13. _Tungstate of lead._

Having thus enumerated the several species of lead ore, we may remark,

that galena is the only one which occurs in sufficiently great masses to

become the object of mining and metallurgy. This mineral is found in

small quantity among the crystalline primitive rocks, as granite. It is

however among the oldest talc-schists and clay slates, that it usually

occurs. But galena is much more abundant among the transition rocks,

being its principal locality, where it exists in interrupted beds,

masses, and more rarely in veins. The blackish transition limestone is

of all rocks that which contains most galena; as at Pierreville in

Normandy; at Clausthal, Zellerfeldt, and most mines of the Harz; at

Fahlun, in Sweden; in Derbyshire and Northumberland, &c. In the

transition graywacke of the south of Scotland, the galena mines of

Leadhills occur. The galena of the primitive formations contains more

silver than that of the calcareous.

The principal lead mines at present worked in the world, are the

following: 1. Poullaouen and Huelgoët near Carhaix in France, department

of Finisterre, being veins of galena, which traverse a clay slate

resting upon granite. They have been known for upwards of three

centuries; the workings penetrate to a depth of upwards of 300 yards,

and in 1816 furnished 500 tons of lead per annum, out of which 1034

pounds avoirdupois of silver were extracted. 2. At Villeforte and

Viallaz, department of the Lozère, are galena mines said to produce 100

tons of lead _per annum_, with 400 kilogrammes of silver (880 libs.

avoird.). 3. At Pezey and Macot, to the east of Moutiers in Savoy, a

galena mine exists in talc-schist, which has produced annually 200 tons

of lead, and about 600 kilogrammes of silver (1320 libs avoird.). 4. The

mine of Vedrin, near Namur in the Low Countries, is opened upon a vein

of galena, traversing compact limestone of a transition district; it has

furnished 200 tons of lead, from which 385 pounds avoird. of silver were

extracted. 5. In Saxony the galena mines are so rich in silver as to

make the lead be almost overlooked. They are enumerated under silver

ores. 6. The lead mines of the Harz, have been likewise considered as

silver ores. 7. Those of Bleyberg in the Eifel are in the same

predicament. 8. The galena mines of Bleyberg and Villach in Carinthia,

in compact limestone. 9. In Bohemia, to the south-west of Prague. 10.

The mines of Joachimsthal, and Bleystadt, on the southern slope of the

Erzgebirge, produce argentiferous galena. 11. There are numerous lead

mines in Spain, the most important being in the granite hills of

Linarès, upon the southern slope of the Sierra Morena, and in the

district of the small town of Canjagar. Sometimes enormous masses of

galena are extracted from the mines of Linarès. There are also mines of

galena in Catalonia, Grenada, Murcia, and Almeria, the ore of the last

locality being generally poor in silver. 12. The lead mines of Sweden

are very argentiferous, and worked chiefly with a view to the silver.

13. The lead mines of Daouria are numerous and rich, lying in a

transition limestone, which rests on primitive rocks; their lead is

neglected on account of the silver.

14. Of all the countries in the world, Great Britain is that which

annually produces the greatest quantity of lead. According to M.

Villefosse, in his _Richesse Minerale_, published in 1810, we had

furnished every year 12,500 tons of lead, whilst all the rest of Europe

taken together, did not produce so much; but from more recent documents,

that estimate seems to have been too low. Mr. Taylor has rated the total

product of the United Kingdom _per annum_ at 31,900 tons, a quantity

fully 2-1/2 times greater than the estimate of Villefosse (see Conybeare

and Phillips’ Geology, p. 354). Mr. Taylor distributes this product

among the different districts as follows:--

Tons.

Wales, (Flintshire and Denbighshire) 7,500

Scotland, (in transition graywacke) 2,800

Durham, Cumberland, and Yorkshire, (in carboniferous lime) 19,000

Derbyshire, (probably in carboniferous lime) 1,000

Shropshire 800

Devon and Cornwall, (transition and primitive rocks) 800

------

Total 31,900

We thus see that Cumberland, and the adjacent parts of the counties of

Durham and York, furnish of themselves nearly three-fifths of the total

product. Derbyshire was formerly much more productive. In Cornwall and

Devonshire, the lead ore is found in veins in _killas_, a clay-slate

passing into greywacke. In North Wales and the adjacent counties, as

well as in Cumberland and Derbyshire, the lead occurs in the

carboniferous limestone.

The English lead-miners distinguish three different kinds of deposits of

lead ore; _rake-veins_, _pipe-veins_, and _flat-veins_. The English word

vein corresponds to the French term _filon_; but miners make use of it

indifferently in England and France, to indicate all the deposits of

this ore, adding an epithet to distinguish the different forms; thus,

_rake veins_ are true veins in the geological acceptation of the word

vein; _pipe-veins_ are masses usually very narrow, and of oblong shape,

most frequently parallel to the plane of the rocky strata; and

_flat-veins_ are small beds of ores interposed in the middle of these

strata.

_Rake-veins_ are the most common form in which lead ore occurs in

Cumberland. They are in general narrower in the sandstone which covers

the limestone, than in the calcareous beds. A thickness of less than a

foot in the former, becomes suddenly 3 or 4 feet in the latter; in the

rich vein of Hudgillburn, the thickness is 17 feet in the _Great

limestone_, while it does not exceed 3 feet in the overlying _Watersill_

or sandstone. This influence exercised on the veins by the nature of the

enclosing rock, is instructive; it determines at the same time almost

uniformly their richness in lead ore, an observation similar to what has

been made in other countries, especially in the veins of Kongsberg in

Norway. The Cumberland veins are constantly richer, the more powerful

they are, in the portions which traverse the calcareous rocks, than in

the beds of sandstone, and more particularly the schistose rocks. It is

rare in the rock called _plate_ (a solid slaty clay) for the vein to

include any ore; it is commonly filled with a species of potter’s earth.

The upper calcareous beds are also in general more productive than the

lower ones. In most of these mines, the veins were not worked till

lately below the fifth calcareous bed (the four-fathom limestone), which

is 307 yards beneath the millstone-grit; and as the first limestone

stratum is 108 yards beneath it, it follows that the thickness of the

part of the ground where the veins are rich in lead does not in general

exceed 200 yards. It appears however that veins have been mined in the

neighbourhood of Alston Moor, downwards to the eleventh calcareous

stratum, or Tyne bottom limestone, which is 418 yards under the

millstone-grit of the coal formation, immediately above the whin-sill;

and that they have been followed above the first limestone stratum, as

high as the grindstone sill, which is only 83 yards below the same

stratum of millstone-grit; so that in the total thickness of the

plumbiferous formation there is more than 336 yards. It has been

asserted that lead veins have been traced even further down, into the

_Memerby_ scar limestone; but they have not been mined.

The greatest enrichment of a vein takes place commonly in the points

where its two sides, being not far asunder, belong to the same rock; and

its impoverishment occurs when one side is calcareous and the other a

schistose clay. The minerals which most frequently accompany the galena,

are carbonate of lime, fluate of lime, sulphate of baryta, quartz, and

pyrites.

The pipe-veins (_amas_ in French), are seldom of great length; but some

have a considerable width; their composition being somewhat similar to

that of the _rake-veins_. They meet commonly in the neighbourhood of the

two systems, sometimes being in evident communication together; they are

occasionally barren; but when a wide pipe-vein is metalliferous, it is

said to be very productive.

The _flat veins_, or _strata veins_, seem to be nothing else than

expansions of the matter of the vein between the planes of the strata;

and contain the same ores as the veins in their vicinity. When they are

metalliferous, they are worked along with the adjacent rake vein; and

are productive to only a certain distance from that vein, unless they

get enriched by crossing a rake vein. Some examples have been adduced of

advantageous workings in _flat veins_ in the _great limestone_ of

Cumberland, particularly in the mines of Coalcleugh and Nenthead. The

_rake veins_, however, furnish the greater part of the lead which

Cumberland and the adjacent counties send every year into the market.

Mr. Forster gives a list of 165 lead mines, which have been formerly, or

are now, worked in that district of the kingdom.

The metalliferous limestone occupies, in Derbyshire, a length of about

25 miles from north-west to south-east, under a very variable breadth,

which towards the south, amounts to 25 miles. Castleton to the north,

Buxton to the north-west, and Matlock to the south-east, lie nearly upon

its limits. It is surrounded on almost all sides by the millstone grit

which covers it, and which is, in its turn, covered by the coal strata.

The nature of the rocks beneath the limestone is not known. In

Cumberland the metalliferous limestone includes a bed of trap,

designated under the name of _whinsill_. In Derbyshire the trap is much

more abundant, and it is thrice interposed between the limestone. These

two rocks constitute of themselves the whole mineral mass, through a

thickness of about 550 yards, measuring from the millstone grit; only in

the upper portion, that is near the millstone grit, there is a pretty

considerable thickness of argillo-calcareous schists.

Four great bodies or beds of limestone are distinguishable, which

alternate with three masses of trap, called toadstone. The lead veins

exist in the calcareous strata, but disappear at the limits of the

toadstone. It has now been ascertained however that they recur in the

limestone underneath.

_Treatment of the Ores of Lead._

The mechanical operations performed upon the lead ores in Great Britain,

to bring them to the degree of purity necessary for their metallurgic

treatment, may be divided into three classes, whose objects are,--

A Dictionary of Arts, Manufactures and Mines containing a clear exposition of their principles and practice · 第 248 / 421 题