CHAPTER II.

THE ELEMENTARY SUBSTANCES.

On the following page is a list of the sixty-six elementary substances

now generally recognized as such. Their respective symbols and their

atomic weights, both in exact and approximate numbers, are also given.

These substances, then, nearly seventy in number, are those from which

are made up all material things now known to man. While it is not

necessary for any one to retain such a list in memory, every person who

desires any considerable knowledge of chemistry should be acquainted

with each name and the symbol attached to it, and should know something

of the natural sources and the properties of the substances designated.

Six Suggestions Conveyed by this Table.

A careful and intelligent reading of the list affords several important

suggestions. The following are some of them:—

_First. The elements are not very numerous._ They are in fact very few,

as compared with the countless number of substances they may form by

their proper combinations.

_Second. They are however sufficiently numerous to produce the many

substances recognized in nature._ For, consider how human language may

have many words and yet all these may be spelled out by combinations

of few letters. Some English dictionaries register over a hundred

thousand words, yet these are all made by the combinations of less than

thirty letters. Now it is easy to comprehend how the few letters of an

alphabet may be even still further combined in various ways so as to

produce additional words almost without limit: in a similar manner it

may be easily imagined that the sixty-five elementary substances have

ample capabilities for giving rise not only to the compounds now known,

but to yet more and more, almost without limit. It is true that the

chemist discovers that some of the chemical elements appear to have a

limited power of union, but in others he finds an apparently unbounded

capacity to form new arrangements and combinations.

-------------------------------------------------------------------

The Chemist’s Elementary Substances.

===========+==================+================+===============

Name | | Exact | Approximate

of Element.| Atomic Symbol. | Atomic | Atomic Weight.

| | Weight. |

-----------+------------------+----------------+----------------

Aluminum | Al | 27.0090 | 27.

Antimony | Sb (Stibium) | 119.9550 | 120.

Arsenic | As | 74.9180 | 74.9

Barium | Ba | 136.7630 | 136.8

Bismuth | Bi | 207.5230 | 207.5

Boron | B | 10.9410 | 10.9

Bromine | Br | 79.7680 | 79.8

Cadmium | Cd | 111.8350 | 111.8

Caesium | Cs | 132.5830 | 132.6

Calcium | Ca | 39.9900 | 40.

Carbon | C | 11.9736 | 12.

Cerium | Ce | 140.4240 | 140.4

Chlorine | Cl | 35.3700 | 35.4

Chromium | Cr | 52.0090 | 52.

Cobalt | Co | 58.8870 | 58.9

Copper | Cu (Cuprum) | 63.1730 | 63.2

Didymium | D | 144.5730 | 144.6

Erbium | E | 165.8910 | 165.9

Fluorine | Fl | 18.9840 | 19.

Gallium | Ga | 68.8540 | 68.9

Glucinum | G or Be | |

| (Beryllium) | 9.0850 | 9.1

Gold | Au (Aurum) | 196.1550 | 196.2

Hydrogen | H | 1.0000 | 1.

Indium | In | 113.3980 | 113.4

Iodine | I | 126.5570 | 126.6

Iridium | Ir | 192.6510 | 192.7

Iron | Fe (Ferrum) | 55.9130 | 55.9

Lanthanum | La | 135.5260 | 138.5

Lead | Pb (Plumbum) | 206.4710 | 206.5

Lithium | Li | 7.0073 | 7.

Magnesium | Mg | 23.9590 | 24.

Manganese | Mn | 53.9060 | 53.9

Mercury | Hg (Hydrargyrum)| 199.7120 | 199.7

Molybdenum | Mo | 95.5270 | 95.5

Nickel | Ni | 57.9280 | 57.9

Niobium | Nb | 93.8120 | 93.8

Nitrogen | N | 14.0210 | 14.

Osmium | Os | 198.4940 | 198.5

Oxygen | O | 15.9633 | 16.

Palladium | Pd | 105.7370 | 105.7

Phosphorus | P | 30.9580 | 31.

Platinum | Pt | 194.4150 | 194.4

Potassium | K (Kalium) | 39.0190 | 39.

Rhodium | Rh | 104.0550 | 104.1

Rubidium | Rb | 85.2510 | 85.3

Ruthenium | Ru | 104.2170 | 104.2

Scandium | Sc | 43.9800 | 44.

Selenium | Se | 78.7970 | 78.8

Silicon | Si | 28.1950 | 28.2

Silver | Ag (Argentum) | 107.6750 | 107.7

Sodium | Na (Natrium) | 22.9980 | 23.

Strontium | Sr | 87.3740 | 87.4

Sulphur | S | 31.9840 | 32.

Tantalum | Ta | 182.1440 | 182.1

Tellurium | Te | 127.9600 | 128.

Thallium | Tl | 203.7150 | 203.7

Thorium | Th | 233.4140 | 233.4

Tin | Sn (Stannum) | 117.6980 | 117.7

Titanium | Ti | 47.9997 | 48.

Tungsten | W (Wolframium) | 183.6100 | 183.6

Uranium | U | 238.4820 | 238.5

Vanadium | Va | 51.2560 | 51.3

Ytterbium | Yb | 172.7610 | 172.8

Yttrium | Y | 89.8160 | 89.8

Zinc | Zn | 64.9045 | 64.9

Zirconium | Zr | 89.3670 | 89.4

-----------+------------------+----------------+-------------------

_Third. The elements are mostly uncommon._ Only about one-sixth of

them possess names that are familiar to ordinary readers. Thus carbon,

copper, gold, iron, lead, mercury, nickel, silver, sulphur, tin, zinc,

are almost the only ones in the list that can be said to suggest

familiar things. Indeed some members of this list exist in the earth

in extremely small quantities; but man by his ingenuity and industry

has gathered up even these and brought them near to the hand of every

civilized being. Thus gold exists in the earth—so far as man has access

to the earth—in only very minute amounts; yet gold has a multitude

of common uses beside its employment in coinage. Various forms of

decorative art, like gilded lettering on books, afford familiar

examples. So also mercury, which in the ordinary thermometer is very

familiar to every one, exists in the earth in but minute amounts.

When the chemist examines still more narrowly the composition of the

terrestrial globe, he discovers an inequality yet more extraordinary

than that hinted at. Thus it appears that probably one-half of our

entire planet consists of a single substance (that is, oxygen) and

that one-quarter of it consists of another single substance (that

is, silicon). Since an amount equal to three-quarters of the earth’s

matter, by weight, is made up of but two elements, the remaining ones

must necessarily exist in much smaller proportions.

The following table, given by Roscoe and Schorlemmer, shows the average

composition of the earth’s crust—so far as it is accessible to human

investigation by means at present known:

Percentage Composition of the Earth’s Solid Crust (by Weight).

Oxygen, 44.0 to 48.7 per cent.

Silicon, 22.8 36.2 ”

Aluminum, 9.9 6.1 ”

Iron, 9.9 2.4 ”

Calcium, 6.6 0.9 ”

Magnesium, 2.7 0.1 ”

Sodium, 2.4 2.5 ”

Potassium, 1.7 3.1 ”

————— —————

100.0 100.0

According to this table, the sum total of the amounts of _all the

elements not mentioned_ may be estimated as less than one-tenth of

one per cent. of the whole. This statement is rendered all the more

striking when it is considered that in this minute fractional part must

be included all coal and all the useful metals, except iron.

Another authority[1] declares that it is probable that an amount equal

to ninety-nine one-hundredths of the entire weight of the solid, liquid

and gaseous matter of our globe, is made up of only thirteen elementary

substances. The elements referred to and their relative proportions are

approximately represented in the diagram following:

[1] Professor J. P. Cooke.

Diagram of the Composition of our Globe (by Weight.)

+---------------------+---------------------+------------+

| | SULPHUR, HYDROGEN, | |

| | CHLORINE, NITROGEN, | 53 OTHERS |

| +---------------------+------------+

| | POTASSIUM, SODIUM, |

| | IRON, CARBON, |

| SILICON, ¼ +----------------------------------+

| | ALUMINUM, } |

| | MAGNESIUM, } ⅙ |

| | CALCIUM, } |

+---------------------+----------------------------------+

| |

| |

| |

| OXYGEN, ½ |

| |

| |

| |

+--------------------------------------------------------+

_Fourth. Most of the elements are metals._ This may not appear to the

ordinary reader until he is informed that terminations in _um_, as in

case of aluminum, barium, cadmium, calcium and others are intended to

suggest that the substances so designated are metals. Most of the other

elements having names not terminating in _um_ are called non-metals.

_Fifth. Each chemical element has an atomic symbol_, an abridgement, in

some form, of its name.

_Sixth. Each chemical element has an atomic weight._ As the atomic

weight of hydrogen is 1, without any fraction, it is easily understood

that the weight of one atom of hydrogen is taken as the unit of the

system. An inspection of the numbers given shows that in many cases the

atoms weigh amounts that are very nearly exact multiples of the weight

of an atom of hydrogen.

READING REFERENCES.

Atomic Weights, Calculations of

=Becker=, George F.—Atomic Weight Determinations: a digest of

the investigations published since 1814. (Published as Part IV

of the _Constants of Nature_, in Smithsonian Miscellaneous

Collections, No. 358.) 1880.

=Clarke=, Frank W.—A Recalculation of the Atomic Weights.

(Published as Part V of the _Constants of Nature_,

in Smithsonian Miscellaneous Collections, No. 441.) 1882.

———— Am. Chem. Jour. iii, 263. (1881.)

Atomic Weights, Periodicity of

=Meyer=, Lothar.—Chem. News, xli, 203.

Atomic Weights, Mendelejeff’s Law of

=Am.= Chem. Jour.—iii, 455.

=Cooke=, J. P.—Chem. Philosophy, p. 265.

=Wurtz=, Ad.—Atomic Theory, p. 154.

Atomic Weights, Arithmetical Relations of

=Hodges=, M. D. C.—Silliman’s Journal, 3d Ser. x, 277.

=Newlands=, J. A. R.—Chem. News, xlix, 198.

Atomic Weight of Oxygen.

=Odling=, W.—Jour. of Chem. Soc. of London, xi, 107.

Atomic Weight of Thallium.

=Cookes=, Wm.—Chem. News, xxix, 14, 29, 39, 55, 65, 75, 85,

97, 105, 115, 126, 137, 147, 157.

Atomic Weights, Prout’s Hypothesis of

=Cooke=, J. P.—Chemical Philosophy, 270.

=Clarke=, F. W.—Am. Chem. Journal, iii, 272. (1881.)

=Gerber=.—Silliman’s Journal, 3d Ser. xxvi, 236.

Atoms, Absolute Weight of

=Annaheim=, J.—Jour. of Chem. Soc. of London, xxxi, 31.

Elements, Defunct

=Bolton=, H. C.—American Chemist, i, 1.

Elements, Suggestions that Elements are Compound.

=Lockyer=, J. N.—Nature, Jan’y 2 and 9, also Nov. 6, 1879.

=Hastings=, C. S.—Criticism of above. Am. Chem. Jour., i, 15.

Chemistry · 第 2 / 26 章