeratory system
will be found very powerful, and it presents the great advantage of
permitting its interior to be readily inspected and cleansed. It is best
made of laminated tin, hardened with a little copper alloy.
The mode of working the preceding apparatus will be understood by the
following instructions. Into the alembic, _a_, let as much fermented
liquor be admitted as will protect its bottom from being injured by the
fire, reserving the main body in the charging-back. Whenever the
ebullition in the alembic has raised the temperature of the water-bath
_g_, _g_, to the desired pitch, whether that be 170°, 175°, or 180°, the
thermostatic instrument is to be adjusted by its screw-nut, and then the
communication with the charging-back is to be opened by moving the index
of the stopcock o, over a proper portion of its quadrantal arch. The
wash will now descend in a slender equable stream, through the pipe _o_,
_f_, thence spread into the horizontal tube _p_, _p_, and issue from the
orifices of distribution, as seen in the figure, into the respective
flat trays or spouts. The manner of its progress is seen for one set of
trays, in _fig._ 1059. The direction of the stream in each shelf is
evidently the reverse of that in the shelf above and below it; the
turned-up end of one shelf corresponding to the discharge slope of its
neighbour.
By diffusing the cool wash or wine in a thin film over such an ample
range of surfaces, the constant tendency of the bath to exceed the
proper limit of temperature is counteracted to the utmost, without waste
of time or fuel; for the wash itself, _in transitu_, becomes
boiling-hot, and experiences a powerful steam distillation. By this
arrangement a very moderate influx of cold water, through the
thermostatic stopcock, suffices to temper the bath; such an extensive
vaporization of the wash producing a far more powerful refrigerant
influence than its simple heating to ebullition. It deserves to be
remarked, that the maximum distillatory effect, or the bringing over the
greatest quantity of pure spirits in the least time, and with the least
labour and fuel, is here accomplished without the least steam pressure
in the alembic; for the passages are all pervious to the vapour;
whereas, in almost every wash-still heretofore contrived for similar
purposes, the spirituous vapours must force their way through successive
layers of liquid, the total pressure produced by which causes undue
elevation of temperature, and obstruction to the process. Whatever
supplementary refrigeration of the vapours in their passage through the
bath may be deemed proper, will be administered by the thermostatic
regulator.
Towards the end of the process, after all the wash has entered the
alembic, it may be sometimes desirable, for the sake of despatch, to
modify the thermostat, by its adjusting-screw, so that the bath may take
a higher temperature, and allow the residuary feints to run rapidly
over, into a separate cistern. This weak fluid may be pumped back into
the alembic, as the preliminary charge of a fresh operation.
The above plan of a water-bath regulated by the thermostat, may be used
simply as a rectifying cistern, without transmitting the spirit or wash
down through it. The series of shelves will cause the vapours from the
still to impinge against a most extensive system of metallic surfaces,
maintained at a steady temperature, whereby their watery and crude
constituents will be condensed and thrown back, while their fine
alcoholic particles will proceed forwards to the refrigeratory. Any
ordinary still may be readily converted into this self-rectifying form,
by merely interposing the cistern, _fig._ 1058., between the alembic and
the worm-tub. The leading novelty of the present invention is the
_movable_ system of shelves or trays, enclosed in metallic cases,
separated by water, combined with the thermostatic regulator. By this
combination, any quality of spirits may be procured at one step from
wash or wine, by an apparatus, simple, strong and easily kept in order.
The empyreumatic taint which spirits are apt to contract from the action
of the naked fire on the bottom of the still, may be entirely prevented
by the use of a bath of potash lye, _p_, _p_, _fig._ 1057.; for thus a
safe and effectual range of temperature, of 300° F., may be conveniently
obtained. The still may also be used without the bath vessel.
[Illustration: 1062]
Mr. D. T. Shears, of Southwark, obtained a patent in March, 1830, for
certain improvements and additions to stills, which are ingenious. They
are founded upon a previous patent, granted to Joseph Corty, in 1818; a
section of whose contrivance is shown in _fig._ 1062., consisting of a
first still _a_, a second still _b_, a connecting tube _c_, from the one
end to the other, and the tube _d_, which leads from the second
still-head down through the bent tube _e_, _e_, to the lower part of the
condensing apparatus.
The original improvements described under Corty’s patent, consisted
further, in placing boxes _f_, _f_, _f_, of the condensing apparatus in
horizontal positions, and at a distance from each other, in order that
the vapour might ascend through them, for the purpose of discharging the
spirit by the top tube _g_, and pipe _h_, into the worm, in a highly
rectified or concentrated state. In each of the boxes _f_, there is a
convex plate or inverted dish _i_, _i_, _i_, and the vapour in rising
from the tube _e_, strikes against the concave or under part of the
first dish, and then escapes round its edges, and over its convex
surface, to the under part of the second dish, and so on to the top, the
condensed part of the vapour flowing down again into the still, and the
spirit passing off by the pipe _h_, at top; and as the process of
condensation will be assisted by cooling the vapour as it rises, cold
water is made to flow over the tops of the boxes _f_, from a cock _k_,
and through small channels or tubes on the sides of the boxes, and is
ultimately discharged by the pipe _l_, at bottom.
[Illustration: 1063]
_Fig._ 1063. represents a peculiarly shaped tube _a_, through which the
spirit is described as passing after leaving the end of the worm at _b_,
which tube is open to the atmospheric air at _z_; _c_, is the passage
through which the carbonic acid gas is described as escaping into the
vessel of water _d_.
[Illustration: 1064 1065]
Now the improvements claimed under the present patent, are exhibited in
_figs._ 1064, 1065, and 1066. _Fig._ 1064. represents the external
appearance of a still, the head of which is made very capacious, to
guard against over-boiling by any mismanagement of the fire; _fig._
1065. is the same, partly in section. On the top of the still-head is
formed the first-described rectifying apparatus, or series of condensing
boxes. The vapour from the body of the still filling the head, meets
with the first check from the dish or lower vessel _i_, and after
passing under its edges, ascends and strikes against the lower part of
the second dish or vessel _i_, and so on, till it ultimately leaves the
still-head by the pipe at top.
This part of the apparatus is slightly altered from the former, by the
substitution of hollow convex vessels, instead of the inverted dishes
before described, which vessels have rims descending from their under
surfaces, for the purpose of retaining the vapour. The cold water,
which, as above described, flowed over the tops of the boxes _f_, for
the purpose of cooling them, now flows also through the hollow convex
vessels _i_, within the boxes, and by that means greatly assists the
refrigerating process, by which the aqueous parts of the vapour are more
readily condensed, and made to fall down and flow back again into the
body of the still, while the spirituous parts pass off at top to the
worm, in a very high state of rectification.
After the water employed for the refrigeration has passed over all the
boxes, and through all the vessels, it is carried off by the pipe _m_,
through the vessel _n_, called the wash-heater; that is, the vessel in
which the wash is placed previous to introducing it into the still. The
pipe _m_, is coiled round in the lower part of the vessel _n_, in order
that the heated water may communicate its caloric to the wash, instead
of losing the heat by allowing the water to flow away. After the heated
water has made several turns round the wash heater, it passes out at the
curved pipe _o_, which is bent up, in order to keep the coils of the
pipe within always full of water.
Instead of the coiled pipe _n_, last described, the patentee proposes
sometimes to pass the hot water into a chamber in a tub or wooden
vessel, as at _n_, in _fig._ 1061., in which the wash to be heated
occupies the upper part of the vessel, and is separated from the lower
part by a thin metallic partition.
The swan-neck _h_, _figs._ 1064. and 1065., which leads from the head of
the still, conducts the spirit from the still through the wash-heater,
where it becomes partially cooled, and gives out its heat to the wash;
and from thence the spirit passes to the worm tub, and being finally
condensed, is passed through a safety tube, as (_fig._ 1058.) before
described, and by the funnel is conducted into the cask below.
[Illustration: 1066 1067]
Should any spirit rise in the wash-heater during the above operation, it
will be carried down to the worm by the neck _p_, and coiled pipe, and
discharged at its lower end; or it may be passed into the still-head, as
shown in _fig._ 1062.
A patent was obtained by Mr. Æneas Coffey, in August, 1830, for a still,
which has been since mounted in several distilleries. It is economical
in fuel, labour, and time, but is said not to produce a clean spirit,
without peculiar attention.
The apparatus is represented in _fig._ 1067. _a_, _b_, _c_, _d_, is a
sectional view of that part of the still wherein the wash is deprived of
its alcohol, and the vapours analyzed. It is described as consisting of
a chamber or vessel _a_, with the vertical chamber _b_, _c_, placed
above it; the lower half of this chamber is divided into compartments by
horizontal plates _e_, _e_, _e_, of thin copper or other metal; each of
these plates is turned down at one side, until it nearly touches the
plate next underneath it, as shown in the figure; thus leaving a passage
throughout the whole of them, by which any liquid falling on the top
plate may descend into the next under it, and from that to the third,
and so on, from plate to plate, at the alternate ends, until it arrives
at the last plate, wherein it falls into the vessel _a_, by the pipe
_f_; each of these plates is furnished with several light valves,
opening upwards, through which any steam or vapour may ascend; it may
also be perforated with holes, but they must not be so numerous or so
large as to allow of all the steam passing through them without raising
the valves; _c_, is a pipe by which the alcoholic vapour, after it has
been analyzed, and has acquired the proper strength, is conducted into
the vessel _d_, which is made perfectly close; the vapour will here be
condensed on the surface of the pipe _g_, _g_, _g_; from this chamber it
will descend in a liquid state into the pipe _h_, whence it may be
conducted to a worm or refrigerator, to be cooled in the ordinary way;
_i_, is a vessel through which the spent wash flows, after being
operated upon in the distilling apparatus, and is discharged in a state
of ebullition; _j_, is a vessel or chamber containing the wash to be
distilled. A force pump may be substituted, to force the wash through
the pipes _k_, and distilling apparatus, with the velocity required.
The patentee states that it is requisite the wash should be passed
through the pipe _k_, with sufficient velocity and force, so as to
prevent the deposition of sediment in the pipe; the wash in its passage
through the pipe _k_, will gradually become increased in temperature as
it passes through the spent wash in the chamber, and the close vessel
_d_, until it is discharged nearly at the boiling point on the upper
plate in the chamber, where it comes in contact with the vapours arising
from the vessel _a_.
It is to be observed, that the wort does not reach the boiling point
while in the pipe _k_, _k_; to ascertain which, a thermometer is placed
on the pipe, and by increasing or diminishing the quantity of wash, its
temperature may be regulated. The wash, after being discharged from the
pipe _k_, descends from plate to plate as before mentioned, at which
time a supply of steam from a boiler, or generator is admitted into the
apparatus, through the pipe.
The lower part of this pipe in the vessel _a_, is pierced with a number
of small holes, so as to spread the steam over the vessel; it then rises
upwards, passing through the plate by the small holes and valves, and
through the stratum or sheet of wash flowing over them; the wash, as it
descends, gives out a portion of its alcohol to the steam, as it passes
over every plate, until it is entirely deprived of its spirit, which it
will generally do by the time it arrives at the 7th or 8th plate; but it
is better to employ a greater number, to guard against accidents or
neglect.
A small steam pipe rises from the chamber _a_, with its upper end
opening into the box or chamber; into this chamber the end of a worm
projects from the cistern of cold water; the steam rising up the pipe is
nearly all condensed in the worm, and flows back into the chamber _a_,
by the pipe. The small portion of the steam uncondensed, is allowed to
escape at the upper end of the worm, and the flame of a small lamp or
taper is to be constantly kept over the orifice; when, should the least
quantity of alcohol descend with the wash into the chamber _a_, it will
rise with the steam through the pipe and worm, and immediately take fire
from the flame of the lamp or taper, thereby warning the attendant to
increase the supply of steam or diminish the quantity of wash, as may
seem necessary.
[Illustration: 1068]
I shall conclude this article with a description of the cheap still
which is commonly employed by the chemists in Berlin for rectifying
alcohol. _a_, is the ash-pit; _b_, the fireplace; _c_, _c_, the flues,
which go spirally round the sides of the cucurbit _d_; _e_, the capital,
made of block tin, and furnished with a brass edge, which fits tight to
a corresponding edge on the mouth of _d_; _f_, _f_, the slanting pipes
of the capital; _g_, the oval refrigeratory, made of copper; _h_, the
water-gauge glass tube; _i_, a stopcock for emptying the vessel; _k_,
do., for drawing off the hot water from the surface; _l_, tube for the
supply of cold water. A double cylinder of tin is placed in the
refrigeratory, of which the outer one _m_, _m_, stands upon three feet,
and is furnished with a discharge pipe _n_. The inner one _o_, _o_,
which is open above, receives cold water through the pipe _p_, and lets
the warm water flow off through the short tube _q_, into the
refrigeratory. In the narrow space between the two cylinders, the
vapours proceeding from the capital are condensed, and pass off in the
liquid state through _n_. The refrigeratory is made oval, in order to
receive two condensers alongside of each other in the line of the longer
axis; though only one, and that in the middle, is represented in the
figure.
STOCKING MANUFACTURE. See HOSIERY.
STONE, is earthy matter, condensed into so hard a state as to yield only
to the blows of a hammer, and therefore well adapted to the purposes of
building. Such was the care of the antients to provide strong and
durable materials for their public edifices, that but for the desolating
hands of modern barbarians, in peace and in war, most of the temples and
other public monuments of Greece and of Rome would have remained perfect
at the present day, uninjured by the elements during 2000 years. The
contrast, in this respect, of the works of modern architects, especially
in Great Britain, is very humiliating to those who boast so loudly of
social advancement; for there is scarcely a public building of recent
date, which will be in existence one thousand years hence. Many of the
most splendid works of modern architecture are hastening to decay, in
what may be justly called the very infancy of their existence, if
compared with the date of those erected in antient Italy, Greece, and
Egypt. This is remarkably the case with the three bridges of London,
Westminster, and Blackfriars; the foundations of which began to perish
most visibly in the very lifetime of their constructors. Every stone
intended for a durable edifice, ought to be tested as to its durability,
by immersion in a saturated solution of sulphate of soda, and exposure
during some days to the air. The crystallization which ensues in its
interior, will cause the same disintegration of its substance which
frost would occasion in a series of years.
[Illustration: 1069 1070 1071 1072]
STONE, ARTIFICIAL, for statuary and other decorations of architecture,
has been made for several years with singular success at Berlin, by Mr.
Feilner. His materials are nearly the same with those of English
pottery; and the plastic mass is fashioned either in moulds, or by hand.
His kilns, which are peculiar in form, and economical in fuel, deserve
to be generally known. _Figs._ 1069. and 1070. represent his round kiln;
_fig._ 1069. being an oblique section in the line A, B, C, of _fig._
1070., which is a ground plan in the line D, _a_, _b_, E, of _fig._
1069. The inner circular space _c_, covered with the elliptical arch, is
filled with the figures to be baked, set upon brick supports. The hearth
is a few feet above the ground; and there are steps before the door _d_,
for the workmen to mount by, in charging the kiln. The fire is applied
on the four sides under the hearth. The flame of each passes along the
straight flues _f i_, _f i_, and _f k_. In the second annular flue _g_,
_g_, as also in the third _l_, _l_, the flame of each fire is kept
apart, being separated from the adjoining, by the stones _h_ and _m_. In
the fourth flue _n_, the flames again come together, as also in _o_, and
ascend by the middle opening. Besides this large orifice, there are
several small holes, _p_, _p_, in the hearth over the above flues, to
lead the flames from the other points into contact with the various
articles. There are also channels _q_, _q_, in the sides, enclosed by
thin walls _r_, to promote the equable distribution of the heat; and
these are placed right over the first fire-flues _e_. The partitions
_r_, are perforated with many holes, through which, as well as from
their tops, the flame may be directed inwards and downwards; _s_ are the
vents for carrying off the flames into the upper space _u_, which is
usually left empty. These vents can be closed by iron damper-plates,
pushed in through the side-slits of the dome. _t_, _t_, are peep-holes,
for observing the state of ignition in the furnace; but they are most
commonly bricked up. _Fig._ 1071. is a vertical section, and _fig._
1072. a plan, of an excellent kiln for baking clay to a stony
consistence, for the above purpose, or for burning fire-bricks. A, is
the lower; B, the middle; C, the upper kiln; and D, the hood,
terminating in the chimney E. _a_, _a_, is the ash-pit; _b_, _b_, the
vault for raking out the ashes; it is covered with an iron door _c_.
_d_, is the peep-hole, filled with a clay stopper; _e_, is the
fireplace; _f_, _f_, a vent in the middle of each arch; _g_, _g_, flues
at the sides of the arches, situated between the two fireplaces; _h_,
_i_, _k_, are apertures for introducing the articles to be baked; _l_, a
grate for the fire in the uppermost kiln; _m_, the ash-pit; _n_, the
fire-door; _o_, openings through which the flames of a second fire are
thrown in. At first, only the ground kiln A, is fired, with cleft
billets of pine-wood, introduced at the opening _e_; when this is
finished, the second is fired; and then the third, in like manner. This
kiln is very like the porcelain kiln of Sèvres, and is employed in many
places for baking stoneware.
Mr. Keene obtained a patent, about a year ago, for making a factitious
stone-paste in the following way:--He dissolves one pound of alum in a
gallon of water, and in this solution he soaks 84 pounds of gypsum
calcined in small lumps. He exposes these lumps in the open air for
about eight days, till they become apparently dry, and then calcines
them in an oven at a dull-red heat. The waste heat of a coke oven is
well adapted for this purpose. (See PITCOAL, COKING OF.) These lumps,
being ground and sifted, afford a fine powder, which, when made up into
a paste with the proper quantity of water, forms the petrifying ground.
The mass soon concretes, and after being brushed over with a thin layer
of the petrifying paste, may be polished with pumice, &c., in the usual
way. It then affords a body of great compactness and durability. If half
a pound of copperas be added to the solution of the alum, the gypsum
paste, treated as above, has a fine cream or yellow colour. This stone
stands the weather well.
STONEWARE. (_Fayence_, Fr.; _Steingut_, Germ.) See POTTERY.
STORAX, STYRAX, flows from the twigs and the trunk of the _Liquidambar
styraciflua_, a tree which grows in Louisiana, Virginia, and Mexico.
Liquidamber, as this resin is also called, is a brown or ash-gray
substance, of the consistence of turpentine, which dries up rapidly, has
an agreeable smell, like benzoin, and a bitterish, sharp, burning taste.
It dissolves in four parts of alcohol, and affords 1·4 per cent. of
benzoic acid.
STOVE (_Poële_, _Calorifère_, Fr.; _Ofen_, Germ.); is a fireplace, more
or less close, for warming apartments. When it allows the burning coals
to be seen, it is called a stove-grate. Hitherto stoves have rarely been
had recourse to in this country for heating our sitting-rooms; the
cheerful blaze and ventilation of an open fire being generally
preferred. But last winter, by its inclemency, gave birth to a vast
multitude of projects for increasing warmth and economizing fuel, many
of them eminently insalubrious, by preventing due renewal of the air,
and by the introduction of noxious fumes into it. When coke is burned
very slowly in an iron box, the carbonic acid gas which is generated,
being half as heavy again as the atmospherical air, cannot ascend in the
chimney at the temperature of 300° F.; but regurgitates into the
apartment through every pore of the stove, and poisons the atmosphere.
The large stoneware stoves of France and Germany are free from this
vice; because, being fed with fuel from the outside, they cannot produce
a reflux of carbonic acid into the apartment, when their draught becomes
feeble, as inevitably results from the obscurely burning stoves which
have the doors of the fireplace and ash-pit immediately above the
hearth-stone.
I have recently performed some careful experiments upon this subject,
and find that when the fuel is burning so slowly in the stove as not to
heat the iron surface above the 250th or 300th degree of Fahr., there is
a constant deflux of carbonic acid gas from the ash-pit into the room.
This noxious emanation is most easily evinced by applying the beak of a
matrass, containing a little Goulard’s extract (solution of subacetate
of lead), to a round hole in the door of the ash-pit of a stove in this
languid state of combustion. In a few seconds the liquid will become
milky, by the reception of carbonic acid gas. I shall be happy to afford
ocular demonstration of this fact to any incredulous votary of the
pseudo-economical, anti-ventilation, stoves now so much in vogue. There
is no mode in which the health and life of a person can be placed in
more insidious jeopardy, than by sitting in a room with its chimney
closed up with such a choke-damp-vomiting stove.
That fuel may be consumed by an obscure species of combustion, with the
emission of very little heat, was clearly shown in Sir H. Davy’s
_Researches on Flame_. “The facts detailed on insensible combustion,”
says he, “explain why so much more heat is obtained from fuel when it is
burned quickly, than slowly; and they show that, in all cases, the
temperature of the acting bodies should be kept as high as possible; not
only because the general increment of heat is greater, but likewise
because those combinations are prevented, which, at lower temperatures,
take place without any considerable production of heat. These facts
likewise indicate the source of the great error into which experimenters
have fallen, in estimating the heat given out in the combustion of
charcoal; and they indicate methods by which the temperature may be
increased, and the limits to certain methods.” These conclusions are
placed in a strong practical light by the following simple
experiments:--I set upon the top orifice of a small cylindrical stove, a
hemispherical copper pan, containing six pounds of water, at 60° F., and
burned briskly under it 3-1/2 pounds of coke in an hour; at the end of
which time, 4-1/2 pounds of water were boiled off. On burning the same
weight of coke _slowly_ in the same furnace, surmounted by the same pan,
in the course of 12 hours, little more than one-half the quantity of
water was exhaled. Yet, in the first case, the aerial products of
combustion swept so rapidly over the bottom of the pan, as to
communicate to it not more than one-fourth of the effective heat which
might have been obtained by one of the plans described in the article
EVAPORATION; while, in the second case, these products moved at least 12
times more slowly across the bottom of the pan, and ought therefore to
have been so much the more effective in evaporation, had they possessed
the same power or quantity of heat.
[Illustration: 1073]
Stoves, when properly constructed, may be employed both safely and
advantageously to heat entrance-halls upon the ground story of a house;
but care should be taken not to vitiate the air by passing it over
ignited surfaces, as is the case with most of the patent stoves now
foisted upon the public. _Fig._ 1073. exhibits a vertical section of a
stove which has been recommended for power and economy; but it is highly
objectionable, as being apt to scorch the air. The flame of the fire A,
circulates round the horizontal pipes of cast iron, _b b_, _c c_, _d d_,
_e e_, which receive the external air at the orifice _b_, and conduct it
up through the series, till it issues highly heated at K, L, and may be
thence conducted wherever it is wanted. The smoke escapes through the
chimney B. This stove has evidently two prominent faults; first, it
heats the air-pipes very unequally, and the undermost far too much;
secondly, the air, by the time it has ascended through the zigzag range
to the pipe _e e_, will be nearly of the same temperature with it, and
will therefore abstract none of its heat. Thus the upper pipes, if there
be several in the range, will be quite inoperative, wasting their warmth
upon the sooty air.
[Illustration: 1074]
_Fig._ 1074. exhibits a transverse vertical section of a far more
economical and powerful stove, in which the above evils are avoided. The
products of combustion of the fire A, rise up between two brick walls,
so as to play upon the bed of tiles B, where, after communicating a
moderate heat to the series of slanting pipes whose areas are
represented by the small circles _a_, _a_, they turn to the right and
left, and circulate round the successive rows of pipes _b b_, _c c_, _d
d_, _e e_, and finally escape at the bottom by the flues _g_, _g_,
pursuing a somewhat similar path to that of the burned air among a bench
of gas-light retorts. It is known, that two-thirds of the fuel have been
saved in the gas-works by this distribution of the furnace. For the
purpose of heating apartments, the great object is to supply a vast body
of genial air; and, therefore, merely such a moderate fire should be
kept up in A, as will suffice to warm all the pipes pretty equably to
the temperature of 220° Fahr.; and, indeed, as they are laid with a
slight slope, are open to the air at their under ends, and terminate at
the upper in a common main pipe or tunnel, they can hardly be rendered
very hot by any intemperance of firing. I can safely recommend this
stove to my readers. If the tubes be made of stoneware, its construction
will cost very little; and they may be made of any size, and multiplied
so as to carry off the whole effective heat of the fuel, leaving merely
so much of it in the burned air, as to waft it fairly up the chimney.
I shall conclude this article by a short extract of a paper which was
read before the Royal Society, on the 16th of June, 1836, _upon warming
and ventilating apartments_; a subject to which my mind had been
particularly turned at that time, by the Directors of the Customs Fund
of Life Assurance, on account of the very general state of indisposition
and disease prevailing among those of their officers (nearly 100 in
number) engaged on duty in the Long Room of the Custom House, London.
“The symptoms of disorder experienced by the several gentlemen (about
twenty in number), whom I examined, out of a great many who were
indisposed, were of a very uniform character. The following is the
result of my researches:--
“A sense of tension or fulness of the head, with occasional flushings of
the countenance, throbbing of the temples, and vertigo, followed, not
unfrequently, with a confusion of ideas, very disagreeable to officers
occupied with important and sometimes intricate calculations. A few are
affected with unpleasant perspiration on their sides. The whole of them
complain of a remarkable coldness and languor in their extremities, more
especially the legs and feet, which has become habitual, denoting
languid circulation in these parts, which requires to be counteracted by
the application of warm flannels on going to bed. The pulse is, in many
instances, more feeble, frequent, sharp, and irritable, than it ought to
be, according to the natural constitution of the individuals. The
sensations in the head occasionally rise to such a height,
notwithstanding the most temperate regimen of life, as to require
cupping, and at other times depletory remedies. Costiveness, though not
a uniform, is yet a prevailing symptom.
“The sameness of the above ailments, in upwards of one hundred
gentlemen, at very various periods of life, and of various temperaments,
indicates clearly sameness in the cause.
“The temperature of the air in the Long Room ranged, in the three days
of my experimental inquiry, from 62° to 64° of Fahrenheit’s scale; and
in the Examiner’s Room it was about 60°, being kept somewhat lower by
the occasional shutting of the hot-air valve, which is here placed under
the control of the gentlemen; whereas that of the Long Room is designed
to be regulated in the sunk story, by the fireman of the stove, who
seems sufficiently careful to maintain an equable temperature amidst all
the vicissitudes of our winter weather. Upon the 7th of January, the
temperature of the open air was 50°; and on the 11th it was only 35°;
yet upon both days the thermometer in the Long Room indicated the same
heat, of from 62° to 64°.
“The hot air discharged from the two cylindrical stove-tunnels into the
Long Room was at 90° upon the 7th, and at 110° upon the 11th. This air
is diluted, however, and disguised, by admixture with a column of cold
air, before it is allowed to escape. The air, on the contrary, which
heats the Examiner’s Room, undergoes no such mollification, and comes
forth at once in an ardent blast of fully 170°; not unlike the simoom of
the desert, as described by travellers. Had a similar nuisance, on the
greater scale, existed in the Long Room, it could not have been endured
by the merchants and other visitors on business: but the disguise of an
evil is a very different thing from its removal. The direct air of the
stove, as it enters the Examiner’s Room, possesses, in an eminent
degree, the disagreeable smell and flavour imparted to air by the action
of red-hot iron; and, in spite of every attention on the part of the
fireman to sweep the stove apparatus from time to time, it carries along
with it abundance of burned dusty particles.
“The leading characteristic of the air in these two rooms, is its
dryness and disagreeable smell. In the Long Room, upon the 11th, the air
indicated, by Daniell’s hygrometer, 70 per cent. of dryness, while the
external atmosphere was nearly saturated with moisture. The thermometer
connected with the dark bulb of that instrument stood at 30° when dew
began to be deposited upon it; while the thermometer in the air stood at
64°. In the court behind the Custom-house, the external air being at
35°, dew was deposited on the dark bulb of the hygrometer by a
depression of only 3°; whereas in the Long Room, on the same day, a
depression of 34° was required to produce that deposition. Air, in such
a dry state, would evaporate 0·44 in. depth of water from a cistern in
the course of twenty-four hours; and its influence on the cutaneous
exhalents must be proportionably great.
“As cast iron always contains, beside the metal itself, more or less
carbon, sulphur, phosphorus, or even arsenic, it is possible that the
smell of air passed over it in an incandescent state, may be owing to
some of these impregnations; for a quantity of noxious effluvia,
inappreciably small, is capable of affecting not only the olfactory
nerves, but the pulmonary organs. I endeavoured to test the air as it
issued from the valve in the Examiner’s Room, by presenting to it pieces
of white paper moistened with a solution of nitrate of silver, and
perceived a slight darkening to take place, as if by sulphurous fumes.
White paper, moistened with sulphuretted hydrogen water, was not in the
least discoloured. The faint impression on the first test paper, may be,
probably, ascribed to sulphurous fumes, proceeding from the ignition of
the myriads of animal and vegetable matters which constantly float in
the atmosphere, as may be seen in the sunbeam admitted into a dark
chamber: to this cause, likewise, the offensive smell of air,
transmitted over red-hot iron, may in some measure be attributed, as
well as to the hydrogen resulting from the decomposition of aqueous
vapour, always present in our atmosphere in abundance; especially close
to the banks of the Thames, below London Bridge.
“When a column of air sweeps furiously across the burning deserts of
Africa and Arabia, constituting the phenomenon called simoom by the
natives, the air becomes not only very hot and dry, but highly
electrical, as is evinced by lightning and thunder. Dry sands, devoid of
vegetation, cannot be conceived to communicate any noxious gas or vapour
to the atmosphere, like the malaria of marshes, called miasmata: it is,
hence, highly probable that the blast of the simoom owes its deadly
malignity, in reference to animal as well as vegetable life, simply to
extreme heat, dryness, and electrical disturbance. Similar conditions,
though on a smaller scale, exist in what is called the bell, or cockle,
apparatus for heating the Long Room and the Examiner’s apartment in the
Custom-house. It consists of a series of inverted, hollow, flattened
pyramids of cast iron, with an oblong base, rather small in their
dimensions, to do their work sufficiently in cold weather, when
moderately heated. The inside of the pyramids is exposed to the flames
of coke furnaces, which heat them frequently to incandescence, while
currents of cold air are directed to their exterior surfaces by numerous
sheet-iron channels. The incandescence of these pyramids, or bells, as
they are vulgarly called, was proved by pieces of paper taking fire when
I laid them on the summits. Again, since air becomes electrical when it
is rapidly blown upon the surfaces of certain bodies, it occurred to me
that the air which escapes into the Examiner’s Room might be in this
predicament. It certainly excites the sensation of a cobweb playing
round the head, which is well known to all who are familiar with
electrical machines. To determine this point, I presented a condensing
gold-leaf electrometer to the said current of hot air, and obtained
faint divergence with negative electricity. The electricity must be
impaired in its tension, however, in consequence of the air escaping
through an iron grating, and striking against the flat iron valves, both
of which tend to restore the electric equilibrium. The air blast,
moreover, by being diffused round the glass of the condenser apparatus,
would somewhat mask the appearances. Were it worth while, an apparatus
might be readily constructed for determining this point, without any
such sources of fallacy. The influence of an atmosphere charged with
electricity in exciting headache and confusion of thought in many
persons, is universally known.
“The fetid burned odour of the stove air, and its excessive avidity for
moisture, are of themselves, however, sufficient causes of the general
indisposition produced among the gentlemen who are permanently exposed
to it in the discharge of their public duties.
“From there being nearly a vacuum, as to aqueous vapour, in the said
air, while there is nearly a plenum in the external atmosphere round
about the Custom-house, the vicissitudes of feeling in those who have
occasion to go out and in frequently, must be highly detrimental to
health. The permanent action of an artificial desiccated air on the
animal economy may be stated as follows:--
“The living body is continually emitting a transpirable matter, the
quantity of which, in a grown up man, will depend partly on the activity
of the cutaneous exhalents, and partly on the relative dryness or
moisture of the circumambient medium. Its average amount, in common
circumstances, has been estimated at 20 ounces in twenty-four hours.
“When plunged in a very dry air, the insensible perspiration will be
increased; and, as it is a true evaporation or gasefaction, it will
generate cold proportionably to its amount. Those parts of the body
which are most insulated in the air, and furthest from the heart, such
as the extremities, will feel this refrigerating influence most
powerfully. Hence the coldness of the hands and feet, so generally felt
by the inmates of the apartment, though its temperature be at or above
60°. The brain, being screened by the skull from this evaporating
influence, will remain relatively hot, and will get surcharged, besides,
with the fluids which are repelled from the extremities by the
condensation, or contraction, of the blood-vessels, caused by cold.
Hence the affections of the head, such as tension, and its dangerous
consequences. If sensible perspiration happen, from debility, to break
forth from a system previously relaxed, and plunged into dry air, so
attractive of vapour, it will be of the kind called a cold clammy sweat
on the sides and back, as experienced by many inmates of the Long Room.
“Such, in my humble apprehension, is a rationale of the phenomena
observed at the Custom-house. Similar effects have resulted from hot-air
stoves of a similar kind in many other situations.
“After the most mature physical and medical investigation, I am of
opinion that the circumstances above specified cannot act permanently
upon human beings, without impairing their constitutions, and reducing
the value of their lives. The Directors of the Customs Fund are
therefore justified in their apprehensions, ‘that the mode of heating
the Long Room is injurious to the health of persons employed therein,
and that it must unduly shorten the duration of life.’
“It may be admitted, as a general principle, that the comfort of
sedentary individuals, occupying large apartments during the winter
months, cannot be adequately secured by the mere influx of hot air from
separate stove-rooms: it requires the genial influence of radiating
surfaces in the apartments themselves, such as of open fires, of pipes,
or other vessels filled with hot water or steam. The clothing of our
bodies, exposed to such radiation in a pure, fresh, somewhat cool and
bracing air, absorbs a much more agreeable warmth than it could acquire
by being merely immersed in an atmosphere heated even to 62° Fahr., like
that of the Long Room. In the former predicament, the lungs are supplied
with a relatively dense air, say at 52° Fahr.; while the external
surface of the body or the clothing is maintained at, perhaps, 70° or
75°. This distinctive circumstance has not, I believe, been hitherto
duly considered by the stove doctors, each intent on puffing his own
pecuniary interest; but it is obviously one of great importance, and
which the English people would do well to keep in view; because it is
owing to our domestic apartments being heated by open fires, and our
factories by steam pipes, that the health of our population, and the
expectation of life among all orders in this country, are so much better
than in France and Germany, where hot-air stoves, neither agreeable nor
inoffensive, and in endless variety of form, are generally employed.
“In conclusion, I take leave to state to you my firm conviction that the
only method of warming your Long Room and subsidiary apartments,
combining salubrity, safety, and economy, with convenience in erection
and durable comfort in use, is by a series of steam pipes laid along the
floor, at the line of the desk partitions, in suitable lengths, with
small arched junction-pipes rising over the several doorways, to keep
the passages clear, and at the same time to allow a free expansion and
contraction in the pipes, thereby providing for the permanent soundness
of the joints.”
It would not be difficult to construct a stove or stove-grate which
should combine economy and comfort of warming an apartment, with
briskness of combustion and durability of the fire, without any noxious
deflux of carbonic acid. See CHIMNEY.
STRASS; see PASTES.
STRAW-HAT MANUFACTURE. The mode of preparing the Tuscany or Italian
straw, is by pulling the bearded wheat while the ear is in a soft milky
state, the corn having been sown very close, and of consequence produced
in a thin, short, and dwindled condition. The straw, with its ears and
roots, is spread out thinly upon the ground in fine hot weather, for
three or four days or more, in order to dry the sap; it is then tied up
in bundles and stacked, for the purpose of enabling the heat of the mow
to drive off any remaining moisture. It is important to keep the ends of
the straw air-tight, in order to retain the pith, and prevent its gummy
particles from passing off by evaporation.
After the straw has been about a month in the mow, it is removed to a
meadow and spread out, that the dew may act upon it, together with the
sun and air, and promote the bleaching, it being necessary frequently to
turn the straw while this process is going on. The first process of
bleaching being complete, the lower joint and root is pulled from the
straw, leaving the upper part fit for use, which is then sorted
according to qualities; and after being submitted to the action of
steam, for the purpose of extracting its colour, and then to a
fumigation of sulphur, to complete the bleaching, the straws are in a
condition to be platted or woven into hats and bonnets, and are in that
state imported into England in bundles, the dried ears of the wheat
being still on the straw.
Straw may be easily bleached by a solution of chloride of lime, and also
by sulphuring. For the latter purpose, a cask open at both ends, with
its seams papered, is to be set upright a few inches from the ground,
having a hoop nailed to its inside, about six inches beneath the top, to
support another hoop with a net stretched across it, upon which the
straw is to be laid in successive handfuls loosely crossing each other.
The cask having been covered with a tight overlapping lid, stuffed with
lists of cloth, a brazier of burning charcoal is to be inserted within
the bottom, and an iron dish containing pieces of brimstone is to be put
upon the brazier. The brimstone soon takes fire, and fills the cask with
sulphurous acid gas, whereby the straw gets bleached in the course of
three or four hours. Care should be taken to prevent such a violent
combustion of the sulphur as might cause black burned spots, for these
cannot be afterwards removed. The straw, after being aired and softened
by spreading it upon the grass for a night, is ready to be split,
preparatory to dyeing. Blue is given by a boiling-hot solution of indigo
in sulphuric acid, called _Saxon blue_, diluted to the desired shade;
yellow, by decoction of turmeric; red, by boiling hanks of coarse
scarlet wool in a bath of weak alum water, containing the straw; or
directly, by cochineal, salt of tin, and tartar. Brazil wood and archil
are also employed for dyeing straw. For the other colours, see their
respective titles in this Dictionary.
STRETCHING MACHINE. Cotton goods and other textile fabrics, either white
or printed, are prepared for the market by being stretched in a proper
machine, which lays all their warp and woof yarns in truly parallel
positions. A very ingenious and effective mechanism of this kind was
made the subject of a patent by Mr. Samuel Morand, of Manchester, in
April, 1834, which serves to extend the width of calico pieces, or of
other cloths woven of cotton, wool, silk, or flax, after they have
become shrunk in the processes of bleaching, dyeing, &c. I regret that
the limits of this volume will not admit of its description. The
specification of the patent is published in Newton’s Journal, for
December, 1835.
STRONTIA, one of the alkaline earths, of which _strontium_ is the
metallic basis, occurs in a crystalline state, as a carbonate, in the
lead mines of Strontian in Argyleshire, whence its name. The sulphate is
found crystallized near Bristol, and in several other parts of the
world; but strontitic minerals are rather rare. The pure earth is
prepared exactly like baryta, from either the carbonate or the sulphate.
It is a grayish-white powder, infusible in the furnace, of a specific
gravity approaching that of baryta, having an acrid, burning taste, but
not so corrosive as baryta, though sharper than lime. It becomes hot
when moistened, and slakes into a pulverulent hydrate, dissolves in 150
parts of water at 60°, and in much less at the boiling point, forming an
alkaline solution called _strontia_ water, which deposits crystals in
four-sided tables as it cools. These contain 68 per cent. of water, are
soluble in 52 parts of water at 60°, and in about 2 parts of boiling
water; when heated they part with 53 parts of water, but retain the
other 15 parts, even at a red heat. The dry earth consists of 84·55 of
base, and 15·45 of oxygen. It is readily distinguished from baryta, by
its inferior solubility, and by its soluble salts giving a red tinge to
flame, while those of baryta give a yellow tinge. Fluosilicic acid and
iodate of soda precipitate the salts of the latter earth, but not those
of the former. The compounds of strontia are not poisonous, like those
of baryta. The only preparation of strontia used in the arts is the
NITRATE, which see.
STRYCHNIA, is an alkaline base, extracted from the _Strychnos nux
vomica_, _Strychnos ignatia_, and the _Upas tiente_; which has been
employed in medicine by some of the poison doctors, but is of no use in
any of the arts. When introduced into the stomach, strychnia acts with
fearful energy, causing lock-jaw immediately, and the death of the
animal in a very short time. Half a grain, blown into the throat of a
rabbit, proves fatal in five minutes.
STUCCO. See GYPSUM.
SUBERIC ACID, is prepared by digesting grated cork with nitric acid. It
forms crystals, which sublime in white vapours when heated.
SUBLIMATE, is any solid matter resulting from condensed vapours, and,
SUBLIMATION, is the process by which the volatile particles are raised
by heat, and condensed into a crystalline mass. See CALOMEL and
SAL-AMMONIAC, for examples.
SUBSALT, is a salt in which the base is not saturated with acid; as
subacetate of lead.
SUCCINIC ACID, _Acid of amber_, (_Acide succinique_, Fr.;
_Bernsteinsaüre_, Germ.) is obtained by distilling coarsely pounded
amber in a retort by itself, with a heat gradually raised; or mixed with
one-twelfth of its weight of sulphuric acid, diluted with half its
weight of water. The acid which sublimes is to be dissolved in hot
water, to be saturated with potassa or soda, boiled with bone black, to
remove the foul empyreumatic oily matter, filtered, and precipitated by
nitrate of lead, to convert it into an insoluble succinate; which being
washed, is to be decomposed by the equivalent quantity of sulphuric
acid. Pure succinic acid forms transparent prisms. The succinate of
ammonia is an excellent reagent for detecting and separating iron.
SUGAR (_Sucre_, Fr.; _Zucker_, Germ.); is the sweet constituent of
vegetable and animal products. It may be distinguished into two
principal species. The first, which occurs in the sugar-cane, the
beet-root, and the maple, crystallizes in oblique four-sided prisms,
terminated by two-sided summits; it has a sweetening power which may be
represented by 100; and in circumpolarization it bends the luminous rays
to the right. The second occurs ready formed in ripe grapes and other
fruits; it is also produced by treating starch with diastase or
sulphuric acid. This species forms cauliflower concretions, but not true
crystals; it has a sweetening power which may be represented by 60, and
in circumpolarization it bends the rays to the left. Besides these two
principal kinds of sugar, some others are distinguished by chemists; as
the sugar of milk, of manna, of certain mushrooms, of liquorice-root,
and that obtained from sawdust and glue by the action of sulphuric acid;
but they have no importance in a manufacturing point of view.
Sugar, extracted either from the cane, the beet, or the maple, is
identical in its properties and composition, when refined to the same
pitch of purity; only that of the beet seems to surpass the other two in
cohesive force, since larger and firmer crystals of it are obtained from
a clarified solution of equal density. It contains 5·3 per cent. of
combined water, which can be separated only by uniting it with oxide of
lead, into what has been called a saccharate; made by mixing syrup with
finely ground litharge, and evaporating the mixture to dryness upon a
steam-bath. When sugar is exposed to a heat of 400° F., it melts into a
brown pasty mass, but still retains its water of composition. Sugar thus
fused is no longer capable of crystallization, and is called caramel by
the French. It is used for colouring liqueurs. Indeed sugar is so
susceptible of change by heat, that if a colourless solution of it be
exposed for some time to the temperature of boiling water, it becomes
brown and partially uncrystallizable. Acids exercise such an injurious
influence upon sugar, that after remaining in contact with it for a
little while, though they be rendered thoroughly neutral, a great part
of the sugar will refuse to crystallize. Thus, if 3 parts of oxalic or
tartaric acid be added to sugar in solution, no crystals of sugar can be
obtained by evaporation, even though the acids be neutralized by chalk
or carbonate of lime. By boiling cane sugar with dilute sulphuric acid,
it is changed into starch sugar. Manufacturers of sugar should be,
therefore, particularly watchful against every acidulous taint or
impregnation. Nitric acid converts sugar into oxalic and malic acids.
Alkaline matter is likewise most detrimental to the grain of sugar; as
is always evinced by the large quantity of molasses formed, when an
excess of temper lime has been used in clarifying the juice of the cane
or the beet. When one piece of lump sugar is rubbed against another in
the dark, a phosphorescent light is emitted.
Sugar is soluble in all proportions in water; but it takes four parts of
spirits of wine, of spec. grav. 0·830, and 80 of absolute alcohol, to
dissolve it, both being at a boiling temperature. As the alcohol cools,
it deposits the sugar in small crystals. Caramelized and
uncrystallizable sugar dissolves readily in alcohol. Pure sugar is
unchangeable in the air, even when dissolved in a good deal of water, if
the solution be kept covered and in the dark; but with a very small
addition of gluten, the solution soon begins to ferment, whereby the
sugar is decomposed into alcohol and carbonic acid, and ultimately into
acetic acid.
Sugar forms chemical compounds with the salifiable bases. It dissolves
readily in caustic potash lye, whereby it loses its sweet taste, and
affords on evaporation a mass which is insoluble in alcohol. When the
lye is neutralized by sulphuric acid, the sugar recovers its sweet
taste, and may be separated from the sulphate of potash by alcohol, but
it will no longer crystallize.
That syrup possesses the property of dissolving the alkaline earths,
lime, magnesia, strontites, barytes, was demonstrated long ago by Mr.
Ramsay of Glasgow, by experiments published in Nicholson’s Journal, vol.
xviii. page 9, for September 1807. He found that syrup is capable of
dissolving half as much lime as it contains of sugar; and as much
strontites as sugar. Magnesia dissolved in much smaller quantity, and
barytes seemed to decompose the sugar entirely. These results have been
since confirmed by Professor Daniell. Mr. Ramsay characterized sugar
treated with lime as weak, from its sweetening power being impaired;
from its solution he obtained, after some time, a deposit of calcareous
carbonate. M. Pelouze has lately shown that the carbonic acid in this
case is derived from the atmosphere, and is not formed at the expense of
the elements of the sugar, as Mr. Daniell had asserted.
Sugar forms with oxide of lead two combinations; the one soluble, the
other insoluble. Oxide of lead digested in syrup dissolves to a certain
amount, forms a yellowish liquor, which possesses an alkaline reaction,
and leaves after evaporation an uncrystallizable, viscid, deliquescent
mass. If syrup be boiled with oxide of lead in excess, if the solution
be filtered boiling hot, and if the phial be corked in which it is
received, white bulky flocks will fall to its bottom in the course of 24
hours. This compound is best dried _in vacuo_. It is in both cases
light, tasteless, and insoluble in cold and boiling water; it takes fire
like German tinder (AMADOU), when touched at one point with an ignited
body, and burns away, leaving small globules of lead. It dissolves in
acids, and also in neutral acetate of lead, which forms with the oxide a
subsalt, and sets the sugar free. Carbonic acid gas passed through
water, in which the above saccharate is diffused, decomposes it with
precipitation of carbonate of lead. It consists of 58·26 parts of oxide
of lead, and 41·74 sugar, in 100 parts. From the powerful action
exercised upon sugar by acids and oxide of lead, we may see the fallacy
and danger of using these chemical reagents in sugar-refining. Sugar
possesses the remarkable property of dissolving the oxide, as well as
the subacetate of copper (verdigris), and of counteracting their
poisonous operation. Orfila found that a dose of verdigris, which would
kill a dog in an hour or two, might be swallowed with impunity, provided
it was mixed with a considerable quantity of sugar. When a solution of
sugar is boiled with the acetate of copper, it causes an abundant
precipitate of protoxide of copper; when boiled with the nitrates of
mercury and silver, or the chloride of gold, it reduces the respective
bases to the metallic state.
The following TABLE shows the quantities of Sugar contained in Syrups of
the annexed specific gravities.[63] It was the result of experiments
carefully made.
[63] The author, in minutes of evidence of Molasses Committee of the
House of Commons, 1831, p. 142.
+------------------------+-------------+
|Experimental spec. grav.|Sugar in 100.|
| of solution at 60° F. | by weight. |
+------------------------+-------------+
| 1·3260 | 66·666 |
| 1·2310 | 50·000 |
| 1·1777 | 40·000 |
| 1·440 | 33·333 |
| 1·1340 | 31·250 |
| 1·1250 | 29·412 |
| 1·1110 | 26·316 |
| 1·1045 | 25·000 |
| 1·0905 | 21·740 |
| 1·0820 | 20·000 |
| 1·0685 | 16·666 |
| 1·0500 | 12·500 |
| 1·0395 | 10·000 |
+------------------------+-------------+
If the decimal part of the number denoting the specific gravity of
syrup, be multiplied by 26, the product will denote very nearly the
quantity of sugar per gallon in pounds weight, at the given specific
gravity.[64]
[64] This rule was annexed to an extensive table, representing the
quantities of sugar per gallon corresponding to the specific gravities
of the syrup, constructed by the author for the Excise, in
subserviency to the Beet-root Bill.
Sugar has been analyzed by several chemists; the following TABLE
exhibits some of their results:--
+--------+------------+----------+------+-----+-------+
| | Gay Lussac | | | | |
| |and Thenard.|Berzelius.|Prout.|Ure. | |
+--------+------------+----------+------+-----+-------+
|Oxygen | 56·63 | 49·856 |53·35 |50·33|in 100.|
|Carbon | 42·47 | 43·265 |39·99 |43·38| -- |
|Hydrogen| 6·90 | 6·875 | 6·66 | 6·29| -- |
+--------+------------+----------+------+-----+-------+
_Of the sugar cane, and the extraction of sugar from it._--Humboldt,
after the most elaborate historical and botanical researches in the New
World, has arrived at the conclusion, that before America was discovered
by the Spaniards, the inhabitants of that continent and the adjacent
islands were entirely unacquainted with the sugar canes, with any of our
corn plants, and with rice. The progressive diffusion of the cane has
been thus traced out by the partisans of its oriental origin. From the
interior of Asia it was transplanted first into Cyprus, and thence into
Sicily, or possibly by the Saracens directly into the latter island, in
which a large quantity of sugar was manufactured in the year 1148.
Lafitau relates the donation made by William the Second, king of Sicily,
to the convent of St. Benoit, of a mill for crushing sugar canes, along
with all its privileges, workmen, and dependencies: which remarkable
gift bears the date of 1166. According to this author, the sugar cane
must have been imported into Europe at the period of the Crusades. The
monk Albertus Aquensis, in the description which he has given of the
processes employed at Acre and at Tripoli to extract sugar, says, that
in the Holy Land, the Christian soldiers being short of provisions, had
recourse to sugar canes, which they chewed for subsistence. Towards the
year 1420, Dom Henry, regent of Portugal, caused the sugar cane to be
imported into Madeira from Sicily. This plant succeeded perfectly in
Madeira and the Canaries; and until the discovery of America these
islands supplied Europe with the greater portion of the sugar which it
consumed.
The cane is said by some to have passed from the Canaries into the
Brazils; but by others, from the coast of Angola in Africa, where the
Portuguese had a sugar colony. It was transported in 1506, from the
Brazils and the Canaries, into Hispaniola or Hayti, where several
crushing-mills were constructed in a short time. It would appear,
moreover, from the statement of Peter Martyr, in the third book of his
first Decade, written during the second expedition of Christopher
Columbus, which happened between 1493 and 1495, that even at this date
the cultivation of the sugar cane was widely spread in St. Domingo. It
may therefore be supposed to have been introduced here by Columbus
himself, at his first voyage, along with other productions of Spain and
the Canaries, and that its cultivation had come into considerable
activity at the period of his second expedition. Towards the middle of
the 17th century, the sugar cane was imported into Barbadoes from
Brazil, then into the other English West Indian possessions, into the
Spanish Islands on the coast of America, into Mexico, Peru, Chile, and,
last of all, into the French, Dutch, and Danish colonies.
The sugar cane, _Arundo saccharifera_, is a plant of the graminiferous
family, which varies in height from 8 to 10, or even to 20 feet. Its
diameter is about an inch and a half; its stem is dense, brittle, and of
a green hue, which verges to yellow at the approach of maturity. It is
divided by prominent annular joints of a whitish-yellow colour, the
plane of which is perpendicular to the axis of the stem. These joints
are placed about 3 inches apart; and send forth leaves, which fall off
with the ripening of the plant. The leaves are 3 or 4 feet long, flat,
straight, pointed, from 1 to 2 inches in breadth, of a sea-green tint,
striated in their length, alternate, embracing the stem by their base.
They are marked along their edges with almost imperceptible teeth. In
the 11th or 12th month of their growth, the canes push forth at their
top a sprout 7 or 8 feet in height, nearly half an inch in diameter,
smooth, and without joints, to which the name _arrow_ is given. This is
terminated by an ample panicle, about 2 feet long, divided into several
knotty ramifications, composed of very numerous flowers, of a white
colour, apetalous, and furnished with 3 stamens, the anthers of which
are a little oblong. The roots of the sugar cane are jointed and nearly
cylindrical; in diameter they are about one twelfth of an inch; in their
utmost length 1 foot, presenting over their surface a few short
radicles.
The stem of the cane in its ripe state is heavy, very smooth, brittle,
of a yellowish-violet, or whitish colour, according to the variety. It
is filled with a fibrous, spongy, dirty-white pith, which contains very
abundant sweet juice. This juice is elaborated separately in each
internodary portion, the functions of which are in this respect
independent of the portions above and below. The cane may be propagated
by seeds or buds with equal facility; but it is usually done by cuttings
or joints of proper lengths, from 15 to 20 inches, in proportion to the
nearness of the joints, which are generally taken from the tops of the
canes, just below the leaves.
There are several varieties of the sugar-cane plant. The first, and
longest known, is the creole, or common sugar cane, which was originally
introduced at Madeira. It grows freely in every region within the
tropics, on a moist soil, even at an elevation of 3000 feet above the
level of the sea. In Mexico, among the mountains of Caudina-Masca, it is
cultivated to a height of more than 5000 feet. The quantity and quality
of sugar which it yields, is proportional to the heat of the place where
it grows, provided it be not too moist and marshy.
The second variety of this plant is the Otaheitan cane. It was
introduced into the West Indies about the end of the 18th century. This
variety, stronger, taller, with longer spaces between the joints,
quicker in its growth, and much more productive in sugar, succeeds
perfectly well in lands which seem too much impoverished to grow the
ordinary cane. It sends forth shoots at temperatures which chill the
growth and development of the creole plant. Its maturation does not take
more than a year, and is accomplished sometimes in nine months. From the
strength of its stem, and the woodiness of its fibres, it better resists
the storms. It displays a better inflorescence, weighs a third more,
affords a sixth more juice, and a fourth more sugar, than the common
variety. Its main advantage, however, is to yield four crops in the same
time that the creole cane yields only three. Its juice contains less
feculency and mucilage, whence its sugar is more easily crystallized,
and of a fairer colour.
Besides these two varieties, another kind is described by Humboldt and
Bonpland, under the name of the _violet_ sugar-cane, for its haum and
leaves are of this colour. It was transported from Batavia in 1782. It
flowers a month sooner than the rest, that is, in August, but it yields
less solid sugar, and more liquid, both of which have a violet tint.
In saying that the cane may be propagated by seeds as well as buds, we
must remark, that in all the colonies of the New World, the plant
flowers, indeed, but it then sends forth a shoot (_arrow_), that is, its
stem elongates, and the seed-vessel proves abortive. For this reason,
the bud-joints must there be used for its propagation. It grows to seed,
however, in India. This circumstance occurs with some other plants,
which, when propagated by their roots, cease to yield fertile seeds;
such as the banana, the bread-fruit, the lily, and the tulip.
In the proper season for planting, the ground is marked out by a line
into rows three or four feet asunder, in which rows the canes are
planted about two feet apart. The series of rows is divided into pieces
of land 60 or 70 feet broad, leaving spaces of about 20 feet, for the
convenience of passage, and for the admission of sun and air between the
stems. Canes are usually planted in trenches, about 6 or 8 inches deep,
made with the hand-hoe, the raised soil being heaped to one side, for
covering-in the young cane; into the holes a negro drops the number of
cuttings intended to be inserted, the digging being performed by other
negroes. The earth is then drawn about the hillocks with the hoe. This
labour has been, however, in many places better and more cheaply
performed by the plough; a deep furrow being made, into which the
cuttings are regularly planted, and the mould then properly turned in.
If the ground is to be afterwards kept clear by the horse-hoe, the rows
of canes should be 5 feet asunder, and the hillocks 2-1/2 feet distant,
with only one cane left in one hillock. After some shoots appear, the
sooner the horse-hoe is used, the more will the plants thrive, by
keeping the weeds under, and stirring up the soil. Plant-canes of the
first growth have been known to yield, on the brick-mould of Jamaica, in
very fine seasons, 2-1/2 tons of sugar per acre. The proper season for
planting the cane-slips, containing the buds, namely, the top part of
the cane, stripped of its leaves, and the two or three upper joints, is
in the interval between August and the beginning of November. Favoured
by the autumnal weather, the young plants become luxuriant enough to
shade the ground before the dry season sets in; thereby keeping the
roots cool and moderately moist. By this arrangement the creole canes
are ripe for the mill in the beginning of the second year, so as to
enable the manager to finish his crop early in June. There is no greater
error in the colonist than planting canes at an improper season of the
year, whereby his whole system of operations becomes disturbed and, in a
certain degree, abortive.
The withering and fall of a leaf afford a good criterion of the maturity
of the cane-joint to which it belonged; so that the eight last leafless
joints of two canes, which are cut the same day, have exactly the same
age and the same ripeness, though one of the canes be 15 and the other
only 10 months old. Those, however, cut towards the end of the dry
season, before the rains begin to fall, produce better sugar than those
cut in the rainy season, as they are then somewhat diluted with watery
juice, and require more evaporation to form sugar. It may be reckoned a
fair average product, when one pound of sugar is obtained from one
gallon (English) of juice.
_Rattoons_ (a word corrupted from _rejettons_) are the sprouts or
suckers that spring from the roots or stoles of the canes that have been
previously cut for sugar. They are commonly ripe in 12 months; but canes
of the first growth are called plant-canes, being the direct produce of
the original cuttings or germs placed in the ground, and require a
longer period to bring them to maturity. The first yearly return from
the roots that are cut over, are called first rattoons; the second
year’s growth, second rattoons; and so on, according to their age.
Instead of stocking up his rattoons, holing, and planting the land anew,
the planter suffers the stoles to continue in the ground, and contents
himself, as the cane-fields become thin and impoverished, with supplying
the vacant places with fresh plants. By these means, and with the aid of
manure, the produce of sugar per acre, if not apparently equal to that
from plant-canes, gives perhaps in the long run as great returns to the
owner, considering the relative proportion of the labour and expense
attending the different systems. The common yielding on proper land,
such as the red soil of Trelawney, in Jamaica, is 7 hogsheads, of 16
cwt. each, to 10 acres of rattoons cut annually; and such a plantation
lasts from 6 to 10 years.
When the planted canes are ripe, they are cut close above the ground, by
an oblique section, into lengths of 3 or 4 feet, and transported in
bundles to the mill-house. If the roots be then cut off, a few inches
below the surface of the soil, and covered up with fine mould, they will
push forth more prolific offsets or rattoons, than when left projecting
in the common way.