According to Payen, dried barley possesses the following composition--

Nitrogenous matter 12·96

Starch 66·43

Dextrin 10·00

Fatty matter 2·76

Cellulose 4·75

Mineral matter 3·10

------

100·00

According to Dr Ure, the sp. gr. of ENGLISH BARLEY is 1·25 to 1·33

(average, 1·235), and the weight of the husk is about 1-6th; that of BIGG,

1·227 to 1·265, and weight of husk, 2-9ths.

The analyses of the following varieties of barley, gave as the composition

of the ashes of the grains:--

---------------------------------------------------

|Unknown |Chevalier| From |Chevalier

| | Barley |Moldavia| Barley

-------------+--------+---------+--------+---------

Potash | 21·14 | 20·77 | 37·55 | 7·70

Soda | | 4·56 | 1·06 | 0·36

Lime | 1·65 | 1·48 | 1·21 | 10·36

Magnesia | 7·26 | 7·45 | 10·17 | 1·26

Sesquioxide | | | |

of iron | 2·13 | 0·51 | 1·02 | 1·46

Sulphuric | | | |

acid | 1·91 | 0·79 | 0·27 | 2·99

Silica | 30·68 | 32·73 | 24·56 | 70·77

Phosphoric | | | |

acid | 28·53 | 31·69 | 38·64 | 1·99

Chloride of | | | |

Sodium | 1·10 | | 1·47 | 1·10

---------------------------------------------------

In the 'Journal of the Agricultural Society' for 1873 is a report by

Messrs Lawes and Gilbert of twenty years' experiments with barley. The

soil of a field at Rothampstead, in which the barley had been grown for

twenty years, consisted of heavy loam, with a subsoil of clay resting on

chalk, and was previous to the barley being planted almost exhausted by

cropping. The produce was found to be greatest during the absence of

drought and sudden alterations of temperature, the rather cool but uniform

season of 1854 giving the heaviest crops. The yield from farm-yard manure

and nitrate of soda was found in dry seasons to be rather larger than that

from ammonia salts. Barley manured with phosphates was found to ripen one

to two weeks earlier than when the phosphate was omitted.

The average produce per acre of a few of the principal plots is given

below. The "ammonium salts" are stated to be a mixture of equal parts of

sulphate and chloride; the "alkali salts" consist of the sulphates of

potassium, sodium, and magnesium; the "cinerials" consist of alkali salts,

plus superphosphate:

KEY:

A: Dressed Corn.

B: Straw and Chaff.

C: Total Produce.

D: Corn to 100 Straw.

E: Weight per Bushel of Dressed Corn.

F: Produce of second 10 yrs. over or under first 10 yrs.

-----------------------------+--------+------+----+----+----+--------

Manures per Acre. | A | B | C | D | E | F

-----------------------------+--------+------+----+----+----+--------

|bushels.| cwts.|lbs.| |lbs.|per cwt.

| | | | | |

Unmanured | 20 |11-3/4|2454|86·6|52·3|- 23·6

Mixed cinerials | 27-1/2 |14-3/8|3162|96·4|53·4|- 20·2

Ammonium salts, 200 lbs. | 32-1/2 |18-1/2|3919|89·2|52·1|- 9·7

Ammonium salts, 200 lbs., and| | | | | |

alkali salts | 35 |20-3/4|4317|86·3|52·8|- 5·3

Ammonium salts, 200 lbs., and| | | | | |

superphosphate | 47 |27-5/8|5760|86·8|53·5|+ 2·7

Ammonium salts, 200 lbs., and| | | | | |

cinerials | 46-1/4 |28-1/2|5817|83·2|54·0|- ·3

Rape cake (mean 1300 lbs.) | 45-1/4 |26-7/8|5571|87·3|53·8|

Farmyard manure, 14 tons | 48-1/4 |28-1/4|5933|88·5|54·3|+ 14·8

-----------------------------+--------+------+----+----+----+--------

The authors direct attention to the results obtained by using the cinerial

manure alone, as illustrating the unsoundness of the old "mineral theory,"

according to which plants were supposed to possess a sufficient source of

nitrogen in the atmosphere. They found a greater crop yielded by barley

than wheat, when no manures were employed, as well as when cinerials were

employed, a fact which they attribute to barley being better able than

wheat to supply itself with nitrogen, notwithstanding the deeper roots of

the latter. They state that with both wheat and barley the produce is

slowly falling off under these circumstances. With ammonium salts alone,

and with nitrate of sodium alone, there is much less falling off than when

no nitrogenous manure is used. The falling off was least with the nitrate.

The nitrate gives a rather larger crop for the same amount of nitrogen

supplied, and they found this to hold when both nitrate and ammonia are

applied with cinerials. The addition of superphosphate to ammonium salts

or sodium nitrate greatly increases the produce; the further addition of

potassium, sodium, and magnesium salts they found almost without effect.

The inference was that the barley had obtained an ample supply of potash

from the natural soil, but an insufficient supply of phosphoric acid.

When ammonium salts are used alone, and the quantity of ammonia does not

exceed 50 lbs. per acre, 3·68 lbs. of ammonia will yield an average

increase of 1 bushel of corn and 63 _lbs._ of straw--total, 115 _lbs._;

the extremes in 20 years were 2·25-18·05 _lbs._ When ammonium salts are

applied with superphosphate, 2·21 _lbs._ of ammonia will produce the same

result; the extremes were 1·47-5·36 _lbs._

Silicate of sodium had been applied for eight years and a half to half the

barley plots receiving ammonia; no increase has resulted where ammonia and

superphosphate are employed; but on the other three plots an increase had

taken place, which, in the case of the plot receiving only ammonia and

alkali salts, is very considerable.

The authors think this irregular reaction seems to show that the silicate

has not produced its effect by furnishing silica to the crop, but by some

reaction upon the plant-food of the soil. The rape cake supplied much more

nitrogen than the ammonium salts, and also some phosphates and potash.

Rape cake alone gives a better return than either ammonium salts or sodium

nitrate applied alone; but when the three manures are mixed with

superphosphate, the results for equal amounts of nitrogen show the rape

cake to be decidedly inferior. From the above experiments it is inferred

that a supply of carbonaceous matter does not increase the crop of barley.

A farm-yard manure containing about 0·64 per cent. of nitrogen supplied

far more plant food than any of the other manures. On an average of

twenty years it was found that about 8 lbs. of ammonia in the form of dung

would produce a bushel of barley, with its equivalent of straw.

In all cases which were comparable it was found that barley appropriates

more of the nitrogenous manure than wheat, save with farmyard manure. A

large amount of nitrogen applied by manure is not taken up by the crop.

Experiments in the barley field proved that large residues from ammonium

salts and sodium nitrate show a small but distinct effect upon succeeding

crops, the influence extending over many years. From an examination of the

drainage waters from lands dressed with the nitrates of ammonium and

sodium, the authors conclude that ammonium salts, as well as sodium

nitrate, will be more economically applied in the spring than in the

winter. Manures containing organic nitrogen are clearly not so liable to

loss from drainage.

Experiments were made on the growth of barley after turnips, and also in

an ordinary four-course rotation. After growing turnips ten years

consecutively with purely cinerial manures, and carting off the produce,

the yield of barley was much smaller than in the experimental field, where

barley was grown after barley. The turnips, though very small crops, had

exhausted the soil of nitrogen to a greater extent than corn crops would

have done. On one plot where rape cake had been applied to the turnips,

the produce of barley was 8-1/4 bushels more than when none had been used.

In the rotation experiments barley was grown after turnips (carted off),

and was followed by beans and wheat. In one series all the crops were

unmanured; in another the turnips received superphosphate; in a third the

turnips received an abundant cinerial and nitrogenous manure.

The mean produce of the six crops of barley obtained in twenty-four years

of rotation was as follows:

------------------------------------------------

|Dressed | Straw and

Character of Rotation. | Corn. | Chaff.

--------------------------+---------+-----------

| bushels.| cwt.

Unmanured continuously | 38-3/8 | 21-3/4

Superphosphate for turnips| |

only | 29-3/8 | 16-1/2

Mixed manure for turnips | |

only | 44-3/8 | 25-1/4

--------------------------+---------+-----------

Mean produce of unmanured |} |

barley in barley |} 21-1/2 | 12-1/8

field during the same |} |

season |} |

------------------------------------------------

The unmanured turnips were so very small in quantity, that the barley in

the first series was practically grown after a fallow; this barley,

however, was a much larger crop than that grown after turnips manured with

superphosphate only, the available nitrogen of the soil in this case being

exhausted by the turnips.

In the last series the residue of the abundant manure applied to the

turnip crop suffices to produce a good crop of barley.

_Qual., Uses, &c._ Its employment and value as food, and in the

manufacture of malt, are well known. It forms good wholesome bread well

adapted for persons who live luxuriously; but which, for the abstemious

and the delicate, is inferior to that made of wheat, as it is rather less

nutritious, and less easy of digestion, and commonly proves laxative to

those unaccustomed to its use. Barley-flour and barley-meal are also more

perishable than wheat-flour; being very apt to acquire a hot nauseous

taste, which even the heat of the oven does not remove. In a medical point

of view, barley is regarded as the mildest and least irritating of the

cereals. It has always been in high estimation as a demulcent and

emollient. The decoction (BAR'LEY-WATER), made with pearl barley, is a

common and useful drink in inflammatory diseases, particularly in those of

the chest and urinary organs. Among the Ancients, decoctions of barley

([Greek: krathê]) were the principal aliments and medicines employed in

acute diseases.

Barley was extensively cultivated by the Romans and many other nations of

antiquity, as well as by the ancient inhabitants of Gaul. The Greeks are

said to have trained their athletes on it.

The best tests of the genuineness of barley are its colour, freedom from

dust, grit, and insects. The microscope will lead to the detection of any

cheaper grains if mixed with it. It is rarely adulterated, although it is

said to be extensively used for the purpose of sophisticating wheat,

annatto, and roll liquorice.

[Illustration: Barley Starch.]

=Barley, Cau'stic.= Sabadilla.

=Barley, Pat'ent.= _Syn._ FARI'NA HOR'DEI, L. Pearl barley reduced to fine

powder by grinding in a mill.

=Barley, Pearl.= _Syn._ PEARL'ED BARLEY*; HOR'DEUM DECORTICATUM (B. P.),

L.; ORGE PERLÉ, Fr.; PERLENGRAUPEN, Ger. The seeds of _hordeum distichon_

deprived of the husks. That of commerce is usually made by steaming

spring-barley, to soften the skin, then drying it, and grinding it in a

mill with the stones set wide apart, so as to round and polish the grains,

and to separate the whole of the husk except that left in the furrow of

the seed. SCOTCH PEARL-BARLEY and FRENCH BARLEY resemble the last, but are

smaller, being generally made from winter-barley or bigg. FARO DE ORZO is

another variety made from sprat-barley. See BARLEY (_above_).

=Barley, Scotch.= _Syn._ HULLED BARLEY[double-dagger],

POT-B.[double-dagger]; HOR'DEUM MUNDA'TUM, L.; ORGE MONDÉ, Fr.;

GERSTENGRAUPEN, GRAUPEN, Ger. The grains deprived of the husk by a mill,

as noticed above, but less completely, and without rounding them.

=BAR'LEY SUGAR.= See CONFECTIONERY, and SUGAR.

=BARM.= See YEAST.

=BAROM'ETER= (_baros_, weight; _metron_, measure). _Syn._

WEATHER-GLASS[double-dagger]; BAROM'ETRUM, L.; BAROMÈTRE, Fr.; BAROMETER,

WETTERGLAS, Ger. An instrument for measuring the weight or pressure of the

atmosphere. It was invented by Torricelli, of Florence, A.D. 1643.

The barometer is made of several forms, but the principle of its

construction, with the exception of the aneroid barometer, is the same in

each, and essentially consists of a column of fluid (usually mercury)

supported in vacuo, in a glass tube, by the pressure of the atmosphere on

its surface. The annexed figures exhibit the principal varieties at

present known; several of which have been proposed with the view of

improving the original instrument, either by increasing its range, or its

portability. None, however, equal in simplicity, cheapness, and

usefulness, the old forms proposed by Torricelli, and represented by the

figs. 1 & 2. To avoid confusion, the graduated scales and cases of the

instruments are not shown.

[Illustration:

1. Torricelli's cistern barometer.

2. " syphon "

3. Huygen's barometer.

4. " " modified.

5. Wheel barometer.

6. Bernoulli's syphon barometer.

7. Aminton's conical "

8. Gay Lussac's "

9. " " " modified by M. Bunten.

_a_, Tube containing a column of mercury.

_b_, Mercurial cistern.

_c_, A column of mercury supporting another of water, _d_.

_e_, _e_, Weights, one of which floats on the surface of the mercury,

and by means of the cord _f_ moves the index _g_.

_h_, Graduated dial.

_k_, Capillary hole drilled laterally to admit air.]

The construction of a barometer requires the utmost skill and care of a

practised artist, and will therefore be seldom undertaken by the amateur

or experimentalist--a fact which renders it unnecessary for us to enter

into the details here. In the choice of his instrument the purchaser must

greatly depend on the known experience and integrity of the manufacturer;

as nothing but lengthened use, and frequent comparisons with other

instruments, can possibly prove its excellence. An ordinary barometer,

however carefully made, is found to suffer gradual deterioration, from the

external air insinuating itself between the mercury and the glass tube, by

which the perfection of the vacuum is destroyed. Various plans have been

proposed to remedy this inconvenience and source of error. Prof. Daniell

forms the bottom part of the tube, to the extent of about 1/3rd of an

inch, of solid platinum, welded to the glass. This plan has proved

completely satisfactory. Dr Ure proposes the use of platinum-foil for the

same purpose. Before purchasing an instrument it is as well to ascertain

that this has been done. In those called 'STANDARD BAROMETERS' the scale

is movable and adjustable by a delicate screw, so as to enable the

observer to bring the lower point or zero (0) of the scale coincident with

the surface of the mercury in the cistern. Exact contact is readily

effected by making the point, and its image as seen by reflection from the

surface of the mercury, to coincide. In this case the cistern is made of

glass. Provided the ivory scale be connected with the zero-point with a

strip of brass, correction as to temperature is very nearly effected by

this simple adjustment. The WHEEL-BAROMETER is chiefly serviceable as a

domestic or land weather-glass.

Of the many forms of mercurial barometer, that perhaps known as Fortin's

is the best. In this instrument the cistern and the lower portion of the

tubes is shown in the annexed figure.

[Illustration]

[Illustration]

"The cistern is made of boxwood, with a movable leather bottom _b b_, and

a glass cylinder, _b_, is inserted into it above, all except the glass

being encased in brass. In the bottom of the brass box a screw, C, works

on the upper end of which the leather rests, so that by elevating or

depressing this screw, the bottom of the cistern, and with it the cistern

level of the mercury, can also be raised or depressed at pleasure. A small

ivory pin, _p_, ending in a point is fixed to the upper frame of the

cistern, and when an observation is made, the surface of the mercury is

made to coincide with the point of the pin as the standard level from

which the barometric column is to be measured. The tube of the barometer,

the upper part of which is shown in the lower figure, is enclosed in one

of brass, which has two directly opposite slits in it for showing the

height of the column, and on the sides of these the graduation is marked.

A brass collar, _d, d_, slides upon the tube with a vernier, _v, v_,

marked on it for reading the height with the greatest exactness and in

which two oblong holes are cut, a little wider than the slits in the brass

tube. When a reading is taken the collar is so placed that the last streak

of light is cut off by the two upper edges of the holes or until they form

a tangent to the convex mercurial curve. By this means the observer is

sure that his eye is on a level with the top of the column and that the

reading is taken exactly for this point. Fortin's barometer is generally

arranged so as to be portable, in which case the screw, _c_, is sent in

until the mercury fills the whole cistern, by which the air is kept from

entering the tube during transport, the leather yielding sufficiently at

the same time to allow for expansion for increase of temperature. It packs

in a case which serves as a tripod when the instrument is mounted for use.

On this tripod it is suspended about the middle, swinging upon two axles

at right angles to each other, so that the cistern may act the part of a

plummet, in keeping the tube vertical--the position essential to all

measurements."[107]

[Footnote 107: Chambers's 'Encyclopædia.']

_How to Manage a Barometer._--It is of the first importance to have the

instrument hung perfectly perpendicular. This is best effected by means of

a plummet line. It should be placed in a good light, but protected from

direct sunlight and also from rain. If air should accidentally find its

way into a common cistern barometer, it may be got rid of by first fixing

the ivory piston, so as to prevent the escape of the mercury, then by

means of the screw raising the mercurial column nearly to the top of the

tube, then by slowly inverting the instrument and tapping the cistern

gently, the air may then perhaps ascend to the cistern and thus escape. In

transporting a barometer from place to place it is best to carry it by

hand; and if packed it is almost needless to say that the float must be

firmly fixed and the mercurial column raised by means of the screw, so as

to prevent any escape of the metal.

_Reading the Barometer._--The mercury in the cistern must first be brought

by means of the screw to the 'zero,' and then the vernier must be screwed

up so that its horizontal edge forms a tangent to the mercurial curve. The

vernier is an instrument for reading off the graduated scale of the

barometer correctly to 1/100th or 1/500th of an inch.

Buchan gives the following description of the vernier and of the method of

using it: "It consists (see figures _a_ and _b_) of a piece similar to the

scale of the barometer along which it slides. It will be observed from

figure _a_ that ten divisions of the vernier are exactly equal to eleven

divisions of the scale, that is, to eleven tenths of an inch. Hence each

division of the vernier is equal to a tenth of an inch, together with a

tenth of a tenth, or a hundredth, or to ten hundredths, and one hundredth,

that is, to eleven hundredths of an inch. Similarly two divisions of the

vernier are equal to twenty-two hundredths of an inch, which expressed as

a decimal fraction is 0·22 inch, three divisions of the vernier is 0·33

inch, &c. Suppose the vernier set as previously described--that is, having

the zero line of the vernier a tangent to the convex curve of the mercury

in the column. If the vernier and scale occupy the relative positions as

in figure _a_, then the height of the barometer is 30·00 inches, but if

they stand as in figure _b_, we set about reading it in this way: (1) The

zero of the vernier being between 29 and 30, the reading is more than 29

inches, but less than 30 inches, and we obtain the first figure 29 inches.

(2) Counting the tenths of an inch from 29 upwards we find that the

vernier indicates more than seven tenths and less than eight tenths,

giving the second figure seven tenths or 0·7 inch. (3) Casting the eye

down the scale to see the point at which a division of the scale and a

division of the vernier lie in one and the same straight line, we observe

this to take place at line 9 of the vernier; this gives this last figure

nine hundredths or 0·09 inch, and placing all these figures in one line we

find that the height of the barometer is 29·79 inches. This sort of

vernier gives readings true to the hundredth of an inch. If the inch be

divided into half tenths or twentieths, and twenty-five divisions of the

vernier equal twenty-four divisions of the scale, it follows that the

difference of these divisions is two thousandths of an inch."

[Illustration]

A still more divided vernier is always used with the best barometers, and

though a little troublesome to read at first, yet if the method of reading

the simpler one just described be understood, the difficulty will be

easily overcome.

_Uses, &c._ The barometer is employed for ascertaining the amount of

atmospherical refraction in astronomical calculations, for measuring

altitudes, and in prognosticating the weather. For the last purpose, on

land, it sometimes proves a false prophet; but at sea, its monitions are

highly trustworthy. As a mere weather-glass, the indications, as read off

from the scale of the instrument, are generally sufficiently accurate; but

in all observations connected with meteorology, altitudes, astronomy, &c.,

certain corrections must be made; the height of the mercury being

influenced both by the size of the tube and by the temperature of the air

by which it is surrounded, as well as by variations in the weight or

pressure of the atmosphere. (See _below_.)

_Barometrical Corrections_:--

1. As to CAPILLARITY:--This applies to all cistern-barometers formed of

tubes of very small diameters, owing to the mercury assuming a convex

surface in the tube. As the tube increases in diameter, so the depression

of the mercury lessens. Hence, the "interior diameter" of a barometer

"should, in every case, exceed one-fourth of an inch." (Brande.) Syphon

barometers that have each of their legs of equal size, require no

correction, as the depression is equal at both ends.

TABLE _of Barometrical Corrections for_ CAPILLARITY,

_from the_ 'Encycl. Brit.'

--------------------+------------------

Diam. of Tube. | Depression.

--------------------+------------------

·10 inch. | ·1403 inch. +

·15 " | ·0863 "

·20 " | ·0581 "

·25 " | ·0407 "

·30 " | ·0292 "

·35 " | ·0211 "

·40 " | ·0153 "

·45 " | ·0112 "

·50 " | ·0083 "

·60 " | ·0044 "

·70 " | ·0023 "

·80 " | ·0012 "

--------------------+------------------

2. As to TEMPERATURE:--These depend on the expansion of the mercury, and

of the scale on which the divisions are marked. The rule for reducing an

observed height to the corresponding height at the freezing-point, or 32°

Fahr., the usual standard temperature, is--Subtract 1·10000th part of the

observed height of the barometer for every degree of Fahr. above 32° at

the time of the observation. Or--

(obs. t. - 32) × obs. h. × ·0001 = corr. req.

_Measurement of Heights by the Barometer._--When a barometer is at the

foot of a mountain, the pressure it sustains is greater than that to which

it is subjected at the top, by the weight of the column of air intervening

between the top and the bottom.

The height can be obtained from the following table by calculating the

number of feet which must have been ascended to cause the observed fall;

and then making a correction for temperature by multiplying the number

obtained from the table, which may be called A, by the following formula:

_t_ is the temperature of the lower and _t'_ of the upper station:--

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