1. SMALL LABORATORY FURNACE for crucibles, with nickel-plated burner
tubes. This takes crucibles up to 2-1/2 by 2-1/4 inches outside, and with
a three-feet chimney, as supplied with the furnace, will, it is stated,
melt copper, gold, silver, &c., in about ten minutes, or cast-iron in
thirty-five minutes from the time the gas is lighted. Small muffle
fittings, with muffles 2-1/4 by 3 by 2-1/2 inches inside, can be supplied
with this furnace.
2. SMALL CRUCIBLE FURNACE, with fixed chimney. This furnace is more
especially designed for gold, silver, copper, &c., and, as sent out with a
four-feet chimney and a single lid, is amply powerful, and practically of
a very convenient form.
3. SMALL MUFFLE FURNACE, with three feet chimney. This requires about
eighteen inches longer chimney than the small crucible furnace to obtain
the same temperature in the same time, owing to a slight loss of heat by
radiation from the stoppers.
4. _a._ LARGE MUFFLE FURNACE. This is identical in design and construction
with the smaller one. The clear working space inside the muzzle is 3-7/8
by 5 inches, by about 3 inches deep. This is recommended as a useful
furnace for watch dial enamellers, assayers, photo-enamel burning, and for
all purposes where exact temperatures are required not exceeding the
fusing point of cast iron.
The burner of this furnace is twice the size of the small laboratory
furnace, and requires a gas supply from a pipe and tap of half-an-inch
bore. The burner is the same shape as the muffle, and is unfit for
crucible work.
_b._ EXTRA LARGE MUFFLE FURNACE 4-1/2 by 3-3/4 by 7 inches clear inside
working space. This will take a No. 3 plumbago pot, and with half an inch
gas pipe, giving a supply of about 35 feet per hour, will, it is affirmed,
melt 3 or 4 lbs. of brass in about 25 minutes, and the same quantity of
cast iron in 60 or 70 minutes from the time the gas is first lighted,
without the slightest trouble or attention.
5. LADLE FURNACE. This takes ladles up to 6-1/2 inches diameter, and will
melt 6 or 8 lbs. of zinc in about 15 minutes, or the same quantity of
lead, tin, &c., in about half the time. It is said to be a convenient and
powerful arrangement for dentists, heating soldering-irons, making
granulated zinc, sand baths, &c.
6. SMALL LABORATORY FURNACE, complete for crucibles, muffles, ladles, and
sand baths.
7. FLETCHER'S INJECTOR GAS FURNACE (with Blast). This furnace is intended
for general purposes, and for the treatment of refractory substances at
high temperatures. The patentee states "that it will burn perfectly in the
same space any available gas supply from 10 to 50 feet per hour, or more,
if required, giving temperatures in exact proportion; and any operation
may be repeated at any time by taking a note of the position of the air
slide which governs the combustion of the gas."
Mr Fletcher gives the power of the small furnace as follows:--With an 1/2
inch gas supply-pipe, day pressure, starting with the furnace cold, it
will melt silver in 3 minutes, cast iron in 8 minutes, cast steel in 25
minutes.
With a supply of 50 feet per hour, the same results are stated to be
obtained in a little over half the time, and so on in proportion with a
greater or less gas supply. It is also said to work satisfactorily for
gold, &c., melting it with a supply of gas too small for any other
furnace, and the maximum temperatures obtained are limited, only by the
available gas supply and the fusibility of the casing. The highest
temperature as obtained by measuring by Wedgwoods' Pyrometer, is said to
be 9000 Fahrenheit. This furnace is stated to be particularly suited for
gold and silver melting, and refining, iron assays, and general crucible
work, and safe in the hands of the most careless workman. It is adapted
for crucibles not exceeding 4 inches by 2-1/4, 5 inches by 3-1/2, 7-1/2
inches by 5. For further information respecting furnaces intended for use
in the laboratory and assay office, the reader is referred to 'Watt's
Dictionary of Chemistry,' also to 'Ure's Dictionary of Arts, Manufactures,
and Mines,' for description of the furnaces employed in the different
metallurgical operations; and to the 'Chemical News' (June 30th, 1876, and
February 2nd, 1877), for a description of a new decomposing furnace. See
ASSAYING, CHIMNEYS, COPPER, CRUCIBLE, FUEL, &c.
=FUR'NISHING.= It is essential for the sake of neatness, and for a
pleasing effect to the eye, that there should be a harmony of colours, and
also a similarity of style, in the main articles of furniture. The tints
of the carpet, of the paper or paint of the walls, and of the
window-curtains, should be all in harmony in each room; that is, either
possess a general resemblance of colour, or various colours in pleasing
contrast and harmony with each other. If the preponderating colour of the
curtains is scarlet, and the colour of the walls or carpet blue, a most
inharmonious and unpleasing effect is produced; but brown and green, or
green and gold, will be in harmony, and may, therefore, be placed
together. Carpets being the most expensive articles, it is safest to buy
them first, and then to let their colour guide us in the tone and style of
the curtains, paper-hangings, chair-covers, hearth-rugs, and the various
minor articles. It is also economical to buy carpets of the same pattern
for several rooms, because in the event of removal to a house with
different sized apartments, a piece of one carpet may be taken to alter
the size of another.
=FUR'NITURE.= See FRENCH POLISHING, OIL, POLISH, VARNISH, &c.
=FURS.= Of these the most valuable are Ermine and Sable. Fur skins, when
unprepared, or merely dried, go under the name of 'Peltry.' (Brande.)
Furs may be preserved from moths and other insects by placing a little
colocynth pulp (bitter apple), or spice (cloves, pimento, &c.), wrapped in
muslin, among them; or they may be washed in a very weak solution of
corrosive sublimate in warm water (10 to 15 gr. to the pint), and
afterwards carefully dried. As well as every other species of clothing,
they should be kept in a clean, dry place, from which they should be taken
out occasionally, well beaten, and exposed to the air, and re-turned.
=FU'SEL-OIL.= _Syn._ FOUSEL OIL, POTATO-OIL, OIL OF POTATO SPIRIT, GRAIN
OIL, GRAIN-SPIRIT OIL, MARC-BRANDY OIL, CRUDE HYDRATED OXIDE OF AMYL.
_Source._ An offensive, strong-smelling oil, produced along with alcohol
during the fermentation of grain, potatoes, &c., on the large scale, and
which gives the peculiar and disagreeable flavour and odour to raw
whiskey. It is found chiefly in the last portion of the spirit which
passes over, called the 'faints,' to which it imparts its characteristic
odour and flavour. By rectifying the faints at a very gentle heat, most of
the alcohol and water first pass over together with only a little fusel
oil, whilst the latter forms the residuum in the still. Various names (as
_above_) are given to the crude oil thus obtained, according to its
source. In each case it essentially consists of hydrated oxide of amyl,
but trifling and variable quantities of other organic compounds are mixed
with it, which slightly modify its character, more particularly its odour
and flavour. The oil of potato spirit is the purest form of crude fusel
oil.
_Obs._ The exertions of the distiller are directed, as much as possible,
to lessen the formation of fusel oil during the fermentation of his
'worts,' and to eliminate, during the distillation and rectification of
his liquors, the greatest possible proportion of that with which they may
be contaminated.
_Prop., &c._ Fusel oil is a nearly colourless volatile liquid, with a
rather high boiling point, a durable, penetrating, offensive smell, and an
acrid, burning taste; when swallowed, it occasions nausea, giddiness,
headache, &c.; in slightly larger quantities, vomiting, delirium,
oppressive respiration, and lessened sensibility to pain; its vapour also
produces these effects. In quantity, it is a narcotic poison. The greater
intoxicating power of whiskey, more especially that from raw grain, than
other spirit, is due to the larger quantity of fusel oil which it
contains. This appears to be well known to the lower class of whiskey
drinkers in these countries, and to the consumers of corn brandy in some
of the northern parts of Europe. The last are said to frequently demand to
be served with "a glass of good fusel." In England fusel oil is chiefly
used for lamps and varnishes.
_Purific._ The AMYLIC ALCOHOL (ALCOHOL AMYLICUM) of the Dublin College is
thus prepared. Introduce the ordinary fusel oil of the distilleries into a
small still or retort, connected with a condenser, and apply heat; as soon
as the oil begins to flow over, unmixed with water, the receiver should be
changed, and the distillation resumed, and carried nearly to dryness; the
product in the second receiver, and the oily matter which separates from
the water in the first receiver, are to be reserved for use. It is
employed in the preparation of VALERIANATE OF SODA. See AMYL.
=FU'SIBLE ALLOY'.= _Syn._ FUSIBLE METAL. _Prep._ 1. Bismuth, 2 parts;
lead, 5 parts; tin, 3 parts. Melts in boiling water.
2. (D'Arcet's.) Bismuth, 8 parts; lead, 5 parts; tin, 3 parts. Melts below
212° Fahr.
3. (Walker.) Bismuth 8, tin 4, lead 5 parts; antimony, 1 part. The metals
should be repeatedly melted and poured into drops, until they are well
mixed.
4. (Onion's.) Lead, 3 parts; tin, 2 parts; bismuth, 5 parts. Melts at 197°
Fahr.
5. To the last, after removing it from the fire, add of quicksilver
(warm), 1 part. Liquid at 172°, solid at 140° Fahr.
_Obs._ The first four of the above are used to make TOY-SPOONS, to
surprise children by their melting in hot liquors. A little mercury may be
added to lower their melting points. Nos. 2 and 3 are specially adapted
for making ELECTROTYPE MOULDS. The beautiful casts of the French medals
known to all electrotypers as Clichée moulds are in the alloy No. 3. The
above alloys are also used to form PENCILS for writing on asses' skin, or
paper prepared by rubbing burnt hartshorn into it, &c.; also as a METAL
BATH in the laboratory. The last is used for ANATOMICAL INJECTIONS.
=FU'SION.= _Syn._ FUSIO, L. The liquefaction of solid bodies by the action
of heat. The term AQUEOUS FUSION has been applied to the melting of salts
in their combined water when heated; and the term IGNEOUS FUSION, to the
liquefaction of bodies by heat alone.
The vessels in which substances are fused are formed of various materials
and shapes, according to the properties of the solid operated on, and
principally with reference to the degree of heat required for its fusion.
In every case the containing vessel should be capable of sustaining the
proper degree of heat, without either melting or cracking, and should also
be unacted on by the substances melted in them. See CRUCIBLE, FURNACE, &c.
=FÜRSTENBALSAM, Bamberger für Frauen=--BAMBERG PRINCE'S BALSAM FOR WOMEN.
An embrocation for strengthening women after confinement. A hexagonal eau
de Cologne bottle containing about 100 grammes of a clear reddish-brown
fluid, which is a filtered mixture of equal parts of spirit of lavender
(Sp. Lavand. Co.) and spirit of soap, mixed with a little camphor and
ammonia. (Hager.)
=FUS'TIC.= _Syn._ FUSTIC WOOD. Two distinct dye-stuffs are known by this
name, but are distinguished by the adjectives 'old' and 'young.'
=Fustic, Old.= _Syn._ BOIS JAUNE, Fr. The wood of the _Maclura tinctoria_.
Its decoction dyes woollens yellow of different shades, according to the
'mordant.' Alum, tartar, and spirits of tin brighten the tint; acetate and
sulphate of iron and common salt darken it; with sulphate of iron it gives
olives and browns; with the indigo vat and sulphate of indigo green. These
colours are very permanent. Its yellow turns on the lemon when pale, and
on the orange when darker. 1 lb. of old fustic will dye 3 to 5 lbs. of
wool.
=Fustic, Young.= _Syn._ YELLOW FUSTIC; FUSTET, Fr. The wood of the _Rhus
Cotinus_ or Venice sumach. It gives a yellow turning on the green, but its
colours are not very permanent. It is chiefly used in combination with
other dye-stuffs.
=GAL'BANUM.= _Syn._ GUM GALBANUM; GALBANUM (B. P.), L. "A gum-resin
derived from an unascertained umbelliferous plant. In irregular tears
about the size of a pea, usually agglutinated into masses; of a
greenish-yellow colour, translucent, having a strong disagreeable odour,
and an acrid bitter taste." (B. P.) Its properties are similar to the
other fetid antispasmodic gum-resins. It ranks between ASSAF[OE]TIDA and
AMMONIACUM.
=Galbanum, Strained.= _Syn._ PREPARED GALBANUM; GALBANUM COLATUM, G.
PRÆPARATUM (Ph. L.), L. From crude galbanum, as prepared ammoniacum.
Formerly the common practice was to melt it in the dry state, by heat
cautiously and quickly applied, and to strain it through a piece of coarse
canvas stretched across a wooden frame or 'horse.' The 'strained galbanum'
of the shops is seldom pure. The following forms are current in the trade
for its 'reduction,' as this species of adulteration is technically
termed:--
1. Galbanum (true), 9 lbs.; strain as above, then add, towards the end
black resin (clean), 3 lbs.; and when the whole is melted, further add of
Venice turpentine, 2 lbs.--_Product._ 12 lbs.
2. Strained galbanum and black resin, of each 6 lbs.; melt, and add, of
strained assaf[oe]tida, 2 oz.; Venice turpentine, 3 lbs.--_Prod._ 14-1/2
lbs.
=Galbanum, Facti''tious Strained.= _Syn._ GALBANUM COLATUM FACTITIUM, L.
_Prep._ 1. From black resin, 4 lbs.; melt, and add of Venice turpentine, 2
lbs.; assaf[oe]tida, 2-1/2 oz.; oils of juniper and fennel, of each 1-1/2
dr.; water, 1/2 pint.
2. As the last, adding soft soap, 5 oz. Sometimes the small and 'waste' of
the chests are added to the above to improve them.
=GALÈNE-EINSPRITZUNG--Galen's Injection= (J. F. Schwarzlose Söhne,
Berlin). According to Hager:--Gum Arabic, 25 grammes; water, 65·5 grammes;
sugar of lead, 4·5 grammes; tinct. opii with saffron, 5 grammes. According
to Schädler:--Sulphocarbolate of zinc, 3 grammes; gum Arabic, 20 grammes;
tinct. opii, 2 grammes; water, 100 grammes.
=GALL.= _Syn._ BILE; BILIS, CHOLE, FEL, L. A bitter fluid secreted by the
liver; in part flowing into the intestines, and in part regurgitating into
the gall-bladder. Its uses in the animal economy appears to be--to
separate the chyle from the chyme, to promote digestion of oleaginous
substances, and to assist in exciting the peristaltic action of the
intestines. The fæces appear to owe their colour chiefly to the presence
of bile, since, without, they appear of a dirty pipe-clay colour.
The gall of various animals was formerly used in medicine. From whatever
source it was obtained, it was believed to be calefacient, desiccant,
detergent, discutient, and parturifacient; but besides these properties,
each variety was conceived to possess virtues peculiarly its own. Thus,
bear-gall (fel ursi) was reputed anti-epileptic; eel-gall (fel
anguillarum), parturifacient; hare-gall (fel leporis), "good in cataract;"
and ox-gall (fel bovis), "sovereign against stiff joints, rheumatics,
angry ulcers, and stomach colics." The gall of the bat, goat, hen, hog,
partridge, silurus, &c., were also employed as remedies. At the present
time ox-gall is the only one used in medicine and the arts.
Ox-gall has been recently reintroduced into medicine by Dr Allnatt and
others, and in certain cases of dyspepsia and biliary derangement appears
to be a valuable remedy.
Crude ox-gall is extensively employed by the scourers of woollen cloth,
clothes renovators, &c. It rapidly extracts grease and oil from textile
fabrics without injuring the colour. See CONSTIPATION, DYSPEPSIA, OX-GALL,
&c.
=Gall, Glass.= See SANIVER.
=GAL'LATE.= _Syn._ GALLAS. L. A salt of gallic acid. The alkaline gallates
are soluble. They rapidly suffer decomposition in the presence of excess
of the base, and the liquor gradually acquires a blackish colour. The
gallates of most of the other metallic oxides are insoluble.
=GALLEN-MIXTUR FÜR PFERDE=--GALL MIXTURE FOR HORSES (F. Barth, veterinary
surgeon, Freibach-by-Altenhofen, Carinthia). A clear decanted solution of
8 parts wood tar in 92 parts common kienöl (ol. pini). (Hager.)
=Gallen-Mixtur=--GALL MIXTURE (Ph. Barth, Marburg in Steiermark). The same
preparation as the above, coloured with 3/4 per cent. of dragon's blood.
(Wittstein.)
=Gallen-Tinctur=--GALL TINCTURE (Dr G. Krieger, Garz). 5 parts wood tar,
10 parts water, 30 parts spirit, 1 part corrosive sublimate, and 1/20 part
rosanilin, mixed with a gentle heat, allowed to deposit, and filtered.
(Hager.)
=GAL'LIC ACID.= H_{3}C_{7}H_{3}O_{5}.Aq. _Syn._ ACIDUM GALLICUM (B. P.),
L. "A crystalline acid prepared from galls." (B. P. L.) It may be also
obtained from other vegetable substances. It appears to be a product of
the oxidation of tannic acid, and probably does not exist ready formed in
recent vegetables.
_Prep._ 1. (Dumas.) Nut-galls, reduced to powder, are moistened with
water, and exposed to the action of the air, in a warm situation (say 70°
to 80° Fahr.), for two or three months, adding more water, from time to
time, to make up for that lost by evaporation. At the end of the above
period the mouldy, dark-coloured mass is strongly pressed in a cloth, and
the solid portion boiled in a considerable quantity of water. The solution
(filtered whilst hot) deposits, on cooling, crystals of gallic acid,
which, after being thoroughly drained and pressed dry between bibulous
paper, are purified by boiling them along with about 1/6th of their weight
of prepared animal charcoal in 8 parts of water, and filtering, &c., as
before.
2. (Graham.) A strong infusion or decoction of galls is precipitated with
sulphuric acid in the cold; the resulting thick mass is mixed with dilute
sulphuric acid (cold), and the liquid expressed; the 'marc' is next
treated with sulphuric acid diluted with twice its weight of water, and
after boiling the mixture for some minutes the whole is allowed to cool;
the resulting crystals are purified as before.
3. (Liebig.) A strong aqueous solution of tannic acid (tannin) is added to
sulphuric acid as long as a precipitate falls; the powder is collected,
washed, and dissolved by the aid of heat in dilute sulphuric acid; the
solution, after being boiled for a few minutes, deposits, on cooling,
crystals of gallic acid in considerable quantity.
4. (Scheele.) A filtered decoction of galls is exposed for some months in
an open vessel; after a time it grows mouldy, and becomes covered with a
thick, glutinous pellicle; in two or three months the sides of the vessel
and the under portion of the pellicle are found to be covered with small
yellow crystals of gallic acid, which are purified as directed above. (See
No. 1.)
5. (Ph. D., B. P.) The Dublin contains two formulæ for gallic acid, the
one being based on that of Dumas or Scheele, the other on that of Graham
or Liebig.--_a._ From galls (in coarse powder), 1 lb.; water, q. s. to
make a stiff paste; a porcelain dish is ordered, and the exposure in the
moistened condition is to be continued for 6 weeks; the solution of the
first crop of crystals is to be made in 10 fl. oz. of boiling water, and
when the filtrate has cooled to 80° Fahr., it is to be poured off from the
crystals which have formed, which are then to be washed with ice-cold
water, 3 fl. oz., and dried--first in blotting paper, and finally by a
steam or water heat. By boiling the undissolved portion of the galls with
45 fl. oz. of fresh water, more crystals may be obtained.
_b._ Powdered gall-nuts, 1 lb., are steeped for 24 hours in water, 1 pint,
and after being placed in a porcelain displacement apparatus, are treated
with water, 1-1/2 pint, added in successive portions; oil of vitriol, 5
fl. oz., diluted with an equal volume of water, and allowed to cool, is
now added to the percolated infusion, and after thorough admixture the
liquid is filtered from the viscid precipitate which forms; oil of
vitriol, 5 fl. oz. (diluted as before), is then added to the filtrate, the
precipitates, enveloped in calico, are submitted to powerful pressure, and
subsequently dissolved in oil of vitriol, 16 fl. oz., previously diluted
with water, 56 fl. oz.; the solution is boiled for 20 minutes, and set
aside for a week; at the end of this time the deposit which forms is
dissolved in three times its weight of boiling water, and the solution
treated as before.
_Prop._ Gallic acid forms small, feathery, and nearly colourless crystals,
which have a beautiful silky lustre; that of commerce is usually of a
pale-yellow colour; it is soluble in 100 parts of cold water, and in 3
parts of boiling water; it is also soluble in alcohol, and slightly so in
ether; the aqueous solution is decomposed by exposure to the air;
dissolved in hot oil of vitriol, it forms a deep, rich, red solution,
which, when thrown into water, drops the gallic acid, deprived of some of
its water. This substance is soluble in the alkalies, and dyes cloth like
madder. When strongly heated, gallic acid is converted into metagallic
acid, or into pyrogallic acid, according to the manner in which the heat
is applied.
_Tests._ Gallic acid is distinguished from tannic acid by not affecting
solutions of gelatin, the protosalts of iron, or the salts of the
alkaloids, and by giving a deep bluish-black precipitate with the
sesquisalts of iron, which disappears when the liquid is heated. It is
distinguished from pyrogallic acid by its inferior insolubility in water,
and by its not affecting the solutions of the protosalts of iron. To
detect gallic acid mixed with tannic acid, the latter should be removed,
either by digesting the substance in ether, or by immersing for some time
in its solution a piece of skin depilated by lime, previously to applying
the tests.
_Pur._ Free from colour; decomposed by heat; soluble in water and in
rectified spirit. It turns preparations of the sesquioxide of iron,
dissolved in water, of a bluish black colour, but throws down nothing from
a solution of isinglass.
_Uses, &c._ The principal use of pure gallic acid is in the art of
_photography_. It has recently been employed in _medicine_, as an internal
astringent, in doses of 3 to 10 gr., thrice a day, or oftener; in
hæmorrhage and fluxes, as well as for checking the night sweats in
phthisis. Dr Todd says, that in all cases of internal hæmorrhage, or
hæmorrhagic tendency, it is the best astringent or styptic we possess. As
an external astringent, it is greatly inferior to tannic acid. It has been
given in doses of 15 to 30 gr. in tape-worm, "but without any benefit."
(Pereira.)
_Purification._ Gallic acid, as obtained by either of the above forms, is
never quite pure; but it may be rendered absolutely pure by combining it
with oxide of lead, and decomposing the compound (gallate of lead) by
sulphuretted hydrogen. The sulphuret of lead acts like animal charcoal in
removing the colour. (Liebig.) Commercial gallic acid "may be rendered
nearly white by dissolving it in 20 times its weight of boiling distilled
water, and causing the solution to traverse a stratum of prepared animal
charcoal, spread upon a calico filter. When the liquid passes through
colourless, it should be evaporated to 1-6th its volume, and then suffered
to cool, in order to the separation of the crystallised acid." (Ph. D.)
=GALLIC FERMENTATION.= This name has been given to the peculiar process by
which tannic acid is converted into gallic acid, under the joint influence
of moisture and atmospheric oxygen. According to the researches of M.
Antoine Larocque, the peculiar ferment of nut-galls which operates this
change also converts sugar into alcohol and carbonic acid, in the same way
as yeast does; whilst beer yeast, muscular flesh, and caseous matter
change tannin into gallic acid. The similarity of the gallic and vinous
fermentation may hence be reasonably inferred.
=GALLIUM.= A new metal discovered in August, 1875, by means of the
spectroscope, by M. Lecoq Boisbaudran, in a specimen of blende from the
mines of Pierrefitte, in the Pyrenees. The new element was named gallium
in honour of France, the discoverer's native country.
Gallium gives a spectrum composed of two bands in the violet, one of the
bands being brilliant, and of wave length 417, and the other, a feeble one
of wave length, 403·3.
The Pierrefitte blende contains one part of gallium in four hundred
thousand. It is, however, found much more abundantly in a black blende
from Bensberg, on the Rhine, one hundred thousand parts of this latter
yielding one part of gallium.
Gallium resembles lead in appearance, but is less blue in colour. Exposed
to moist air it tarnishes slightly. It is a little harder than lead, is
flexible, malleable, and may be easily cut with a knife. If melted and
poured upon glass, it adheres to it, and forms a mirror which is whiter
than that caused by mercury. A red heat fails to volatilise it to any
appreciable extent, and it is only slightly oxidised at that temperature;
therefore it is not tarnished when exposed to the air. Hot nitric acid
dissolves it, but the cold acid has scarcely any action on it. It melts at
30·15 C. When once fused, it preserves the liquid condition even for
several months at 0° C.,[324] until it is touched by some solid body, or
by a piece of solid gallium, when it congeals to a crystalline solid,
having a specific gravity of 5·93; when fused it has a specific gravity of
6·08. It crystallises in square octohedra. In properties gallium is more
or less intermediate between the metals aluminium and indium.
[Footnote 324: In consequence of this curious property gallium was first
described as a liquid metal.]
Chemical reactions of gallium:--The following are the chief reactions of
the salts of gallium when in solution. With ammonia they give a white
gelatinous precipitate, soluble, but not readily in excess of the
precipitant; potash gives a similar precipitate, soluble in excess;
acetate of ammonia, on boiling in a solution free from excess of acid,
precipitates a basic compound; barium carbonate readily precipitates
gallium salts in the cold. A sulphate and a chloride of gallium have
already been obtained. These salts are both very soluble; the sulphate is
a non-deliquescent substance, the chloride, on the contrary, is
excessively so, and decomposed by a large excess of water. Gallium also
forms an alum consisting of the double sulphate with ammonium. Gallium
alum is a beautifully crystalline body, more soluble in cold than in hot
water.
At a meeting of the 'Academie des Sciences' in March, 1878, M. de
Baubradon stated that he had determined the atomic weight of gallium. The
mean of two experiments showed it to be 69·9.
The 'Comptes Rendus' for February, 1878 (No. 7), contains a communication
from MM. Lecoq de Boisbaudran and E. Jungfleisch, on the extraction of
gallium from the ores in which it is found associated with indium.
The following is the process given by the authors:--The blende of
Bendsberg is pulverised and then roasted in a Perret furnace, by which
treatment the greater part of the indium is volatilised. The residue is
treated with sulphuric acid in quantity sufficient to dissolve almost all
the zinc, and there is thus obtained a residue which is treated with
excess of sulphuric acid.
The persalts of iron present are then reduced by means of metallic zinc,
and the filtrate fractionally precipitated with carbonate of sodium; the
precipitates are redissolved in sulphuric acid, and the reduction with
zinc and the fractional precipitation repeated, the latter operation being
in both cases watched by the spectroscope.
The precipitate containing the gallium concentrated in a small bulk, is
redissolved in acid, and the excess of the latter reagent removed by
evaporation, after which it is boiled with much water. The filtrate
separated from the sediment containing titanic acid, which form is treated
with sulphuretted hydrogen, then mixed with acetate of ammonium and again
treated with sulphuretted hydrogen, which throws down the galliferous
sulphide of zinc free from alumina. Again the precipitate is dissolved in
sulphuric acid, and the solution fractionally precipitated with carbonate
of sodium, which operation, guided as it is by spectral examination,
entirely removes the zinc. By once more dissolving in the exactly
necessary amount of sulphuric acid, and treating with sulphuretted
hydrogen, cadmium, lead, indium and zinc are removed, and the filtrate is
then largely diluted with water and boiled. The bulky sub-salt of gallium
which separates at this temperature is treated with potash, which leaves
iron, indium, &c., undissolved, and the alkaline liquor when treated with
sulphuretted hydrogen, and subsequently with sulphuric acid to slight
acidity, yields a deposit consisting mainly of sulphide of indium.
The slightly acid liquid is then boiled with much water, and the deposit
of sub-salt of gallium thus obtained is dissolved in potash, and the
solution subjected to electrolysis, by which means a metallic deposit of
gallium is obtained.
It is interesting to note how accurately many of the chemical physical
properties to gallium had, previously to its discovery, been predicted by
the Russian chemist, Mendelejeff, by reasoning on the so-called "periodic
law," which he thus defines:--"The properties of the simple bodies, as
also the properties and constitution of their combinations, are periodic
functions of the atomic weights of the elements."
In 1864 an English chemist named Mr Newlands, observing certain relations
existing between the atomic weights of many of the elements, was the first
to arrange them in such a manner or serial form as to suggest that when
certain gaps were observed in the atomic weights of a series, new elements
might be assumed to exist. Guided by this theory, Mendelejeff affirmed
that the "periodic law" not only indicates vacancies in the classificatory
scheme of the known elements, but enables us to predict the properties of
elements as yet undiscovered, and of their compounds. Thus, of one of the
vacancies observable in the table of the elements arranged according to
his classification, Mendeljeff asserted, that should the element (which he
named _Eka aluminium_) with the corresponding atomic number be discovered,
it would possess the following characteristics:--It would most probably,
like indium and thallium, be discovered by the aid of spectrum analysis.
Gallium, as we have seen, was found by this means. The formula of its
oxide would be El_{2}O_{3}; the oxide of gallium is best represented by
Ga_{2}O_{3}.
The salts would have the general formula ElX_{3}; the salts of gallium
have most probably the general formula GaX_{3}. It will form an alum
isomorphous with common alum, this we have seen gallium does. Its salts
would be precipitable by barium carbonate; the gallium salts are thrown
down by this reagent. It would not oxidise in the air; gallium does not
tarnish upon exposure to the air. It would decompose water at a red heat;
gallium readily does this at high temperatures. Its specific gravity (and
this is very remarkable) would be about 5·9; gallium has a specific
gravity of 5·93. Its atomic weight would be about 68; that of gallium is
69·9.
The hypothetical _Eka aluminium_ of Mendelejeff appears therefore to
correspond with the gallium of Boisbaudran.
=GALLS.= _Syn._ GALL-NUTS, NUT-GALLS; GALLA (B. P.); GALLÆ (Ph. E.).
"Excrescences on _Quercus infectoria_ caused by the puncture and deposited
ova of _Diplolepis Gallæ tinctoriæ_." The best galls are blueish-black,
heavy, and not yet perforated; intensely astringent. They are imported
from Aleppo, and are known in commerce as black or blue galls (GALLÆ
NIGRÆ, G. C[OE]RULÆ). The next quality is termed, from their colour, green
galls (GALLÆ VIRIDES). Both are gathered before the insect has escaped,
and are styptic and powerfully astringent. White galls (GALLÆ ALBÆ) are
lighter, less astringent, and inferior.
_Uses, &c._ Galls are extensively employed in the art of dyeing, and
constitute one of the principal ingredients in all the shades of black,
and are also employed to fix or improve several other colours. A decoction
of galls, to which a little green copperas and gum Arabic has been added,
forms common writing ink. In _medicine_ they are used as an astringent, in
hæmorrhages and fluxes, in doses of 10 to 20 gr.; and topically, under the
form of infusion or decoction, as a gargle in relaxation of the uvula; as
an injection in gleet and leucorrh[oe]a; as a lotion or fomentation in
flabby ulcers, prolapsus ani, &c.; and as an ointment in piles, watery
ulcers, &c. The infusion or decoction is also used as an antidote to
poisoning by the alkaloids, and was formerly given as a tonic in
intermittents. See GALLIC ACID, INK, &c.
=GALL'STONE.= _Syn._ CALCULUS BILIOSUS, C. CYSTICUS BOVINUS, L. Formed in
the gall-bladder of neat cattle in winter, when they are fed upon dry
food. Used as a yellow pigment, and in medicine--_Dose_, 1 gr.; in
dyspepsia and flatulency. Man is also subject to gall-stone, the presence
or passage of which is attended with the most acute pain, frequently
accompanied with nausea and sickness. In no case should a patient
suffering from a paroxysm such as above described delay to seek immediate
medical aid. The following treatment is recommended for the benefit of
those only who, like emigrants and others, may be unable to obtain
professional assistance.
The pain and spasm should be endeavoured to be alleviated by full doses of
laudanum, given in soda water. If there be much sickness, the laudanum
should be given in the form of an enema. If the paroxysm be excessive, the
cautious inhalation of ether or chloroform should be tried. When the pain
is of long duration, leeching should be had recourse to. Ice applied
freely to the pit of the stomach has sometimes been found to give relief.
See CALCULUS.
=GALV'ANIZED IRON.= See IRON and ZINCING.
=GAM'BOGE.= _Syn._ (CAMBOGE; CAMBOGIA, L. B. P.) GAMBOGIA, L. "A gum-resin
obtained from _Garcinia Morella_." (B. P.) Gamboge is an active hydragogue
and drastic purgative, which occasionally proves useful in torpor of the
abdominal and pelvic viscera; but which is highly dangerous in an
irritable or inflammatory state of the stomach or bowels, and during
pregnancy. It is very apt to induce nausea and vomiting. In large
quantities it is a violent poison. "The deaths which have occurred from
the use of enormous quantities of Morrison's pills are mainly ascribable
to the gamboge contained in those medicines." (Pereira.)--_Dose_, 1 to 5
gr., made into pills or mixture, every 4 to 6 hours; in obstinate
constipation, in dropsies, in apoplexy and like cerebral affections, and
in worms (especially tape-worm), either alone or combined with other
cathartics. See COMPOUND EXTRACT OF COLOCYNTH.
=GAME.= The flesh of game is believed to possess strengthening qualities
superior to that of poultry. It also contains less fat. Game is tender and
easy of digestion, and it has a delicate and marked flavour. It forms a
valuable diet for the invalid, by reason of its easy digestibility.
Respecting the choice and preservation of game, Eliza Acton writes--"Buck
venison, which is in season only from June to Michaelmas, is considered
finer than doe venison, which comes into the market in October, and
remains in season through November and December; neither should be cooked
at any other part of the year.
"The greater the depth of fat upon the haunch the better the quality of
the meat will be, provided it be clear and white, and the lean of a dark
hue.
"If the cleft of the hoof, which is always left on the joint, be small and
smooth, the animal is young; but it is old when the marks are the reverse
of these.[325] Although the haunch is the prime and favourite joint of
venison, the neck and shoulder are also excellent, dressed in various
ways, and make much-approved _pasties_. A free current of air in a larder
where venison is kept is always a great advantage.
[Footnote 325: Venison is not in perfection when young.]
"All moisture should be wiped daily, or even more frequently, from the
venison with soft cloths, when any appears upon the surface, and every
precaution must be taken to keep off the flies when the venison is not
hung in a wire safe. Black pepper thickly powdered on it will generally
answer the purpose.
"Hares and rabbits are stiff when freshly killed, and if young the ears
tear easily, and the claws are smooth and sharp. A hare in cold weather
will remain good for ten or fourteen days; care only must be taken to
prevent the inside from becoming musty, which it will do if it has been
emptied in the field. Pheasants, partridges, and other game, may be chosen
by nearly the same tests as poultry--by opening the bill the staleness
will be detected easily if they have been kept too long by the hardness of
the bill. With few exceptions game depends almost entirely for the fine
flavour and the tenderness of its flesh, on the time which it is allowed
to hang before it is cooked, and it is never good when very fresh; but it
does not follow that it should be sent to table in a really offensive
state."
=Game, Hashed.= _Ingredients._--The remains of cold game, one onion stuck
with three cloves, a few whole peppers, a strip of lemon peel, salt to
taste, thickening of butter and flour, one glass of port wine, one
tablespoonful of lemon juice, one tablespoonful of ketchup, and one pint
of water or weak stock.
Proceed as follows:--Cut the remains of cold game into joints, reserve the
best pieces, and put the inferior ones and the trimmings into a stewpan
with the onion, pepper, lemon peel, salt, and water or weak stock; stew
these for about an hour, and strain the gravy; thicken it with butter and
flour; add the wine, lemon juice, and ketchup; lay in the pieces of game,
and place them by the side of the fire until they are warmed through,
avoiding boiling, otherwise the game will become too hard. Just on the
point of simmering serve, and garnish the dish with sippets of toasted
bread. _Time._ Altogether, an hour and a quarter.
[asterism] The above recipe applies to any kind of game.
If desirable, the flavour may be varied by adding flavoured vinegars,
curry powder, &c.; these, however, cover the gamey taste of the dish, and
are, therefore, not to be recommended.
=Grouse, to Roast.= _Ingredients._--Grouse, butter, a thick slice of
toasted bread. _Mode._--Let the birds hang as long as possible; pluck and
draw them; wipe (but do not wash them) inside and out, and truss them
without the head, the same as for a roast fowl. Put them down to a sharp
clear fire, keep them well basted the whole of the time they are cooking,
and serve them on buttered toast, soaked in the dripping-pan, with a
little melted butter poured over them, or with bread sauce and gravy.
_Time._ Half an hour; if liked thoroughly done, thirty-five minutes.
Seasonable from the 12th of August to the beginning of December. (Mrs
Beeton.)
=Hare, Jugged.= _Ingredients._--One hare, a bunch of sweet herbs, two
onions, each stuck with three cloves, six whole allspice, half a
teaspoonful of black pepper, a strip of lemon peel, thickening of butter
and flour, two table-spoonfuls of mushroom ketchup, quarter of a pint of
port wine. _Mode._--Wash the hare nicely, cut it up into joints (not too
large), and flour and brown them; then put them into a stewpan with the
herbs, onions, cloves, allspice, pepper, and lemon peel; cover them with
hot water, and when it boils carefully remove all the scum, and let it
simmer gently till tender, which will be in about 1-3/4 hour, or longer
should the hare be very old. Take out the pieces of hare, thicken the
gravy with flour and butter, add the ketchup and port wine, let it boil
for about ten minutes, strain it through a sieve over the hare, and serve.
A few fried forcemeat balls should be added at the moment of serving, or,
instead of frying them, they may be stewed in the gravy, about ten minutes
before the hare is wanted for use. Do not omit to serve red-currant jelly
with it. _Time._ Altogether, two hours. Seasonable from September to the
end of February. (Mrs Beeton.)
=Hare, to Roast.= _Ingredients._--Hare, forcemeat, a little milk, and
butter. To be eaten in perfection, the hare must hang for some time. After
it is skinned wash it well, and soak it for an hour in warm water to draw
out the blood. Make a forcemeat, wipe the hare dry, fill the belly with
it, and sew it up. Bring the hind and fore legs close to the body towards
the head, run a skewer through each, fix the head between the shoulders by
means of another skewer, and be careful to leave the ears on. Put a string
round the body from skewer to skewer and tie it above the back.
_Mode._--The hare should be kept at a distance from the fire when it is
first laid down. Baste it well with milk for a short time, and afterwards
with butter; and particular attention must be paid to the basting, so as
to preserve the meat on the back juicy and nutritive. When it is almost
roasted enough, flour the hare, and baste well with butter. When nicely
frothed dish it, remove the skewers, and send it to table with a little
gravy in the dish, and a tureen of the same. Red-currant jelly must be
served with it. If the liver is good it may be parboiled, minced, and
mixed with the stuffing; but it should not be used unless quite fresh.
_Time._ A middling-sized hare an hour and a quarter; a large hare one and
a half to two hours. (Mrs Beeton.)
=Partridges, to Roast.= Let the birds hang as long as they can possibly be
kept without becoming offensive; pick them carefully, draw and singe them,
wipe the insides thoroughly with a clean cloth, truss them with the head
turned under the wing and the legs drawn close together, not crossed.
Flour them when first laid to the fire, and baste them plentifully with
butter. Serve them with bread sauce and good brown gravy; a little of this
last should be poured over them. _Time._ 30 or 40 minutes. In preparing
them for the spit the crop must be removed through a slit cut in the back
of neck, the claws clipped close, and the legs held in boiling water for a
minute, that they may be skinned more easily. (Eliza Acton.)
=Pheasant, to Roast.= Let it hang as many days as possible without
becoming tainted. Pluck off the feathers carefully, cut a slit in the back
of the neck to remove crop, then draw the bird in the usual way, and
either wipe the inside very clean with a damp cloth, or pour water through
it; wipe the outside also, but with a dry cloth; cut off the toes, turn
the head of the bird _under_ the wing, with the bill laid straight along
the breast; skewer the legs, which must not be crossed; flour the pheasant
well, lay it to a brisk fire, and baste it constantly and plentifully with
well-flavoured butter. Send bread sauce and good brown gravy to table with
it. _Time._ Three quarters of an hour, a few minutes less if liked very
much underdone, five or ten more for thorough roasting, with a _good_ fire
in both instances. In season from October to the end of January. (Eliza
Acton.)
=Rabbit, to Boil.= Rabbits that are three parts grown, or, at all events,
which are still quite young, should be chosen for boiling. Wash them well,
truss them firmly, with the heads turned and skewered to the sides, drop
them into sufficient boiling water to keep them quite covered until they
are cooked, and simmer them gently from thirty to forty-five minutes; when
_very_ young they will require even less time than this. Cover them with
rich white sauce mixed with livers parboiled, finely pounded, and well
seasoned with cayenne and lemon juice; or with white onion sauce, or with
parsley and butter, made with milk or cream instead of water (the livers,
minced, are often added to the last of these), or with good mushroom
sauce. _Time._ 30 to 45 minutes. (Eliza Acton.)
=Rabbit, to Roast.= This is much improved by having the backbone taken
out. When this is done line the inside with thin slices of bacon, fill it
with forcemeat, sew it up, truss, and roast it at a clear, brisk fire, and
baste it constantly with butter. Flour it well soon after it is laid down.
Serve it with good brown gravy, and with currant jelly, when this last is
liked. _Time._ 3/4 hour to 1 hour; less if small. (Eliza Acton.)
=Venison, Haunch of, to Roast.= To prepare the venison for the spit wash
it slightly with tepid water, or merely wipe it thoroughly with damp
cloths, and dry it afterwards with clean ones; then lay over the fat side
a large sheet of thickly-buttered paper, and next a paste of flour and
water about three quarters of an inch thick; cover this again with two or
three sheets of stout paper, secure the whole well with twine, and lay the
haunch to a sound, clear fire; baste the paper immediately with butter or
clarified dripping, and roast the joint from three hours and a half to
four and a half, according to its weight and quality. Doe venison will
require half an hour less time than buck. Twenty minutes before the joint
is done remove the paste and paper, baste the meat in every part with
butter, and dredge it very lightly with flour; let it take a pale-brown
colour, and send it to table as hot as possible, with gravy in a tureen
and good currant jelly. _Time._ 3-1/2 to 4-1/2 hours. The kind of gravy
appropriate to venison is a matter on which individual taste must decide.
(Eliza Acton.)
=Venison, Hashed.= _Ingredients._--The remains of roast venison, its own
or mutton gravy, thickening of butter and flour. _Mode._--Cut the meat
from the bones in neat slices, and, if there is sufficient of its own
gravy left, put the meat into this, as it is preferable to any other.
Should there not be enough put the bones and trimmings into a stewpan with
about a pint of mutton gravy; let them stew gently for an hour, and strain
the gravy. Put a little flour and butter into the stewpan, keep stirring
until brown, then add the strained gravy, and give it a boil up; skim and
strain again, and when a little cool put in the slices of venison. Place
the stewpan by the side of the fire, and when on the point of simmering
serve. Do not allow it to boil. Send red-currant jelly to table with it.
_Time._ Altogether, an hour and a half. A small quantity of Harvey sauce,
ketchup, or port wine, may be added to enrich the gravy.
=GAN'GRENE.= See MORTIFICATION.
=GAN'TEINE.= A composition used to clean kid and other leather gloves.
_Prep._ 1. (M. Buhan.) Curd soap (in small shavings), 1 part; water, 3
parts; mix with heat, and stir in of essence of citron, 1 part.
2. (SAPONINE,--Duvignau.) Soap (in powder), 250 parts; water, 155 parts;
dissolve with heat, cool, and add, of _eau de javelle_, 165 parts,
solution of ammonia, 10 parts, and rub the whole to a smooth paste.
Patent. A small portion of either of the above is rubbed over the glove
with a piece of flannel (always in one direction), until it is
sufficiently clean. See GLOVES.
=GARAN'CINE.= See MADDER RED.
=GAR'DENING.= See HORTICULTURE.
=GAR'GLE.= _Syn._ GARGARISM, THROATWASH; GARGARISMA, GARGARISMUS,
GARGARISMUM, L. A liquid medicine applied to the back part of the mouth or
upper part of the throat. Gargles are applied by allowing a small mouthful
to run as much as possible over the affected part, by holding the head
backwards and breathing through it, by which means the liquid is agitated
and its action promoted.
Gargles are not to be swallowed. It often happens, however, that patients,
either by accident or from negligence, do swallow a certain quantity,
notwithstanding the instructions given them to the contrary. Care should
therefore be taken to avoid making gargles of such substances as may
occasion unpleasant symptoms in small doses, though they may not, perhaps,
amount to poisoning.
Gargles usually have for their basis either simple water, or milk, wine,
or vinegar, diluted with water, to which, in both cases, sugar, honey, or
syrup is generally added. Their other ingredients vary with the
indication, but must, in all cases, be either in the liquid form, or
soluble in the liquid used as the excipient.
Gargles are commonly dispensed in mixture bottles. The quantity used at a
time, under ordinary circumstances, may be about 2-3rds of a
wine-glassful.
=Gargle.= _Syn._ GARGARISMA, G. COMMUNE, G. SIMPLEX, L. _Prep._ 1. (St. B.
Hosp.) Honey or honey of roses, 1-1/2 fl. oz.; strong vinegar, 2-1/2 fl.
oz.; barley water, 1 pint.
2. (St. George's.) Oxymel, 1 fl. dr.; decoction of barley, 5 fl. dr. In
common sore throats, &c. The formulæ of several other hospitals are
similar.
=Gargle of Ac'etate of Ammo''nia.= _Syn._ GARGARISMS AMMONIÆ ACETATIS, L.
_Prep._ (Wendt.) Solution of acetate of ammonia and honey of roses, of
each 1 fl. oz.; elder-flower water, 8 fl. oz.; mix. In the ulcerated sore
throat of scarlet fever.
=Gargle of Acetate of Manganese.= _Syn._ GARGARISMA MANGANESII ACETATIS.
_Prep._ Acetate of Manganese, 1 drachm; water, 7 fluid ounces; clarified
honey, 1 oz. The chloride and sulphate of manganese are also used, about
1/2 drachm or 2 scruples to 6 oz. of barley water.
=Gargle of Ace'tic Acid.= _Syn._ OXYMEL GARGLE; GARGARISMA ACIDI ACETICI,
L. _Prep._ 1. (St. B. Hosp.) Acetic acid, 1 dr.; oxymel, 2 fl. dr.; water
to make up 4 fl. oz.
2. Barley water, 12 fl. oz.; acetic acid, 1-1/2 fl. oz.; honey, 6 dr.
Antiseptic. For sore throat.
=Gargle of Aluminium Chloride.= _Syn._ GARGARISMA ALUMINII CHLORIDI.
_Prep._ (Throat Hosp.) Solution of chloride of aluminium 12 minims, water
1 fl. oz. Astringent and antiseptic.
=Gargle of Al'um.= _Syn._ GARGARISMA ALUMINIS, L. _Prep._ 1. (Augustin.)
Oak-bark (in powder), 1 oz.; water, 1-1/2 pint; boil to a pint, filter,
cool, and add, of alum, 1/2 dr.; brandy, 2 fl. oz. In inflammation of the
mouth and throat.
2. (Cavarra.) Alum, 3 dr.; water, 6 fl. oz.; dissolve. In offensive
breath.
3. (Foy.) Alum, 1 dr.; tincture of myrrh, 2 fl. dr.; tincture of bark, 4
fl. dr.; honey of roses, 2 oz.; laudanum, 20 drops; wine, 2/3 pint. In
scurvy.
4. (Grant.) Alum, 1 oz.; tincture of myrrh, 1/2 fl. oz.; peppermint water,
7 fl. oz. In relaxation of the uvula, &c.
5. (Mid. Hosp.) Alum, 1 dr.; honey, 2 dr.; water to make 6 fl. oz. As No.
4.
6. (P. Cod.) Alum, 40 gr.; honey of roses, 1 oz.; infusion of roses, 6 fl.
oz. As the last.
7. (Ratier.) Alum, 1 oz.; infusion of red roses and barley water, of each
3 fl. oz.; honey of roses, 2 oz. As No. 4.
8. (Westm. Hosp.) Alum, 1 dr.; dilute sulphuric acid, 1 fl. dr.; treacle,
4 dr.; water to 15 fl. oz.
9. (Ph. Wirtem.) Alum and nitre, of each 3 oz.; cream of tartar, 4 oz.;
dilute acetic acid, 4 lbs.; dissolve, evaporate to dryness, and powder the
residuum. For use, 1/2 oz. of the powder is dissolved in water, 8 fl. oz.
Highly recommended in inflammation of the fauces and tonsils. This forms
Zobel's 'SPECIFIC FOR QUINSY,'
=Gargle, Antiscorbu'tic.= _Syn._ GARGARISMA ANTISCORBUTICUM, L. _Prep._
(P. Cod.) Bitter species, 1 dr.; boiling water, 8 oz.; macerate 1 hour,
strain, and add, syrup of honey, 2 oz.; antiscorbutic tincture, 1 oz.
=Gargle, Antisep'tic.= _Syn._ GARGARISMA ANTISEPTICUM, L. _Prep._ (Fr.
Hosp.) Decoction of bark, 6 oz.; camphor, 20 gr.; sal-ammoniac, 12 gr. In
putrid sore throat, &c.
=Gargle, Astrin'gent.= _Syn._ GARGARISMA ASTRINGENS, L. _Prep._ 1.
(Collier.) Tincture of galls, 2 fl. dr.; honey, 1/2 oz.; water, 6 fl. oz.
In relaxation of the uvula and fauces.
2. (Collier.) Honey, 4 dr.; tincture of myrrh, 3 dr.; powdered alum, 40
gr.; compound infusion of roses, 5-1/2 fl. oz. As the last, and in fetid
sore throat.
3. (Sir A. Cooper.) Alum, 2 dr.; decoction of bark, 12 oz.; honey of
roses, 1-1/2 oz.
4. (Dr A. T. Thomson.) Infusion of roses, 7 fl. oz.; dilute sulphuric
acid, 1 fl. dr.; tincture of catechu, 6 fl. dr.; laudanum, 1-1/2 fl. dr.
For relaxation of the uvula. See GARGLE OF ALUM.
=Gargle of Bo''rax.= _Syn._ GARGARISMA BORACIS, L. _Prep._ 1. (Ellis.)
Borax, 1 dr.; tincture of myrrh, 4 fl. dr.; clarified honey, 1 fl. oz.;
rose water, 4 fl. oz.
2. (Fr. Hosp.) Borax, 2 dr.; honey or capillaire, 1 oz.; rose water, 7 fl.
oz.
3. (Guy's Hosp.) Borax, 2 dr.; honey of roses, 1 oz.; barley water, 7 fl.
oz.
4. (Mid. Hosp.) Borax, 1 dr.; simply oxymel, 2 dr.; water to make 3 fl.
oz. The above are used in thrush or aphthous sore mouth, ptyalism, &c.
=Gargle of Bromide of Potassium.= _Syn._ GARGARISMA POTASSII BROMIDI.
_Prep._ (Throat Hosp.) Bromide of potassium, 10 grains; water, 1 fl. oz.
Sedative.
=Gargle of Cap'sicum.= _Syn._ GARGLE OF CAYENNE PEPPER; GARGARISMA
CAPSICI, L. _Prep._ 1. (Dr Griffith.) Tincture of capsicum, 1/2 fl. oz.;
rose water, 8 fl. oz.
2. (St. B. Hosp.)--_a._ Capsicum, 3 dr.; common salt, 1 oz.; boiling
water, 1 pint; macerate for 12 hours, strain, and add of distilled
vinegar, 1 pint.
_b._ Tincture of capsicum, 1 fl. dr.; compound infusion of roses, 8 fl.
oz.
3. (U. C. Hosp.) Tincture of capsicum, 1 fl. dr.; honey, 6 dr.; water to 4
fl. oz. Used in ulcerated sore throat, scarlet fever, &c.
=Gargle of Carbolic Acid.= _Syn._ GARGARISMA ACIDI CARBOLICI. _Prep._
(Throat Hosp.). Carbolic acid, 2 gr.; glycerin, 25 minims; water, 1 fluid
ounce. Stimulant and antiseptic.
=Gargle of Chlo''rate of Potas'sa.= _Syn._ GARGARISMA POTASSÆ CHLORATIS,
L. _Prep._ (Beasley.) Chlorate of potassa, 1 dr.; honey of roses, 1 oz.;
water, 7 oz. Used in malignant sore throat, scarlatina, &c.
=Gargle of Chlo''ride of Lime.= _Syn._ GARGARISMA CALCIS CHLORINATÆ, L.
_Prep._ From chloride of lime, 1 dr.; water, 1/2 pint; agitate together
for 10 minutes, filter through linen, and add of simple syrup, 1 fl. oz.
Used in putrid sore throat, scarlet fever, &c.
=Gargle of Chloride of So'da.= _Syn._ GARGARISMA SODÆ CHLORINATÆ, L.
_Prep._ 1. (Copland.) Liquor of chloride of soda, 12 fl. dr.; honey, 1/2
oz.; water, 6 fl. oz.
2. (Hosp. Form.) Chlorinated solution of soda, 4 fl. dr.; water to 4 fl.
oz. Used as the last.
=Gargle of Chlo''rine Water.= _Syn._ GARGARISMA CHLORINII, L. _Prep._ 1.
(Fr. Hosp.) Chlorine water, 1/2 fl. oz.; syrup, 1 fl. oz.; water, 4-1·2
fl. oz.
2. (Mid. Hosp.) Chlorine water, 2 fl. oz.; distilled water, 10 fl. oz.
_Use._ As the last.
=Gargle of Cincho'na Bark.= _Syn._ GARGARISMA CINCHONÆ, L. _Prep._ 1. From
decoction of cinchona, 7 fl. oz.; simple oxymel, 1 fl. oz. Antiseptic and
astringent in relaxation, &c.
2. (Acidulated; GARGARISMA CINCHONÆ ACIDUS, L.) Hydrochloric acid, 1-1/2
fl. dr.; honey, 1-1/2 oz.; decoction of bark to make up 8 fl. oz.
=Gargle, Com'mon.= _Syn._ GARGARISMA COMMUNE, L. _Prep._ 1. (Ed. Hosp.)
Water, 6 fl. oz.; nitre, 1 dr.; honey of roses, 1 oz. For ordinary sore
throat, &c.
2. (Lond. Hosp.) Alum, 1 dr.; dilute sulphuric acid, 2 fl. dr.; tincture
of myrrh, 4 fl. dr.; water to 12 fl. oz.
=Gargle of Cy'anide of Mercury.= _Syn._ GARGARISMA HYDRARGYRI CYANIDI, L.
_Prep._ 1. (Brera.) Cyanide of mercury, 10 gr.; honey of roses, 1 oz.;
barley water, 1 pint.
2. (Cullerier.) Cyanide of mercury, 10 gr.; linseed tea, 1 pint. Used in
the same cases as mercurial gargle.
=Gargle, Deter'gent.= _Syn._ GARGARISMA DETERGENS, L. _Prep._ 1. (P. Cod.)
Alcoholised sulphuric acid, 1 fl. dr.; honey of roses, 2 oz.; barley
water, 8 oz.
2. (Dr A. T. Thomson.) Nitre, 2 dr.; honey of roses, 4 fl. dr.; infusion
of roses, 5-1/2 fl. oz. In inflammatory sore throat.
=Gargle, Emol'lient.= _Syn._ GARGARISMA EMOLLIENS, L. _Prep._ 1. (Buchan.)
Marshmallow root, 1 oz.; figs, 2 oz.; water, 1 quart; boil to a pint and
strain. Demulcent, soothing.
2. (Trousseau & Reveil.) Barley water, 8 oz.; honey, 1-1/2 oz. Both are
used in inflammatory affections of the throat and mouth.
=Gargle of Horserad'ish.= _Syn._ GARGARISMA ARMORACIÆ, L. _Prep._
(Collier.) Compound spirit of horseradish, 1 fl. oz.; honey, 2 oz.; water,
4 fl. oz. A good gargle for scurvy of the fauces and pharynx, vulgarly
called the 'inward scurvy.'
=Gargle of Hydrochlo''ric Acid.= _Syn._ MURIATIC ACID GARGLE; GARGARISMA
ACIDI HYDROCHLORICI. L. _Prep._ 1. (Guy's Hosp.) Hydrochloric acid, 30
drops; honey of roses, 2 oz.; barley water, 6 fl. oz.
2. (Ratier.) Hydrochloric acid, 2 fl. dr.; clarified honey, 2 fl. oz.;
barley water, 1 pint.
3. (St. B. Hosp.) Red-rose leaves, 2 dr.; boiling water, 1 pint;
hydrochloric acid, 1-1/2 fl. dr.; digest 1 hour, and strain. In
inflammatory sore throat, ulcerations of the mouth, scarlet fever, &c.
=Gargle of I'odine.= _Syn._ GARGARISMA IODINII, L. _Prep._ 1. Iodine, 10
gr.; iodide of potassium, 12 gr.; rectified spirit and simple syrup, of
each, 1 fl. oz.; water, 5 fl. oz. In chronic enlargement of the tonsils,
in scrofulous habits.
2. (Dr Ross.) Tincture of iodine, 1-1/2 fl. dr.; tincture of opium, 1 fl.
dr.; water, 6 fl. oz.
3. (St. T. Hosp.) Compound tincture of iodine, 2 fl. dr.; water, 5 fl. oz.
In ulceration of the tonsils.
=Gargle, Mercu''rial.= _Syn._ GARGARISMA HYDRARGYRI, G. MERCURIALE, L.
_Prep._ 1. (G. HYD. BICHLORIDI.) Corrosive sublimate, 2 to 5 gr.; barley
water, 1 pint; honey of roses, 2 fl. oz. For syphilitic ulcers in the
throat.
2. (Plenck.) Calomel, 6 gr.; quicksilver, 30 gr.; powdered gum, 3 dr.;
syrup of poppies, 1/2 oz.; triturate till the globules of metal disappear,
and add of decoction of clematis, 26 fl. oz.; honey of roses, 1 oz.;
essence of myrrh, 1 dr. (or tincture of myrrh, 1 fl. oz.). In syphilitic
and putrid sore throat.
=Gargle of Mustard.= _Syn._ GARGARISMA SINAPIS. _Prep._ (Fleury). Black
mustard seed, bruised 4 ounces; salt, 4 scruples; vinegar, 8 scruples;
warm water, 7 ounces. Digest and filter.
=Gargle of Myrrh.= _Syn._ GARGARISMA MYRRHÆ, L. _Prep._ 1. (Ainslie.)
Tincture of myrrh, 6 fl. dr.; vinegar, 1 fl. dr.; honey of roses, 1-1/2
fl. oz.; barley water, 12 fl. oz.
2. (Ph. Chirur.) Tincture of myrrh, 1/2 oz.; honey of roses, 1-1/2 oz.;
lime water, 6 fl. oz. In scarlatina and putrid sore throat. See ASTRINGENT
GARGLE, &c.
=Gargle of Ni'tre.= _Syn._ GARGARISMA SALIS NITRI, G. POTASSÆ NITRATIS, L.
_Prep._ 1. Nitre, 2 dr.; honey or syrup, 1/2 oz.; rose water, 5-1/2 fl.
oz.
2. (Brande.) Nitre, 2 dr.; oxymel, 1 fl. oz.; barley water, 7 fl. oz. In
inflammatory sore throat. See COMMON GARGLE.
=Gargle of Oak-Bark.= _Syn._ GARGARISMA CORTICIS QUERCÛS, L. _Prep._ 1.
Oak-bark, 2 dr.; boiling water, 6 fl. oz.; macerate 1 hour, and strain.
2. (Ellis.) Decoction of oak-bark, 1 pint; alum, 1/2 dr.; brandy, 2 fl.
oz. In chronic sore throat, relaxation of the uvula, &c.
=Gargle of Oxide of Manganese.= _Syn._ GARGARISMA MANGANESII OXIDI.
_Prep._ (Pareira). Black oxide of manganese, 2 dr.; decoction of barley, 5
fl. oz.
=Gargle of Pel'litory.= _Syn._ GARGARISMA PYRETHRI. _Prep._ 1. Pellitory
root, 4 dr.; water, 16 fl. oz.; boil to 8 fl. oz., and add of liquor of
ammonia 2 fl. dr.
2. (Swediaur.) Infusion of pellitory, 1 pint; vinegar, 3 fl. oz.;
sal-ammoniac, 3 dr. To promote the maturation and healing of throat
ulcers.
=Gargle of Permanganate of Potash.= _Syn._ GARGARISMA POTASSÆ
PERMANGANATIS. _Prep._ (Throat Hosp.) Solution of permanganate of potash
(B. P.), 6 minims; distilled water, 1 fl. oz. Antiseptic.
=Gargle of Ro''ses.= _Syn._ GARGARISMA ROSÆ, G. ROSARUM, L. _Prep._
(Kendrick.) Conserve of roses, 3 oz.; boiling water, 16 fl. oz.; infuse 1
hour; add of dilute sulphuric acid, 2 fl. dr., and strain. Antiseptic,
astringent; used in several indications.
=Gargle of Subacetate of Lead.= _Syn._ GARGARISMA PLUMBI SUBACETATIS.
_Prep._ (Ratier.) Liquid subacetate of lead, 1/2 dr.; barley water, 1 lb.;
syrup, 1 fl. oz.
=Gargle of Turpentine.= _Syn._ GARGARISMA TEREBINTHINATUM. _Prep._
(Geddings.) Oil of turpentine, 2 dr.; mucilage, 6-1/2 fl. oz. In
salivation.
=Gargle, Spirit.= _Syn._ GARGARISMA SPIRITUOSUM, G. SPIRITÛS VINI, L.
_Prep._ 1. (Dr Watson.) French brandy, 1 fl. oz.; water, 1/4 pint.
2. (St. George's.) Proof spirit, 1 fl. oz.; oxymel, 5 fl. dr.; decoction
of barley, to make up 6 fl. oz. In relaxations and salivation.
=Gargle, Stim'ulant.= _Syn._ GARGARISMA STIMULANS, L. _Prep._ (Dr
Copland.) Infusion of roses, 6-1/2 fl. oz.; dilute hydrochloric acid, 40
drops; tincture of capsicum, 1-1/2 fl. dr.; honey, 3 dr. See GARGLE OF
CAPSICUM.
=Gargle of Tan'nin.= _Syn._ GARGARISMA ACIDI TANNICI, L. _Prep._ 1.
(Beral.) Tannin, 1 dr.; honey of roses, 2 oz.; rose water, 2 fl. oz.;
distilled water, 8 fl. oz.
2. (Jannart.) As the last, but using only half the quantity of tannin. In
salivation and aphthous ulcerations.
=Gargle of Verd'igris.= _Syn._ GARGARISMA ÆRUGINUS, G. CUPRI ACETATIS, L.
_Prep._ (Guy's Hosp.) Oxymel of verdigris, 4 dr.; honey of roses, 2 oz.;
barley water, 3-1/2 fl. oz. Used as a detergent for ulcers in the throat.
If swallowed it produces violent vomiting. The addition of 2-1/2 oz. of
water to the above produces a gargle sufficiently strong for most cases.
=Gargle of Vin'egar.= See GARGLE OF ACETIC ACID.
=Gargle of Zinc.= _Syn._ GARGARISMA ZINCI, G. Z. SULPHATIS, L. _Prep._ (Dr
Copland.) Sulphate of zinc, 20 gr.; oxymel, 1 fl. oz.; rose water, 7 fl.
oz. In aphthous sores, relaxations, ulceration of the tonsils, &c.
=GAR'LIC.= _Syn._ ALLIUM, L. The _Allium sativum_ of botanists. It is
diaphoretic, diuretic, expectorant, stimulant, and tonic; and externally,
irritant, rubefacient, and even vesicant.--_Dose_, 1/2 dr. to 1-1/2 dr.;
in enfeebled digestion, chronic diarrh[oe]a, old chronic coughs, atonic
dropsies, and worms. An antispasmodic and counter-irritant liniment is
made of the juice, which was formerly esteemed in chest diseases and
infantile convulsions. A small clove of garlic, or a few drops of the
juice, was formerly introduced into the ear in certain forms of deafness.
As a condiment its properties resemble those of the onion, than which it
is much more powerful.
=GAR'NET.= In _mineralogy_, one of the precious stones or gems. The finest
specimens of noble garnet (SYRIAN or ORIENTAL GARNET) are brought from
Pegu. According to chemical analysis, the garnet is a double silicate of
alumina and lime, coloured with iron and manganese.
=Garnet, Facti''tious.= See PASTES.
=GA'RUM.= [L.] A species of pickle or sauce prepared of fish, in a state
of incipient putrefaction, strongly salted and seasoned with aromatics.
According to Pliny, the Romans used a species of lobster for this purpose.
=GAS.= _Syn._ GAZ, Fr. A permanently elastic aëriform fluid. In English
the term 'air' is now usually restricted to the gaseous mixture forming
the atmosphere, but it was formerly used as a synonym for 'gas.' The
principal gases are the elementary bodies hydrogen, chlorine, oxygen and
nitrogen, and the compounds ammonia, carbonic acid, carbonic oxide,
carburetted hydrogen, hydrochloric acid, phosphoretted hydrogen, protoxide
of nitrogen, sulphuretted hydrogen, and sulphurous acid. See these
substances under their respective heads.
=Gas.= _Syn._ COAL GAS, ILLUMINATING G. The term 'gas' is popularly
applied to the important mixture of hydrocarbons produced by the
destructive distillation of pit-coal, and now employed as a source of
artificial light in most of large towns of Europe and America. Although
artificial illumination by means of coal-gas was, previous to 1819, used
in Great Britain in isolated cases, and had been employed for the
occasional lighting up of the mansion of Culrose Abbey in Scotland, by
Lord Dundonald, as far back as 1787; and by Murdoch, in 1798, for lighting
the foundry of Boulton and Watts in Soho, it does not appear to have been
generally adopted in London, and the other large towns of England and
Scotland until that year; since which time to the present artificial gas
illumination has steadily progressed, and increased to so enormous an
extent, that some works are now delivering millions of cubic feet of
coal-gas a day. The apparatus used in the manufacture of gas on the large
scale consists essentially of a system of closed retorts (_a_) of cast
iron or fire-clay, generally having the form of a flattened cylinder, and
arranged in sets of three or five, and heated by the same coal fire, as
shown in the accompanying drawing.
[Illustration]
The quantity of coal required to charge each retort is about two bushels,
and it takes about four hours for the coal to give off all its gas. When
it has done this the resulting coke is removed from the retort, and a
fresh charge of coal is thrown into it, the mouth of the retort being then
closed with a thick iron plate, and luted with clay. An iron pipe ascends
from the upper side of the front of the retort, projecting from the
furnace, and after describing a curve at its upper extremity, this iron
pipe opens into a much wider tube, called the _hydraulic main_ (_b_),
which latter passes horizontally along the front of the range of furnaces,
the tubes from all the retorts dipping into it. The hydraulic main is
always kept half full of the water and the tar which condenses from the
ascending gas; owing to which arrangement the opening into each retort is
effectually closed by a water-valve, and thus permits a fresh charge of
coals to be thrown in, and of coke to be withdrawn in any one or more of
the retorts, without interfering with the distillation going on in the
others.
The aqueous portion of the liquid deposited in the hydraulic main, which
is known as the _ammoniacal liquor_, and forms the principal source of the
commercial salts of ammonia, consists principally of solution of carbonate
of ammonium, but contains also sulphide, cyanide, and sulphocyanide of
ammonium. After it leaves the hydraulic main, the gas passes into the
_condenser_ (_e_), which is composed of a series of bent iron tubes (shown
in the plate), these being kept cool either by the large surface they
expose to the air, or, if necessary, by means of a stream of cold water
applied to the outside.
Any of the volatile hydrocarbons or salts of ammonia escaping condensation
in the hydraulic main are arrested in the condensers, but not always;
hence it is necessary to afterwards carry the gas through a _scrubber_
(not figured in the plate) or case containing pieces of coke, over which a
stream of water being made to trickle, absorbs any remaining ammoniacal
vapours. The gas next passes through the _lime purifier_ (_f_), an iron
box fitted with shelves, on which is placed slaked lime, which absorbs the
carbonic acid, and part, but not the whole of, the sulphuretted hydrogen
contained in the gas. Of the many methods devised for the removal of the
sulphuretted hydrogen, none appears to be so successful and economical as
that which consists in passing the gas over a mixture of sulphate of iron,
slaked lime, and sawdust.
The gas, after it has become purified by the foregoing processes, is
passed into the gasometer (_g_) (part of which is represented in the
plate), whence it passes into the mains, by which it is conveyed to the
various condensers. Another prejudicial impurity formed in gas is carbon
disulphide, which when burned gives rise to small quantities of sulphuric
acid, and this in time attacks certain kinds of furniture, as well as the
bindings of books.
Dr Angus Smith effects the removal of the disulphide by passing the gas
through a solution of plumbic oxide in caustic soda, diffused through
sawdust.
The quality of coal-gas is largely dependent upon the temperature employed
in its manufacture. If the retorts are insufficiently heated, the result
will be the formation of certain easily-condensable hydrocarbons, which
not only diminish the bulk of the gas, but cause considerable
inconvenience by collecting in and blocking up the pipes. On the contrary,
should too much heat be used, the gas becomes partially decomposed by
contact with the red-hot retort, and deposits on its sides the substance
known as "gas carbon," thus not only removing to a certain extent the
constituent to which the gas owes its illuminating power, but
impoverishing its lighting qualities still more, by diluting it with an
unnecessary quantity of liberated hydrogen. These latter effects are
forcibly illustrated in the following analysis of the gas collected from
Wigan cannel coal at different periods of the distillation.
The best gas is said to be produced when the retorts are heated to a
bright cherry red.
In 100 Volumes. 1st Hour. 5th Hour. 10th Hour.
Olefiant gas and volatile hydro-carbons 13·0 7·0 0·0
Marsh gas 82·5 56·0 20·0
Carbonic oxide 3·2 11·0 10·0
Hydrogen 0·0 21·3 60·0
Nitrogen 1·3 4·7 10·0
"The value of gas as an illuminating agent may be said to depend on the
amount of hydrocarbons present, and on the relation which the carbon bears
to the hydrogen in these substances. In marsh gas, CH_{4}, which is,
practically speaking, non-luminous, the per-centage composition is, carbon
75, and hydrogen 25. In olefiant gas, C_{2}H_{4}, the carbon is 85·7, and
the hydrogen 14·3, and the gas possesses a correspondingly greater amount
of illuminating value. In acetylene, C_{2}H_{2}, we have a gas of still
greater illuminating value, the proportion of carbon to hydrogen being
also greater, the per-centage composition being, carbon 92·3, and hydrogen
7·7. In benzol, C_{6}H_{6}, we have the same per-centages; while in
naphthalene, C_{10}H_{8}, a still higher ratio between the carbon and
hydrogen exists, and a corresponding increased value in light-giving
power. It was formerly taken as an axiom that the illuminating value of a
mixture of gases was also proportionate to the relation between the carbon
and hydrogen, but although this is very good as a rough criterion in
practice, the statement must not be accepted as strictly true. The
illuminating power of a mixture of gases is known now to depend far more
on the nature of the particular compounds present, than upon the absolute
proportion between the hydrogen and carbon; for while on the one hand it
is possible to have a gas (marsh gas) containing as much as 75·4 per cent.
of carbon, and yet which is valueless for illuminating purposes; it is
also possible to have a mixture of gases in which the per-centage of
carbon is far less, although the illuminating value is much greater."[326]
[Footnote 326: 'Chemistry, Theoretical, Practical, and
Analytical,'--Mackenzie.]
Coal gas consists of a mixture of the following bodies:
Marsh gas (light carbonetted hydrogen).
Olefiant gas (heavy " " ).
Hydrogen.
Carbonic oxide.
Nitrogen.
Vapours of liquid hydro-carbons.
Vapour of bisulphide of carbon.
The yield of gas, and also the illuminating power of the product, vary
greatly with different kinds of coal. The average yield may be roughly
estimated at 10,000 cubic feet of gas per ton of coal.[327]
[Footnote 327: For practical details respecting the manufacture of this
product, see the article COAL GAS in 'Ure's Dictionary of Arts,
Manufactures, &c.,' 'Wagner's Chemical Technology,' and 'Chemistry,
Theoretical, Practical, and Analytical.']
Anthracite is by no means suited for a gas coal. The best coals for this
purpose are those which are bituminous; they comprise caking coal, parrot
coal, and certain varieties of cannel coal. London gas (which is generally
deficient in illuminating power) is manufactured principally from Durham
and Newcastle coal.
In addition to the elementary composition of the coal, the amount and
nature of the volatile matter contained in it is an important factor in
its value as a source for gas. It should also yield a small amount of ash,
and be as free as possible from sulphur, besides which its ultimate
analysis should show a comparatively small proportion of oxygen. If there
be an excess of this latter element, the production of the hydrocarbon
illuminants will be diminished, since the hydrogen which would go to their
formation would unite with the oxygen to form useless water.
The late Charles Mansfield proposed to increase the illuminating power of
ordinary coal-gas, and to render water gas or even atmospheric air
luminiferous, by passing them through sponges or over trays containing
mineral naphtha or benzole; and a patent was taken out for this purpose.
The gas so treated imbibes or dissolves a portion of the liquid, and burns
with increased brilliancy. The method of saturating the gas with the
liquid hydrocarbon is as follows:--"The apparatus consists of a brass
reservoir or chamber attached to the end of the gas-pipe, near the burner.
This reservoir may be in the shape of an oil-flask, made air-tight, with a
screw-joint, or other means of supplying any highly volatile oil,
turpentine, or mineral naphtha, and should be kept about half full. Into
this reservoir the gas-pipe ascends a little above the surface of the oil;
a very small jet-pipe of gas, regulated by a stop-cock, is branched off
below this chamber, to supply a minute flame, so as to cause a sufficient
evaporation from the oil to unite with the gas in the flask receiver. The
whole is, of course, surmounted with the usual burner and lamp-glass."
The naphthalising of gas did not work well on a large scale. Recently,
however, an attempt was made to get up a company in England to work a
French patented process, which differed only from that of Mansfield's in
the substitution of another hydrocarbon (probably a petroleum product) for
benzol. The chemical and technical journals exposed this invention, and
prevented the sinking of capital in a worthless undertaking. On a small
scale, simple 'naphthalisers' appear to work very well.
The illuminating power of gas, as well as of other sources of light, may
be directly ascertained by what is termed the 'comparison of shadows,' or
indirectly, and more conveniently, by chemical analysis.[328] See AIR GAS,
ILLUMINATION.
[Footnote 328: See 'Watts's Dictionary of Chemistry,' vol. i.]
=GASTROPHAN= (Apotheker J. Fürst, Prague). For strengthening the digestion
and improving the appetite. Quassia, 30 grammes; orange berries, 15
grammes; galangal, 4 grammes; cardamoms, 2 grammes; star anise oil, 10
drops; orange-peel oil, 10 drops; spirit, 180 grammes; water, 120 grammes;
digested and filtered. (Hager.)
=GASTROPHILE= (Dr Borchard). There are several numbers of this
preparation. Soda water, containing common salt, perhaps in some of the
numbers mixed with Glauber's salts.
=GAZ'OGENE.= [Fr.] _Syn._ AËRATING MACHINE. A portable apparatus for
aërating water and other liquids. Many forms have been given to this
instrument, but in all the principle is the same. Powders for generating
carbonic acid gas are placed in a separate compartment, and the liquid to
be aërated in another. The two compartments are connected by a suitable
tube, and a second tube, furnished with a spring tap, affords an exit for
the aërated liquid. By the aid of the gazogene, water, wine, ale, &c., may
in a few minutes be fully saturated with carbonic acid gas, and so
rendered brisk and piquant. By using fruit syrups, manufactured from
English and foreign fruits, the most delicious aërated summer beverages
can be made, resembling those so much esteemed by travellers in the South
of Europe and the sea-board cities of the Western world.
The following are the proportions of soda and acid required for charging
gazogenes:
For 2 pints, powdered tartaric acid, 280 grains; bicarbonate of soda, 340
grains.
For 3 pints, powdered tartaric acid, 340 grains; bicarbonate of soda, 420
grains.
For 5 pints, tartaric acid, 620 grains; carbonate of soda, 760 grains.
Put the acid and soda in different coloured papers.
=GEDACHTNISS-LIMONADE--Mnemonic Lemonade= (manufactured by G. M. Raufer,
Vienna). A mixture of 15 parts phosphoric acid, 15 parts glycerin, 70
parts water. (Schädler.)
=GEHOR INSTRUMENT.= Instrument for deafness (Apotheker F. Brunner,
Troppau). A little tube of silver plate, 2 centimètres long and as thick
as a straw, with a small mussel-shaped widening at one end, which is
wrapped in cotton wool, to be inserted in the ear.
=GEHOR LIQUOR=, Schweizer--Swiss Cure for Deafness (Raudnitz). Water mixed
with a little coarse brandy. (Wittstein.)
=GEHOROL--Oil for Deafness= (C. Brockelmann, Soest). Provence oil
adulterated with sunflower oil and mixed with very small traces of camphor
and cajeput, sassafras, and rosemary oils. (Hager.)
=GEL'ATIN.= _Syn._ GELATINE; GÉLATINE, Fr.; GELATINA, L. Animal jelly,
obtained by the prolonged action of boiling water on the organic tissue of
the bones, tendons, and ligaments, the cellular tissue, the skin, and the
serous membranes. Glue and size are coarse varieties of gelatin, prepared
from hoofs, hides, skins, &c.; and isinglass is a purer kind, obtained
from the air bladders of some other membranes of fish.
_Prop., &c._ Gelatin is insoluble in cold water, but dissolves with
greater or less readiness on the application of heat, according to the
source where it is obtained, and in this state forms a tremulous and
transparent jelly on cooling; it is insoluble in both alcohol and ether,
and is decomposed by the strong alkalies and acids; with tannic acid it
forms an insoluble compound of a buff colour, which is the basis of
leather; when acted on by cold concentrated sulphuric acid, it yields
glycocoll or gelatin sugar; and when boiled with strong alkalies, it
yields glycocoll and leucine. Chlorine passed into a solution of gelatin
occasions a dense white precipitate (chlorite of gelatin), which
ultimately forms a tough, elastic, pearly mass, somewhat resembling
fibrin.
_Tests._ Its aqueous solution is recognised as follows:--1. It gelatinises
on cooling. 2. It is precipitated by alcohol. 3. Bichloride of mercury
gives a whitish flocculent precipitate. 4. Tannic acid or infusion of
galls gives a copious yellowish-white, curdy precipitate, which, on being
stirred, coheres into an elastic mass, insoluble in water, and incapable
of putrefaction, and which, when dried, assumes the appearance of
over-tanned leather. 5. The gelatinising property is destroyed by nitric
acid. 6. It is not affected by either alum or acetate of lead. In this
respect it differs from chondrin.
_Qual._ The goodness of commercial gelatin intended for food is readily
proved by pouring boiling water over it, and digesting the two together
for a short time. If it is pure and wholesome, its colour remains
unaltered, and during its solution it continues entirely free from smell.
The resulting solution and jelly are also odourless, neutral to
test-paper, free from unpleasant taste, and perfectly transparent. If it
forms a yellow gluey-looking mass, and evolves an offensive odour, it
should be rejected as of inferior quality, and unfit for culinary
purposes.
_Uses, &c._ Gelatin is largely employed as an article of food, as in
soups, jellies, &c.; but its value in this respect has been, perhaps,
overrated.[329] Animals fed exclusively on gelatin die of starvation. But
when mixed with other food, especially with substances abounding in
albumen, casein, or fibrin, gelatin may be useful as an aliment, and serve
directly to nourish the gelatinous tissues. (Liebig.) Hence gelatin is a
fitting substance to form part (but only a part) of the diet of
convalescents, as it conveys nutrition directly to these tissues, without
tasking the diminished powers of life for its conversion; but its use
should be accompanied by a proper quantity of azotised animal food to
supply the elements to the blood, for the support and increase of the
muscular tissue, or fleshy portion of the body. In France gelatin obtained
from bones is employed as a part of the diet in hospitals with the best
effect, materially abridging the period of convalescence; but when given
alone, all animals soon become disgusted with it, and die if not supplied
with other food. (D'Arcet.) See GLUE, ISINGLASS, and _below_.
[Footnote 329: The reader interested in this subject should consult a
paper by Carl Voit in the 'Zeitschrift für Biologie,' viii, 297-388.]
=Gelatin, Bone.= Obtained from crushed bones by boiling with water, or by
the action of steam and water successively, either with or without
pressure; or by maceration in dilute hydrochloric acid, to extract the
phosphate of lime, the remaining gelatinous mass being well washed in cold
water, and afterwards dissolved in boiling water in the usual manner. A
little carbonate of soda is commonly added to the last water. Gelatin has
even been extracted from fossil bones. "A soup was prepared from one of
the bones of the great mastodon by the préfet of one of the departments of
France." (Pereira.) Butchers' meat contains, on an average, 24% of dry
flesh, 56% of water, and 20% of bone. The last will yield, by proper
treatment, nearly 1-3rd of its weight of dry gelatin, or a quantity equal
to about 6% of the meat from which it is cut. This, as well as other
varieties of gelatin, is frequently blanched by sulphurous acid or animal
charcoal, and tinged of various colours with the ordinary vegetable dyes.
Thus, blue is given with sulphate of indigo or the juice of blue berries;
green, with the juice of spinach; and red, with juice of red-beet.
=Gelatin, French.= _Syn._ CAKE GELATIN. Gelatin made up into small thin
cakes, like the finer sorts of glue. A good deal of it is prepared in
Paris from the cuttings of the skins used in making kid gloves and
slippers.
=Gelatin, Patent.= Various qualities of gelatin are manufactured from glue
pieces, or cuttings of the hides of beasts and skins of calves, and from
inferior isinglass. According to Mr Nelson's specification, the crude
materials, freed from hair, wool, flesh, and fat, after being thoroughly
washed and 'scored,' are macerated for 10 days in a lye of caustic soda,
and are then placed in covered vessels at a temperature varying from 60°
to 70° Fahr., until they become tender; they are next washed to free them
from alkali, and are then exposed to the vapour of burning sulphur until
they acquire a sensibly acid reaction; they are now dissolved in water
contained in earthen vessels heated to 150° Fahr., and the solution, after
being strained, is put into 'settling vessels,' and heated to 100° to 120°
Fahr., for 8 or 9 hours; at the end of this time the clear liquor is drawn
off, and poured on the 'cooling slabs,' to the depth of about 1/2 an inch.
As soon as the jelly is cold, it is cut into pieces, and washed in water
until perfectly free from acid. It is then redissolved in water at about
85°, the solution poured out on slabs as before, and when cold, it is cut
up, and, lastly, dried on nets.
According to another specification (Rattray's Patent) glue-pieces are
steeped in water until they begin to putrefy, then washed with water,
drained, and put from 12 to 24 hours into water strongly soured with
sulphurous acid; they are afterwards washed first with cold water, and
then in water at 120° Fahr., and are lastly converted into size by
digestion for 24 hours in water at 120° Fahr., the resulting solution
being filtered through bags of double woollen-cloth.
Patent gelatins are often sold cut up in imitation of 'picked isinglass,'
to which, for the preparation of jellies, soups, and blancmanges, they are
not much inferior.
=Gelatin, Rough.= _Syn._ GELATINE BRUT, Fr. From the skulls of oxen, the
spongy insides of the horns and ribs, and from several other soft bony
parts (deprived of fat), by washing them in water, digesting in an equal
weight of hydrochloric acid of 6° Baume, in cold weather, and 4° or 5° in
summer, for 10 days, then in acid of only 1° Baume for 24 hours longer;
afterwards soaking and washing in successive portions of cold water until
all the acid is washed out, adding an ounce of carbonate of soda to the
last water. Used to make glue, &c. A similar article is prepared from the
bones of sheep. The pieces, after being treated as above, are steeped in
boiling water for a few minutes, wiped dry, and shaken together in a bag
to remove the internal pellicle; after which they are cut into squares or
dice to disguise them, and finally dipped into a hot solution of gelatin
to varnish them. In this state the article is called 'GELATINE BRUT FIN,'
Used to make soup. It keeps better than the cakes of portable soup. When
less carefully prepared, it is also used to make glue for fine work. See
BONE GELATIN.
=GELEE (pour le Goitre).= See LINIMENT OF IODIDE OF POTASSIUM.
=GELSEMIUM SEMPERVIRENS.= _Syn._ GELSEMIUM NITRIDUM, GELSEMIUM
SEMPERVIRENS, GELSEMIUM LUCIDUM, ANONYMUS SEMPERVIRENS, BIGNONIA
SEMPERVIRENS; LISANTHUS SEMPERVIRENS. The YELLOW JASMINE, or WOODBINE. The
CAROLINA JASMINE.
Different botanists have placed the plant in different natural orders. De
Candolle assigns it to the _Loganiaceæ_; Decaisne to the _Apocynaceæ_;
Chapman to the _Rubiaceæ_.
The root, which is the only part of this plant employed in medicine, and
of which a fluid extract has been introduced into the United States
Pharmacop[oe]ia, as met with in English commerce occurs in two states;
either in packets prepared by the shakers of New Lebanon, which contain
the root in small pieces, formed into a compact mass by hydraulic
pressure, and in which state it is difficult to powder; or it is simply
sold cut up into pieces varying from two to eight inches in length, and
one-third to three fourths of an inch in diameter. It is frequently mixed
with about half its bulk of long, wiry, pale-brown rootlets.
The so-called gelsemium root consists chiefly of subterranean stem with a
small proportion of true root, occasionally a slender piece of the aërial
stem may be found intermixed, and is readily distinguished by its purplish
colour and hollow centre, and by the silky and tow-like fibre, rendered
visible when the epidermis is peeled off (fig. 1 _e_).
The true root is hard and woody, slightly undulated in outline, very
sparingly branched, except in the slender pieces, externally of a pale
brown colour, nearly smooth, and furnished with a thin scurfy cuticle,
which is slightly cracked longitudinally. When a transverse section is
examined with a lens, the bark of the root is seen to be very thin, and to
consist of two layers, the inner one being usually almost as pale as the
woody portion, and of somewhat soft texture, the outer one is darker and
more compact (fig. 1 _b_, _c_).
The meditullium, or woody portion of the root occupies nearly its whole
diameter, is of a pale yellowish bright colour, the yellow tint becoming
much more distinct when the root is wetted. The medullary rays are white
and very distinct, and the woody tissue between the rays is very porous,
the pores being very small, but visible to the unaided eye, especially
when the root is broken instead of cut (fig. 1 _d_). There is no pith or
central cavity in the root. The root has a bitter taste and pleasant
flavour, somewhat between those of senega and green tea; this is more
readily perceived in the tincture.
The subterranean stem (fig. 1 _a_) is also furnished with rootlets, but is
easily distinguished from the root by the presence of a small, dark
coloured, central cavity representing the pith, and by the external
surface being rougher, and frequently variegated with dark longitudinal
lines, which are the remains of the same purplish cuticle which presents
so marked a feature in the aërial stem. The bark is thicker than that of
the true root, and the inner layer is usually dark brown. If the
subterranean stem is broken slowly and carefully, a thin row of silky
fibres projects fully a quarter of an inch from the broken edge. The
fibres do not appear when the bark of the root is broken, and thus serve
to distinguish the stem of this drug from the root. Experiments as to the
relative value of the bark of the root and stem are wanting. The bark of
the stem has the same bitter taste as that of the root, and if it be
hereafter shown that it is equally active, the above character of
scattered strong fibres, taken in conjunction with the flavour of the drug
and its porous structure, will serve to distinguish it from all other
roots and stems used in materia medica.[330]
[Footnote 330: Holmes.]
_Medicinal properties._--The American medical journals record the
successful administration of gelsemium in a great number and variety of
diseases, including intermittent, remittent, typhoid, and yellow fevers,
the irritative fevers of childhood, inflammation of the lungs and pleura,
dysentery, rheumatism, and other inflammatory affections, neuralgia,
obstinate menstruation, delirium tremens, morbid wakefulness, St. Vitus'
dance, hysteria, epilepsy, spasmodic stricture of the urethra, and
gonorrh[oe]a. Dr Hurd, an American physician, reports very favorably of
the drug as a cardiac sedative, and considers it more efficient than any
other remedy in the palpitation and the difficult breathing that accompany
heart disease; and Dr Hill, of Maine, finds it when combined with bromide
of potassium useful in irritable bladder.
[Illustration]
Its principal use, however, in American medical practice has been as a
febrifuge. In periodic fevers it has been employed with great advantage,
as well as in cases of intermittent fever, which having failed to yield to
quinine alone, succumbed, when this latter medicine was combined with
gelsemium.
In England gelsemium has been successfully employed for the relief of
facial neuralgia, or of the pain caused in the face and jaws by decayed
teeth; as well as in obscure nervous affections and severe headaches. It
is given principally in the form of tincture; but sometimes in powder in
doses of from one to two grains.
The therapeutic action of gelsemium is believed to be due to the sedative
effect it exercises on the nervous and arterial systems--hence its power
in controlling the nervous irritability so prevalent during fever. In
moderate doses it causes a sensation of agreeable langour, accompanied
with muscular relaxation; in larger doses, dizziness, dilated pupil,
double vision, general muscular debility and prostration; these symptoms
being accompanied by a diminution in the force and frequency of the pulse
as well as in the respiration. At the same time the patient becomes
insensible to pain; but is free from stupor and delirium. These symptoms
are said to pass off, after a time, and to be attended with no unpleasant
results.
The 'Lancet' as well as many of the American medical journals record
several cases of poisoning arising from giving an overdose of this drug.
The symptoms are a great prostration of nervous energy, accompanied by
paralysis of sensation and motion. When death occurs it is probably owing
to syncope. The antidotes are, first, an emetic, and after this has acted,
stimulants, such as carbonate of ammonia with brandy, or aromatic spirits
of ammonia. In cases accompanied with insensibility, recourse should be
had to electricity.
Kollock, in the 'American Journal of Pharmacy' for 1855, states that he
found the root on analysis to yield volatile oil, dry acrid resin, fatty
resin, fixed oil, gallic acid, starch, pectic acid, albumen, extractive
matter, lignin, gum, a yellow colouring matter, mineral matter (chiefly
salts of potassium, calcium, magnesium, iron and silica), and an alkaloid,
to which the name gelseminine or gelsemia has been given. Kollock also
states that the leaves and flowers contain the same ingredients as the
root, although in much smaller quantities.
Eberle, in the 'American Journal of Pharmacy' for 1864, says he failed to
obtain gelseminine from the root. In a paper contributed to the 'American
Journal of Pharmacy,' for January, 1870, by Dr Wormley, the author stated
that he said he not only succeeded in obtaining pure gelseminine from the
root, but also a peculiar acid which he calls gelseminic, or gelsemic[331]
acid; which he regards as existing in combination with the gelsemia,
forming the gelsemate of gelsemia.
[Footnote 331: Professor Sonneschien, having submitted the so-called
_Gelseminic Acid_ to analysis thinks there can be no doubt that it is
perfectly identical with æsculin, a glucoside obtained from the bark of
the horse-chesnut--the _Esculus hippocastanum_.]
Probably the alkaloid gelseminine may at some future time be introduced
into medicine, since it would appear to be the chief ingredient to which
the root owes its activity. It is strongly poisonous. Dr Wormley injected
one eighth of a grain under the skin of a large cat, which in 40 minutes
exhibited great prostration, and died in an hour and a half from the time
of the injection of the poison. The properties of the gelseminic acid, the
resin, the volatile oil, and other ingredients of the root, have not been
fully investigated. See TINCTURE OF GELSEMIUM, GELSEMININE.
In the 'American Journal of Pharmacy' for April, 1877, Dr Wormley gives
the following directions for the preparations of gelseminic acid, and
gelsemine:--A given volume of fluid extract, acidulated with acetic acid,
is slowly added with constant stirring to about eight volumes of water;
after the separated resinous matter has completely deposited, the liquid
is filtered, and the filtrate concentrated on a water bath, to something
less than the volume of fluid extract employed. The gelseminic acid is
then extracted from the concentrated fluid by ether, after which the
liquid is treated with slight excess of carbonate of sodium, and the
gelsemine extracted with ether or chloroform. For the extraction of the
first of these principles, it is not essential that the liquid should be
acidulated, but in the presence of a free acid the results are more
satisfactory.
=GEMS=. _Syn_. JEWELS; GEMMÆ, L. "Gems are precious stones, which, by
their colour, limpidity, lustre, brilliant polish, purity, and rarity, are
sought after as objects of dress and decoration. They form the principal
part of the crown jewels of kings, not only from their beauty, but because
they are supposed to comprise the greatest value in the smallest bulk; for
a diamond, no larger than a nut, or an acorn, may be the representative
sign of the territorial value of a whole country, the equivalent in
commercial exchange for a hundred fortunes, acquired by severe toils and
privations." "Among these beautiful minerals mankind have agreed in
forming a select class, to which the title of gems or jewels has been
appropriated; while the term precious stone is more particularly given to
substances which often occur under a more considerable volume than fine
stones ever do. Diamonds, sapphires, emeralds, rubies, topazes, hyacinths,
and chrysoberyls, are reckoned the most valuable gems;--crystalline
quartz, pellucid, opalescent, or of various hues, amethyst, lapis lazuli,
malachite, jasper, agate, &c., are ranked in the much more numerous and
inferior class of ornamental stones." (Ure.)
_Tests._ The only tests applicable to gems and precious stones are the
determination of their relative hardness and their specific gravity. By
the first test, pastes or factitious gems are readily detected; but beyond
this, owing to the difficulty of applying it, it ceases to be useful to
persons unconnected with the trade. The determination of the specific
gravity is, however, of more general application, as gems are generally
dismounted when offered for sale, or are so set that they may be removed
from their 'mountings' without injury or inconvenience. See SPECIFIC
GRAVITY, and _below_.
_Obs._ The relative hardness of the different substances is measured by
the power they possess of cutting or scratching the other substances
having a smaller number attached to them in the table. Thus, no gem but
the DIAMOND (20) will scratch either the RUBY (17) or the SAPPHIRE (16);
and, for the same reason, a blue stone that will cut the EMERALD or the
TOPAZ can be no other than the SAPPHIRE. The sp. gr. is ascertained in the
usual manner, and will be found sufficiently indicative of the true nature
of the stone when considered in connection with its other characteristics.
The index of refraction is a certain key to the quality of the stone, in
the hands of those who are capable of determining it, and may be applied
to either mounted or unmounted gems. The most convenient instrument for
the purpose is Wollaston's 'REFLECTING-GONIOMETER,'
=Gems, Facti''tious.= These, with few exceptions, are made of very pure,
fusible, highly transparent, and dense glass, usually termed 'PASTE' or
'STRASS,' which is generally formed of oxide of lead, potassa, and silica,
with small quantities of other ingredients to increase the brilliancy and
clearness. The characteristic tints are imparted by the addition of
metallic oxides. The beauty of artificial stones and gems depends,
chiefly, upon the tint of the real stones being exactly imitated, and upon
proper care and skill being exercised in the cutting, polishing, and
mounting them. All the coloured glasses, and enamels, may be worked up
into artificial gems.
TABLE _of the Hardness, Specific Gravity, and
Refractive Power of the principal_ GEMS _and_ PRECIOUS
STONES, _and some other_ MINERALS; _compiled expressly
for this work_.
----------------------------------------------------------------------------------
| Name. | Relative | Specific Gravity. | Index of Reflection. |
| | Hardness. | | |
---------------------------------------------------------------------------------|
| Agate | 12 | 2·6 | |
| Amethyst (occidental) | 11 | 2·7 | |
| Calcareous spar | 6 | 2·7 | |
| Chalk | 3 | 2·7 | |
| Chrysolite | 10 | 3·7 | |
| Cornelian | 11 | 2·7 | |
| Crystal | 11 | 2·6 | |
| Diamond (bluish) | 19 | 3·3 | } |
| " (cubic) | 18 | 3·2 | } |
| " (from Ormus) | 20 | 3·7 | } 2·439 |
| " (pink) | 19 | 3·4 | } |
| " (yellowish) | 19 | 3·3 | } |
| " (average colourless)| 19 to 20 | 3·3 to 3·55 | } |
| Emerald | 12 | 2·8 | |
| Fluor spar | 7 | 3·5 | 1·434 |
| Garnet | 12 | 4·4 | 1·815 |
| Glass | { } | 2·3 to 3·62 | 1·525 to 2·028 |
| " (crystal or flint) | {various} | 3·0 " 3·6 | 1·830 " 2·028 |
| " (plate) | { } | 2·5 " 2·6 | 1·514 " 1·542 |
| Gypsum | 5 | 2·3 | |
| Jasper (green) | 11 | 2·7 | |
| " (reddish yellow) | 9 | 2·6 | |
| Onyx | 12 | 2·6 | |
| Opal | 10 | 2·6 | |
| Quartz | 10 | 2·7 | 1·548 |
| Ruby | 17 | 4·2 | } 1·779 |
| " (pale, from Brazil) | 17 | 3·5 | } |
| " (spinelle) | 13 | 3·4 | 1·764 |
| Sapphire (deep blue) | 16 | 3·8 | } 1·794 |
| " (paler) | 17 | 3·8 | } |
| Sardonyx | 12 | 2·6 | |
| Schoerl | 10 | 3·6 | |
| Topaz | 15 | 4·2 | |
| " (Bohemian) | 11 | 2·8 | |
| " (whitish) | 14 | 3·5 | |
| Tourmaline | 10 | 3·0 | |
| Zeolite | 8 | 2·1 | |
| Zircon | -- | -- | 1·961 |
----------------------------------------------------------------------------------
MM. Fremy and Feil have lately succeeded in manufacturing artificial
corundum, ruby and topaz, having a composition the same as the natural
stones. The process by which they have effected this consists in fusing
together at a red heat, in the furnace of a glass works for a considerable
time, a fusible aluminate (such as aluminate of lead), and some silicious
body.
The silica is found to unite with the lead, and to liberate the alumina in
the crystalline form. When equal weights of alumina and red lead are
heated together in a crucible made of some refractory silicious substance,
the above conditions if the temperature has been maintained sufficiently
long and high ensue, and there is found in the crucible at the end of the
operation a layer of silicate of lead, and very frequently another of pure
crystallised alumina or corundum.
The ruby colour is given by adding to the mixture in the crucible two or
three per-cent. of bichromate of potash, the blue being produced by the
addition of a small quantity of oxide of cobalt, with a trace only of
bichromate of potash. A film of silicate of lead very frequently adheres
to the ruby crystals, and this has to be removed.
In some instances, however, the crystals occur nearly pure, and are
precisely similar to the natural gems in crystalline form, composition,
hardness, and lustre.
Upon being heated, the artificial ruby, like the natural one, loses its
rose colour, and recovers it again on cooling. It is said that the
factitious gems hitherto obtained are not, as a rule, equal in lustre to
the natural ones, and are consequently not so well suited for jewellers'
work; also that they do not present to the lapidary conditions favorable
to cleavage or cutting. They are, however, very well adapted for the works
of watches. See ENAMELS, PASTES, &c.
=GENE'VA.= See GIN and HOLLANDS.
=GEN'TIAN ROOT.= _Syn._ GENTINÆ RADIX, L. The dried root of _Gentiana
lutea_, or 'yellow gentian.' _Dose_, 10 to 30 gr.; as a simple bitter
tonic, and stomachic, in dyspepsia, loss of appetite, gout, &c. It was
formerly a favourite remedy in agues. "Joined with galls or tormentil, and
given in sufficient quantity, it has not failed in any intermittents in
which I have tried it." (Dr Cullen.) In excessive doses it is apt to relax
the bowels and disturb the system. When taken for some time, it imparts
its bitter flavour to the perspiration and urine. See DECOCTION, EXTRACT,
&c.
=GEN'TIANIN.= _Syn._ GENTIANINE; GENTIANINA, L. A substance obtained by
MM. Henry and Caventou from the root of common gentian.
_Prep._ 1. Gentian root (in powder) is digested for 2 or 3 days in cold
ether, with agitation, and the filtered tincture evaporated to dryness;
the residuum is dissolved in rectified spirit, and the solution is again
evaporated; the semi-crystalline mass is, lastly, redissolved in either
alcohol or ether, and crystallised by careful evaporation.
2. (Magendie.) The ethereal extract is exhausted with cold alcohol
(rectified spirit), as before, and the resulting tincture is evaporated to
dryness; the residuum is dissolved in water, calcined magnesia added in
excess, and the whole boiled and filtered; the sediment is digested in
ether, and the ethereal tincture allowed to crystallise by slow
evaporation.
_Prop., &c._ Gentianin forms golden-yellow needles, scarcely soluble in
cold water, but very soluble in alcohol and ether. It is a powerful bitter
and stomachic.--_Dose_, 1/2 gr. to 2 gr.
=GER'MAN PASTE.= _Prep._ From pea-meal, 2 lbs.; sweet almonds (blanched),
1 lb.; fresh butter or lard, 1/4 lb.; moist sugar, 5 oz.; hay saffron, 1/2
dr.; beat to a smooth paste, adding cold water q. s., granulate the mass
by passing it through a colander, and expose the product to the air in a
warm place, until quite hard and dry. The addition of 2 or 3 eggs improves
it. Used to feed larks, nightingales, and other insectivorous birds. It
will keep good for 12 months in a dry place.
=GER'MAN SILVER.= _Syn._ ALBATA, ARGENTAN, _Electrum_, NICKEL SILVER,
TUTENAG, VIRGINIAN PLATE, WHITE COPPER. A well-known alloy, the finer
varieties of which nearly equal silver in whiteness and susceptibility of
receiving a high polish, whilst they surpass it in hardness and
durability. The following formulæ are from the highest authorities, or are
the results of actual analysis of the finest commercial samples:--
_Prep._ 1. Copper, 50 parts; nickel, 20 parts; zinc, 30 parts. Very
malleable, and takes a high polish.
2. Copper, 50 parts; nickel, 26 parts; zinc, 24 parts. Closely resembles
silver; an excellent sample.