CHAPTER LIX

CHEMISTRY OF FERMENTATION.

328. Ferments.--A large number of chemical changes are brought

about through the direct agency of bodies called ferments; their

action is called fermentation. Ferments are sometimes lifeless

chemical products found in living bodies; but in other cases they

are humble plants.

329. Yeast is one of the most common of living ferments, wild

yeast being a microscopic plant found on the ground near apple-

trees and grape-vines, and often in the air. The cultivated

variety is sold by grocers. The temperature best suited to the

rapid multiplication of the germs forming the ferment plant is 25

degrees to 35 degrees.

330. Alcoholic and Acetic Fermentation.--The changes which the

juice of the apple undergoes in forming cider and vinegar are a

good illustration of fermentation by a living plant. Apple-juice

contains sucrose. Yeast germs from the air, getting into this

unfermented liquor, cause it to "work." This process changes

sucrose to glucose, and glucose to alcohol and CO2, and is known

as alcoholic fermentation. The latter reaction, C6H12O6 = 2 C2H6O

+ 2 CO, is only partially correct, as other products are formed.

The juice has now become cider; the sugar alcohol. After a time,

if left exposed, another organism finds its way to the alcohol,

and transforms it into acetic acid, HC2H8O2, and H2O. This

process is called acetic fermentation. C2H6O + O2 = HC2H3O2 +

H2O. For this fermentation, a liquor should not have over ten per

cent of alcohol. Mother of vinegar consists of the germs that

caused the fermentation. Still a third species of ferment may

cause another action, changing acetic acid to H2O and CO2. The

vinegar then tastes flat. HC2H3O2 + 4 O = 2H2O + 2 CO2.

Some mineral acids, as H2SO4 and HCl, and some organic acids, are

regarded as lifeless ferments. To this class are thought to

belong the diastase of malt and the pepsin of the stomach. This

variety of ferments exists in the seeds of all plants, and

changes starch to glucose.

331. Bread which is raised by yeast is fermented, the object

being to produce CO2, bubbles of which, with the alcohol, cause

the dough to rise and make the bread light.

Grapes and other fruits ferment and produce wines, etc., from

which distilled liquors are obtained.

332. Lactic Fermentation changes the sugar of milk, lactose, to

lactic acid, i.e. sour milk. In canning fruit, any germs present

are killed by heating, and those from the air are excluded by

sealing the can. Milk has been kept sweet for years by boiling,

and tightly covering the receptacle with two or three folds of

cotton cloth.

333. Putrefaction is fermentation in which the products of decay

are ill-smelling. Saprophytes attack the dead matter, feed on it,

and cause it to putrefy. This action, as well as that of ordinary

fermentation, used to be attributed solely to oxygen. Germs bring

back organic matter to a more elementary state, and so have a

very important function. By some scientists, digestion is

regarded as a species of fermentation, probably due to the action

of lifeless ferments; e.g. sucrose cannot be taken into the

system, but is first fermented to glucose.

334. Most Infectious Diseases are now thought to be due to

parasites of various kinds, such as bacteria, microbes, etc.,

with which the victim often swarms, and which feed on his

tissues, multiplying with enormous rapidity. Such diseases are

small-pox, intermittent and yellow fevers, etc. Consumption, or

tuberculosis, is believed to be caused by a microbe which

destroys the lungs. In some diseases not less than fifteen

billions of the organisms are estimated to exist in a cubic inch.

These multiply so rapidly that from a single germ in forty-eight

hours may be produced nearly three hundred billions. These germs

do not spring into life spontaneously from inorganic matter, but

come from pre-existent similar forms. Parasites are not so rare

in the system even of a healthy person as is generally supposed.

They are found on our teeth and in many of the tissues of the

body.

Several infectious diseases are now warded off or rendered less

virulent by vaccination, the philosophy of which is that the

organisms are rendered less dangerous by domestication; several

crops, or generations, are grown in a prepared liquid, each less

injurious than its parent. Some of the more domesticated ones are

introduced into the system, and the person has only a modified

form of the disease, often scarcely any at all, and is for a more

or less limited time insured against further danger.

Dust particles and motes floating in the air are in part germs,

living or dead, often requiring only moisture and mild

temperature for resuscitation. Most of these are harmless.

An Introduction to Chemical Science · 第 56 / 58 章