CHAPTER XVI

ELECTRICITY AND RADIOACTIVITIES

Among the most marvelous scientific developments of the nineteenth

century those in the electrical field claim universal attention. It was

only as recently as 1844 that Morse introduced electric telegraphy. The

telephone was introduced by Alexander Graham Bell in 1876 and Edison

built one of his early dynamos in 1878 and in 1879 made his first high

resistance incandescent lamp for parallel operation. The first Edison

power and lighting station was opened at 257 Pearl Street, New York

City, in 1882.

Although electrical phenomena were understood in a general way

thousands of years ago, they were not studied and applied to practical

purposes until the sixteenth century when William Gilbert carried out

his classical experiments in the reign of Queen Elizabeth. The Leyden

jar was discovered in the early half of the eighteenth century. From

experiments carried out with these jars a great number of important

inventions were derived and our knowledge of electricity was for many

years dependent upon researches of this kind. Benjamin Franklin in

experimenting with the Leyden jar found that its electrical discharges

were similar to those of lightning and he subsequently discovered that

the inner part of the jar, when charged with a frictional current, was

positively electrical while the outer portion was negative.

The voltaic pile was invented in 1796 as a result of Galvani's

experiments in physiological electricity and Sir Humphry Davy exhibited

the first practical electrical lamp before the Royal Society in 1809.

The dynamo was, in substance, invented by Faraday, and described by

him before the Royal Society in 1831. This was, perhaps, the greatest

of all electrical triumphs because it gave engineers a practical means

of generating and using electrical currents of any desired dimensions.

Bunsen in 1840 devised a means for making carbon rods for arc lamps,

and Edison made practical carbon incandescent lamp filaments in 1879.

Faraday's invention promoted all of these lighting discoveries.

The engine-driven electric dynamo was made a practical machine in 1870

and thenceforward became the source of power of a great multitude of

secondary machines, such as electric street cars, marine engines, power

plants, and forging hammers.

A new and profitable field was opened for the use of electricity by

the invention of the electric furnace. Sir Humphry Davy produced

his electric arc in 1808 and was greatly impressed with its fusing

properties. He melted many metals with the arc and found that it fused

platinum just as easily as an ordinary tallow candle melts beeswax.

The electric furnace, which is now extensively used in chemical and

metallurgical works, is simply a large electric arc provided with means

for containing the heat. Furnaces lined with carbon are now heated to

over 4,000 degrees centigrade.

When the electrical manufacture of aluminum on a large scale was

started at Niagara, Dr. Edward Acheson, who was impressed by the

industrial needs of cheap abrasives, accidentally discovered that by

heating a piece of porcelain to a high temperature in an electric

furnace and bringing it in contact with pure carbon, the carbon was

rendered very hard. In 1891 he carried on experiments with high

currents and a mixture of ground coke and sand. He found a method of

fusing these so that the oxygen of the sand passed off with carbon

in the form of carbonic acid gas, and the reduced metallic silicon

combined with an equal atomic weight of carbon and produced a new body

which he named carborundum. The success met with in making carborundum

led to the devising of a method of manufacturing artificial graphite in

the electric furnace. A soft, non-coalescing graphite was made in 1906.

This is extensively used in lubricating heavy machinery.

Dr. Acheson produced the first chemically pure artificial carbon in his

electric furnace in 1911. By using pressure during consolidation this

carbon may eventually be converted into diamonds.

Another valuable product of the electric furnace, acetylene gas, was

discovered in Dublin by Edmund Davy in 1836. Subsequently numerous

chemists discovered means for making carbides. T. Sterry Hunt, an

American chemist, observed in 1886 that oxides of the alkaline metals

and of calcium, magnesium, aluminum, silicon, and boron could be

reduced in the electric furnace in the presence of carbon and could be

alloyed with other metals. He also found that silicon and acetylene

could be made that way.

T. L. Wilson, a Canadian engineer, in attempting to make aluminum

bronze in an electric furnace, devised an experiment for reducing lime

with carbon. He found that this produced calcium carbide and secured a

patent for the invention in 1892. Variations of this process are now

used for manufacturing nitrogen and nitrates from atmospheric nitrogen.

Wireless developments have resulted from the work of many separate

investigators. K. A. Steenheil in 1838 used the earth return in live

telegraphy and suggested the possibility of wireless telegraphy.

Joseph Henry produced the first high-frequency oscillations in America

in 1840. Lord Kelvin in 1853 enunciated the mathematical principles

governing uncoupled electrical oscillatory circuits. Joseph Heyworth

patented a wireless telegraphic process in 1862. Clark Maxwell in 1867

predicted the existence of electromagnetic radiations and these were

demonstrated by Hertz in 1887. Hughes discovered the phenomena of the

coherer and Branby used Hughes's coherer for wireless wave detection

in 1892. A. E. Dolbear secured United States patents for a system of

wireless telegraphy using aerials in 1886. Sir Oliver Lodge described

his wireless system before the Royal Society in 1894 and in the same

year Popoff issued descriptions of his wireless system.

Wireless telegraphy became commercially practicable in 1897 when G.

Marconi secured the promotion of the Wireless Telegraph and Signal

Company in England. Marconi succeeded in turning to commercial account

a long series of brilliant discoveries in electricity, and this success

has led to numerous kindred discoveries. De Forest's three-electrode

thermionic detector, known as an Audion, invented in 1907 and improved

in 1911 by Lieben and Reiss, in 1913 by Meisser and in 1914 by

Langmuir, opened up great possibilities for sound transmission by

wireless telephony.

The electric deposition and refining of metals have been referred to

in previous chapters. Many industries are based upon these. Niepce

produced commercially successful photographs in 1838. Earlier, in

1824, he had etched plates for printing and in that year published his

photo-engraving of Cardinal d'Amboise. Fox Talbot patented a mixture

of gelatine and bichromate of potash to take the place of the bitumen

used by Niepce as a plate coating. Gillot found in 1872 that Fox

Talbot's method of making intaglio plates could also be used for making

relief blocks. In 1885-1886, F. E. Ives sealed two single-line screws

together and made a new fine cross-line screen, which resulted in the

development of the half-tone process. Ives at this time also developed

the three-color photo-engraving process.

Photography and photo-engraving are so widely used and are so

intimately connected with our civilization that few people now realize

that the great industries based upon them are the results of a few

scientific discoveries of a couple of American and European scientists

made only a generation or two ago.

[Illustration: GIFTS FOR TUTANKHAMEN BROUGHT BY HUY, VICEROY OF

ETHIOPIA. THE MAN IN THE GAY COSTUME, AT THE RIGHT, MAY BE A PHŒNICIAN.

(EGYPTIAN PAINTING)]

[Illustration: TUTANKHAMEN'S TOMB--BRINGING UP THE HATHOR COUCH. THE

COW WAS SACRED TO ISIS OR HATHOR OF WHOM THE HORNS WITH THE MOON DISK

WERE EMBLEMS]

[Illustration: QUEEN NEFERTITI, MOTHER-IN-LAW OF TUTANKHAMEN

This wonderful work of an unknown Egyptian sculptor represents the

wife of Ahknaton, the "heretic" king of Egypt (originally Amenhotep or

Amenophis IV). The original is now in the Berlin Museum.]

Chemists had long recognized the fact that certain chemicals like

preparations of zinc, fluorine, and phosphorus were phosphorescent. It

was found early in the eighties that Welsbach gas mantles, when placed

on a photographic plate and exposed in a dark room for two weeks,

made a fine picture. Invisible rays in the mantle imprint its image.

Röntgen, in 1895, discovered what are now known as the X-rays. This

discovery was the result of experiments begun in 1859 by Plucker to

ascertain the cause of fluorescence in light glass, and Sir William

Crookes, between 1879 and 1885, carried out beautiful experiments on

fluorescence. These were the immediate pioneers of the discovery of the

cathode rays and the other great radio discoveries of recent years.

Crookes, remembering Faraday's suggestions concerning a fourth state of

matter, expressed the opinion, in 1885, that the matter constituting

cathode rays is neither solid, gaseous, or liquid, but in a fourth

state which transcends the gaseous condition. Perren found in 1895 that

the rays carried electrically negative charges and Sir J. J. Thomson

noticed that their velocities are appreciably less than the speed of

light. Owing, however, to their great momentum, hardly anything can

long endure their impacts. They fuse platinum and make diamonds buckle

up into coke.

Electrons, which constitute the cathode rays, were originally studied

in Crookes vacuum tubes, though they are now found to pervade the

universe.

Larmor in 1897 proposed an electronic theory of magnetism.

Henri Becquerel was the first to discover radioactivity. He made

radiographs from uranium salts in 1896. M. and Madame Curie undertook

the investigation of uranium and found that among the minerals

occurring in pitchblende, or uranium ore, bismuth and barium showed

radioactive properties, whereas when these metals are found in their

ordinary ores they are not radioactive. This discovery led to the

finding of two new metals, polonium and radium. Radium is now obtained

by fractional distillation of solutions obtained from American and

Australian pitchblende.

Helium, one of the lightest substances known, was discovered in 1895

by Sir William Ramsay, and liquefied, at a temperature 3 degrees above

absolute zero, or -270 degrees centigrade, by Onnes in 1908. Helium

appears to be one of the ultimate products of the disintegration of all

radioactive elements.

Some of the most interesting discoveries about radioactivity are very

recent. Radium prepared from uranium in 1915 was found in 1919 to have

increased proportionately to the square of the time interval. The

amount of radium in some preparations was found to have increased ten

times in four years. The old idea of the constant fluxation of matter

was thus shown to have been based upon a scientific truth.

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