SPINEL

Two of the more famous stones in the British crown jewels are the Black

Prince’s Ruby and the Timur Ruby, but neither of these stones is really

ruby. Like the great red gem in the crown that belonged to the Russian

Empress Catherine II, these two British stones are spinel. Although

spinel occurs in many colors, such as yellow, green, violet, brown, and

black, it is the red spinel that usually is seen in the gem trade. There

are several varieties of red spinel, such as _ruby spinel_, _balas

ruby_, _rubicelle_, and _almandine spinel_—all of which refer to the

color resemblance to ruby.

[Illustration: The hues and tints of spinel show subtle variations

that are matched only by those of tourmaline. Unlike tourmaline,

however, spinel may be bright ruby red. The cut stones curving

around two pieces of rough from Burma weigh (left to right) 30

carats (Ceylon), 34 carats (Burma), 36 carats (Burma), 30 carats

(Ceylon), and 22 carats (Ceylon). (Three-fourths actual size.)]

Spinel is an oxide of magnesium and aluminum, and it is not related to

ruby. However, because its hardness (8) is only slightly less than that

of ruby and its brilliance is about equal to that of ruby, spinel makes

an excellent substitute for that gem. Also, because it is more

plentiful, spinel costs much less. It is interesting that red spinel,

like ruby, gets its color from the presence of traces of chromium.

Synthetic blue spinel is widely used as a substitute for aquamarine, and

synthetic spinels of other colors are used as substitutes for many gems.

However, the synthetic stones are not ordinarily made in the subtle

shades so characteristic of natural spinel. Completely colorless spinel

apparently exists only as a synthetic material. Actually, because of its

hardness, durability, and many attractive colors, spinel makes a fine

gemstone in its own right.

Like ruby and several other gemstones, spinel is found chiefly in the

gem gravels of Ceylon, Burma, and Thailand. Appreciable amounts of

spinel occur in the Ceylon gem gravels as worn, rounded pebbles of many

colors. In the Burmese gravel deposits the spinel is often found as

well-formed octahedral crystals. Near Moguk, in Burma, spinel has been

found in its original position in the limestone rocks as well as in the

eroded stream deposits.

VARIETIES

Almandine spinel: Purplish red

Rubicelle: Orange-red

Balas ruby: Rose red

Ruby spinel: Deep red

Chlorospinel: Translucent grass green

Ceylonite or pleonaste: Opaque dark green, brown, or black

Picotite or chrome spinel: Translucent dark yellow-brown or

green-brown

QUARTZ

(INCLUDES ROCK CRYSTAL, AMETHYST, AND CITRINE)

Few gemstones can compete with quartz for variety of color. Having a

hardness of 7 and occurring in many beautiful varieties, only the

relative abundance of quartz prevents the species from attaining top

rank among gemstones.

The two kinds of quartz, crystalline and cryptocrystalline

(fine-grained) quartz, occur in all kinds of mineral deposits throughout

the world. Much of this material is suitable for cutting gems.

Colorless crystalline quartz, or _rock crystal_, makes attractive

faceted gems, and it is used as a suitable substitute for diamond and

zircon even though it lacks the fire and brilliance of those gemstones.

Some very large, flawless crystals of colorless crystalline quartz have

been found. The great Warner Crystal Ball, with a diameter of 12⅞ inches

and weighing 106¾ pounds, was cut from such a crystal. In addition to

the name rock crystal, colorless crystalline quartz appears in the

jewelry trade under such names as rhinestone (not to be confused with

the glass substitute), Herkimer diamond (from Herkimer County, N. Y.),

and Cape May diamond (from Cape May, N. J.).

The most popular variety of quartz is _amethyst_, a transparent form

whose color ranges from pale violet to deep purple. In many cut stones

of amethyst the color intensity changes sharply from section to section.

This is due to irregular color zoning common to amethyst crystals. The

actual cause of the purple color in amethyst is not very well

understood. There are fewer cut stones of amethyst in very large sizes

because of the rarity of large, flawless, well-colored crystals.

[Illustration: This 4500-carat pale smoky quartz egg from California

rests on a gold stand set with Montana sapphires. The unique gem was

cut and its stand was designed and made by Capt. John Sinkankas as a

difficult exercise in the lapidary art. The quartz egg is 4 inches

long and almost 3 inches in diameter.]

The name _citrine_ (from the French word for lemon) attempts to describe

the yellow color of another variety of quartz. Actually, the normal

coloring of citrine varies from yellow to red-orange and red-brown, but

the yellow sometimes rivals the yellow of topaz. In addition to the

normal color range, the colors of citrine may grade through a grayish

yellow variety known as _cairngorm_ and a grayish variety called _smoky

quartz_ to a black variety called _morion_. Other varieties that add

color dimensions to the group of quartz gemstones are _rose quartz_ and

_milky quartz_. Like amethyst, the reason for the color in rose quartz

has not been definitely established. Milky quartz owes its color to

myriads of tiny cavities containing water or liquid carbon dioxide.

[Illustration: A 783-carat step-cut citrine of deep, rich color

dwarfs a 278-carat brilliant-cut citrine (at left), a 90-carat smoky

quartz, and a 91-carat briolette of citrine. The smoky quartz, from

Switzerland, is so dark that it appears to be opaque. The other

three stones came from Brazil. The briolette and brilliant-cut

citrines were cut and donated to the Smithsonian Institution by

Albert R. Cutter. (Slightly less than half actual size.)]

The range of color in quartz is somewhat surprising, considering that

the mineral is a simple silicon dioxide. Some of the colors, as with

corundum and some other gemstones, are due to traces of impurities. In

quartz, these consist mainly of oxides of iron, manganese, and titanium.

However, all the reasons for quartz coloration in its many varieties are

not known.

[Illustration: Pastel rose quartz has a delicate beauty in any cut.

The 375-carat step cut (top), the 84-carat step cut, and the

46-carat marquise came from Brazil. (Two-thirds actual size.)]

[Illustration: Amethyst, a purplish quartz, is the birthstone for

February. Here it is represented by a 1362-carat stone from Brazil

(top), a 54-carat stone from Pennsylvania (left), and a 21-carat

stone from North Carolina. (Almost actual size.)]

In addition to possessing wide variation of color, quartz, like sapphire

and certain other gemstones, can exhibit asterism or chatoyancy. The

well-known _tiger’s-eye_ from West Griqualand, South Africa, owes its

eye effect to the fact that its material is a replacement of fibrous

asbestos by cryptocrystalline quartz. The color of tiger’s-eye arises

from the partial alteration of the asbestos to yellow-brown iron oxides

before it is replaced by quartz. Inclusions of rutile, tourmaline, or

actinolite needles may produce attractive patterns in quartz, but they

do not always cause chatoyancy. The material containing such inclusions

is called sagenitic quartz, or it may be descriptively named, such as

rutilated quartz, tourmalinated quartz, and so forth. Sagenitic quartz

is usually cut as cabochons rather than as faceted stones since the

inclusions are of greater interest than the quartz itself.

If the foreign inclusions consist of tiny flakes of hematite or mica,

the quartz assumes a spangled appearance and is called _aventurine_.

Crystals of quartz varieties that are opaque or that contain visible

inclusions normally are cut as cabochons to take advantage of the body

color or to make the inclusions more visible. Crystals of the

transparent varieties are fashioned in any of several cutting styles,

depending on whether it is desired to take maximum advantage of color or

of brilliance. Because of its availability in fairly large, flawless

pieces in various colors, quartz has been used extensively in carving.

The Chinese have excelled in carving large, ornate objects of rock

crystal.

Although quartz occurs in many varieties and its crystals are cut in

many styles, it is easily identified by its refractive index of 1.55,

specific gravity of 2.65, and hardness of 7.

CRYSTALLINE VARIETIES

Amethyst: Purple to violet

Cairngorm: Smoky yellow

Citrine: Yellow to red-orange and red-brown

Milky quartz: White

Morion: Black

Rock crystal: Colorless

Rose quartz: Rose to pink

Smoky quartz: Gray to black

CRYPTOCRYSTALLINE VARIETIES (CHALCEDONY)

Agate: Pronounced color banding

Aventurine: Inclusions of sparkling flakes

Bloodstone: Dark green dotted with red

Carnelian: Red to yellow-red

Cat’s-eye: Chatoyant

Chrysoprase: Green

Jasper: Opaque brown to red-brown, green, yellow, etc.

Onyx: Color banding in straight layers of contrasting color

Sard: Light to dark brown

Sardonyx: Sard or carnelian bands alternating with white bands

Tiger’s-eye: Bright brownish yellow, sometimes blue: chatoyant

CHRYSOBERYL

(INCLUDES ALEXANDRITE AND CAT’S-EYE)

With color ranging from shades of yellow and brown through blue-green to

olive, and with a hardness of 8½, chrysoberyl has most of the

characteristics necessary for a fine gem. Rare stones of high-quality

chrysoberyl demand fairly high prices, and they are sought eagerly by

the connoisseur of gemstones.

Chrysoberyl is beryllium aluminate, and thus is closely related to the

gemstone spinel, which is magnesium aluminate. When pure, chrysoberyl is

colorless and relatively uninteresting as a gemstone because of its lack

of color dispersion and its moderate refractive index of 1.75. However,

few pure samples are known, as chrysoberyl normally contains some iron

or chromium in place of aluminum and some iron in place of beryllium. As

a result of such impurities, the color of chrysoberyl my be yellowish,

greenish, or brownish.

Chrysoberyl and beryl are the only important gemstones containing the

element beryllium. The minerals beryllonite, euclase, hambergite, and

phenakite also contain this element, but they are rare and seldom are

seen as cut gems.

[Illustration: One of the finest chrysoberyl cat’s-eyes in existence

is the 58-carat Maharani from Ceylon. (Actual size.)]

The _alexandrite_ variety of chrysoberyl has two colors in delicate

balance, and it changes from a columbine red to an emerald green when

viewed under different light. When viewed in daylight, which is richer

in green, the color balance shifts toward green, and that hue is seen by

the observer. Under artificial light, normally richer in red, the color

balance shifts toward red, and the stone seems to have changed to that

color. This extremely rare stone, named after Czar Alexander II of

Russia, is found only occasionally, in Russia and Ceylon. The Russian

stones, found with emerald in mica schist, tend to be smaller than the

Ceylon stones and have a color change going from emerald green to

violet-red. The Ceylon stones, found as pebbles in gem gravels, have a

color change going from a less-emerald green to a browner red. The

66-carat, record-size alexandrite in the National Collection shows the

color change typical of Ceylon stones. A synthetic stone is commonly

marketed as synthetic alexandrite, but this substitute not only is

man-made but is actually synthetic corundum instead of synthetic

chrysoberyl.

[Illustration: In addition to its fine cat’s-eyes and its

color-changing alexandrite varieties, chrysoberyl occurs in handsome

stones that vary in depth of color. Shown here with an uncut twinned

crystal of gem quality from Brazil are a 46-carat stone from Brazil

(left) and a 121-carat stone from Ceylon. The uncut crystal is a

gift of Bernard T. Rocca, Sr. (Two-thirds actual size.)]

_Cat’s-eye_ chrysoberyl contains myriads of tiny fiberlike channels

arranged in parallel position. When the stone is cut as a cabochon, a

band of light is reflected from the curved top of the stone, producing

an effect that resembles the slit pupil of a cat’s eye.

VARIETIES

Alexandrite: Green in daylight, changing to red in artificial light

Cat’s-eye: Chatoyant

Gems in the Smithsonian Institution · 第 13 / 22 题