OPAL

Opal has been admired for its great beauty since ancient times, but this

gemstone lacked commercial appeal until the discovery of the Australian

black opal late in the 19th century.

Opal is somewhat brittle, is sensitive to heat, and, in some cases,

tends to deteriorate despite the best of care. Therefore, this stone

lacks many of the physical characteristics required for an ideal gem.

These deficiencies would eliminate other species from the list of

gemstones, but the great beauty of its flashing and shifting color

patterns has made opal increasingly popular. Even its name, coming from

the ancient Sanskrit “upala,” means precious stone.

With a hardness between 5½ and 6½, opal is the softest of the more

popular gems. It is sufficiently hard, however, to be used in jewelry,

where its setting usually helps to protect it from shock and abrasion.

[Illustration: Black opal, so called because the color flashes

appear against a dark background, is found in Australia. It is quite

rare, and large pieces such as the ones shown here have become

extremely valuable. (Almost actual size.)]

Opal is unlike most gemstones in that its flashing color is not due to

the color of the stone itself, or even to the color of its included

impurities. Rather, it is due to the way in which tiny opal particles

are grouped during its formation. Detailed photographs taken through an

electron microscope show clearly how precious opal is deposited as

spheres that are so small they are indistinguishable under powerful

optical microscopes. These spheres are packed together in very orderly

networks, row upon row and layer upon layer, with tiny open spaces, also

in rows, between them. Masses of common opal lack this orderly internal

arrangement of spheres. White light striking the precious opal is

reflected independently by each row of spheres, much like the

reflections from a series of slats in a venetian blind. Since these rows

of spheres are spaced at distances approximately the same as the

wavelength of light, a phenomenon known as _diffraction_ occurs. The

separate reflections interfere with each other in an organized manner,

cancelling out some of the light wavelengths and reinforcing others,

producing color. The brilliant color flashes are of different hues

depending on the sizes of the spheres of opal and, therefore, the

distances between rows. To provide the best display of this optical

effect, opal is almost always cut in cabochon form rather than as

faceted stones.

[Illustration: Fire opals have rich fire; some have background

colors that vary from bright yellow through orange and red; and some

are colorless. Stones such as the ones shown here, which weigh 7,

11, and 22 carats, have made Querétaro, Mexico, famous as their

source. (Actual size.)]

[Illustration: This rare 34-carat opal from Brazil resembles closely

the opals found in Australia. (Actual size.)]

Common opal, which shows milky opalescence, does not exhibit color

flashes, and it is not used as a gemstone. Each of the common

varieties—such as hyalite, cacholong, and hydrophane—has its own

slightly different set of characteristics, but only precious opal, with

its dazzling color display, is important for gem purposes. To take full

advantage of the small amounts of gem material available, or to bring

out its color better, _precious_ opal is often cut as thin pieces and

mounted as doublets on some other backing. Also, the seams in rock

sometimes are cut so that the thin layer is exposed on a thicker backing

of the adjoining rock. Precious opal, or gem opal, is classified as

_white opal_ when the color flashes are in a whitish or light

background, _black opal_ when the background material is gray,

blue-gray, or black, and _fire opal_ when the background is more

translucent and red, reddish orange, or reddish yellow.

Precious opal has been found in several areas of the world—in nodules,

in seams in rock, or as replacements of other minerals or even of wood

and shell. Hungarian deposits were well known in Roman times, but these

and other deposits became insignificant with the discovery of opal in

Australia in the late 19th century. Opal deposits were discovered in

1889 at White Cliffs in New South Wales, and other important discoveries

in Australia followed, including deposits at Lightning Ridge in New

South Wales that produce very dark stones and the rich fields of white

opal at Coober Pedy in South Australia. Mexico has remained for a long

time the principal source of richly colored fire opals, with the most

important deposits located in the state of Querétaro, where mines have

been worked intermittently since 1835. This has made the town of

Querétaro today the center for the trade and cutting of Mexican opal.

VARIETIES

White opal: Color flashes in light-colored background material

Black opal: Color flashes in dark gray or bluish background material

Fire opal: Orange or reddish background material

Gems in the Smithsonian Institution · 第 12 / 22 题