single impulse, as a blow or thrust, or of one frequently and regularly
repeated, such as a jarring or vibratory movement, depends wholly on
these molecular forces; and it is on such propagation that sound and
very probably light depend. To conceive the manner in which a motion
may be conveyed from one part of a substance to another, whether solid
or fluid, we may attend to what takes place when a wave is made to
run along a stretched string, or the surface of still water. Every
part of the string, or water, is in succession moved from its place,
and agitated with a motion similar to that of the original impulse,
leaving its place and returning to it, and when one part ceases to move
the next receives as it were the impression, and forwards it onward.
This may seem a slow and circuitous process in description; but when
sound, for example, is conveyed through the air, we are to consider,
1st, that the air, the substance actually in motion, is extremely light
and acted upon by a very powerful elasticity, so that the force which
propagates the motion, or by which the particles adjacent act on, and
urge forward, each other, is very great, compared with the quantity of
materials set in motion by it: and the same is true, even in a greater
degree, in liquids and solids; for in these the elastic forces are even
greater, in proportion to the weight, than in air.
(270.) A general notion of the mode in which sounds are conveyed
through the air was not altogether deficient among the ancients; but
it is to Newton that we owe the first attempt to analyze the process,
and show correctly what takes place in the communication of motion
from particle to particle. Reasoning on the properties of the air as
an elastic body, he showed the effect of an impulse on any portion of
it to consist in a condensation of the air immediately adjacent in the
direction of the impulse, which then, re-acting by its spring, drives
back the portion which had advanced to its original place, and at the
same time urges forward the portion before it, in the direction of the
impulse, so that every particle alternately advances and retreats.
But, in pursuing this idea into its details, Newton fell into some
errors which were pointed out by Cramer, though their origin was not
traced, nor the reasoning corrected, till the subject was resumed by
Lagrange and Euler; nor is this any impeachment of the penetration of
our immortal countryman. The mathematical theory of the propagation
of sound, and of vibratory and undulatory motions in general, is
one of the utmost intricacy; and, in spite of every exertion on the
part of the most expert geometers, continues to this day to give
continual occasion for fresh researches; while phenomena are constantly
presenting themselves, which show how far we are from being able to
deduce all the particulars, even of cases comparatively simple, by any
direct reasoning from first principles.
(271.) Whenever an impulse of any kind is conveyed by the air, to our
ears, it produces the impression of sound; but when such an impulse
is regularly and uniformly repeated in extremely rapid succession, it
gives us that of a musical note, the pitch of the note depending on
the rapidity of the succession (see art. 153.). The sense of harmony,
too, depends on the periodical recurrence of coincident impulses on the
ear, and affords, perhaps, the only instance of a sensation for whose
pleasing impression a distinct and intelligible reason can be assigned.
(272.) Acoustics, then, or the science of sound, is a very considerable
branch of physics, and one which has been cultivated from the earliest
ages. Even Pythagoras and Aristotle were not ignorant of the general
mode of its transmission through the air, and of the nature of harmony;
but as a branch of science, independent of its delightful application
in the art of music, it could be hardly said to exist, till its nature
and laws became a matter of experimental enquiry to Bacon and Galileo,
Mersenne and Wallis; and of mathematical investigation to Newton, and
his illustrious successors, Lagrange and Euler. From that time its
progress, as a branch both of mathematical and experimental science,
has been constant and accelerated. A curious and beautiful method of
observation, due to Chladni, consists in the happy device of strewing
sand over the surfaces of bodies in a state of sonorous vibration,
and marking the figures it assumes. This has made their motions
susceptible of ocular examination, and has been lately much improved
on, and varied in its application, by M. Savart, to whom we also owe a
succession of instructive researches on every point connected with the
subject of sound, which may rank among the finest specimens of modern
experimental enquiry. But the subject is far from being exhausted; and,
indeed, there are few branches of physics which promise at once so much
amusing interest, and such important consequences, in its bearings on
other subjects, and especially, through the medium of strong analogies,
on that of light.
_Light and Vision._
(273.) The nature of light has always been involved in considerable
doubt and mystery. The ancients could scarcely be said to have any
opinion on the subject, unless, indeed, it could be considered such
to affirm that distant bodies could not be put into communication
without an intermedium; and that, therefore, there must be _something_
between the eye and the thing seen. What that something is, however,
they could only form crude and vague conjectures. One supposed that
the eyes themselves emit rays or emanations of some unknown kind, by
which distant objects are as it were felt; a singularly unfortunate
idea, since it gives no reason why objects should not be equally
well seen in the dark--no account, in short, of the part performed
by _light_ in vision. Others imagined that all visible objects are
constantly throwing out from them, in all directions, some sort of
resemblances or spectral forms of themselves, which, when received by
the eyes, produce an impression of the objects. Vague and clumsy as
this hypothesis obviously is, it assigns to the object a power, and to
light a diffusive propagation in all directions, which are, the one and
the other, independent of our eyes, and therefore goes to separate the
phenomena of _light_ from those of _vision_.
(274.) The hypothesis of Newton is a refinement and improvement on
this idea. Instead of spectra or resemblances, he supposes luminous
objects actually to dart out from them in all directions, particles,
of inconceivable minuteness (as indeed they must be, having such
an enormous velocity (see 17.), not to dash in pieces every thing
they strike upon). These particles he supposes to be acted upon by
attractive and repulsive forces, residing in all material bodies, the
latter extending to some very small distance beyond their surfaces; and
by the action of these forces to be turned aside from their natural
straight-lined course, without ever coming in actual contact with the
particles themselves of the bodies on which they fall, but either being
turned back and _reflected_ by the repulsive forces before they reach
them, or penetrating between their intervals, as a bird may be supposed
to fly through the branches of a forest, and undergoing all their
actions, to take at quitting them a direction finally determined by
the position of the surface at which they emerge with respect to their
course.
(275.) This hypothesis, which was discussed and reasoned upon by Newton
in a manner worthy of himself, affords, by the application of the
same dynamical laws which he had applied with so much success to the
explanation of the planetary motions, not merely a plausible, but a
perfectly reasonable and fair explanation of all the _usual_ phenomena
of light known in his time. His own beautiful discoveries, too, of
the different refrangibilities of the differently coloured rays,
were perfectly well represented in this theory, by simply admitting
a difference of velocity in the particles, which produce in the eye
the sensations of different colours. And had the properties of light
remained confined to these, there would have been no occasion to have
resorted to any other mode of conceiving it.
(276.) A very different hypothesis had, however, been suggested about
the same period by Huyghens, who supposed light to be produced in the
same manner with sound, by the communication of a vibratory motion
from the luminous body to a highly elastic fluid, which he imagined
as filling all space, and as being less condensed within the limits
of space occupied by matter, and that to a greater or less extent,
according to the nature of the occupying substance. Thus, in place of
any thing actually thrown off, he substituted waves, or vibrations,
propagated in all directions from luminous bodies, through this medium,
or ether, as he called it. Huyghens, being himself a consummate
mathematician, was enabled to trace many of the consequences of this
hypothesis, and to show that the ordinary laws of reflection and
refraction were represented or accounted for by it, as well as by
Newton’s. But the hypothesis of Huyghens has not been fully successful
in accounting for what may be considered the chief of all optical
facts, the production of colours in the ordinary refraction of
light by a prism, of which the theory of Newton gives a complete and
elegant explanation; and the discovery of which by him marks one of
the greatest epochs in the annals of experimental science. This, which
has been often urged in objection to it, remains still, if not quite
unanswered, at least only imperfectly removed.
(277.) Other phenomena, however, were not wanting to afford a further
trial of the _explanatory powers_ of either hypothesis. The diffraction
or inflection of light, discovered by Grimaldi, a Jesuit of Bologna,
seemed to indicate that the rays of light were turned aside from their
straight course by merely passing near bodies of every description.
These phenomena, which are very curious and beautiful, were minutely
examined by Newton, and referred by him to the action of repulsive
forces extending to a sensible distance from the surfaces of bodies;
and his explanation, so far as the facts known to him are concerned,
appears as satisfactory as could reasonably be then expected; and much
more so than any thing which could at that time be produced on the side
of the hypothesis of Huyghens, which, in fact, seemed incapable of
giving any account whatever of them.
(278.) Another class of delicate and splendid optical phenomena, which
had begun to attract attention somewhat previous to Newton’s time,
seemed to leave both hypotheses equally at a loss. These were the
colours exhibited by very thin films, either of a liquid (such as a
soap-bubble), or of air, as when two glasses are laid together with
only air between them. These colours were examined by Newton with a
minuteness and care altogether unexampled in experimental philosophy
at that time, and with which few researches undertaken since will bear
to stand in competition. Their result was a theory of a very singular
nature, which he grounded on an hypothesis of what he termed _fits of
easy transmission and reflection_; and which supposed each ray of light
to pass in its progress periodically through a succession of states
such as would alternately dispose it to penetrate or be reflected back
from the surface of a body on which it might fall. The simplest way
in which the reader may conceive this hypothesis, is to regard every
particle of light as a sort of little magnet revolving rapidly about
its own centre while it advances in its course, and thus alternately
presenting its attractive and repulsive pole, so that when it arrives
at the surface of a body with its repulsive pole foremost, it is
repelled and reflected; and when the contrary, attracted, so as to
enter the surface. Newton, however, very cautiously avoided announcing
his theory in this or any similar form, confining himself entirely to
general language. In consequence, it has been confidently asserted
by all his followers, that the doctrine of fits of easy reflection
and transmission, as laid down by him, is substantially nothing more
than a statement of facts. Were it so, it is clear that any other
theory which should offer a just account of the same phenomena must
ultimately involve and coincide with that of Newton. But this, as we
shall presently see, is not the case; and this instance ought to serve
to make us extremely cautious how we employ, in stating physical laws
derived from experiment, language which involves any thing in the
slightest degree theoretical, if we would present the laws themselves
in a form which no future research shall modify or subvert.
(279.) A third class of optical phenomena, which were likewise
discovered while Newton was yet engaged in his optical researches, was
that exhibited by doubly refracting crystals. In what the phenomenon of
double refraction consists, we have already had occasion to explain.
The fact itself was first noticed by Erasmus Bartolin in the crystal
called Iceland spar; and was studied with attention by Huyghens, who
ascertained its laws, and referred it with remarkable ingenuity and
success to his theory of light, by the additional hypothesis of such
a constitution of his ethereal medium within the crystal as should
enable it to convey an impulse faster in one direction than another:
as if, for example’s sake, we should suppose a sound conveyed through
the air with different degrees of rapidity in a vertical and horizontal
direction.
(280.) Some remarkable facts accompanying the double refraction
produced by Iceland spar, which Bartolin, Huyghens, and Newton, had
observed, led the latter to conceive the singular idea that a ray of
light after its emergence from such a crystal acquires _sides_, that
is to say, distinct relations to surrounding space, which it carries
with it through its whole subsequent course, and which give rise to all
those curious and complicated phenomena which are now known under the
name of the _polarization of light_. These results, however, appeared
so extraordinary, and offered so little handle for further enquiry,
that their examination dropped, as if by common consent; Newton himself
resting content with urging strongly the apparent incompatibility of
these properties with the Huyghenian doctrine, but without making any
attempt to explain them by his own.
(281.) From the period of Newton’s optical discoveries to the
commencement of the present century, no great accession to our
knowledge of the nature of light was made, if we except one, which,
from its invaluable practical application, must ever hold a prominent
place in the annals both of art and science: we mean, the discovery
of the principle of the achromatic telescope, which originated in a
discussion between the celebrated geometer Euler, Klingenstierna, an
eminent Swedish philosopher, and our own countryman, the admirable
optician Dollond, on the occasion of certain abstract theoretical
investigations of the former, which led him to speculate on its
_possibility_, and which ultimately terminated in its complete and
happy _execution_ by the latter; a memorable case in science, though
not a singular one, where the speculative geometer in his chamber,
apart from the world, and existing among abstractions, has originated
views of the noblest practical application.[49]
(282.) The explanation which our knowledge of optical laws affords of
the mechanism of the eye, and the process by which vision is performed,
is as complete and satisfactory as that of hearing by the propagation
of motion through the air. The camera obscura, invented by Baptista
Porta in 1560, gave the first idea how the actual images of external
objects might be conveyed into the eye, but it was not till after a
considerable interval that Kepler, the immortal discoverer of those
great laws which regulate the periods and motions of the planets,
pointed out distinctly the offices performed by the several parts
of the eye in the act of vision. From this to the invention of the
telescope and microscope there would seem but a small step, but it is
to accident rather than design that it is due; and its re-invention
by Galileo, on a mere description of its effects, may serve, among
a thousand similar instances, to show that inestimable practical
applications lie open to us, if we can only once bring ourselves
to conceive their possibility, a lesson which the invention of the
achromatic telescope itself, as we have above related it, not less
strongly exemplifies.
(283.) The little instrument with which Galileo’s splendid discoveries
were made was hardly superior in power to an ordinary finder of the
present day; but it was rapidly improved on, and in the hands of
Huyghens attained to gigantic dimensions and very great power. It was
to obviate the necessity of the enormous length required for these
telescopes, and yet secure the same power, that Gregory and Newton
devised the reflecting telescope, which has since become a much
more powerful instrument than its original inventors probably ever
contemplated.
(284.) The telescope, as it exists at present, with the improvements
in its structure and execution which modern artists have effected, must
assuredly be ranked among the highest and most refined productions of
human art; that in which man has been able to approximate most closely
to the workmanship of nature, and which has conferred upon him, if
not another sense, at least an exaltation of one already possessed
by him that merits almost to be regarded as a new one. Nor does it
appear yet to have reached its ultimate perfection, to which indeed
it is difficult to assign any bounds, when we take into consideration
the wonderful progress which workmanship of every kind is making,
and the delicacy, far superior to that of former times, with which
materials may now be wrought, as well as the ingenious inventions and
combinations which every year is bringing forth for accomplishing the
same ends by means hitherto unattempted.[50]
(285.) After a long torpor, the knowledge of the properties of light
began to make fresh progress about the end of the last century,
advancing with an accelerated rapidity, which has continued unabated
to the present time. The example was set by our late admirable and
lamented countryman, Dr. Wollaston, who re-examined and verified
the laws of double refraction in Iceland spar announced by Huyghens.
Attention being thus drawn to the subject, the geometry of Laplace
soon found a means of explaining at least one portion of the mystery
of this singular phenomenon, by the Newtonian theory of light, applied
under certain supposed conditions; and the reasoning which led him to
the result (at that time quite unexpected), may justly be regarded as
one of his happiest efforts. The prosecution of the subject, which had
now acquired a high degree of interest, was encouraged by the offer
of a prize on the part of the French Academy of Sciences; and it was
in a memoir which received this honourable reward on that occasion,
in 1810, that Malus, a retired officer of engineers in the French
army, announced the great discovery of the _polarization of light_ by
ordinary reflection at the surface of a transparent body.
(286.) Malus found that when a beam of light is reflected from the
surface of such a body at a certain angle, it acquires precisely the
same singular property which is impressed upon it in the act of double
refraction, and which Newton had before expressed by saying that it
possessed _sides_. This was the first circumstance which pointed out a
connection between that hitherto mysterious phenomenon and any of the
ordinary modifications of light; and it proved ultimately the means of
bringing the whole within the limits, if not of a complete explanation,
at least of a highly plausible theoretical representation. So true is,
in science, the remark of Bacon, that no natural phenomenon can be
adequately studied _in itself alone_, but, to be understood, must be
considered _as it stands connected with all nature_.
(287.) The new class of phenomena thus disclosed were immediately
studied with diligence and success, both abroad by Malus and Arago, and
at home by our countryman Dr. Brewster, and their laws investigated
with a care proportioned to their importance; when another and
apparently still more extraordinary class of phenomena presented
itself in the production of the most vivid and beautiful colours
(every way resembling those observed by Newton in thin films of air
or liquids, only infinitely more developed and striking,) in certain
transparent crystallized substances, when divided into flat plates in
particular directions, and exposed in a beam of polarized light. The
attentive examination of these colours by Wollaston, Biot, and Arago,
but more especially by Brewster, speedily led to the disclosure of a
series of optical phenomena so various, so brilliant, and evidently
so closely connected with the most important points relating to the
intimate structure of crystallized bodies, as to excite the highest
interest,--that sort of interest which is raised when we feel we are
on the eve of some extraordinary discovery, and expect every moment
that some leading fact will turn up, which will throw light on all that
appears obscure, and reduce into order all that seems anomalous.
(288.) This expectation was not disappointed. So long before the time
we are speaking of as the first year of the present century, our
illustrious countryman, the late Dr. Thomas Young, had established a
principle in optics, which, regarded as a physical law, has hardly its
equal for beauty, simplicity, and extent of application, in the whole
circle of science. Considering the manner in which the vibrations of
two musical sounds arriving at once at the ear affect the sense with
an impression of sound or silence according as they conspire or oppose
each other’s effects, he was led to the idea that the same ought to
hold good with light as with sound, if the theory which makes light
analogous to sound be the true one; and that, therefore, two rays of
light, setting off from the same origin, at the same instant, and
arriving at the same place by different routes, ought to strengthen
or wholly or partially destroy each other’s effects according to
the difference in length of the routes described by them. That two
lights should in any circumstances combine to produce darkness may
be considered strange, but is _literally true_; and it had even been
noticed long ago as a singular and unaccountable fact by Grimaldi, in
his experiments on the inflection of light. The experimental means by
which Dr. Young confirmed this principle, which is known in optics
by the name of the _interference_ of the rays of light, were as
simple and satisfactory as the principle itself is beautiful; but the
verifications of it, drawn from the explanation it affords of phenomena
apparently the most remote, are still more so. Newton’s colours of thin
films were the first phenomena to which its author applied it with full
success. Its next remarkable application was to those of diffraction,
of which, in the hands of M. Fresnel, a late eminent French geometer,
it also furnished a complete explanation, and that, too, in cases to
which Newton’s hypothesis could not apparently be made to apply, and
through a complication of circumstances which might afford a very
severe test of any hypothesis.
(289.) A simple and beautiful experiment on the interferences of
polarized light due to Fresnel and Arago enabled them to bring Dr.
Young’s law to bear on the colours produced by crystallized plates in a
polarized beam, and by so doing afforded a key to all the intricacies
of these magnificent but complex phenomena. Nothing now was wanting to
a rational theory of double refraction but to frame an hypothesis of
some mode in which light might be conceived to be propagated through
the elastic medium supposed to convey it in such a way as not to be
contradictory to any of the facts, nor to the general laws of dynamics.
This essential idea, without which every thing that had been before
done would have been incomplete, was also furnished by Dr. Young, who,
with a sagacity which would have done honour to Newton himself, had
declared, that to accommodate the doctrine of Huyghens to the phenomena
of polarized light it is necessary to conceive the mode of propagation
of a luminous impulse through the ether, differently from that of a
sonorous one through the air. In the latter, the particles of the air
_advance_ and _recede_; in the former, those of the ether must be
supposed to _tremble laterally_.
(290.) Taking this as the groundwork of his reasoning, Fresnel
succeeded in erecting on it a theory of polarization and double
refraction, so happy in its adaptation to facts, and in the coincidence
with experience of results deduced from it by the most intricate
analysis, that it is difficult to conceive it unfounded. If it be
so, it is at least the most curiously artificial system that science
has yet witnessed; and whether it be so or not, so long as it serves
to group together in one comprehensive point of view a mass of facts
almost infinite in number and variety, to reason from one to another,
and to establish analogies and relations between them; on whatever
hypothesis it may be founded, or whatever arbitrary assumptions it
may make respecting structures and modes of action, it can never be
regarded as other than a most real and important accession to our
knowledge.
(291.) Still, it is by no means impossible that the Newtonian theory of
light, if cultivated with equal diligence with the Huyghenian, might
lead to an equally plausible explanation of phenomena now regarded
as beyond its reach. M. Biot is the author of the hypothesis we have
already mentioned of a rotatory motion of the particles of light about
their axes. He has employed it only for a very limited purpose; but
it might doubtless be carried much farther; and by admitting only the
regular emission of the luminous particles at equal intervals of time,
and in similar states of motion from the shining body, which does not
seem a very forced supposition, all the phenomena of interference at
least would be readily enough explained without the admission of an
ether.
(292.) The optical examination of crystallized substances affords
one among many fine examples of the elucidation which every branch
of science is capable of affording to every other. The indefatigable
researches of Dr. Brewster and others have shown that the phenomena
exhibited by polarized light in its transmission through crystals
afford a certain indication of the most important points relating to
the structure of the crystals themselves, and thus become most valuable
characters by which to recognise their internal constitution. It was
Newton who first showed of what importance as a physical character,--as
the indication of other properties,--the action of a body on light
might become; but the characters afforded by the use of polarized light
as an instrument of experimental enquiry are so marked and intimate,
that they may almost be said to have furnished us with a kind of
intellectual sense, by which we are enabled to scrutinize the internal
arrangement of those wonderful structures which Nature builds up by
her refined and invisible architecture, with a delicacy eluding our
conception, yet with a symmetry and beauty which we are never weary
of admiring. In this point of view the science of optics has rendered
to mineralogy and crystallography services not less important than to
astronomy by the invention of the telescope, or to natural history by
that of the microscope; while the relations which have been discovered
to exist between the optical properties of bodies and their crystalline
forms, and even their chemical habitudes, have afforded numerous
and beautiful instances of general laws concluded from laborious and
painful induction, and curiously exemplifying the simplicity of nature
as it emerges slowly from an entangled mass of particulars in which, at
first, neither order nor connection can be traced.
CHAP. III.
OF COSMICAL PHENOMENA.
_Astronomy and Celestial Mechanics._
(293.) Astronomy, as has been observed in the former part of this
discourse, as a science of observation, had made considerable progress
among the ancients: indeed, it was the only branch of physical science
which could be regarded as having been cultivated by them with any
degree of assiduity or real success. The Chaldean and Egyptian records
had furnished materials from which the motions of the sun and moon
could be calculated with sufficient exactness for the prediction of
eclipses; and some remarkable cycles, or periods of years in which
the lunar eclipses return in very nearly the same order, had been
ascertained by observation. Considering the extreme imperfection of
their means of measuring time and space, this was, perhaps, as much
as could have been expected at that early period, and it was followed
up for a while in a philosophical spirit of just speculation, which,
if continued, could hardly have failed to lead to sound and important
conclusions.
(294.) Unfortunately, however, the philosophy of Aristotle laid it
down as a principle, that the celestial motions were regulated by laws
proper to themselves, and bearing no affinity to those which prevail
on earth. By thus drawing a broad and impassable line of separation
between celestial and terrestrial mechanics, it placed the former
altogether out of the pale of experimental research, while it at the
same time impeded the progress of the latter by the assumption of
principles respecting natural and unnatural motions, hastily adopted
from the most superficial and cursory remark, undeserving even the
name of observation. Astronomy, therefore, continued for ages a
science of mere record, in which theory had no part, except in so
far as it attempted to conciliate the inequalities of the celestial
motions with that assumed law of uniform circular revolution which
was alone considered consistent with the perfection of the heavenly
mechanism. Hence arose an unwieldy, if not self-contradictory, mass
of hypothetical motions of sun, moon, and planets, in circles, whose
centres were carried round in other circles, and these again in others
without end,--“cycle on epicycle, orb on orb,”--till at length, as
observation grew more exact, and fresh epicycles were continually
added, the absurdity of so cumbrous a mechanism became too palpable to
be borne. Doubts were expressed, to which the sarcasm of a monarch[51]
gave a currency they might not have obtained in a period when men
scarcely dared trust themselves to think; and at length Copernicus,
promulgating his own, or reviving the Pythagorean doctrine, which
places the sun in the centre of our system, gave to astronomy a
simplicity which, contrasted with the complication of the preceding
views, at once commanded assent.
(295.) An elegant writer[52], whom we have before had occasion to
quote, has briefly and neatly accounted for the confused notions which
so long prevailed respecting the constitution of our system, and the
difficulty experienced in acquiring a true notion of the disposition
of its parts. “We see it,” he observes, “not in _plan_, but in
_section_.” The reason of this is, that our point of observation lies
in its general plane, but the notion we aim at forming of it is not
that of its section, but of its plan. This is as if we should attempt
to read a book, or make out the countries on a map, with the eye on a
level with the paper. We can only judge directly of the distances of
objects by their sizes, or rather of their change of distance by their
change of size; neither have we any means of ascertaining, otherwise
than indirectly, even their positions, one among the other, from their
apparent places as seen by us. Now, the variations in apparent size
of the sun and moon are too small to admit of exact measure without
the use of the telescope, and the bodies of the planets cannot even be
distinguished as having any distinct size with the naked eye.
(296.) The Copernican system once admitted, however, this difficulty
of conception, at least, is effectually got over, and it becomes
a mere problem of geometry and calculation to determine, from the
observed places of a planet, its real orbit about the sun, and the
other circumstances of its motion. This Kepler accomplished for the
orbit of Mars, which he ascertained to be an ellipse having the sun
in one of its foci; and the same law, being extended by inductive
analogy to all the planets, was found to be verified in the case of
each. This with the other remarkable laws which are usually cited in
physical astronomy by the name of Kepler’s laws, constitute undoubtedly
the most important and beautiful system of geometrical relations which
have ever been discovered by a mere inductive process, independent of
any consideration of a theoretical kind. They comprise within them a
compendium of the motions of all the planets, and enable us to assign
their places in their orbits at any instant of time past or to come
(disregarding their mutual perturbations), provided certain purely
geometrical problems can be numerically resolved.
(297.) It was not, however, till long after Kepler’s time that the
real importance of these laws could be felt. Regarded in themselves,
they offered, it is true, a fine example of regular and harmonious
disposition in the greatest of all the works of creation, and a
striking contrast to the cumbersome mechanism of the cycles and
epicycles which preceded them; but there their utility seemed to
terminate, and, indeed, Kepler was reproached, and not without a
semblance of reason, with having rendered the actual calculation of
the places of the planets more difficult than before, the resources of
geometry being then inadequate to resolve the problems to which the
strict application of his laws gave rise.
(298.) The first result of the invention of the telescope and its
application to astronomical purposes, by Galileo, was the discovery
of Jupiter’s disc and satellites,--of a system offering a beautiful
miniature of that greater one of which it forms a portion, and
presenting to the eye of sense, at a single glance, that disposition of
parts which in the planetary system itself is discerned only by the eye
of reason and imagination (see 195.). Kepler had the satisfaction of
seeing it ascertained, that the law which he had discovered to connect
the times of revolution of the planets with their distances from the
sun, holds good also when applied to the periods of circulation of
these little attendants round the centre of their principal; thus
demonstrating it to be something more than a mere empirical rule, and
to depend on the intimate nature of planetary motion itself.
(299.) It had been objected to the doctrine of Copernicus, that, were
it true, Venus should appear sometimes horned like the moon. To this
he answered by admitting the conclusion, and averring that, should we
ever be able to see its actual shape, it _would_ appear so. It is easy
to imagine with what force the application would strike every mind when
the telescope confirmed this prediction, and showed the planet just as
both the philosopher and his objectors had agreed it ought to appear.
The history of science affords perhaps only one instance analogous to
this. When Dr. Hutton expounded his theory of the consolidation of
rocks by the application of heat, at a great depth below the bed of
the ocean, and especially of that of marble by actual fusion; it was
objected that, whatever might be the case with others, with calcareous
or marble rocks, at least, it was impossible to grant such a cause
of consolidation, since heat decomposes their substance and converts
it into quicklime, by driving off the carbonic acid, and leaving a
substance perfectly infusible, and incapable even of agglutination
by heat. To this he replied, that the pressure under which the heat
was applied would prevent the escape of the carbonic acid; and that
being retained, it might be expected to give that fusibility to the
compound which the simple quicklime wanted. The next generation saw
this anticipation converted into an observed fact, and verified by the
direct experiments of Sir James Hall, who actually succeeded in melting
marble, by retaining its carbonic acid under violent pressure.
(300.) Kepler, among a number of vague and even wild speculations on
the causes of the motions whose laws he had developed so beautifully
and with so much patient labour, had obtained a glimpse of the general
law of the inertia of matter, as applicable to the great masses of the
heavenly bodies as well as to those with which we are conversant on
the earth. After Kepler, Galileo, while he gave the finishing blow to
the Aristotelian dogmas which erected a barrier between the laws of
celestial and terrestrial motion, by his powerful argument and caustic
ridicule, contributed, by his investigations of the laws of falling
bodies and the motions of projectiles, to lay the foundation of a
true system of dynamics, by which motions could be determined from a
knowledge of the forces producing them, and forces from the motions
they produce. Hooke went yet farther, and obtained a view so distinct
of the mode in which the planets might be retained in their orbits
by the sun’s attraction, that, had his mathematical attainments been
equal to his philosophical acumen, and his scientific pursuits been
less various and desultory, it can hardly be doubted that he would have
arrived at a knowledge of the law of gravitation.
(301.) But every thing which had been done towards this great end,
before Newton, could only be regarded as smoothing some first
obstacles, and preparing a state of knowledge, in which powers like his
could be effectually exerted. His wonderful combination of mathematical
skill with physical research enabled him to invent, at pleasure, new
and unheard-of methods of investigating the effects of those causes
which his clear and penetrating mind detected in operation. Whatever
department of science he touched, he may be said to have formed afresh.
Ascending by a series of close-compacted inductive arguments to the
highest axioms of dynamical science, he succeeded in applying them
to the complete explanation of all the great astronomical phenomena,
and many of the minuter and more enigmatical ones. In doing this, he
had every thing to create: the mathematics of his age proved totally
inadequate to grapple with the numerous difficulties which were to
be overcome; but this, so far from discouraging him, served only to
afford new opportunities for the exertion of his genius, which, in the
invention of the method of fluxions, or, as it is now more generally
called, the differential calculus, has supplied a means of discovery,
bearing the same proportion to the methods previously in use, that
the steam-engine does to the mechanical powers employed before its
invention. Of the optical discoveries of Newton we have already spoken;
and if the magnitude of the objects of his astronomical discoveries
excite our admiration of the mental powers which could so familiarly
grasp them, the minuteness of the researches into which he there set
the first example of entering, is no less calculated to produce a
corresponding impression. Whichever way we turn our view, we find
ourselves compelled to bow before his genius, and to assign to the
name of NEWTON a place in our veneration which belongs to no other in
the annals of science. His era marks the accomplished maturity of the
human reason as applied to such objects. Every thing which went before
might be more properly compared to the first imperfect attempts of
childhood, or the essays of inexpert, though promising, adolescence.
Whatever has been since performed, however great in itself, and worthy
of so splendid and auspicious a beginning, has never, in point of
intellectual effort, surpassed that astonishing one which produced the
Principia.
(302.) In this great work, Newton shows all the celestial motions known
in his time to be consequences of the simple law, that every particle
of matter attracts every other particle in the universe with a force
proportional to the product of their masses directly, and the square
of their mutual distance inversely, and is itself attracted with an
equal force. Setting out from this, he explains how an attraction
arises between the great spherical masses of which our system consists,
regulated by a law precisely similar in its expression; how the
elliptic motions of planets about the sun, and of satellites about
their primaries, according to the exact rules inductively arrived at
by Kepler, result as necessary consequences from the same general law
of force; and how the orbits of comets themselves are only particular
cases of planetary movements. Thence proceeding to applications of
greater difficulty, he explains how the perplexing inequalities of
the moon’s motion result from the sun’s disturbing action; how tides
arise from the unequal attraction of the sun as well as of the moon
on the earth, and the ocean which surrounds it; and, lastly, how the
precession of the equinoxes is a necessary consequence of the very same
law.
(303.) The immediate successors of Newton found full occupation
in verifying his discoveries, and in extending and improving the
mathematical methods which it had now become manifest were to prove
the keys to an inexhaustible treasure of knowledge. The simultaneous
but independent discovery of a method of mathematical investigation in
every respect similar to that of Newton, by Leibnitz, while it created
a degree of national jealousy which can now only be regretted, had the
effect of stimulating the continental geometers to its cultivation, and
impressing on it a character more entirely independent of the ancient
geometry, to which Newton was peculiarly attached. It was fortunate
for science that it did so; for it was speedily found that (with one
fine exception on the part of our countryman Maclaurin, followed up,
after a long interval, by the late Professor Robison of Edinburgh, with
equal elegance,) the geometry of Newton was like the bow of Ulysses,
which none but its master could bend; and that, to render his methods
available beyond the points to which he himself carried them, it was
necessary to strip them of every vestige of that antique dress in which
he had delighted to clothe them. This, however, the countrymen of
Newton were very unwilling to do; and they paid the penalty in finding
themselves condemned to the situation of lookers on, while their
continental neighbours both in Germany and France were pushing forward
in the career of mathematico-physical discovery with emulous rapidity.
(304.) The legacy of research which Newton may be said to have left
to his successors was truly immense. To pursue, through all its
intricacies, the consequences of the law of gravitation; to account for
all the inequalities of the planetary movements, and the infinitely
more complicated, and to us more important ones, of the moon; and to
give, what Newton himself certainly never entertained a conception
of, a demonstration of the stability and permanence of the system,
under all the accumulating influence of its internal perturbations;
this labour, and this triumph, were reserved for the succeeding
age, and have been shared in succession by Clairaut, D’Alembert,
Euler, Lagrange and Laplace. Yet so extensive is the subject, and so
difficult and intricate the purely mathematical enquiries to which it
leads, that another century may yet be required to go through with
the task. The recent discoveries of astronomers have supplied matter
for investigation, to the geometers of this and the next generation,
of a difficulty far surpassing any thing that had before occurred.
Five primary planets have been added to our system; four of them
since the commencement of the present century, and these, singularly
deviating from the general analogy of the others, and offering _cases
of difficulty_ in theory, which no one had before contemplated. Yet
even the intricate questions to which these bodies have given rise
seem likely to be surpassed by those which have come into view, with
the discovery of several comets revolving in elliptic orbits, like the
planets, round the sun, in very moderate periods. But the resources of
modern geometry seem, so far from being exhausted, to increase with the
difficulties they have to encounter, and already, among the successors
of Lagrange and Laplace, the present generation has to enumerate a
powerful array of names, which promise to render it not less celebrated
in the annals of physico-mathematical research than that which has just
passed away.
(305.) Meanwhile the positions, figures, and dimensions of all the
planetary orbits, are now well known, and their variations from century
to century in great measure determined; and it has been generally
demonstrated, that all the changes which the mutual actions of the
planets on each other can produce in the course of indefinite ages,
are _periodical_, that is to say, increasing to a certain extent (and
that never a very great one), and then again decreasing; so that the
system can never be destroyed or subverted by the mutual action of its
parts, but keeps constantly oscillating, as it were, round a certain
mean state, from which it can never deviate to any ruinous extent. In
particular the researches of Laplace, Lagrange, and Poisson, have shown
the ultimate invariability of the mean distance of each planet from the
sun, and consequently of its periodic time. Relying on these grand
discoveries, we are enabled to look forward, from the point of time
which we now occupy, many thousands of years into futurity, and predict
the state of our system without fear of material error, but such as
may arise from causes whose existence at present we have no reason to
suppose, or from interference which we have no right to anticipate.
(306.) A correct enumeration and description of the fixed stars in
catalogues, and an exact knowledge of their position, supply the
only effectual means we can have of ascertaining what changes they
are liable to, and what motions, too slow to deprive them of their
usual epithet, _fixed_, yet sufficient to produce a sensible change
in the lapse of ages, may exist among them. Previous to the invention
of the compass, they served as guides to the navigator by night; but
for this purpose, a very moderate knowledge of a few of the principal
ones sufficed. Hipparchus was the first astronomer, who, excited
by the appearance of a new star, conceived the idea of forming a
catalogue of the stars, with a view to its use as an astronomical
record, “by which,” says Pliny, “posterity will be able to discover,
not only whether they are born and die, but also whether they change
their places, and whether they increase or decrease.” His catalogue,
containing more than 1000 stars, was constructed about 128 years before
Christ. It was in the course of the laborious discussion of his own and
former observations of them, undertaken with a view to the formation of
this catalogue, that he first recognised the fact of that slow, general
advance of all the stars eastward, when compared with the place of
the equinox, which is known under the name of the precession of the
equinoxes, and which Newton succeeded in referring to a motion in the
earth’s axis, produced by the attraction of the sun and moon.
(307.) Since Hipparchus, at various periods in the history of
astronomy, catalogues of stars have been formed, among which that
of Ulugh Begh, comprising about 1000 stars, constructed in 1437, is
remarkable as the production of a sovereign prince, working personally
in conjunction with his astronomers; and that of Tycho Brahe,
containing 777 stars, constructed in 1600, as having originated in a
phenomenon similar to that which drew the attention of Hipparchus. In
more recent times, astronomers provided with the finest instruments
their respective eras could supply, and established in observatories,
munificently endowed by the sovereigns and governments of different
European nations, have vied and are still vying with each other,
in extending the number of registered stars, and giving the utmost
possible degree of accuracy to the determination of their places.
Among these, it would be ungrateful not to claim especial notice
for the superb series of observations which, under a succession of
indefatigable and meritorious astronomers, has, for a very long period,
continued to emanate from our own national observatory of Greenwich.
(308.) The distance of the fixed stars is so immense, that every
attempt to assign a limit, _within which_ it _must_ fall, has hitherto
failed. The enquiries of astronomers of all ages have been directed
to ascertain this distance, by taking the dimensions of our own
particular system of sun and planets, or of the earth itself, as the
unit of a scale on which it might be measured. But although many have
imagined that their observations afforded grounds for the decision
of this interesting point, it has uniformly happened either that the
phenomena on which they relied have proved to be referable to other
causes not previously known, and which the superior accuracy of their
researches has for the first time brought to light; or to errors
arising from instrumental imperfections and unavoidable defects of the
observations themselves.
(309.) The only indication we can expect to obtain of the actual
distance of a star, would consist in an annual change in its apparent
place corresponding to the motion of the earth round the sun, called
its _annual parallax_, and which is nothing more than the measure
of the apparent size of the earth’s orbit as seen from the star.
Many observers have thought they have detected a measurable amount
of this parallax; but as astronomical instruments have advanced in
perfection, the quantity which they have successively assigned to it
has been continually reduced within narrower and narrower limits,
and has invariably been commensurate with the errors to which the
instruments used might fairly be considered liable. The conclusion this
strongly presses on us is, that it is really a quantity too small to
admit of distinct measurement in the present state of our means for
that purpose; and that, therefore, the distance of the stars must be
a magnitude of such an order as the imagination almost shrinks from
contemplating. But this increase in our scale of dimension calls for
a corresponding enlargement of conception in all other respects. The
same reasoning which places the stars at such immeasurable remoteness,
exalts them at the same time into glorious bodies, similar to, and even
far surpassing, our own sun, the centres perhaps of other planetary
systems, or fulfilling purposes of which we can have no idea, from any
analogy in what passes immediately around us.
(310.) The comparison of catalogues, published at different periods,
has given occasion to many curious remarks, respecting changes both
of place and brightness among the stars, to the discovery of variable
ones which lose and recover their lustre periodically, and to that of
the disappearance of several from the heavens so completely as to have
left no vestige discernible even by powerful telescopes. In proportion
as the construction of astronomical and optical instruments has gone on
improving, our knowledge of the contents of the heavens has undergone
a corresponding extension, and, at the same time, attained a degree of
precision which could not have been anticipated in former ages. The
places of all the principal stars in the northern hemisphere, and of a
great many in the southern, are now known to a degree of nicety which
must infallibly detect any real motions that may exist among them,
and has in fact done so, in a great many instances, some of them very
remarkable ones.
(311.) It is only since a comparatively recent date, however, that
any great attention has been bestowed on the smaller stars, among
which there can be no doubt of the most interesting and instructive
phenomena being sooner or later brought to light. The minute
examination of them with powerful telescopes, and with delicate
instruments for the determination of their places, has, indeed, already
produced immense catalogues and masses of observations, in which
thousands of stars invisible to the naked eye are registered; and has
led to the discovery of innumerable important and curious facts, and
disclosed the existence of whole classes of celestial objects, of a
nature so wonderful as to give room for unbounded speculation on the
extent and construction of the universe.
(312.) Among these, perhaps the most remarkable are the revolving
double stars, or stars which, to the naked eye or to inferior
telescopes, appear single; but, if examined with high magnifying
powers, are found to consist of two individuals placed almost close
together, and which, when carefully watched, are (many of them) found
to revolve in regular elliptic orbits about each other; and so far
as we have yet been able to ascertain, to obey the same laws which
regulate the planetary movements. There is nothing calculated to give a
grander idea of the scale on which the sidereal heavens are constructed
than these beautiful systems. When we see such magnificent bodies
united in pairs, undoubtedly by the same bond of mutual gravitation
which holds together our own system, and sweeping over their enormous
orbits, in periods comprehending many centuries, we admit at once that
they must be accomplishing ends in creation which will remain for ever
unknown to man; and that we have here attained a point in science
where the human intellect is compelled to acknowledge its weakness, and
to feel that no conception the wildest imagination can form will bear
the least comparison with the intrinsic greatness of the subject.
_Geology._
(313.) The researches of physical astronomy are confessedly incompetent
to carry us back to the origin of our system, or to a period when
its state was, in any great essential, different from what it is
at present. So far as the causes now in action go, and so far as
our calculations will enable us to estimate their effects, we are
equally unable to perceive in the general phenomena of the planetary
system either the evidence of a beginning, or the prospect of an end.
Geometers, as already stated, have demonstrated that, in the midst of
all the fluctuations which can possibly take place in the elements of
the orbits of the planets, by reason of their mutual attraction, the
general balance of the parts of the system will always be preserved,
and every departure from a mean state periodically compensated. But
neither the researches of the physical astronomer, nor those of
the geologist, give us any ground for regarding our system, or the
globe we inhabit, as of eternal duration. On the contrary, there are
circumstances in the physical constitution of our own planet which at
least obscurely point to an origin and a formation, however remote,
since it has been found that the figure of the earth is not globular
but elliptical, and that its attraction is such as requires us to admit
the interior to be more dense than the exterior, and the density to
increase with some degree of regularity from the surface towards the
centre, and _that_, in layers arranged elliptically round the centre,
circumstances which could scarcely happen without some such successive
deposition of materials as would enable pressure to be propagated with
a certain degree of freedom from one part of the mass to another, even
if we should hesitate to admit a state of primitive fluidity.
(314.) But from such indications nothing distinct can be concluded;
and if we would speculate to any purpose on a former state of our
globe and on the succession of events which from time to time may have
changed the condition and form of its surface, we must confine our
views within limits far more restricted, and to subjects much more
within the reach of our capacity, than either the creation of the world
or its assumption of its present figure. These, indeed, were favourite
speculations with a race of geologists now extinct; but the science
itself has undergone a total change of character, even within the last
half century, and is brought, at length, effectually within the list
of the inductive sciences. Geologists now no longer bewilder their
imaginations with wild theories of the formation of the globe from
chaos, or its passage through a series of hypothetical transformations,
but rather aim at a careful and accurate examination of the records
of its former state, which they find indelibly impressed on the great
features of its actual surface, and to the evidences of former life
and habitation which organised remains imbedded and preserved in its
strata indisputably afford.
(315.) Records of this kind are neither few nor vague; and though the
obsoleteness of their language when we endeavour to interpret it too
minutely, may, and no doubt often does, lead to misapprehension, still
its general meaning is, on the whole, unequivocal and satisfactory.
Such records teach us, in terms too plain to be misunderstood, that
the whole or nearly the whole of our present lands and continents
were formerly at the bottom of the sea, where they received deposits
of materials from the wearing and degradation of other lands not now
existing, and furnished receptacles for the remains of marine animals
and plants inhabiting the ocean above them, as well as for similar
spoils of the land washed down into its bosom.
(316.) These remains are occasionally brought to light; and their
examination has afforded indubitable evidence of the former existence
of a state of animated nature widely different from what now obtains
on the globe, and of a period anterior to that in which it has been
the habitation of man, or rather, indeed, of a series of periods, of
unknown duration, in which both land and sea teemed with forms of
animal and vegetable life, which have successively disappeared and
given place to others, and these again to new races approximating
gradually more and more nearly to those which now inhabit them, and at
length comprehending species which have their counterparts existing.
(317.) These wrecks of a former state of nature, thus wonderfully
preserved (like ancient medals and inscriptions in the ruins of an
empire), afford a sort of rude chronology, by whose aid the successive
depositions of the strata in which they are found may be marked out
in epochs more or less definitely terminated, and each characterized
by some peculiarity which enables us to recognise the deposits of any
period, in whatever part of the world they may be found. And, so far
as has been hitherto investigated, the _order_ of succession in which
these deposits have been formed appears to have been the same in every
part of the globe.
(318.) Many of the strata which thus bear evident marks of having been
deposited at the bottom of the sea, and of course in a horizontal
state, are now found in a position highly inclined to the horizon, and
even occasionally vertical. And they often bear no less evident marks
of violence, in their bending and fracture, the dislocation of parts
which were once contiguous, and the existence of vast collections of
broken fragments which afford every proof of great violence having been
used in accomplishing some at least of the changes which have taken
place.
(319.) Besides the rocks which carry this internal evidence of
submarine deposition, are many which exhibit no such proofs, but on the
contrary hold out every appearance of owing their origin to volcanoes
or to some other mode of igneous action; and in every part of the
world, and among strata of all ages, there occur evidences of such
action so abundant, and on such a scale, as to point out the volcano
and the earthquake as agents which may have been instrumental in the
production of those changes of level, and those violent dislocations
which we perceive to have taken place.
(320.) At all events, in accounting for those changes, geologists
have no longer recourse, as formerly, to causes purely hypothetical,
such as a shifting of the earth’s axis of rotation, bringing the sea
to overflow the land, by a change in the place of the longer and
shorter diameters of the spheroidal figure, nor to tides produced by
the attraction of comets suddenly approaching very near the earth,
nor to any other fanciful and arbitrarily assumed hypotheses; but
rather endeavour to confine themselves to a careful consideration
of causes evidently in action at present, with a view to ascertain
how far they, in the first instance, are capable of accounting for
the facts observed, and thus legitimately bringing into view, as
residual phenomena, those effects which cannot be so accounted for.
When this shall have been in some measure accomplished, we shall be
able to pronounce with greater security than at present respecting the
necessity of admitting a long succession of tremendous and ravaging
catastrophes and cataclysms,--epochs of terrific confusion and violence
which many geologists (perhaps with justice) regard as indispensable to
the explanation of the existing features of the world. We shall learn
to distinguish between the effects which require for their production
the sudden application of convulsive and fracturing efforts, and those,
probably not less extensive, changes which may have been produced by
forces equally or more powerful, but acting with less irregularity,
and so distributed over time as to produce none of those _interregnums_
of chaotic anarchy which we are apt to think (perhaps erroneously)
great disfigurements of an order so beautiful and harmonious as that of
nature.
(321.) But to estimate justly the effects of causes now in action in
geology is no easy task. There is no _à priori_ or deductive process by
which we can estimate the amount of the annual erosion, for instance,
of a continent by the action of meteoric agents, rain, wind, frost,
&c., nor the quantity of destruction produced on its coasts by the
direct violence of the sea, nor the quantity of lava thrown up _per
annum_ by volcanoes over the whole surface of the earth, nor any
similar effect. And to consult experience on all such points is a
slow and painful process if rightly gone into, and a very fallible
one if only partially executed. Much, then, at present must be left
to opinion, and to that sort of clear-judging tact which sometimes
anticipates experience; but this ought not to stand in the way of our
making every possible effort to obtain accurate information on such
points, by which alone geology can be rendered, if not an experimental
science, at least a science of that kind of active observation which
forms the nearest approach to it, where actual experiment is impossible.
(322.) Let us take, for example, the question, “What is the actual
direction in which changes of relative level are taking place between
the existing continents and seas?” If we consult partial experience,
that is, _all_ the information that we possess respecting ancient
sea-marks, soundings, &c., we shall only find ourselves bewildered in
a mass of conflicting, because imperfect, evidence. It is obvious that
the only way to decide the point is to ascertain, by very precise and
careful observations at proper stations on coasts, selected at points
where there exist natural marks not liable to change in the course of
at least a century, the true elevation of such marks above the _mean_
level of the sea, and to multiply these stations sufficiently over the
whole globe to be capable of affording real available knowledge. Now,
this is not a very easy operation (considering the accuracy required);
for the _mean_ level of the sea can be determined by no single
observation, any more than the mean height of the barometer at a given
station, being affected both by periodical and accidental fluctuations
due to tides, winds, waves, and currents. Yet if an instrument adapted
for the purpose were constructed, and rendered easily attainable, and
rules for its use carefully drawn up, there is little doubt we should
soon (by the industry of observers scattered over the world) be in
possession of a most valuable mass of information, which could not fail
to afford a point of departure for the next generation, and furnish
ground for the only kind of argument which ever can be conclusive on
such subjects.
(323.) Geology, in the magnitude and sublimity of the objects of
which it treats, undoubtedly ranks, in the scale of the sciences,
next to astronomy; like astronomy, too, its progress depends on the
continual accumulation of observations carried on for ages. But, unlike
astronomy, the observations on which it depends, when the whole extent
of the subject to be explored is taken into consideration, can hardly
yet be said to be more than commenced. Yet, to make up for this, there
is another important difference, that while in the latter science it is
impossible to recall the past or anticipate the future, and observation
is in consequence limited to a single fact in a single moment; in
the former, the records of the past are always present;--they may be
examined and re-examined as often as we please, and require nothing
but diligence and judgment to put us in possession of their whole
contents. Only a very small part of the surface of our globe has,
however, been accurately examined in detail, and of that small portion
we are only able to scratch the mere exterior, for so we must consider
those excavations which we are apt to regard as searching the bowels
of the earth; since the deepest mines which have been sunk penetrate
to a depth hardly surpassing the ten thousandth part of the distance
between its surface and its centre. Of course inductions founded on
such limited examination can only be regarded as provisional, except
in those remarkable cases where the same great formations in the same
order have been recognised in very distant quarters, and without
exception. This, however, cannot long be the case. The spirit with
which the subject has been prosecuted for many years in our own country
has been rewarded with so rich a harvest of surprising and unexpected
discoveries, and has carried the investigation of our island into such
detail, as to have excited a corresponding spirit among our continental
neighbours; while the same zeal which animates our countrymen on their
native shore accompanies them in their sojourns abroad, and has
already begun to supply a fund of information respecting the geology of
our Indian possessions, as well as of every other point where English
intellect and research can penetrate.
(324.) Nothing can be more desirable than that every possible facility
and encouragement should be afforded for such researches, and indeed
to the pursuits of the enlightened resident or traveller in every
department of science, by the representatives of our national authority
wherever our power extends. By these only can our knowledge of the
actual state of the surface of the globe, and that of the animals
and vegetables of the ancient continents and seas, be extended and
perfected, while more complete information than we at present possess
of the habits of those actually existing, and the influence of changes
of climate, food, and circumstances, on them, may be expected to render
material assistance to our speculations respecting those which have
become extinct.
CHAP. IV.
OF THE EXAMINATION OF THE MATERIAL CONSTITUENTS OF THE WORLD.
_Mineralogy._
(325.) The consideration of the history and structure of our globe, and
the examination of the fossil contents of its strata, lead us naturally
to consider the materials of which it consists. The history of these
materials, their properties as objects of philosophical enquiry, and
their application to the useful arts and the embellishments of life,
with the characters by which they can be certainly distinguished one
from another, form the object of mineralogy, taken in its most extended
sense.
(326.) There is no branch of science which presents so many points
of contact with other departments of physical research, and serves
as a connecting link between so many distant points of philosophical
speculation, as this. To the geologist, the chemist, the optician, the
crystallographer, the physician, it offers especially the very elements
of their knowledge, and a field for many of their most curious and
important enquiries. Nor, with the exception of chemistry, is there any
which has undergone more revolutions, or been exhibited in a greater
variety of forms. To the ancients it could scarcely be said to be at
all known, and up to a comparatively recent period, nothing could
be more imperfect than its descriptions, or more inartificial and
unnatural than its classification. The more important minerals in the
arts, indeed, those used for economical purposes and those from which
metals were extracted, had a certain degree of attention paid to them,
for the sake of their utility and commercial value, and the precious
stones for that of ornament. But until their crystalline forms were
attentively observed and shown to be determinate characters on which
dependence could be placed, no mineralogist could give any correct
account of the real distinction between one mineral and another.
(327.) It was only, however, when chemical analysis had acquired
a certain degree of precision and universal applicability that
the importance of mineralogy as a science began to be recognized,
and the connection between the external characters of a stone and
its ingredient constituents brought into distinct notice. Among
these characters, however, none were found to possess that eminent
distinctness which the crystalline form offers; a character, in the
highest degree geometrical, and affording, as might be naturally
supposed, the strongest evidence of its necessary connection with the
intimate constitution of the substance. The full importance of this
character was, however, not felt until its connection with the texture
or cleavage of a mineral was pointed out, and even then it required
numerous and striking instances of the critical discernment of Haüy
and other eminent mineralogists in predicting from the measurements
of the angles of crystals which had been confounded together that
differences would be found to exist in their chemical composition, all
which proved fully justified in their result before the essential value
of this character was acknowledged. This was no doubt in great measure
owing to the high importance set by the German mineralogists on those
external characters of touch, sight, weight, colour, and other sensible
qualities, which are little susceptible, with the exception of weight,
of exact determination, and which are subject to material variations
in different specimens of the same mineral. By degrees, however, the
necessity of ascribing great weight to a character so definite was
admitted, especially when it was considered that the same step which
pointed out the intimate connection of external form with internal
structure furnished the mineralogist with the means of reducing all
the forms of which a mineral is susceptible under one general type, or
primitive form, and afforded grounds for an elegant theoretical account
of the assumption of definite figures _ab initio_.
(328.) A simple and elegant invention of Dr. Wollaston, the reflecting
goniometer, gave a fresh impulse to that view of mineralogy which makes
the crystalline form the essential or leading character, by putting
it in the power of every one, by the examination of even the smallest
portion of a broken crystal, to ascertain and verify that essential
character on which the identity of a mineral in the system of Haüy
was made to depend. The application of so ready and exact a method
speedily led to important results, and to a still nicer discrimination
of mineral species than could before be attained; and the confirmation
given to these results by chemical analysis stamped them with a
scientific and decided character which they have retained ever since.
(329.) Meanwhile the progress made in chemical analysis had led to
the important conclusion that every chemical compound susceptible of
assuming the solid state assumed with it a determinate crystalline
form; and the progress of optical science had shown that the
fundamental crystalline form, in the case at least of transparent
bodies, drew with it a series of optical properties no less curious
than important in relation to the affections of light in its passage
through such substances. Thus, in every point of view, additional
importance became added to this character; and the study of the
crystalline forms of bodies in general assumed the form of a separate
and independent branch of science, of which the geometrical forms of
the mineral world constituted only a particular case. Mineralogy,
however, as a branch of natural history, remains still distinct either
from optics or crystallography. The mineralogist is content, and thinks
he has performed his task, if not as a natural historian at least as
a classifier and arranger, if he only gives such a characteristic
description of a mineral as shall effectually distinguish it from every
other, and shall enable any one who may encounter such a body in any
part of the world to impose on it its name, assign it a place in his
system, and turn to his books for a further description of all that
the chemist, the optician, the lapidary, or the artist, may require to
know. Still this is no easy matter: the laborious researches of the
most eminent mineralogists can hardly yet be said to have effectually
accomplished it; and its difficulty may be appreciated by the small
number of simple minerals, or minerals of perfectly definite and
well-marked characters, which have been hitherto made out. Nor can
this indeed be wondered at, when we consider that by far the greater
portion of the rocks and stones which compose the external crust of the
globe consists of nothing more than the accumulated _detritus_ of older
rocks, in which the fragments and powder of an infinite variety of
substances are mingled together, in all sorts of varying proportions,
and in such a way as to defy separation. Many of these rocks, however,
so compounded, occur with sufficient frequency and uniformity of
character to have acquired names and to have been usefully applied;
indeed, in the latter respect, minerals of this description far surpass
all the others. As objects of natural history, therefore, they are well
worthy of attention, however difficult it may be to assign them a place
in any artificial arrangement.
(330.) This paucity of simple minerals, however, is probably rather
apparent than real, and in proportion as the researches of the chemist
and crystallographer shall be extended throughout nature, they will
no doubt become much more numerous. Indeed, in the great laboratories
of nature it can hardly be doubted that almost every kind of chemical
process is going forwards, by which compounds of every description are
continually forming. Accordingly, it is remarked, that the lavas and
ejected scoriæ of volcanoes are receptacles in which mineral products
previously unknown are constantly discovered, and that the primitive
formations, as they are called in geology, which bear no marks of
having been produced by the destruction of others, are also remarkable
for the beauty and distinctness of character of their minerals.
(331.) The great difficulty which has been experienced in attempts to
classify mineral substances by their chemical constituents has arisen
from the observed presence, in some specimens of minerals bearing
that general resemblance in other respects as well as agreement in
form which would seem to entitle them to be considered as alike, of
ingredients foreign to the usual composition of the species, and that
occasionally in so large a proportion as to render it unjustifiable
to refer their occurrence to accidental impurities. These cases, as
well as some anomalies observed in the classification of minerals by
their crystalline forms, which seemed to show that the same substance
might occasionally appear under two distinct forms, as well as some
remarkable coincidences between the forms of substances quite distinct
from each other in a chemical point of view, have within a recent
period given rise to a branch of the science of crystallography of a
very curious and important nature. The _isomorphism_ of certain groups
of chemical elements has already afforded us an example illustrative
of the manner in which inductions sometimes receive unexpected
verifications (see 180.). The laws and relations thus brought to light
are among the most curious and interesting parts of modern science,
and seem likely in their further developement to afford ample scope
for the exercise of chemical and mineralogical research. They have
already afforded innumerable fine examples of that important step in
science by which anomalies disappear, and occasional incongruities
become reconciled under more general expressions of physical laws,
and thus unite in affording support to those very views which they
promised, when first observed, to overset. Nothing, indeed, can be
more striking than to see the very ingredient which every previous
chemist and mineralogist would agree to disregard and reject as a
mere casual impurity brought forward and appealed to in support of a
theory expressly directed to the object of rescuing science from the
imputation of disregarding, under any circumstances, the plain results
of direct experiment.
_Chemistry._
(332.) The laws which concern the intimate constitution of bodies,
not as respects their _structure_ or the manner in which their parts
are put together, but as regards their _materials_ or the ingredients
of which those parts are composed, form the objects of chemistry. A
solid body may be regarded as a fabric, more or less regularly and
artificially constructed, in which the materials and the workmanship
may be separately considered, and in which, though the latter be
ruined and confounded by violence, the former remain unchanged in
their nature, though differently arranged. In liquid or aërial bodies,
too, though there prevails a less degree of difference in point of
structure, and a greater facility of dispersion and dissipation, than
in solids, yet an equal diversity of _materials_ subsists, giving to
them properties differing extremely from each other.
(333.) The inherent activity of matter is proved not only by the
production of motion by the mutual attractions and repulsions of
distant or contiguous masses, but by the changes and apparent
transformations which different substances undergo in their sensible
qualities by mere mixture. If water be added to water, or salt to salt,
the effect is an increase of quantity, but no change of quality. In
this case, the mutual action of the particles is entirely mechanical.
Again, if a blue powder and a yellow one, each perfectly dry, be mixed
and well shaken together, a green powder will be produced; but this
is a mere effect arising in the eye from the intimate mixture of the
yellow and blue light separately and independently reflected from
the minute particles of each; and the proof is had by examining the
mixture with a microscope, when the yellow and blue grains will be seen
separate and each quite unaltered. If the same experiment be tried with
coloured liquids, which are susceptible of mixing without chemical
action, a compound colour is likewise produced, but no examination
with magnifiers is in that case sufficient to detect the ingredients;
the reason obviously being, the excessive minuteness of the parts, and
their perfect intermixture, produced by agitating two liquids together.
From the mixture of two powders, extreme patience would enable any one,
by picking out with a magnifier grain after grain, to separate the
ingredients. But when liquids are mixed, no mechanical separation is
any longer practicable; the particles are so minute as to elude all
search. Yet this does not hinder us from regarding such a compound as
still a mere mixture, and its properties are accordingly intermediate
between those of the liquids mixed. But this is far from being the
case with all liquids. When a solution of potash, for example, and
another of tartaric acid, each perfectly liquid, are mixed together in
proper proportions, a great quantity of a solid saline substance falls
to the bottom of the containing vessel, which is quite different from
either potash or tartaric acid, and the liquid from which it subsided
offers no indications by its taste or other sensible qualities of the
ingredients mixed, but of something totally different from either.
It is evident that this is a phenomenon widely different from that
of mere mixture; there has taken place a great and radical change in
the intimate nature of the ingredients, by which a new substance is
produced which had no existence before. And it has been produced by the
_union_ of the ingredients presented to each other; for when examined
it is found that nothing has been _lost_, the weight of the whole
mixture being the sum of the weights mixed. Yet the potash and tartaric
acid have disappeared entirely, and the weight of the new product is
found to be exactly equal to that of the tartaric acid and potash
employed, taken together, abating a small portion held in solution in
the liquid, which may be obtained however by evaporation. They have
therefore combined, and adhere to one another with a cohesive force
sufficient to form a solid out of a liquid; a force which has thus been
called into action by merely presenting them to each other in a state
of solution.
(334.) It is the business of chemistry to investigate these and similar
changes, or the reverse of such changes, where a single substance is
resolved into two or more others, having different properties from it,
and from each other, and to enquire into all the circumstances which
can influence them; and either determine, modify, or suspend their
accomplishment, whether such influence be exercised by heat or cold, by
time and rest, or by agitation or pressure, or by any of those agents
of which we have acquired a knowledge, such as electricity, light,
magnetism, &c.
(335.) The wonderful and sudden transformations with which chemistry is
conversant, the violent activity often assumed by substances usually
considered the most inert and sluggish, and, above all, the insight
it gives into the nature of innumerable operations which we see daily
carried on around us, have contributed to render it the most popular,
as it is one of the most extensively useful, of the sciences; and
we shall, accordingly, find none which have sprung forward, during
the last century, with such extraordinary vigour, and have had such
extensive influence in promoting corresponding progress in others. One
of the chief causes of its popularity is, perhaps, to be sought for in
this, that it is, of all the sciences, perhaps, the most completely an
experimental one; and even its theories are, for the most part, of that
generally intelligible and readily applicable kind, which demand no
intense concentration of thought, and lead to no profound mathematical
researches. The simple process of inductive generalization, grounded on
the examination of numerous facts, all of them presenting considerable
intrinsic interest, has sufficed, in most instances, to lead, by a
clear and direct road, to its highest laws yet known. But, on the other
hand, these laws, when stated, are not yet fully sufficient to lead us,
except in very limited cases, to a deductive knowledge of particulars
never before examined, at least, not without great caution, and
constant appeal to experiment as a check on our reasoning; so that we
are justified in regarding the _axioms_ of chemistry, the true handles
of deductive reasoning, as still unknown, and, perhaps, likely long
to remain so. This is no fault of its cultivators, who have comprised
in their list the highest and most varied talents and industry, but
of the inherent complexity of the subject, and the infinite multitude
of causes which are concerned in the production of every, even the
simplest, chemical phenomenon.
(336.) The history of chemistry (on which, however, we are not about
to enlarge,) is one of great interest to those who delight to trace
the steps by which mankind advance to the discovery of truth through
a series of mistakes and failures. It may be divided, 1st, into
the period of the alchemists, a lamentable epoch in the annals of
intellectual wandering; 2dly, that of the phlogistic doctrines of
Beccher and Stahl, in which, as if to prove the perversity of the human
mind, of two possible roads the wrong was chosen; and a theory obtained
universal credence on the strength of an induction, valid as such, but
wrongly interpreted, which is negatived, _in every instance_, by an
appeal to the balance. This, too, happened, not by reason of unlucky
coincidences, or individual oversights, but of necessity, and from an
inherent defect of the theory itself, which thus impeded the progress
of the science, as far as a science of experiment can be impeded by
a false theory, by perplexing its cultivators with the appearance of
contradictions in their experiments where none really subsisted, by
destroying all their confidence in the numerical exactness of their
own results, and by involving the subject in a mist of visionary and
hypothetical causes in place of the true acting principles. Thus, in
the combustion of any substance which is incapable of flying away in
fumes, an increase of weight takes place,--the ashes are heavier than
the fuel. Whenever this was observed, however, it was passed carelessly
over as arising from the escape of phlogiston, or the principle of
inflammability, which was considered as being either the element of
fire itself, or in some way combined with it, and thus essentially
_light_. It is now known that the increase of weight is owing to
the absorption of, and combination with, a quantity of a peculiar
ingredient called _oxygen_, from the air, a principle essentially
_heavy_. So far as weight is concerned, it makes no difference whether
a body having weight enters, or one having levity escapes; but there
is this plain difference in a philosophical point of view, that oxygen
is a real producible substance, and phlogiston is no such thing: the
former is a _vera causa_, the latter an hypothetical being, introduced
to account for what the other accounts for much better.
(337.) The third age of chemistry--that which may be called
emphatically modern chemistry--commenced (in 1786) when Lavoisier, by
a series of memorable experiments, extinguished for ever this error,
and placed chemistry in the rank of one of the exact sciences,--a
science of number, weight, and measure. From that epoch to the
present day it has constantly advanced with an accelerated progress,
and at this moment may be regarded as more progressive than ever.
The principal features in this progress may be comprised under the
following general heads:--
1. The discovery of the proximate, if not the ultimate, elements
of all bodies, and the enlargement of the list of known
elements to its present extent of between fifty and sixty
substances.
2. The developement of the doctrine of latent heat by Black,
with its train of important consequences, including the
scientific theory of the steam-engine.
3. The establishment of Wenzel’s law of definite proportions on
his own experiments, and those of Richter, a discovery
subsequently merged in the more general wording and better
development of Dalton’s atomic theory.
4. The precise determination of the atomic weights of the
different chemical elements, mainly due to the astonishing
industry of Berzelius, and his unrivalled command of chemical
resources, as well as to the researches of the other chemists
of the Swedish and German school.
5. The assimilation of gases and vapours, by which we are led
to regard the former, universally, as particular cases of
the latter, a generalization resulting chiefly from the
experiments of Faraday on the condensation of the gases,
and those of Gay-Lussac and Dalton, on the laws of their
expansion by heat compared with that of vapours.
6. The establishment of the laws of the combination of gases and
vapours by definite volumes, by Gay-Lussac.
7. The discovery of the chemical effects of electricity, and
the decomposing agency of the Voltaic pile, by Nicholson
and Carlisle; the investigation of the laws of such
decompositions, by Berzelius and Hisinger: the decomposition
of the alkalies by Davy, and the consequent introduction into
chemistry of new and powerful agents in their metallic bases.
8. The application of chemical analysis to all the objects of
organized and unorganized nature, and the discovery of
the ultimate constituents of all, and the proximate ones
of organic matter, and the recognisance of the important
distinctions which appear to divide these great classes of
bodies from each other.
9. The applications of chemistry to innumerable processes in the
arts, and among other useful purposes to the discovery of the
essential medical principles in vegetables, and to important
medicaments in the mineral kingdom.
10. The establishment of the intimate connection between
chemical composition and crystalline form, by Haüy
and Vauquelin, with the successive rectifications the
statement of that connection has undergone in the hands of
Mitscherlich, Rose, and others, with the progress of chemical
and crystallographical knowledge.
(338.) To pursue these several heads into detail would lead us into
a treatise on chemistry; but a few remarks on one or two of them, as
they bear upon the general principles of all scientific enquiry, will
not be irrelevant. And first, then, with reference to the discovery
of new elements, it will be observed, that philosophical chemistry no
more aims at determining the one essential element out of which all
matter is framed--the one ultimate principle of the universe--than
astronomy at discovering the origin of the planetary movements in
the application of a determinate projectile force in a determinate
direction, or geology at ascending to the creation of the earth. There
may be such an element. Some singular relations which have been pointed
out in the atomic weights of bodies seem to suggest to minds fond of
speculation that there is; but philosophical chemistry is content to
wait for some striking fact, which may either occur unexpectedly or
be led to by the slow progress of enlarged views, to disclose to us
its existence. Still, the multiplication of so-considered elementary
bodies has been considered by some as an inconvenience. We confess
we do not coincide with this view. Whatever they be, the obstinacy
with which they resist decomposition shows that they are ingredients
of a very high and primary importance in the economy of nature; and
such as, in any state of science, it would be indispensably necessary
to be perfectly familiar with. Like particular theorems in geometry,
which, though not rising to the highest point of generality, have yet
their several scopes and ranges of extensive application, they must be
well and perfectly understood in all their bearings. Should we ever
arrive at an analysis of these bodies, the chemical properties of the
new elements which will then come into view will be known only by our
knowledge of these, or of other compounds of the same class, which they
may be capable of forming. Not but that such an analysis would be a
most important and indeed triumphant achievement, and change the face
of chemistry; but it would undo nothing that has been done, and render
useless no point of knowledge which we have yet arrived at.
(339.) The atomic theory, or the law of definite proportions, which
is the same thing presented in a form divested of all hypothesis,
after the laws of mechanics, is, perhaps, the most important which
the study of nature has yet disclosed. The extreme simplicity which
characterizes it, and which is itself an indication, not unequivocal,
of its elevated rank in the scale of physical truths, had the effect
of causing it to be announced at once by Mr. Dalton, in its most
general terms, on the contemplation of a few instances[53], without
passing through subordinate stages of painful inductive ascent by the
intermedium of subordinate laws, such as, had the contrary course been
pursued by him, would have been naturally preparatory to it, and such
as would have led others to it by the prosecution of Wenzel’s and
Richter’s researches, had they been duly attended to. This is, in fact,
an example, and a most remarkable one, of the effect of that natural
propensity to generalize and simplify (noticed in 171.), which, if it
occasionally leads to over-hasty conclusions, limited or disproved by
further experience, is yet the legitimate parent of many of our most
valuable and soundest results. Instances like this, where great and,
indeed, immeasurable steps in our knowledge of nature are made at once,
and almost without intellectual effort, are well calculated to raise
our hopes of the future progress of science, and, by pointing out the
simplest and most obvious combinations as those which are actually
found to be agreeable to the harmony of creation, to hold out the
cheering prospect of difficulties diminishing as we advance, instead of
thickening around us in increasing complexity.
(340.) A consequence of this immediate presentation of the law of
definite proportions in its most general form is, that its subordinate
laws--those which limit its generality in particular cases, which
diminish the number of combinations abstractly possible, and restrain
the indiscriminate mixture of elements,--remain to be discovered. Some
such limitations have, in fact, been traced to a certain extent, but by
no means so far as the importance of the subject requires; and we have
here abundant occupation for chemists for some time.
(341.) The determination of the atomic weights of the chemical
elements, like that of other standard physical data, with the utmost
exactness, is in itself a branch of enquiry not only of the greatest
importance, but of extreme difficulty. Independent of the general
reasons for desiring accuracy in this respect, there is one peculiar
to the subject. It has been suggested (by Dr. Prout), and strongly
insisted on (by Dr. Thomson), that all the numbers representing these
weights, constituting a scale of great extent, in which the extremes
already known are in proportion to each other, as 1 to upwards of 200,
are simple even multiples of the least of them. If this be really the
case, it opens views of such importance as to justify any degree of
labour and pains in the verification of the law as a purely inductive
one. But in the actual state of chemical analysis, with all deference
to such high authority, we confess it appears to us to stand in great
need of further confirmation, since it seems doubtful whether such
accuracy has yet been attained as to enable us to answer positively
for a fraction not exceeding the three or four hundredth part of the
whole quantity to be determined: at least the results of the first
experimenters, obtained with the greatest care, differ often by a
greater amount; and this degree of exactness, at least, would be
required to verify the law satisfactorily in the higher parts of the
scale.
(342.) The mere agitation of such a question, however, points out
a class of phenomena in physical science of a remote and singular
kind, and of a very high and refined order, which could never become
known but in an advanced state of science, not only practical, but
theoretical,--we mean, such as consist in observed relations among the
_data_ of physics, which show them to be quantities not _arbitrarily_
assumed, but depending on laws and causes which they may be the means
of at length disclosing. A remarkable instance of such a relation is
the curious law which Bode observed to obtain in the progression of the
magnitudes of the several planetary orbits. This law was interrupted
between Mars and Jupiter, so as to induce him to consider a planet
as wanting in that interval;--a deficiency long afterwards strangely
supplied by the discovery of _four_ new planets in that very interval,
all of whose orbits conform in dimension to the law in question, within
such moderate limits of error as may be due to causes independent of
those on which the law itself ultimately rests.[54]
(343.) Neither is it irrelevant to our subject to remark, that the
progress which has been made in this department of chemistry, and
the considerable exactness actually attainable in chemical analysis,
have been owing, in great measure, to a circumstance which might at
first have been hardly considered likely to exercise much influence
on the progress of a science,--the discovery of platina. Without the
resources placed at the ready disposal of chemists by this invaluable
metal, it is difficult to conceive that the multitude of delicate
analytical experiments which have been required to construct the fabric
of existing knowledge could have ever been performed. This, among many
such lessons, will teach us that the most important uses of natural
objects are not those which offer themselves to us most obviously. The
chief use of the moon for man’s immediate purposes remained unknown to
him for five thousand years from his creation. And, since it cannot but
be that innumerable and most important uses remain to be discovered
among the materials and objects already known to us, as well as among
those which the progress of science must hereafter disclose, we may
hence conceive a well-grounded expectation, not only of constant
increase in the physical resources of mankind, and the consequent
improvement of their condition, but of continual accessions to our
power of penetrating into the arcana of nature, and becoming acquainted
with her highest laws.
CHAP. V.
OF THE IMPONDERABLE FORMS OF MATTER.
_Heat._
(344.) One of the chief agents in chemistry, on whose proper
application and management the success of a great number of its
enquiries depends, and many of whose most important laws are disclosed
to us by phenomena of a chemical nature, is HEAT. Although some of
its effects are continually before our eyes as matters of the most
common occurrence, insomuch that there is scarcely any process in the
useful arts and manufactures which does not call for its intervention,
and although, independent of this high utility, and the proportionate
importance of a knowledge of its nature and laws, it presents in itself
a subject of the most curious speculation; yet there is scarcely
any physical agent of which we have so imperfect a knowledge, whose
intimate nature is more hidden, or whose laws are of such delicate and
difficult investigation.
(345.) The word heat generally implies the sensation which we
experience on approaching a fire; but, in the sense it carries in
physics, it denotes the cause, whatever it be, of that sensation, and
of all the other phenomena which arise on the application of fire,
or of any other heating cause. We should be greatly deceived if we
referred only to sensation as an indication of the presence of this
cause. Many of those things which excite in our organs, and especially
of those of taste, a sensation of heat, owe this property to chemical
stimulants, and not at all to their being actually _hot_. This error
of judgment has produced a corresponding confusion of language, and
hence had actually at one period[55] crept into physical philosophy
a great many illogical and absurd conclusions. Again, there are a
number of chemical agents, which, from their corroding, blackening, and
dissolving, or drying up the parts of some descriptions of bodies, and
producing on them effects not generally unlike (though intrinsically
very different from) those produced by heat, are said, in loose and
vulgar language, to burn them; and this error has even become rooted
into a prejudice, by the fact that some of these agents are capable
of becoming actually and truly _hot_ during their action on moist
substances, by reason of their combination with the water the latter
contain. Thus, quicklime and oil of vitriol both exercise a powerful
corrosive action on animal and vegetable substances, and both become
violently hot by their combination with water. They are, therefore,
set down in vulgar parlance as substances of a hot nature; whereas,
in their relations to the physical cause of heat, they agree with the
generality of bodies similarly constituted.
(346.) The nature of heat has hitherto been chiefly studied under the
general heads of--
1st, Its sources, or the phenomena which it usually accompanies.
2d, Its communication from its sources to substances capable of
receiving it, and from these to others, with a view to
discover the laws which regulate its distribution through
space or through the bodies which occupy it.
3d, Its effects, on our senses, and on the bodies to which it is
communicated in its various degrees of intensity, by which,
means are afforded us of measuring these degrees.
4th, Its intimate relations to the atoms of matter, as exhibited
in its capability of acquiring a latent state under certain
circumstances, and of entering into something like chemical
combinations.
(347.) The most obvious sources of heat are, the sun, fire, animal
life, fermentations, violent chemical actions of all kinds, friction,
percussion, lightning, or the electric discharge, in whatever manner
produced, the sudden condensation of air, and others, so numerous,
and so varied, as to show the extensive and important part it has
to perform in the economy of nature. The discoveries of chemists,
however, have referred most of these to the general head of chemical
combination. Thus, fire, or the combustion of inflammable bodies, is
nothing more than a violent chemical action attending the combination
of their ingredients with the oxygen of the air. Animal heat is, in
like manner, referable to a process bearing no remote analogy to
a slow combustion, by which a portion of carbon, an inflammable
principle existing in the blood, is united with the oxygen of the air
in respiration; and thus carried off from the system: fermentation
is nothing more than a decomposition of chemical elements loosely
united, and their re-union in a more permanent state of combination.
The analogy between the sun and terrestrial fire is so natural as to
have been chosen by Newton to exemplify the irresistible force of an
inference derived from that principle. But the nature of the sun and
the mode in which its wonderful supply of light and heat is maintained
are involved in a mystery which every discovery that has been made
either in chemistry or optics, so far from elucidating, seems only to
render more profound. Friction as a source of heat is well known: we
rub our hands to warm them, and we grease the axles of carriage-wheels
to prevent their setting fire to the wood; an accident which, in
spite of this precaution, does sometimes happen. But the effect of
friction, as a means of producing heat with little or no consumption
of materials, was not fully understood till made the subject of direct
experiment by count Rumford, whose results appear to have established
the extraordinary fact, that an unlimited supply of heat may be derived
by friction from the same materials. Condensation, whether of air by
pressure, or of metals by percussion, is another powerful source of
heat. Thus, iron may be so dexterously hammered as to become red-hot,
and the rapid condensation of a confined portion of air will set tinder
on fire.
(348.) The most violent heats known are produced by the concentration
of the solar rays by burning glasses,--by the combustion of oxygen and
hydrogen gases mixed in the exact proportion in which they combine to
produce water,--and by the discharge of a continued and copious current
of electricity through a small conductor. As these three sources of
heat are independent of each other, and each capable of being brought
into action in a very confined space, there seems no reason why they
might not all three be applied at once at the same point, by which
means, probably, effects would be produced infinitely surpassing any
hitherto witnessed.
(349.) Heat is communicated either by _radiation_ between bodies at a
distance, or by _conduction_ between bodies in contact, or between the
contiguous parts of one and the same body. The laws of the radiation
of heat have been studied with great attention, and have been found
to present strong analogies with that of light in some points, and
singular differences in others. Thus, the heat which accompanies the
sun’s rays comports itself, in all respects, like light; being subject
to similar laws of reflection, refraction, and even of polarization, as
has been shown by Berard. Yet they are not identical with each other;
Sir William Herschel having shown, by decisive experiments, verified by
those of Sir H. Englefield, that there exist in a solar beam both rays
of heat which are not luminous, and rays of light which have no heating
power.
(350.) The heat, radiated by terrestrial fires, and by bodies
_obscurely_ hot, by whatever means they have acquired their heat
(even by exposure to the sun’s rays), differs very materially from
solar heat in their power of penetrating transparent substances. This
singular and important difference was first noticed by Mariotte, and
afterwards made the subject of many curious and interesting experiments
by Scheele, who found that terrestrial heat, or that radiated from
fires or heated bodies, is intercepted and detained by glass or
other transparent bodies, while solar heat is not; and that, being
so detained, it heats them: which the latter, as it passes freely
through them, is incapable of doing. The more recent researches of
Delaroche, however, have shown that this detention is complete only
when the temperature of the source of heat is low; but that, as that
temperature is higher, a portion of the heat radiated acquires a
power of penetrating glass; and that the quantity which does so bears
continually a larger and larger proportion to the whole, as the heat
of the radiant body is more intense. This discovery is very important,
as it establishes a community of nature between solar and terrestrial
heat; while at the same time it leads us to regard the actual
temperature of the sun as far exceeding that of any earthly flame.
(351.) A variety of theories have been framed to account for these
curious phenomena; but the subject stands rather in need of further
elucidation from experiment, and is one which merits, and will probably
amply repay, the labours of those who may hereafter devote their
attention to it. The theory of the radiation of heat, in general, which
seems to agree best with the known phenomena, is that of M. Prevost,
who considers all bodies as constantly radiating out heat in all
directions, and receiving it by a similar means of communication from
others, and thus tending, in any space filled, wholly or in part, with
bodies at various temperatures, to establish an equilibrium or equality
of heat in all parts. The application of this idea to the explanation
of the phenomenon of dew we have already seen (see 167.). The laws
of such radiation, under various circumstances, have been lately
investigated in a beautiful series of experiments on the cooling of
bodies by their own radiation in vacuo, by Messrs. Dulong and Petit,
which offer some of the best examples in science of the inductive
investigation of quantitative laws.
(352.) The communication of heat between bodies in contact, or between
the different parts of the same body, is performed by a process called
conduction. It is, in fact, only a particular case of radiation, as
has been explained above (217.); but a case _so_ particular as to
require a separate and independent investigation of its laws. The most
important consideration introduced into the enquiry by this peculiarity
is that of time. The communication of heat by conduction is performed,
for the most part, with extreme slowness, while that performed by
direct radiation is probably not less rapid than the propagation
of light itself. The analysis of the delicate and difficult points
which arise in the investigation of this subject in its reduction
to direct geometrical treatment has been executed with admirable
success by the late Baron Fourrier, whose recent lamented death has
deprived science of an ornament it could ill spare, thinned as its
ranks have been within the last few years. This acute philosopher and
profound mathematician has developed, in a series of elaborate memoirs
presented to the French Institute, the laws of the communication of
heat through the interior of solid masses, placed under the influence
of any external heating and cooling causes, and has in particular
applied his results to the conditions on which the maintenance of the
actual observed temperature on the earth’s surface depends; to the
possible influence of a supposed central heat on our climates; and to
the determination of the actual amount of the heat, derived to us from
the sun, or at least that portion of it on which the difference of the
seasons depends.
(353.) The principal effects of heat are the sensations of warmth or
cold consequent on its entry or egress into or out of our bodies; the
dilatation it causes in the dimensions of all substances in which it is
accumulated; the changes of state it produces in the melting of solids,
and the conversion of them and of liquids into vapour; and the chemical
changes it performs by actual decompositions effected in the intimate
molecules of various substances, especially those of which vegetables
and animals are composed; to which we may add, the production of
electric phenomena under certain circumstances in the contact of
metals, and the developement of electric polarity in crystallised
substances.
(354.) Cold has been considered by some as a positive quality, the
effect of a cause antagonist to that of heat; but this idea seems
now (with perhaps a single exception) to be universally abandoned.
The sensation of cold is as easily explicable by the passage of heat
outwards through the surface of the body as that of heat by its ingress
from without; and the experiments cited in proof of a radiation of
cold are all perfectly explained by Prevost’s theory of reciprocal
interchange. It is remarkable, however, how very limited our means
of producing intense cold are, compared with those we possess of
effecting the accumulation of heat in bodies. This is one of the
strongest arguments adducible in favour of the doctrines of those who
maintain the possibility of exhausting the heat of a body altogether,
and leaving it in a state absolutely devoid of it. But we ought to
consider, that the known methods of generating heat chiefly turn on the
production of chemical combinations: we may easily conceive, therefore,
that, to obtain equally powerful corresponding frigorific effects, we
ought to possess the means of effecting a disunion equally extensive
and rapid between such elements, actually combined, as have already
produced heat by their union. This, however, we can only accomplish by
engaging them in combinations still more energetic, that is to say,
in which we may reasonably expect more heat to be produced by the new
combination than would be destroyed or abstracted by the proposed
decomposition. Chemistry, however, (unaided by electric agency,)
affords no means of suddenly breaking the union of two elements, and
presenting _both_ in an uncombined state. A certain analogy to such
disunion, however, and its consequences, may be traced in the sudden
expansion of condensed gases from a liquid state into vapour, which is
the most powerful source of cold known.
(355.) The dilatation of bodies by heat forms the subject of that
branch of science called pyrometry. There is no body but is capable
of being penetrated by heat, though some with greater, others with
less rapidity; and being so penetrated, all bodies (with a very few
exceptions, and those depending on very peculiar circumstances,) are
dilated by it in bulk, though with a great diversity in the amount
of dilatation produced by the same degree of heat. Of the several
forms of natural bodies, gases and vapours are observed to be most
dilatable; liquids next, and solids least of all. The dilatation of
solids has been made a subject of repeated and careful measurement by
several experimenters; among whom, Smeaton, Lavoisier, and Laplace, are
the principal. The remarkable discovery of the unequal dilatation of
crystallised bodies by Mitscherlich has already been spoken of. (266.)
That of gases and vapours was examined about the same time by Dalton
and Gay-Lussac, who both arrived independently at the conclusion of an
equal dilatability subsisting in them all, which constitutes one of the
most remarkable points in their history.
(356.) The dilatation of air by heat affords, perhaps, the most
unexceptionable means known of measuring degrees of heat. The
thermometer, as originally constructed by Cornelius Drebell, was an
air thermometer. Those now in common use measure accessions of heat
not by the degree of dilatation of air but of mercury. It has been
shown, by the researches of Dulong and Petit, that its indications
coincide exactly with that of the air-thermometer in moderate
temperatures; though at very elevated ones they exhibit a sensible,
and even considerable, deviation. By this instrument, which owes its
present convenience and utility to the happy idea of Newton, who first
thought of fixing determinate points on its scale, we are enabled
to estimate, or at least identify, the degrees of heat; and thereby
to investigate with accuracy the laws of its communication and its
other properties. Were we sure that equal additions of heat produced
equal increments of dimension in any substance, the indications of a
thermometer would afford a true and secure _measure_ of the quantity
present; but this is so far from being the case, that we are nearly in
total ignorance on this important point; a circumstance which throws
the greatest difficulty in the way of all theoretical reasoning, and
even of experimental enquiry. The laws of the dilatation of liquids, in
consequence of this deficiency of necessary preliminary knowledge, are
still involved in great obscurity, notwithstanding the pains which have
been bestowed on them by the elaborate experiments and calculations of
Gilpin, Blagden, Deluc, Dalton, Gay-Lussac, and Biot.
(357.) The most striking and important of the effects of heat consist,
however, in the liquefaction of solid substances, and the conversion of
the liquids so produced into vapour. There is no solid substance known
which, by a sufficiently intense heat, may not be melted, and finally
dissipated in vapour; and this analogy is so extensive and cogent,
that we cannot but suppose that all those bodies which are liquid
under ordinary circumstances, owe their liquidity to heat, and would
freeze or become solid if their heat could be sufficiently reduced.
In many we see this to be the case in ordinary winters; for some,
severe frosts are requisite; others freeze only with the most intense
artificial colds; and some have hitherto resisted all our endeavours;
yet the number of these last is few, and they will probably cease to be
exceptions as our means of producing cold become enlarged.
(358.) A similar analogy leads us to conclude that all aëriform
fluids are merely liquids kept in the state of vapour by heat. Many
of them have been actually condensed into the liquid state by cold
accompanied with violent pressure; and as our means of applying these
causes of condensation have improved, more and more refractory ones
have successively yielded. Hence we are fairly entitled to extend our
conclusion to those which we have not yet been able to succeed with;
and thus we are led to regard it as a general fact, that the liquid and
aëriform or vaporous states are entirely dependent on _heat_; that were
it not for this cause, there would be nothing but solids in nature; and
that, on the other hand, nothing but a sufficient intensity of heat is
requisite to destroy the cohesion of every substance, and reduce all
bodies, first to liquids, and then into vapour.
(359.) But solids, themselves, by the abstraction of heat shrink in
dimension, and at the same time become harder, and more brittle;
yielding less to pressure, and permitting less separation between
their parts by tension. These facts, coupled with the greater
compressibility of liquids, and the still greater of gases, strongly
induce us to believe that it is heat, and heat alone, which holds
the particles of all bodies at that distance from each other which
is necessary to allow of compression; which in fact gives them
their elasticity, and acts as the antagonist force to their mutual
attraction, which would otherwise draw them into actual contact, and
retain them in a state of absolute immobility and impenetrability.
Thus we learn to regard heat as one of the great maintaining powers of
the universe, and to attach to all its laws and relations a degree of
importance which may justly entitle them to the most assiduous enquiry.
(360.) It was first ascertained by Dr. Black that when heat produces
the liquefaction of a solid, or the conversion of a liquid into vapour,
the liquid or the vapour resulting is no _hotter_ than the solid or
liquid from which it was produced, though a great deal of heat has been
expended in producing this effect, and has actually entered into the
substance.
(361.) Hence he drew the conclusion that it has become _latent_, and
continues to exist in the product, maintaining it in its new state,
without increasing its temperature. He further proved, that when the
vapour condenses, or the liquid freezes, this latent heat is again
given out from it. This great discovery, with its natural and hardly
less important concomitant, that of the difference of specific heats in
different bodies, or the different quantities of heat they require to
raise their temperature equally, are the chief reasons for regarding
heat as a material substance in a more decided manner than light, with
which in its radiant state it holds so close an analogy.
(362.) The subject of latent heat has been far less attentively
studied than its great practical importance would appear to demand,
when we consider that it is to this part of physical science that the
theory of the steam-engine is mainly referable, and that material
improvements may not unreasonably be expected in that wonderful
instrument, from a more extended knowledge than we possess of the
latent heats of different vapours. This is not the case, however,
with the subject of specific heat, which was followed up immediately
after its first promulgation with diligence by Irvine; and, after a
brief interval, by Lavoisier and Laplace, as well as by our countryman
Crawfurd, who determined the specific heats of many substances, both
solid and liquid. After a considerable period of inactivity, the
subject was again resumed by Delaroche and Berard, and subsequently
by Dulong and Petit: the result of whose investigations has been the
inductive establishment of one of those simple and elegant physical
laws which carry with them, if not their own evidence, at least their
own recommendation to our belief, as being in unison with every thing
we know of the harmony of nature. The law to which we allude is
this:--that the atoms of all the simple chemical elements have exactly
the same capacity for heat, or are all equally heated or cooled by
equal accessions or abstractions of heat. It is only among laws like
this that we can expect to find a clew capable of guiding us to a
knowledge of the true nature of heat, and its relations to ponderable
matter.
_Magnetism and Electricity._
(363.) These two subjects, which had long maintained a distinct
existence, and been studied as separate branches of science, are at
length effectually blended. This is, perhaps, the most satisfactory
result which the experimental sciences have ever yet attained. All
the phenomena of magnetic polarity, attraction, and repulsion, have
at length been resolved into one general fact, that two currents of
electricity, moving in the same direction repel, and in contrary
directions attract, each other. The phenomena of the communication
of magnetism and what is called its induced state, alone remain
unaccounted for; but the interesting theory which has been developed
by M. Ampere, under the name of Electro-dynamics, holds out a hope
that this difficulty will also in its turn give way, and the whole
subject be at length completely merged, as far as the consideration of
the acting causes goes, in the more general one of electricity. This,
however, does not prevent magnetism from maintaining its separate
importance as a department of physical enquiry, having its own peculiar
laws and relations of the highest practical interest, which are capable
of being studied quite apart from all consideration of its electrical
origin. And not only so, but to study them with advantage, we must
proceed as if that origin were totally unknown, and, at least up to
a certain point, and that a considerably advanced one, conduct our
enquiries into the subject on the same inductive principles as if this
branch of physics were absolutely independent of all others.
(364.) Iron, and its oxides and alloys, were for a long time the only
substances considered susceptible of magnetism. The loadstone was
even one of the examples produced by Bacon of that class of physical
instances to which he applies the term “Instantiæ monodicæ”--_singular
instances_. And the history of magnetism affords a beautiful comment
on his remark on instances of this sort. “Nor should our enquiries,”
he observes, “into their nature be broken off, till the properties and
qualities found in such things as may be esteemed wonders in nature
are reduced and comprehended under some certain law; so that all
irregularity or singularity may be found to depend upon some common
form, and the wonder only rest in the exact differences, degrees,
or extraordinary concurrence, and not in the species itself.” The
discovery of the magnetism of nickel, which though inferior to that
of iron, is still considerable; that of cobalt, yet feebler, and
that of titanium, which is only barely perceptible, have effectually
broken down the imaginary limit between iron and the other materials
of the world, and established the existence of that general law of
continuity which it is one chief business of philosophy to trace
throughout nature. The more recent discoveries of M. Arago (mentioned
in 160.) have completed this generalization, by showing that there
is no substance but which, under proper circumstances, is capable of
exhibiting unequivocal signs of the magnetic virtue. And to obliterate
all traces of that line of separation which was once so broad, we are
now enabled, by the great discovery of Oërsted, to communicate at and
during pleasure to a coiled wire of any metal indifferently all the
properties of a magnet;--its attraction, repulsion, and polarity; and
_that_ even in a more intense degree than was previously thought to
be possible in the best natural magnets. In short, in this case, and
in this case only, perhaps, in science, have we arrived at that point
which Bacon seems to have understood by the discovery of “forms.” “The
_form_ of any nature,” says he, “is such, that where it is, the given
nature must infallibly be. The form, therefore, is perpetually present
when that nature is present; ascertains it universally, and accompanies
it every where. Again, this form is such, that when removed, the given
nature infallibly vanishes. Lastly, a true form is such as can deduce
a given nature from some essential property, which resides in many
things.”