ANTIMONIAL COMPOUNDS.

By other processes the early experimenters obtained various other

products. By simply heating crude antimony in a crucible they would

sometimes get a vitreous substance in consequence of some of the silica

of the crucible combining with the antimony. That was their glass of

antimony, which was generally an oxide with some sulphide. In other

cases the so-called liver of antimony resulted, a compound containing

a larger proportion of the sulphide. This they also called crocus

metallorum or saffron of the metals, and one or other of these products

was originally the basis of antimonial wine.

It was digested with Rhine wine, and the tartar of the wine formed a

tartrate of antimony, but, as may be supposed, the composition of the

wine was very variable. Emetic tartar was subsequently substituted for

the liver.

The crystalline protoxide of antimony obtained by inflaming,

volatilising, and condensing the regulus was known as argentine flowers

of antimony. The regulus heated with nitric acid yielded a compound of

metal with antimonious acid, and was called mineral bezoar; a compound,

really a suboxide, got by fusing sulphide of antimony and nitre was

called diaphoretic antimony; the chloride, first made by distilling

crude antimony (the native sulphide) with corrosive sublimate, yielded

the thick soft butter of antimony; the addition of water to this

chemical caused the precipitation of a white oxychloride which was

long known as Algaroth’s powder, or mercury of life. It contained no

mercury, but was the most popular emetic before the introduction of

the tartrate. Victor Algarotti, who introduced it, was a physician, of

Verona, who died in 1603. It was alleged that he was poisoned by his

local rivals in consequence of the success of his remedy. He was also

the inventor of a quintessence of gold.

The regulus of antimony in alloy with some tin was used to make the

antimony cups from which antimonial wine originated. It was also made

into the pilulæ perpetuæ, or everlasting pills, which, passing through

the body almost unchanged, were kept as a family remedy and taken

again and again. It is probable that the surface of these pills became

slightly oxidised, and consequently acquired a medicinal effect.

Chronicles of Pharmacy, Vol. 1 (of 2) · 第 260 / 293 题