The scientific attitude of mind, p. 2 30--Natural versus supernatural,
p. 233--Inductive versus deductive reasoning, p. 235--Logical induction
versus hasty generalization, p. 239--The future of Darwinism, p. 241.
APPENDIX
A LIST OF SOURCES
A HISTORY OF SCIENCE--BOOK V
ASPECTS OF RECENT SCIENCE
STUDENTS of the classics will recall that the old Roman historians were
accustomed to detail the events of the remote past in what they were
pleased to call annals, and to elaborate contemporary events into
so-called histories. Actuated perhaps by the same motives, though with
no conscious thought of imitation, I have been led to conclude this
history of the development of natural science with a few chapters
somewhat different in scope and in manner from the ones that have gone
before.
These chapters have to do largely with recent conditions. Now and again,
to be sure, they hark back into the past, as when they tell of the
origin of such institutions as the British Museum, the Royal Society,
and the Royal Institution; or when the visitor in modern Jena imagines
himself transplanted into the Jena of the sixteenth century. But these
reminiscent moods are exceptional. Our chief concern is with strictly
contemporary events--with the deeds and personalities of scientific
investigators who are still in the full exercise of their varied powers.
I had thought that such outlines of the methods of contemporary workers,
such glimpses of the personalities of living celebrities, might form a
fitting conclusion to this record of progress. There is a stimulus in
contact with great men at first hand that is scarcely to be gained in
like degree in any other way. So I have thought that those who have not
been privileged to visit the great teachers in person might like to
meet some of them at second hand. I can only hope that something of
the enthusiasm which I have gained from contact with these men may make
itself felt in the succeeding pages.
It will be observed that these studies of contemporary workers are
supplemented with a chapter in which a hurried review is taken of the
field of cosmical, of physical, and of biological science, with
reference to a few of the problems that are still unsolved. As we have
noted the clearing up of mystery after mystery in the past, it may be
worth our while in conclusion thus to consider the hordes of mysteries
which the investigators of our own age are passing on to their
successors. For the unsolved problems of to-day beckon to the alluring
fields of to-morrow.
I. THE BRITISH MUSEUM
IN the year 1753 a remarkable lottery drawing took place in London.
It was authorized, through Parliament, by "his gracious Majesty" King
George the Second. Such notables as the archbishop of Canterbury and the
lord chancellor of the realm took official interest in its success. It
was advertised far and wide--as advertising went in those days--in the
_Gazette_, and it found a host of subscribers. Of the fifty thousand
tickets--each costing three pounds--more than four thousand were to
be of the class which the act of Parliament naively describes as
"fortunate tickets." The prizes aggregated a hundred thousand pounds.
To be sure, state lotteries were no unique feature in the England of
that day. They formed as common a method of raising revenue in the
island realm of King George II. as they still do in the alleged
continental portion of his realm, France, and in the land of his
nativity, Germany. Indeed, the particular lottery in question was to
be officered by the standing committee on lotteries, whose official
business was to "secure two and a half million pounds for his Majesty"
by this means. But the great lottery of 1754 had interest far beyond the
common run, for it aimed to meet a national need of an anomalous kind--a
purely intellectual need. The money which it was expected to bring was
to be used to purchase some collections of curiosities and of books that
had been offered the government, and to provide for their future care
and disposal as a public trust for the benefit and use of the people.
The lottery brought the desired money as a matter of course, for the
"fool's tax" is the one form of revenue that is paid without stint and
without grumbling. Almost fifty thousand pounds remained in the hands
of the archbishop of Canterbury and his fellow-trustees after the prizes
were paid. And with this sum the institution was founded which has been
increasingly famous ever since as the British Museum.
The idea which had this splendid result had originated with Sir Hans
Sloane, baronet, a highly respected practising physician of Chelsea,
who had accumulated a great store of curios, and who desired to see the
collection kept intact and made useful to the public after his death.
Dying in 1753, this gentleman had directed in his will that the
collection should be offered to the government for the sum of twenty
thousand pounds; it had cost him fifty thousand pounds. The government
promptly accepted the offer--as why should it not, since it had at hand
so easy a means of raising the necessary money? It was determined to
supplement the collection with a library of rare books, for which
ten thousand pounds was to be paid to the Right Honorable Henrietta
Cavendish Holies, Countess of Oxford and Countess Mortimer, Relict of
Edward, Earl of Oxford and Earl Mortimer, and the Most Noble Margaret
Cavendish, Duchess of Portland, their only daughter.
The purchases were made and joined with the Cottonian library, which
was already in hand. A home was found for the joint collection, along
with some minor ones, in Montague Mansion, on Great Russell Street, and
the British Museum came into being. Viewed retrospectively, it seems
a small affair; but it was a noble collection for its day; indeed,
the Sloane collection of birds and mammals had been the finest private
natural history collection in existence. But, oddly enough, the weak
feature of the museum at first was exactly that feature which has been
its strongest element in more recent years--namely, the department of
antiquities. This department was augmented from time to time, notably by
the acquisition of the treasures of Sir William Hamilton in 1773; but it
was not till the beginning of the nineteenth century that the windfall
came which laid the foundation for the future incomparable greatness of
the museum as a repository of archaeological treasures.
In that memorable year the British defeated the French at Alexandria,
and received as a part of the conqueror's spoils a collection of
Egyptian antiquities which the savants of Napoleon's expedition had
gathered and carefully packed, and even shipped preparatory to sending
them to the Louvre. The feelings of these savants may readily be
imagined when, through this sad prank of war, their invaluable treasures
were envoyed, not to their beloved France, but to the land of their
dearest enemies, there to be turned over to the trustees of the British
Museum.
The museum authorities were not slow to appreciate the value of the
treasures that had thus fallen into their hands, yet for the moment
it proved to them something of a white elephant. Montague Mansion was
already crowded; moreover, its floors had never been intended to hold
such heavy objects, so it became imperatively necessary to provide new
quarters for the collection. This was done in 1807 by the erection of
a new building on the old site. But the trustees of that day failed to
gauge properly the new impulse to growth that had come to the museum
with the Egyptian antiquities, for the new building was neither in
itself sufficient for the needs of the immediate future nor yet
so planned as to be susceptible of enlargement with reasonable
architectural effect. The mistakes were soon apparent, but, despite
various tentatives and "meditatings," fourteen years elapsed before
the present magnificent building was planned. The construction, wing by
wing, began in 1823, but it was not until 1846 that the last vestige
of the old museum buildings had vanished, and in their place, spreading
clear across the spacious site, stood a structure really worthy of the
splendid collection for which it was designed.
But no one who sees this building to-day would suspect its relative
youth. Half a century of London air can rival a cycle of Greece or Italy
in weathering effect, and the fine building of the British Museum
frowns out at the beholder to-day as grimy and ancient-seeming as if
its massive columns dated in fact from the old Grecian days which they
recall. Regardless of age, however, it is one of the finest and most
massive specimens of Ionic architecture in existence. Forty-four massive
columns, in double tiers, form its frontal colonnade, jutting forward
in a wing at either end. The flight of steps leading to the central
entrance is in itself one hundred and twenty-five feet in extent; the
front as a whole covers three hundred and seventy feet. Capping the
portico is a sculptured tympanum by Sir Richard Westmacott, representing
the "Progress of Civilization" not unworthily. As a whole, the building
is one of the few in London that are worth visiting for an inspection of
their exterior alone. It seems admirably designed to be, as it is, the
repository of one of the finest collections of Oriental and classical
antiquities in the world.
There is an air of repose about the _ensemble_ that is in itself
suggestive of the Orient; and the illusion is helped out by the pigeons
that flock everywhere undisturbed about the approaches to the building,
fluttering to be fed from the hand of some recognized friend, and
scarcely evading the feet of the casual wayfarer. With this scene before
him, if one will close his ears to the hum of the great city at his
back he can readily imagine himself on classical soil, and, dreaming of
Greece and Italy, he will enter the door quite prepared to find himself
in the midst of antique marbles and the atmosphere of by-gone ages.
I have already pointed out that the turning-point in the history of
the British Museum came just at the beginning of the century, with the
acquisition of the Egyptian antiquities. With this the institution threw
off its swaddling-clothes. Hitherto it had been largely a museum of
natural history; in future, without neglecting this department, it
was to become equally important as a museum of archaeology. The Elgin
marbles, including the wonderful Parthenon frieze, confirmed this
character, and it was given the final touch by the reception, about
the middle of the century, of the magnificent Assyrian collection just
exhumed at the seat of old Nineveh by Mr. (afterwards Sir Henry) Layard.
Since then these collections, with additions of similar character, have
formed by far the most important feature of the British Museum. But in
the mean time archaeology has become a science.
Within recent years the natural history collection has been removed _in
toto_ from the old building to a new site far out in South Kensington,
and the casual visitor is likely to think of it as a separate
institution. The building which it occupies is very modern in appearance
as in fact. It is a large and unquestionably striking structure, and one
that gives opportunity for very radical difference of opinion as to its
architectural beauty. By some it is much admired; by others it is almost
equally scoffed at. Certain it is that it will hardly bear comparison
with the parent building in Great Russell Street.
Interiorly, the building of the natural history museum is admirably
adapted for its purpose. Its galleries are for the most part well
lighted, and the main central hall is particularly well adapted for
an exhibition of specimens, to which I shall refer more at length in
a moment. For the rest there is no striking departure from the
conventional. Perhaps it is not desired that there should be, since long
experience seems to have settled fairly well the problem of greatest
economy of space, combined with best lighting facilities, which always
confronts the architect in founding a natural history museum.
There is, however, one striking novel feature in connection with the
structure of the natural history museum at Kensington which must not
be overlooked. This is the quite unprecedented use of terra-cotta
ornamentation. Without there is a striking display of half-decorative
and half-realistic forms; while within the walls and pillars everywhere
are covered with terracotta bas-reliefs representing the various forms
of life appropriate to the particular department of the museum which
they ornament. This very excellent feature might well be copied
elsewhere, and doubtless will be from time to time.
As to the exhibits proper within the museum, it may be stated in a word
that they cover the entire range of the faunas and floras of the
globe in a variety and abundance of specimens that are hardly excelled
anywhere, and only duplicated by one or two other collections in Europe
and two or three in America.
It would be but a reiteration of what the catalogues of all large
collections exhibit were one to enumerate the various forms here shown,
but there are two or three exhibits in this museum which are more novel
and which deserve special mention. One of these is to be found in a set
of cases in the main central hall. Here are exhibited, in a delightfully
popular form, some of the lessons that the evolutionist has taught us
during the last half-century. Appropriately enough, a fine marble statue
of Darwin, whose work is the fountain-head of all these lessons, is
placed on the stairway just beyond, as if to view with approval this
beautiful exemplification of his work.
One of these cases illustrates the variations of animals under
domestication, the particular specimens selected being chiefly the
familiar pigeon, in its various forms, and the jungle-fowl with its
multiform domesticated descendants.
Another case illustrates very strikingly the subject of protective
coloration of animals. Two companion cases are shown, each occupied by
specimens of the same species of birds and animals--in one case in their
summer plumage and pelage and in the other clad in the garb of winter.
The surroundings in the case have, of course, been carefully prepared
to represent the true environments of the creatures at the appropriate
seasons. The particular birds and animals exhibited are the
willow-grouse, the weasel, and a large species of hare. All of these,
in their summer garb, have a brown color, which harmonizes marvellously
with their surroundings, while in winter they are pure white, to match
the snow that for some months covers the ground in their habitat.
The other cases of this interesting exhibit show a large variety of
birds and animals under conditions of somewhat abnormal variation, in
the one case of albinism and the other of melanism. These cases are,
for the casual visitor, perhaps the most striking of all, although, of
course, they teach no such comprehensive lessons as the other exhibits
just referred to.
The second of the novel exhibits of the museum to which I wish to refer
is to be found in a series of alcoves close beside the central cases in
the main hallway.
Each of these alcoves is devoted to a class of animals--one to mammals,
one to birds, one to fishes, and so on. In each case very beautiful sets
of specimens have been prepared, illustrating the anatomy and physiology
of the group of animals in question. Here one may see, for example, in
the alcove devoted to birds, specimens showing not only details of
the skeleton and muscular system, but the more striking examples of
variation of form of such members as the bill, legs, wings, and tails.
Here are preparations also illustrating, very strikingly, the vocal
apparatus of birds. Here, again, are finely prepared wings, in which
the various sets of feathers have been outlined with different-colored
pigments, so that the student can name them at a glance. In fact, every
essential feature of the anatomy of the bird may be studied here as in
no other collection that I know of. And the same is true of each of the
other grand divisions of the animal kingdom. This exhibit alone gives an
opportunity for the student of natural history that is invaluable. It is
quite clear to any one who has seen it that every natural history museum
must prepare a similar educational exhibit before it can claim to do
full justice to its patrons.
A third feature that cannot be overlooked is shown in the numerous cases
of stuffed birds, in which the specimens are exhibited, not merely
by themselves on conventional perches, but amid natural surroundings,
usually associated with their nests and eggs or young. These exhibits
have high artistic value in addition to their striking scientific worth.
They teach ornithology as it should be taught, giving such clews to
the recognition of birds in the fields as are not at all to be found in
ordinary collections of stuffed specimens. This feature of the museum
has, to be sure, been imitated in the American Museum of Natural History
in New York, but the South Kensington Museum was the first in the field
and is still the leader.
A few words should be added as to the use made by the public of the
treasures offered for their free inspection by the British Museum. I
shall attempt nothing further than a few data regarding actual visits to
the museum. In the year 1899 the total number of such visits
aggregated 663,724; in 1900 the figures rise to 689,249--well towards
three-quarters of a million. The number of visits is smallest in the
winter months, but mounts rapidly in April and May; it recedes slightly
for June and July, and then comes forward to full tide in August, during
which month more than ninety-five thousand people visited the museum
in 1901, the largest attendance in a single day being more than nine
thousand. August, of course, is the month of tourists--particularly of
tourists from America--but it is interesting and suggestive to note
that it is not the tourist alone who visits the British Museum, for the
flood-tide days of attendance are always the Bank holidays, including
Christmas boxing-day and Easter Monday, when the working-people turn out
_en masse_. On these days the number of visits sometimes mounts above
ten thousand.
All this, it will be understood, refers exclusively to the main building
of the museum on Great Russell Street. But, meantime, out in Kensington,
at the natural history museum, more than half a million visits each year
are also made. In the aggregate, then, about a million and a quarter of
visits are paid to the British Museum yearly, and though the bulk of the
visitors may be mere sight-seers, yet even these must carry away many
ideas of value, and it hardly requires argument to show that, as a
whole, the educational influence of the British Museum must be enormous.
Of its more direct stimulus to scientific work through the trained
experts connected with the institution I shall perhaps speak in another
connection.
II. THE ROYAL SOCIETY OF LONDON FOR IMPROVING NATURAL KNOWLEDGE
A SESSION OF THE SOCIETY
THERE is one scientific institution in London more venerable and more
famous even than the British Museum. This, of course, is the Royal
Society, a world-famous body, whose charter dates from 1662, but whose
actual sessions began at Gresham College some twenty years earlier. One
can best gain a present-day idea of this famous institution by attending
one of its weekly meetings in Burlington House, Piccadilly--a great,
castle-like structure, which serves also as the abode of the Royal
Chemical Society and the Royal Academy of Arts. The formality of an
invitation from a fellow is required, but this is easily secured by any
scientific visitor who may desire to attend the meeting. The
programme of the meeting each week appears in that other great British
institution, the _Times_, on Tuesdays.
The weekly meeting itself is held on Thursday afternoon at half-past
four. As one enters the door leading off the great court of Burlington
House a liveried attendant motions one to the rack where great-coat
and hat may be left, and without further ceremony one steps into the
reception-room unannounced. It is a middle-sized, almost square room,
pillared and formal in itself, and almost without furniture, save for
a long temporary table on one side, over which cups of tea are being
handed out to the guests, who cluster there to receive it, and then
scatter about the room to sip it at their leisure. We had come to hear
a lecture and had expected to be ushered into an auditorium; but we had
quite forgotten that this is the hour when all England takes its tea,
the _élite_ of the scientific world, seemingly, quite as much as the
devotees of another kind of society. Indeed, had we come unawares into
this room we should never have suspected that we had about us other than
an ordinary group of cultured people gathered at a conventional
"tea," except, indeed, that suspicion might be aroused by the great
preponderance of men--there being only three or four women present--and
by the fact that here and there a guest appears in unconventional
dress--a short coat or even a velvet working-jacket. For the rest
there is the same gathering into clusters of three or four, the same
inarticulate clatter of many voices that mark the most commonplace of
gatherings.
But if one will withdraw to an inoffensive corner and take a critical
view of the assembly, he will presently discover that many of the faces
are familiar to him, although he supposed himself to be quite among
strangers. The tall figure, with the beautiful, kindly face set in
white hair and beard, has surely sat for the familiar portrait of Alfred
Russel Wallace. This short, thick-set, robust, business-like figure is
that of Sir Norman Lockyer. Yonder frail-seeming scholar, with white
beard, is surely Professor Crookes. And this other scholar, with tall,
rather angular frame and most kindly gleam of eye, is Sir Michael
Foster; and there beyond is the large-seeming though not tall figure,
and the round, rosy, youthful-seeming, beautifully benevolent face of
Lord Lister. "What! a real lord there?" said a little American girl to
whom I enumerated the company after my first visit to the Royal Society.
"Then how did he act? Was he very proud and haughty, as if he could not
speak to other people?" And I was happy to be able to reply that though
Lord Lister, perhaps of all men living, would be most excusable did he
carry in his manner the sense of his achievements and honors, yet in
point of fact no man could conceivably be more free from any apparent
self-consciousness. As one watches him now he is seen to pass from group
to group with cordial hand-shake and pleasant word, clearly the most
affable of men, lord though he be, and president of the Royal Society,
and foremost scientist of his time.
Presently an attendant passed through the tearoom bearing a tremendous
silver mace, perhaps five feet long, surmounted by a massive crown and
cross, and looking like nothing so much as a "gigantic war-club."
This is the mace which, when deposited on the president's desk in the
lecture-room beyond, will signify that the society is in session. "It is
the veritable mace," some one whispers at your elbow, "concerning which
Cromwell gave his classical command to 'Remove that bauble.'" But since
the mace was not made until 1663, some five years after Cromwell's
death, this account may lack scientific accuracy. Be that as it may,
this mace has held its own far more steadily than the fame of its
alleged detractor, and its transportation through the tea-room is the
only manner of announcement that the lecture is about to open in the
hall beyond. Indeed, so inconspicuous is the proceeding, and so quietly
do the members that choose to attend pass into the lecture-hall, leaving
perhaps half the company engaged as before, that the "stranger "--as
the non-member is here officially designated--might very readily fail
to understand that the séance proper had begun. In any event, he cannot
enter until permission has been formally voted by the society.
When he is allowed to enter he finds the meeting-room little different
from the one he has left, except that it is provided with a sort of
throne on a raised platform at one end and with cushioned benches for
seats. On the throne, if one may so term it, sits Lord Lister, scarcely
more than his head showing above what seems to be a great velvet cushion
which surmounts his desk, at the base of which, in full view of the
society, rests the mace, fixing the eye of the "stranger," as it is
alleged to have fixed that of Cromwell aforetime, with a peculiar
fascination. On a lower plane than the president, at his right and left,
sit Sir Michael Foster and Professor Arthur William Rucker, the two
permanent secretaries. At Sir Michael's right, and one stage nearer the
audience, stands the lecturer, on the raised platform and behind the
desk which extends clear across the front of the room. As it chances,
the lecturer this afternoon is Professor Ehrlich, of Berlin and
Frankfort-on-the-Main, who has been invited to deliver the Croonian
lecture. He is speaking in German, and hence most of the fellows are
assisting their ears by following the lecture in a printed translation,
copies of which, in proof, were to be secured at the door.
The subject of the lecture is "Artificial Immunization from Disease."
It is clear that the reader is followed with interested attention, which
now and again gives rise to a subdued shuffle of applause.
The fact that the lecturer is speaking German serves perhaps to suggest
even more vividly than might otherwise occur to one the contrast between
this meeting and a meeting of the corresponding German society--the
Royal Academy of Sciences at Berlin. Each is held in an old building
of palatial cast and dimensions, of which Burlington House, here
in Piccadilly, is much the older--dating from 1664--although its
steam-heating and electric-lighting apparatus, when contrasted with the
tile stoves and candles of the other, would not suggest this. For the
rest, the rooms are not very dissimilar in general appearance, except
for the platform and throne. But there the members of the society are
shut off from the audience both by the physical barrier of the table and
by the striking effect of their appearance in full dress, while here the
fellows chiefly compose the audience, there being only a small company
of "strangers" present, and these in no way to be distinguished by dress
or location from the fellows themselves. It may be added that the custom
of the French Academy of Sciences is intermediate between these two.
There the visitors occupy seats apart, at the side of the beautiful
hall, the main floor being reserved for members. But the members
themselves are not otherwise distinguishable, and they come and go and
converse together even during the reading of a paper almost as if this
were a mere social gathering. As it is thus the least formal, the
French meeting is also by far the most democratic of great scientific
gatherings. Its doors are open to whoever may choose to enter. The
number who avail themselves of this privilege is not large, but it
includes, on occasions, men of varied social status and of diverse races
and colors--none of whom, so far as I could ever discern, attracts the
slightest attention.
At the German meeting, again, absolute silence reigns. No one thinks
of leaving during the session, and to make any sound above a sigh would
seem almost a sacrilege. But at the Royal Society an occasional auditor
goes or comes, there are repeated audible signs of appreciation of the
speaker's words, and at the close of the discourse there is vigorous
and prolonged applause. There is also a debate, of the usual character,
announced by the president, in which "strangers" are invited to
participate, and to which the lecturer finally responds with a brief
_Nachwort_, all of which is quite anomalous from the German or French
stand-points. After that, however, the meeting is declared adjourned
with as little formality in one case as in the others, and the fellows
file leisurely out, while the attendant speedily removes the mace, in
official token that the séance of the Royal Society is over.
THE LIBRARY AND READING-ROOM
But the "stranger" must not leave the building without mounting to the
upper floor for an inspection of the library and reading-room. The rooms
below were rather bare and inornate, contrasting unfavorably with the
elegant meeting-room of the French institute. But this library makes
full amends for anything that the other rooms may lack. It is one of the
most charming--"enchanting" is the word that the Princess Christian is
said to have used when she visited it recently--and perhaps quite the
most inspiring room to be found in all London. It is not very large as
library rooms go, but high, and with a balcony supported by Corinthian
columns. The alcoves below are conventional enough, and the high
tables down the centre, strewn with scientific periodicals in engaging
disorder, are equally conventional. But the color-scheme of the
decorations--sage-green and tawny--is harmonious and pleasing, and the
effect of the whole is most reposeful and altogether delightful.
Chief distinction is given the room, however, by a row of busts on
either side and by certain pieces of apparatus on the centre tables.
The busts, as will readily be surmised, are portraits of distinguished
fellows of the Royal Society. There is, however, one exception to this,
for one bust is that of a woman--Mary Somerville, translator of the
_Mécanique Céleste_, and perhaps the most popular of the scientific
writers of her time. It is almost superfluous to state that the row of
busts begins with that of Newton. The place of honor opposite is held by
that of Faraday. Encircling the room to join these two one sees, among
others, the familiar visages of Dr. Gilbert; of Sir Joseph Banks, the
famous surgeon of the early nineteenth century, who had the honor of
being the only man that ever held the presidential chair of the
Royal Society longer than it was held by Newton; of James Watts, of
"steam-engine" fame; of Sabine, the astronomer, also a president of
the society; and of Dr. Falconer and Sir Charles Lyell, the famous
geologists.
There are numerous other busts in other rooms, some of them stowed away
in nooks and crannies, and the list of those selected for the library
does not, perhaps, suggest that this is the room of honor, unless,
indeed, the presence of Newton and Faraday gives it that stamp. But in
the presence of the images of these two, and of Lyell, to go no farther,
one feels a certain sacredness in the surroundings.
If this is true of the mere marble images, what shall we say of the
emblems on the centre table? That little tubular affair, mounted on a
globe, the whole cased in a glass frame perhaps two feet high, is the
first reflecting telescope ever made, and it was shaped by the hand of
Isaac Newton. The brass mechanism at the end of the next table is the
perfected air-pump of Robert Boyle, Newton's contemporary, one of the
founders of the Royal Society and one of the most acute scientific minds
of any time. And here between these two mementos is a higher apparatus,
with crank and wheel and a large glass bulb that make it conspicuous.
This is the electrical machine of Joseph Priestley. There are other
mementos of Newton--a stone graven with a sun-dial, which he carved as
a boy, on the paternal manor-house; a chair, said to have been his,
guarded here by a silk cord against profanation; bits of the famous
apple-tree which, as tradition will have it, aided so tangibly in
the greatest of discoveries; and the manuscript of the _Principia_
itself--done by the hand of an amanuensis, to be sure, but with
interlinear corrections in the small, clear script of the master-hand
itself. Here, too, is the famous death-mask, so much more interesting
than any sculptured portrait, and differing so strangely in its
broad-based nose and full, firm mouth from the over-refined lineaments
of the sculptured bust close at hand. In a room not far away, to reach
which one passes a score or two of portraits and as many busts of
celebrities--including, by-the-bye, both bust and portrait of Benjamin
Franklin--one finds a cabinet containing other mementos similar to those
on the library tables. Here is the first model of Davy's safety-lamp;
there a chronometer which aided Cook in his famous voyage round the
world. This is Wollaston's celebrated "Thimble Battery." It will slip
readily into the pocket, yet he jestingly showed it to a visitor as
"his entire laboratory." That is a model of the double-decked boat made
by Sir William Petty, and there beyond is a specimen of almost, if not
quite, the first radiometer devised by Sir William Crookes.
As one stands in the presence of all these priceless relics, so vividly
do the traditions of more than two centuries of science come to mind
that one seems almost to have lived through them. One recalls, as if it
were a personal recollection, the founding of the Royal Society itself
in 1662, and the extraordinary scenes which the society witnessed during
the years of its adolescence.
As one views the mementos of Boyle and Newton, one seems to be living in
the close of the seventeenth century. It is a troublous time in England.
Revolution has followed revolution. Commonwealth has supplanted monarchy
and monarchy commonwealth. At last the "glorious revolution" of 1688 has
placed a secure monarch on the throne. But now one external war follows
another, and the new king, William of Orange, is leading the "Grand
Alliance" against the French despot Louis XIV. There is war everywhere
in Europe, and the treaty of Ryswick, in 1697, is but the preparation
for the war of the Spanish Alliance, which will usher in the new
century. But amid all this political turmoil the march of scientific
discovery has gone serenely on; or, if not serenely, then steadily, and
perhaps as serenely as could be hoped. Boyle has discovered the law of
the elasticity of gases and a host of minor things. Robert Hooke is
on the track of many marvels. But all else pales before the fact that
Newton has just given to the world his marvellous law of gravitation,
which has been published, with authority of the Royal Society, through
the financial aid of Halley. The brilliant but erratic Hooke lias
contested the priority of discovery and strenuously claimed a share in
it. Halley eventually urges Newton to consider Hooke's claim in some of
the details, and Newton yields to the extent of admitting that the
great fact of gravitational force varying inversely as the square of
the distance had been independently discovered by Hooke; but he includes
also Halley himself and Sir Christopher Wren, along with Hooke,
as equally independent discoverers of the same principle. To the
twentieth-century consciousness it seems odd to hear Wren thus named as
a scientific discoverer; but in truth the builder of St. Paul's began
life as a professor of astronomy at Gresham College, and was the
immediate predecessor of Newton himself in the presidential chair of the
Royal Society. Now, at the very close of the seventeenth century, Boyle
is recently dead, but Hooke, Wren, Halley, and Newton still survive:
some of them are scarcely past their prime. It is a wonderful galaxy of
stars of the first magnitude, and even should no other such names come
in after-time, England's place among the scientific constellations is
secure.
But now as we turn to the souvenirs of Cooke and Wollaston and Davy
the scene shifts by a hundred years. We are standing now in the closing
epoch of the eighteenth century. These again are troublous times. The
great new colony in the West has just broken off from the parent swarm.
Now all Europe is in turmoil. The French war-cloud casts its ominous
shadow everywhere. Even in England mutterings of the French Revolution
are not without an echo. The spirit of war is in the air. And yet, as
before, the spirit of science also is in the air. The strain of the
political relations does not prevent a perpetual exchange of courtesy
between scientific men and scientific bodies of various nations. Davy's
dictum that "science knows no country" is perpetually exemplified in
practice. And at the Royal Society, to match the great figures that were
upon the scene a century before, there are such men as the eccentric
Cavendish, the profound Wollaston, the marvellously versatile Priestley,
and the equally versatile and even keener-visioned Rumford. Here, too,
are Herschel, who is giving the world a marvellous insight into the
constitution of the universe; and Hutton, who for the first time gains a
clear view of the architecture of our earth's crust; and Jenner, who is
rescuing his fellow-men from the clutches of the most deadly of plagues;
to say nothing of such titanic striplings as Young and Davy, who are
just entering the scientific lists. With such a company about us we are
surely justified in feeling that the glory of England as a scientific
centre has not dimmed in these first hundred and thirty years of the
Royal Society's existence.
And now, as we view the radiometer, the scene shifts by yet another
century, and we come out of cloud-land and into our own proper age. We
are at the close of the nineteenth century--no, I forget, we are fairly
entering upon the twentieth. Need I say that these again are troublous
times? Man still wages warfare on his fellow-man as he has done time
out of mind; as he will do--who shall say how long? But meantime, as
of yore, the men of science have kept steadily on their course. But
recently here at the Royal Society were seen the familiar figures of
Darwin and Lyell and Huxley and Tyndall. Nor need we shun any comparison
with the past while the present lists can show such names as Wallace,
Kelvin, Lister, Crookes, Foster, Evans, Rayleigh, Ramsay, and Lock-yer.
What revolutionary advances these names connote! How little did those
great men of the closing decades of the seventeenth and eighteenth
centuries know of the momentous truths of organic evolution for which
the names of Darwin and Wallace and Huxley stand! How little did
they know a century ago, despite Hutton's clear prevision, of these
marvellous slow revolutions through which, as Lyell taught us, the
earth's crust had been built up! Not even Jen-ner could foresee a
century ago the revolution in surgery which has been effected in our
generation through the teachings of Lister.
And what did Rumford and Davy know of energy in its various
manifestations as compared with the knowledge of to-day, of Crookes
and Rayleigh and Ramsay and Kelvin? What would Joseph Priestley, the
discoverer of oxygen, and Cavendish, the discoverer of nitrogen,
think could they step into the laboratory of Professor Ramsay and see
test-tubes containing argon and helium and krypton and neon and zenon?
Could they more than vaguely understand the papers contributed in recent
years to the Royal Society, in which Professor Ramsay explains how these
new constituents of the atmosphere are obtained by experiments on liquid
air. "Here," says Professor Ramsay, in effect, in a late paper to the
society, "is the apparatus with which we liquefy hydrogen in order to
separate neon from helium by liquefying the former while the helium
still remains gaseous." Neon, helium, liquid air, liquid hydrogen--these
would seem strange terms to the men who on discovering oxygen and
nitrogen named them "dephlogisticated air" and "phlogisti-cated air"
respectively.
Again, how elementary seems the teaching of Her-schel, wonderful though
it was in its day, when compared with our present knowledge of the
sidereal system as outlined in the theories of Sir Norman Lock-yer.
Herschel studied the sun-spots, for example, with assiduity, and even
suggested a possible connection between sun-spots and terrestrial
weather. So far, then, he would not be surprised on hearing the
announcement of Professor Lockyer's recent paper before the Royal
Society on the connection between sun-spots and the rainfall in India.
But when the paper goes on to speak of the actual chemical nature of the
sun-spots, as tested by a spectroscope; to tell of a "cool" stage when
the vapor of iron furnishes chief spectrum lines, and of a "hot" stage
when the iron has presumably been dissociated into unknown "proto-iron"
constituents--then indeed does it go far beyond the comprehension of the
keenest eighteenth-century intellect, though keeping within the range of
understanding of the mere scientific tyro of to-day.
Or yet again, consider a recent paper contributed by Professor Lockyer
to the Royal Society, entitled "The New Star in Perseus: Preliminary
Note"--referring to the new star that flashed suddenly on the vision of
the terrestrial observers at more than first magnitude on February 22,
1901. This "star," the paper tells us, when studied by its spectrum,
is seen to be due to the impact of two swarms of meteors out in
space--swarms moving in different directions "with a differential
velocity of something like seven hundred miles a second." Every
astronomer of to-day understands how such a record is read from the
displacement of lines on the spectrum, as recorded on the photographic
negative. But imagine Sir William Herschel, roused from a century's
slumber, listening to this paper, which involves a subject of which he
was the first great master. "Ebulae," he might say; "yes, they were a
specialty of mine; but swarms of meteors--I know nothing of these. And
'spectroscopes,' 'photographs'--what, pray, are these? In my day there
were no such words or things as spectroscope and photograph; to my mind
these words convey no meaning."
But why go farther? These imaginings suffice to point a moral that he
who runs may read. Of a truth the march of science still goes on as it
has gone on with steady tread throughout the long generations of the
Royal Society's existence. If the society had giants among its members
in the days of its childhood and adolescence, no less are there giants
still to keep up its fame in the time of its maturity. The place of
England among the scientific constellations is secure through tradition,
but not through tradition alone.
III. THE ROYAL INSTITUTION AND THE LOW-TEMPERATURE RESEARCHES
FOUNDATION AND FOUNDER
"GEORGE THE THIRD, by the Grace of God King of Great Britain, France,
and Ireland, Defender of the Faith, etc., to all to whom these presents
shall come, greeting. Whereas several of our loving subjects are
desirous of forming a Public Institution for diffusing the knowledge and
facilitating the general introduction of Useful Mechanical Inventions
and Improvements; and for teaching, by Courses of Philosophical Lectures
and Experiments, the Application of Science to the Common Purposes of
Life, we do hereby give and grant"--multifarious things which need not
here be quoted. Such are the opening words of the charter with which, a
little more than a century ago, the Royal Institution of Great Britain
came into existence and received its legal christening. If one reads on
he finds that the things thus graciously "given and granted," despite
all the official verbiage, amount to nothing more than royal sanction
and approval, but doubtless that meant more in the way of assuring
popular approval than might at first glimpse appear. So, too, of the
list of earls, baronets, and the like, who appear as officers and
managers of the undertaking, and who are described in the charter as
"our right trusty and right well-beloved cousins," "our right trusty
and well-beloved counsellors," and so on, in the skilfully graduated
language of diplomacy. The institution that had the King for patron and
such notables for officers seemed assured a bright career from the very
beginning. In name and in personnel it had the flavor of aristocracy,
a flavor that never palls on British palate. And right well the
institution has fulfilled its promise, though in a far different way
from what its originator and founder anticipated.
Its originator and founder, I say, and say advisedly; for, of course,
here, as always, there is one man who is the true heart and soul of the
movement, one name that stands, in truth, for the whole project, and to
which all the other names are mere appendages. You would never suspect
which name it is, in the present case, from a study of the charter,
for it appears well down the file of graded titles, after "cousins" and
"counsellors" have had their day, and is noted simply as "our trusty
and well-beloved Benjamin, Count of Rumford, of the Holy Roman Empire."
Little as there is to signalize it in the charter, this is the name of
the sole projector of the enterprise in its incipiency, of the
projector of every detail, of the writer of the charter itself even. The
establishment thus launched with royal title might with full propriety
have been called, as indeed it sometimes is called, the Rumford
Institution.
The man who thus became the founder of this remarkable institution was
in many ways a most extraordinary person. He was an American by birth,
and if not the most remarkable of Americans, he surely was destined to
a more picturesque career than ever fell to the lot of any of his
countrymen of like eminence. Born on a Massachusetts farm, he was a
typical "down-east Yankee," with genius added to the usual shrewd,
inquiring mind and native resourcefulness. He was self-educated and
self-made in the fullest sense in which those terms can be applied. At
fourteen he was an unschooled grocer-lad--Benjamin Thompson by name--in
a little New England village; at forty he was a world-famous savant,
as facile with French, Italian, Spanish, and German as with his native
tongue; he had become vice-president and medallist of the Royal
Society, member of the Berlin National Academy of Science, of the French
Institute, of the American Academy of Science, and I know not what other
learned bodies; he had been knighted in Great Britain after serving
there as under-secretary of state and as an officer; and he had risen
in Bavaria to be more than half a king in power, with the titles, among
others, of privy councillor of state, and head of the war department,
lieutenant-general of the Bavarian armies, holder of the Polish order of
St. Stanislas and the Bavarian order of the White Eagle, ambassador to
England and to France, and, finally, count of the Holy Roman Empire.
Once, in a time of crisis, Rumford was actually left at the head of
a council of regency, in full charge of Bavarian affairs, the elector
having fled. The Yankee grocer-boy had become more than half a king.
Never, perhaps, did a man of equal scientific attainments enjoy a
corresponding political power. Never was political power wielded more
justly by any man.
For in the midst of all his political and military triumphs, Rumford
remained at heart to the very end the scientist and humanitarian. He
wielded power for the good of mankind; he was not merely a ruler but
a public educator. He taught the people of Bavaria economy and Yankee
thrift. He established kitchens for feeding the poor on a plan that was
adopted all over Europe; but, better yet, he created also workshops for
their employment and pleasure-gardens for their recreation. He actually
banished beggary from the principality.
It was in the hope of doing in some measure for London what he had done
for Munich that this large-brained and large-hearted man was led to the
project of the Royal Institution. He first discussed his plans with a
committee of the Society for Alleviating the Condition of the Poor, for
it was the poor, the lower ranks of society, whom he wished chiefly to
benefit. But he knew that to accomplish his object, he must work through
the aristocratic channels; hence the name of the establishment and the
charter with its list of notables. The word institution was selected
by Rumford, after much deliberation, as, on the whole, the least
objectionable title for the establishment, as having a general
inclusiveness not possessed by such words as school or college. Yet in
effect it was a school which Rumford intended to found--a school for
the general diffusion of useful knowledge. There were to be classes
for mechanics, and workshops, kitchens, and model-rooms, where the
"application of science to the useful purposes of life" might be
directly and practically taught; also a laboratory for more technical
investigations, with a "professor" in charge, who should also deliver
popular lectures on science. Finally, there was to be a scientific
library.
All these aims were put into effect almost from the beginning. The
necessary funds were supplied solely by popular subscription and by the
sale of lecture tickets (as all funds of the institution have been ever
since), and before the close of the year 1800 Rumford's dream had become
an actuality--as this practical man's dreams nearly always did. The new
machine did not move altogether without friction, of course, but on the
whole all went well for the first few years. The institution had found
a local habitation in a large building in Albemarle Street, the same
building which it still occupies, and for a time Rumford lived there and
gave the enterprise his undivided attention. He appointed the brilliant
young Humphry Davy to the professorship of chemistry, and the even
more wonderful Thomas Young to that of natural philosophy. He saw the
workshops and kitchens and model-rooms in running order--the entire
enterprise fully launched. Then other affairs, particularly an
attachment for a French lady, the widow of the famous chemist Lavoisier
(whom he subsequently married, to his sorrow), called him away from
England never to return. And the first chapter in the history of the
Royal Institution was finished.
METHOD AND RESULT
Rumford, the humanitarian, gone, a curious change came over the spirit
of the enterprise he had founded. The aristocrats who at first were
merely ballast for the enterprise now made their influence felt. With
true British reserve, they announced their belief that the education of
the masses involved a dangerous political tendency. Hence the mechanics'
school was suspended and the workshops and kitchens abolished; in
a word, the chief ends for which the institution was founded were
annulled. The library and the lectures remained, to be sure, but they
were for the amusement of the rich, not for the betterment of the poor.
It was the West End that made a fad of the institution and a society
function of the lectures of Sydney Smith and of the charming youth Davy.
Thus the institution came to justify its aristocratic title and its
regal patronage; and the poor seemed quite forgotten.
But indeed the institution itself was poor enough in these days, after
the first flush of enthusiasm died away, and it is but fair to remember
that without the support of its popular lectures its very existence
would have been threatened. Nor in any event are regrets much in order
over the possible might-have-beens of an institution whose laboratories
were the seat of the physical investigations of Thomas Young, through
which the wave theory of light first gained a footing, and of the
brilliant chemical researches of Davy, which practically founded the
science of electro-chemistry and gave the chemical world first knowledge
of a galaxy of hitherto unknown elements. Through the labors of
these men, and through the popular lecture-courses delivered at the
institution by such other notables of science as Wollaston, Dalton, and
Rum-ford, the enterprise had become world-famous before the close of the
first decade of its existence.
From that day till this the character of the Royal Institution has
not greatly changed. The enterprise shifted around during its earliest
years, while it was gaining its place in the scheme of things; but once
that was found, like a true British institution it held its course with
an inertia that a mere century of time could not be expected to alter.
Rumford was the sole founder of the enterprise, but it was Davy who
gave it the final and definitive cast. He it was who established the
tradition that the Royal Institution was to be essentially a laboratory
for brilliant original investigations, the investigator to deliver
a yearly course of lectures, but to be otherwise untrammelled. It
occupied, and has continued to occupy, the anomalous position of a
school to which pupils are on no account admitted, and whose professors
teach nothing except by a brief course of lectures to which whoever
cares to pay the admission price may freely enter.
But the marvellous results achieved at the Royal Institution have more
than justified the existence of so anomalous an enterprise. Superlatives
are always dangerous, but it may well be doubted whether there is
another single institution in the world where so many novel original
discoveries in physical science have been made as have been brought to
light in the laboratories of the building on Albemarle Street during
this first century of its occupancy; for practically all that is to
be credited to Thomas Young, Humphry Davy, Michael Faraday, and John
Tyndall, not to mention living investigators, is to be credited also to
the Royal Institution, whose professorial chairs these great men have
successively occupied. Davy spent here the best years of his youth
and prime. Faraday, his direct successor, came to the institution in a
subordinate capacity as a mere boy, and was the life of the institution
for half a century. Tyndall gave it forty years of service. What wonder,
then, that the Briton speaks of the institution as the "Pantheon of
Science"?
If you visit the Royal Institution to-day you will find it in most
exterior respects not unlike what it presumably was a century ago. Its
long, stone front, dinged with age, with its somewhat Pantheon-like
colonnade, has an appearance of dignity rather than of striking
impressiveness. The main entrance, jutting full on the sidewalk, is at
the street level, and the glass door gives hospitable glimpses of the
interior. Entering, one finds himself in a main central hall, at the
foot of the main central staircase. The air of eminent respectability
so characteristic of the British institution is over all; likewise
the pervasive hush of British reserve. But you will not miss also the
atmosphere of sincere if uneffusive British courtesy.
At your right, as you mount the stairway, is a large statue of Faraday;
on the wall right ahead is a bronze medallion of Tyndall, placed beneath
a large portrait of Davy. At the turn of the stairs is a marble bust of
Wollaston. Farther on, in hall and library, you will find other busts of
Faraday, other portraits of Davy; portraits of Faraday everywhere,
and various other busts of notables who have had connection with the
institution. You will be shown the lecture-hall where Davy, Faraday,
and Tyndall pronounced their marvellous discourses; the arrangement, the
seats, the cushions even if appearances speak truly, and certainly the
lecture-desk itself, unchanged within the century. You may see the crude
balance, clumsy indeed to modern eyes, with which Davy performed his
wonders. The names and the memories of three great men--Davy,
Faraday, and Tyndall--will be incessantly before you, and the least
impressionable person could not well escape a certain sense of
consecration of his surroundings. The hush that is over everything seems
but fitting.
All that is as it should be. But there are other memories connected with
these surroundings which are not so tangibly presented to the senses.
For where, amid all these busts and portraits, is the image of that
other great man, the founder of the institution, the sole originator
of the enterprise which has made possible the aggregation of all
these names and these memories? Where are the remembrances of
that extraordinary man whom the original charter describes as "our
well-beloved Benjamin, Count of Rumford?" Well, you will find a portrait
of him, it is true, if you search far enough, hung high above a doorway
in a room with other portraits. But one finds it hard to escape the
feeling that there has been just a trifling miscarriage of justice in
the disposal. Doubtless there was no such intention, but the truth seems
to be that the glamour of the newer fame of Faraday has dazzled a little
the eyes of the rulers of the institution of the present generation.
But that, after all, is a small matter about which to quibble. There is
glory enough for all in the Royal Institution, and the disposal of busts
and portraits is unworthy to be mentioned in connection with the lasting
fame of the great men who are here in question. It would matter little
if there were no portrait at all of Rumford here, for all the world
knows that the Royal Institution itself is in effect his monument. His
name will always be linked in scientific annals with the names of Young,
Davy, Faraday, and Tyndall. And it is worthy such association, for
neither in native genius nor in realized accomplishments was Rumford
inferior to these successors.
FROM LIQUID CHLORINE TO LIQUID HYDROGEN
Nor is it merely by mutual association with the history of the Royal
Institution that these great names are linked. There was a curious
and even more lasting bond between them in the character of their
scientific discoveries. They were all pioneers in the study of those
manifestations of molecular activity which we now, following Young
himself, term energy. Thus Rumford, Davy, and Young stood almost alone
among the prominent scientists of the world at the beginning of the
century in upholding the idea that heat is not a material substance--a
chemical element--but merely a manifestation of the activities of
particles of matter. Rumford's papers on this thesis, communicated to
the Royal Society, were almost the first widely heralded claims for this
then novel idea. Then Davy came forward in support of Rumford, with
his famous experiment of melting ice by friction. It was perhaps
this intellectual affinity that led Rumford to select Davy for
the professorship at the Royal Institution, and thus in a sense to
predetermine the character of the scientific work that should be
accomplished there--the impulse which Davy himself received from
Rum-ford being passed on to his pupil Faraday. There is, then, an
intangible but none the less potent web of association between the
scientific work of Rumford and some of the most important researches
that were conducted at the Royal Institution long years after his death;
and one is led to feel that it was not merely a coincidence that some
of Faraday's most important labors should have served to place on a firm
footing the thesis for which Rumford battled; and that Tyndall should
have been the first in his "beautiful book" called _Heat, a Mode of
Motion_, to give wide popular announcement to the fact that at last the
scientific world had accepted the proposition which Rumford had vainly
demonstrated three-quarters of a century before.
This same web of association extends just as clearly to the most
important work which has been done at the Royal Institution in the
present generation, and which is still being prosecuted there--the
work, namely, of Professor James Dewar on the properties of matter at
excessively low temperatures. Indeed, this work is in the clearest sense
a direct continuation of researches which Davy and Faraday inaugurated
in 1823 and which Faraday continued in 1844. In the former year Faraday,
acting on a suggestion of Davy's, performed an experiment which resulted
in the production of a "clear yellow oil" which was presently proved to
be liquid chlorine. Now chlorine, in its pure state, had previously been
known (except in a forgotten experiment of Northmore's) only as a gas.
Its transmutation into liquid form was therefore regarded as a very
startling phenomenon. But the clew thus gained, other gases were
subjected to similar conditions by Davy, and particularly by Faraday,
with the result that several of them, including sulphurous, carbonic,
and hydrochloric acids were liquefied. The method employed, stated in
familiar terms, was the application of cold and of pressure. The results
went far towards justifying an extraordinary prediction made by that
extraordinary man, John Dalton, as long ago as 1801, to the effect that
by sufficient cooling and compressing all gases might be transformed
into liquids--a conclusion to which Dalton had vaulted, with the
sureness of supreme genius, from his famous studies of the properties of
aqueous vapor.
Between Dalton's theoretical conclusion, however, and experimental
demonstration there was a tremendous gap, which the means at the
disposal of the scientific world in 1823 did not enable Davy and Faraday
more than partially to bridge. A long list of gases, including the
familiar oxygen, hydrogen, and nitrogen, resisted all their efforts
utterly--notwithstanding the facility with which hydrogen and oxygen
are liquefied when combined in the form of water-vapor, and the relative
ease with which nitrogen and hydrogen, combined to form ammonia, could
also be liquefied. Davy and Faraday were well satisfied of the truth of
Dalton's proposition, but they saw the futility of further efforts
to put it into effect until new means of producing, on the one hand,
greater pressures, and, on the other, more extreme degrees of cold,
should be practically available. So the experiments of 1823 were
abandoned.
But in 1844 Faraday returned to them, armed now with new weapons, in the
way of better air-pumps and colder freezing mixtures, which the labors
of other workers, chiefly Thilorier, Mitchell, and Natterer, had made
available. With these new means, and without the application of any
principle other than the use of cold and pressure as before, Faraday now
succeeded in reducing to the liquid form all the gases then known with
the exception of six; while a large number of these substances were
still further reduced, by the application of the extreme degrees of
cold now attained, to the condition of solids. The six gases which still
proved intractable, and which hence came to be spoken of as "permanent
gases," were nitrous oxide, marsh gas, carbonic oxide, oxygen, nitrogen,
and hydrogen.
These six refractory gases now became a target for the experiments of a
host of workers in all parts of the world. The resources of mechanical
ingenuity of the time were exhausted in the effort to produce low
temperatures on the one hand and high pressures on the other. Thus
Andrews, in England, using the bath of solid carbonic acid and ether
which Thilorier had discovered, and which produces a degree of cold
of--80° Centigrade, applied a pressure of five hundred atmospheres, or
nearly four tons to the square inch, without producing any change of
state. Natterer increased this pressure to two thousand seven hundred
atmospheres, or twenty-one tons to the square inch, with the same
negative results. The result of Andrews' experiments in particular was
the final proof of what Cagniard de la Tour had early suspected
and Faraday had firmly believed, that pressure alone, regardless of
temperature, is not sufficient to reduce a gas to the liquid state. In
other words, the fact of a so-called "critical temperature," varying
for different substances, above which a given substance is always a gas,
regardless of pressure, was definitively discovered. It became clear,
then, that before the resistant gases would be liquefied means of
reaching extremely low temperatures must be discovered. And for this,
what was needed was not so much new principles as elaborate and
costly machinery for the application of a principle long familiar--the
principle, namely, that an evaporating liquid reduces the temperature of
its immediate surroundings, including its own substance.
Ingenious means of applying this principle, in connection with the means
previously employed, were developed independently by Pictet in Geneva
and Cailletet in Paris, and a little later by the Cracow professors
Wroblewski and Olzewski, also working independently. Pictet, working on
a commercial scale, employed a series of liquefied gases to gain lower
and lower temperatures by successive stages. Evaporating sulphurous acid
liquefied carbonic acid, and this in evaporating brought oxygen under
pressure to near its liquefaction point; and, the pressure being
suddenly released (a method employed in Faraday's earliest experiments),
the rapid expansion of the compressed oxygen liquefies a portion of
its substance. This result was obtained in 1877 by Pictet and Cailletet
almost simultaneously. Cailletet had also liquefied the newly discovered
acetylene gas. Five years later Wroblewski liquefied marsh gas, and the
following year nitrogen; while carbonic oxide and nitrous oxide yielded
to Olzewski in 1884. Thus forty years of effort had been required to
conquer five of Faraday's refractory gases, and the sixth, hydrogen,
still remains resistant. Hydrogen had, indeed, been seen to assume the
form of visible vapor, but it had not been reduced to the so-called
static state--that is, the droplets had not been collected in an
appreciable quantity, as water is collected in a cup. Until this should
be done, the final problem of the liquefaction of hydrogen could not be
regarded as satisfactorily solved.
More than another decade was required to make this final step in the
completion, of Faraday's work. And, oddly enough, yet very fittingly,
it was reserved for Faraday's successor in the chair at the Royal
Institution to effect this culmination. Since 1884 Professor Dewar's
work has made the Royal Institution again the centre of low-temperature
research. By means of improved machinery and of ingenious devices for
shielding the substance operated on from the accession of heat, to which
reference will be made more in detail presently, Professor Dewar was
able to liquefy the gas fluorine, recently isolated by Moussan, and the
recently discovered gas helium in 1897. And in May, 1898, he was able to
announce that hydrogen also had yielded, and for the first time in
the history of science that* elusive substance, hitherto "permanently"
gaseous, was held as a tangible liquid in a cuplike receptacle; and this
closing scene of the long struggle was enacted in the same laboratory in
which Faraday performed the first liquefaction experiment with chlorine
just three-quarters of a century before.
It must be noted, however, that this final stage in the liquefaction
struggle was not effected through the use of the principle of
evaporating liquids which has just been referred to, but by the
application of a quite different principle and its elaboration into a
perfectly novel method. This principle is the one established long ago
by Joule and Thomson (Lord Kelvin), that compressed gases when allowed
to expand freely are lowered in temperature. In this well-known
principle the means was at hand greatly to simplify and improve the
method of liquefaction of gases, only for a long time no one recognized
the fact. Finally, however, the idea had occurred to two men almost
simultaneously and quite independently. One of these was Professor
Linde, the well-known German experimenter with refrigeration processes;
the other, Dr. William Hampson, a young English physician. Each of these
men conceived the idea--and ultimately elaborated it in practice--of
accumulating the cooling effect of an expanding gas by allowing the
expansion to take place through a small orifice into a chamber in which
the coil containing the compressed gas was held. In Dr. Hampson's words:
"The method consists in directing all the gas immediately after its
expansion over the coils which contain the compressed gas that is on its
way to the expansion-point. The cold developed by expansion in the first
expanded gas is thus communicated to the oncoming compressed gas, which
consequently expands from, and therefore to, a lower temperature
than the preceding portion. It communicates in the same way its own
intensified cold to the succeeding portion of compressed gas, which, in
its turn, is made colder, both before and after expansion, than any
that had gone before. This intensification of cooling goes on until the
expansion-temperature is far lower than it was at starting; and if
the apparatus be well arranged the effect is so powerful that even the
smaller amount of cooling due to the free expansion of gas through a
throttle-valve, though pronounced by Siemens and Coleman incapable
of being utilized, may be made to liquefy air without using other
refrigerants."
So well is this principle carried out in Dr. Hamp-son's apparatus for
liquefying air that compressed air passing into the coil at ordinary
temperature without other means of refrigeration begins to liquefy in
about six minutes--a result that seems almost miraculous when it is
understood that the essential mechanism by which this is brought about
is contained in a cylinder only eighteen inches long and seven inches in
diameter.
As has been said, it was by adopting this principle of self-intensive
refrigeration that Professor Dewar was able to liquefy hydrogen. More
recently the same result has been attained through use of the same
principle by Professor Ramsay and Dr. Travers at University College,
London, who are to be credited also with first publishing a detailed
account of the various stages of the process. It appears that the use of
the self-intensification principle alone is not sufficient with hydrogen
as it is with the less volatile gases, including air, for the reason
that at all ordinary temperatures hydrogen does not cool in expanding,
but actually becomes warmer. It is only after the compressed hydrogen
has been cooled by immersion in refrigerating media of very low
temperature that this gas becomes amenable to the law of cooling on
expansion. In the apparatus used at University College the coil of
compressed hydrogen is passed successively through (1) a jar containing
alcohol and solid carbonic acid at a temperature of--80° Centigrade; (2)
a chamber containing liquid air at atmospheric pressure, and (3)
liquid air boiling in a vacuum bringing the temperature to perhaps 2050
Centigrade before entering the Hampson coil, in which expansion and
the self-intensive refrigeration lead to actual liquefaction. With this
apparatus Dr. Travers succeeded in producing an abundant quantity of
liquid hydrogen for use in the experiments on the new gases that were
first discovered in the same laboratory through the experiments on
liquid air--gases about which I shall have something more to say in
another chapter.
PRINCIPLES AND EXPERIMENTS
At first blush it seems a very marvellous thing, this liquefaction
of substances that under all ordinary conditions are gaseous. It is
certainly a little startling to have a cup of clear, water-like liquid
offered one, with the assurance that it is nothing but air; still more
so to have the same air presented in the form of a white "avalanche
snow." In a certain sense it is marvellous, because the mechanical
difficulties that have been overcome in reducing the air to these
unusual conditions are great. Yet, in another and broader view, there
is nothing more wonderful about liquid air than about liquid water, or
liquid mercury, or liquid iron. Long before air was actually liquefied,
it was perfectly understood by men of science that under certain
conditions it could be liquefied just as surely as water, mercury, iron,
and every other substance could be brought to a similar state. This
being known, and the principles involved understood, had there been
nothing more involved than the bare effort to realize these conditions
all the recent low-temperature work would have been mere scientific
child's-play, and liquid air would be but a toy of science. But in point
of fact there are many other things than this involved; new principles
were being searched for and found in the course of the application of
the old ones; new light was being thrown into many dark corners; new
fields of research, some of them as yet barely entered, were being
thrown open to the investigator; new applications of energy, of vast
importance not merely in pure science but in commercial life as well,
were being made available. That is why the low-temperature work must be
regarded as one of the most important scientific accomplishments of our
century.
At the very outset it was this work in large measure which gave the
final answer to the long-mooted question as to the nature of heat,
demonstrating the correctness of Count Rumford's view that heat is
only a condition not itself a substance. Since about the middle of the
century this view, known as the mechanical theory of heat, has been the
constant guide of the physicists in all their experiments, and any
one who would understand the low-temperature phenomena must keep this
conception of the nature of heat clearly and constantly in mind. To
understand the theory, one must think of all matter as composed
of minute isolated particles or molecules, which are always in
motion--vibrating, if you will. He must mentally magnify and
visualize these particles till he sees them quivering before him,
like tuning-forks held in the hand. Remember, then, that, like the
tuning-fork, each molecule would, if left to itself, quiver less and
less violently, until it ran down altogether, but that the motion thus
lessening is not really lost. It is sent out in the form of ether waves,
which can set up like motion in any other particles which they reach, be
they near or remote; or it is transmitted as a direct push--a kick,
if you will--to any other particle with which the molecule comes in
physical contact.
But note now, further, that our molecule, while incessantly giving out
its energy of motion in ether waves and in direct pushes, is at the same
time just as ceaslessly receiving motion from the ether waves made by
other atoms, and by the return push of the molecules against which it
pushes. In a word, then, every molecule of matter is at once a centre
for the distribution of motion (sending out impulses which affect,
sooner or later, every other atom of matter in the universe), and, from
the other point of view, also a centre for the reception of motion from
every direction and from every other particle of matter in the universe.
Whether any given molecule will on the whole gain motion or lose it
depends clearly on the simple mechanical principles of give and take.
From equally familiar mechanical principles, it is clear that our
vibrating molecule, in virtue of its vibrations, is elastic, tending to
be thrown back from every other molecule with which it comes in contact,
just as a vibrating tuning-fork kicks itself away from anything it
touches. And of course the vigor of the recoil will depend upon the
vigor of the vibration and the previous movements. But since these
movements constitute temperature, this is another way of saying that
the higher the temperature of a body the more its molecules will tend to
spring asunder, such separation in the aggregate constituting expansion
of the mass as a whole. Thus the familiar fact of expansion of a body
under increased temperature is explained.
But now, since all molecules are vibrating, and so tending to separate,
it is clear that no unconfined mass of molecules would long remain in
contiguity unless some counter influence tended to draw them together.
Such a counter influence in fact exists, and is termed the "force" of
cohesion. This force is a veritable gravitation influence, drawing every
molecule towards every other molecule. Possibly it is identical with
gravitation. It seems subject to some law of decreasing in power with
the square of the distance; or, at any rate, it clearly becomes less
potent as the distance through which it operates increases.
Now, between this force of cohesion which tends to draw the molecules
together, and the heat vibrations which tend to throw the molecules
farther asunder, there seems to be an incessant battle. If cohesion
prevails, the molecules are held for the time into à relatively fixed
system, which we term the solid state. If the two forces about balance
each other, the molecules move among themselves more freely but maintain
an average distance, and we term the condition the liquid state. But if
the heat impulse preponderates, the molecules (unless restrained from
without) fly farther and farther asunder, moving so actively that when
they collide the recoil is too great to be checked by cohesion, and this
condition we term the gaseous state.
Now after this statement, it is clear that what the low-temperature
worker does when he would liquefy a gas is to become the champion of the
force of cohesion. He cannot directly aid it, for so far as is known it
is an unalterable quantity, like gravitation. But he can accomplish the
same thing indirectly by weakening the power of the rival force. Thus,
if he encloses a portion of gas in a cylinder and drives a piston down
against it, he is virtually aiding cohesion by forcing the molecules
closer together, so that the hold of cohesion, acting through a less
distance, is stronger. What he accomplishes here is not all gain,
however, for the bounding molecules, thus jammed together, come in
collision with one another more and more frequently, and thus their
average activity of vibration is increased and not diminished; in
other words, the temperature of the gas has risen in virtue of the
compression. Compression alone, then, will not avail to enable cohesion
to win the battle.
But the physicist has another resource. He may place the cylinder of gas
in a cold medium, so that the heat vibrations sent into it will be less
vigorous than those it sends out. That is a blow the molecule cannot
withstand. It is quite impotent to cease sending out the impulses
however little comes in return; hence the aggregate motion becomes less
and less active, until finally the molecule is moving so sluggishly
that when it collides with its fellow cohesion is able to hold it there.
Cohesion, then, has won the battle, and the gas has become a liquid.
Such, stated in terms of the mechanical theory of heat, is what is
brought to pass when a gas is liquefied in the laboratory of the
physicist. It remains only to note that different chemical substances
show the widest diversity as to the exact point of temperature at which
this balance of the expansive and cohesive tendencies is affected, but
that the point, under uniform conditions of pressure, is always the same
for the same substance. This diversity has to do pretty clearly with the
size of the individual molecules involved; but its exact explanation is
not yet forthcoming, and, except in a general way, the physicist
would not be able to predict the "critical temperature" of any new gas
presented to him. But once this has been determined by experiment, he
always knows just what to expect of any given substance. He knows, for
example, that in a mixture of gases hydrogen would still remain gaseous
after all the others had assumed the liquid state, and most of them the
solid state as well.
These mechanical conceptions well in mind, it is clear that what the
would-be liquefier of gases has all along sought to attain is merely
the insulation of the portion of matter with which he worked against the
access of heat-impulse from its environment. It is clear that were any
texture known which would permit a heat-impulse to pass through it in
one direction only, nothing more would be necessary than to place a
portion of gas in such a receptacle of this substance, so faced as to
permit egress but not entrance of the heat, and the gas thus enclosed,
were it hydrogen itself, would very soon become liquid and solid,
through spontaneous giving off of its energy, without any manipulation
whatever. Contrariwise, were the faces of the receptacle reversed, a
piece of iron placed within it would be made red-hot and melted though
the receptacle were kept packed in salt and ice and no heat applied
except such as came from this freezing mixture. One could cook a
beefsteak with a cake of ice had he but such a material as this with
which to make his stove. Not even Rumford or our modern Edward Atkinson
ever dreamed of such economy of fuel as that.
But, unfortunately, no such substance as this is known, nor, indeed, any
substance that will fully prevent the passage of heat-impulses in either
direction. Hence one of the greatest tasks of the experimenters has
been to find a receptacle that would insulate a cooled substance even
partially from the incessant bombardment of heat-impulses from without.
It is obvious that unless such an insulating receptacle could be
provided none of the more resistent gases, such as oxygen, could be
long kept liquid, even when once brought to that condition, since an
environment of requisite frigidity could not practicably be provided.
But now another phase of the problem presents itself to the
experimenter. Oxygen has assumed the quiescent liquid state, to be
sure, but in so doing it has fallen below the temperature of its cooling
medium; hence it is now receiving from that medium more energy of
vibration than it gives, and unless this is prevented very soon its
particles will again have power to kick themselves apart and resume the
gaseous state. Something, then, must be done to insulate the liquefied
gas, else it will retain the liquid state for too short a time to be
much experimented with. How might such insulation be accomplished?
The most successful attack upon this important problem has been made by
Professor Dewar. He invented a receptacle for holding liquefied gases
which, while not fulfilling the ideal conditions referred to above, yet
accomplishes a very remarkable degree of heat insulation. In consists of
a glass vessel with double walls, the space between which is rendered
a vacuum of the highest practicable degree. This vacuum, containing
practically no particles of matter, cannot, of course, convey
heat-impulses to or from the matter in the receptacle with any degree
of rapidity. Thus one of the two possible means of heat transfer is shut
off and a degree of insulation afforded the liquefied substance. But
of course the other channel, ether radiation, remains. Even this may be
blocked to a large extent, however, by leaving a trace of mercury vapor
in the vacuum space, which will be deposited as a fine mirror on
the inner surface of the chamber. This mirror serves as an admirable
reflector of the heat-rays that traverse the vacuum, sending more
than half of them back again. So, by the combined action of vacuum and
mirror, the amount of heat that can penetrate to the interior of the
receptacle is reduced to about one-thirtieth of what would enter an
ordinary vessel. In other words, a quantity of liquefied gas which would
evaporate in one minute from an ordinary vessel will last half an hour
in one of Professor Dewar's best vacuum vessels. Thus in one of these
vessels a quantity of liquefied air, for example, can be kept for a
considerable time in an atmosphere at ordinary temperature, and will
only volatilize at the surface, like water under the same conditions,
though of course more rapidly; whereas the same liquid in an ordinary
vessel would boil briskly away, like water over a fire. Only, be it
remembered, the air in "boiling" is at a temperature of about one
hundred and eighty degrees below zero, so that it would instantly freeze
almost any substance placed into it. A portion of alcohol poured on its
surface will be changed quickly into a globule of ice, which will
rattle about the sides of the vessel like a marble. That is not what one
ordinarily thinks of as a "boiling" temperature.
If the vacuum vessel containing a liquefied gas be kept in a cold
medium, and particularly if two vacuum tubes be placed together, so that
no exposed surface of liquid remains, a portion of liquefied air, for
example, may be kept almost indefinitely. Thus it becomes possible
to utilize the liquefied gas for experimental investigation of the
properties of matter at low temperatures that otherwise would be quite
impracticable. Great numbers of such experiments have been performed in
the past decade or so by all the workers with low temperatures already
mentioned, and by various others, including, fittingly enough, the
holder of the Rumford professorship of experimental physics at Harvard,
Professor Trowbridge. The work of Professor Dewar has perhaps been the
most comprehensive and varied, but the researches of Pictet, Wroblewski,
and Olzewski have also been important, and it is not always possible
to apportion credit for the various discoveries accurately, since
the authorities themselves are in unfortunate disagreement in several
questions of priority. But in any event, such questions of exact
priority have no great interest for any one but the persons directly
involved. We may quite disregard them here, confining attention to the
results themselves, which are full of interest.
The questions investigated have to do with the physical properties,
such as electrical conductivity, magnetic condition, light-absorption,
cohesion, and chemical affinities of matter at excessively low
temperatures. It is found that in all these regards most substances are
profoundly modified when excessively cooled. Thus if a piece of any pure
metal is placed in an electric circuit and plunged into liquid air, its
resistance to the passage of the electricity steadily decreases as the
metal cools, until at the temperature of the liquid it is very trifling
indeed. The conclusion seems to be justified that if the metal could be
still further cooled until it reached the theoretical "absolute zero,"
or absolutely heatless condition, the electrical resistance would also
be nil. So it appears that the heat vibrations of the molecules of a
pure metal interfere with the electrical current. The thought suggests
itself that this may be because the ether waves set up by the vibrating
molecules conflict with the ether strain which is regarded by some
theorists as constituting the electrical "current." But this simple
explanation falters before further experiments which show, paradoxically
enough, that the electrical resistance of carbon exactly reverses what
has just been said of pure metals, becoming greater and greater as the
carbon is cooled. If an hypothesis were invented to cover this case
there would still remain a puzzle in the fact that alloys of metals
do not act at all like the pure metals themselves, the electrical
resistance of such alloys being, for the most part, unaffected by
changed temperature. On the whole, then, the facts of electrical
conduction at low temperatures are quite beyond the reach of present
explanation. They must await a fuller knowledge of molecular conditions
in general than is at present available--a knowledge to which the
low-temperature work itself seems one of the surest channels.
Even further beyond the reach of present explanation are the facts as to
magnetic conditions at low temperatures. Even as to the facts themselves
different experimenters have differed somewhat, but the final conclusion
of Professor Dewar is that, after a period of fluctuation, the power of
a magnet repeatedly subjected to a liquid-air bath becomes permanently
increased. Various substances not markedly magnetic at ordinary
temperatures become so when cooled. Among these, as Professor Dewar
discovered, is liquid oxygen itself. Thus if a portion of liquid air be
further cooled until it assumes a semi-solid condition, the oxygen may
be drawn from the mass by a magnet, leaving a pure nitrogen jelly. These
facts are curious enough, and full of suggestion, but like all other
questions having to do with magnetism, they hold for the present
generation the double fascination of insoluble mystery. To be sure, one
may readily enough suggest that if magnetism be really a whirl in the
ether, this whirl is apparently interfered with by the waves of radiant
heat; or, again, that magnetism is presumably due to molecular motions
which are apparently interfered with by another kind of molecular
motions which we call heat vibrations; but there is a vagueness about
the terms of such guesses that leaves them clearly within the category
of explanations that do not explain.
When it comes to the phenomena of light, we can, as is fitting, see
our way a little more clearly, since, thanks to Thomas Young and his
successors, we know pretty definitely what light really is. So when
we learn that many substances change their color utterly at low
temperatures--red things becoming yellow and yellow things white,
for example--we can step easily and surely to at least a partial
explanation. We know that the color of any object depends simply
upon the particular ether waves of the spectrum which that particular
substance absorbs; and it does not seem anomalous that molecules packed
close together at--180° of temperature should treat the ether waves
differently than when relatively wide apart at an ordinary temperature.
Yet, after all, that may not be the clew to the explanation. The packing
of the molecules may have nothing to do with it. The real explanation
may lie in the change of the ether waves sent out by the vibrating
molecule; indeed, the fact that the waves of radiant heat and those of
light differ only in amplitude lends color to this latter supposition.
So the explanation of the changed color of the cooled substance is at
best a dubious one.
Another interesting light phenomenon is found in the observed fact that
very many substances become markedly phosphorescent at low temperatures.
Thus, according to Professor Dewar, "gelatine, celluloid, paraffine,
ivory, horn, and india-rubber become distinctly luminous, with a bluish
or greenish phosphorescence, after cooling to--180° and being stimulated
by the electric light." The same thing is true, in varying degrees,
of alcohol, nitric acid, glycerine, and of paper, leather, linen,
tortoise-shell, and sponge. Pure water is but slightly luminous, whereas
impure water glows brightly. On the other hand, alcohol loses its
phosphorescence when a trace of iodine is added to it. In general,
colored things are but little phosphorescent. Thus the white of egg is
very brilliant but the yolk much less so. Milk is much brighter than
water, and such objects as a white flower, a feather, and egg-shell
glow brilliantly. The most remarkable substances of all, says Professor
Dewar, whom I am all along quoting, are "the platinocyanides among
inorganic compounds and the ketonic compounds among organic. Ammonium
platinocyanide, cooled while stimulated by arc light, glows fully
at--180°; but on warming it glows like a lamp. It seems clear,"
Professor Dewar adds, "that the substance at this low temperature must
have acquired increased power of absorption, and it may be that at
the same time the factor of molecular friction or damping may have
diminished." The cautious terms in which this partial explanation is
couched suggest how far we still are from a full understanding of the
interesting phenomena of phosphorescence. That a molecule should be
able to vibrate in such a way as to produce the short waves of light,
dissevered from the usual linking with the vibrations represented by
high temperature, is one of the standing puzzles of physics. And the
demonstrated increase of this capacity at very low temperatures only
adds to the mystery.
There are at least two of the low-temperature phenomena, however,
that seem a little less puzzling--the facts, namely, that cohesion and
rigidity of structure are increased when a substance is cooled and that
chemical activity is very greatly reduced, in fact almost abolished.
This is quite what one would expect _a priori_--though no wise man would
dwell on his expectation in advance of the experiments--since the whole
question of liquids and solids _versus_ gases appears to be simply a
contest between cohesive forces that are tending to draw the molecules
together and the heat vibration which is tending to throw them apart.
As a substance changes from gas to liquid, and from liquid to solid,
contracting meantime, simply through the lessening of the heat
vibrations of its molecules, we might naturally expect that the solid
would become more and more tenacious in structure as its molecules came
closer and closer together, and at the same time became less and less
active, as happens when the solid is further cooled. And for once
experiment justifies the expectation. Professor De-war found that the
breaking stress of an iron wire is more than doubled when the wire
is cooled to the temperature of liquid air, and all other metals are
largely strengthened, though none other to quite the same degree.
He found that a spiral spring of fusible metal, which at ordinary
temperature was quickly drawn out into a straight wire by a weight
of one ounce, would, when cooled to -182 deg, support a weight of two
pounds, and would vibrate like a steel spring so long as it was cool.
A bell of fusible metal has a distinct metallic ring at this low
temperature; and balls of iron, tin, lead, or ivory cooled to -182
deg and dropped from a height, "in all cases have the rebound greatly
increased. The flattened surface of the lead is only one-third what it
would be at ordinary temperature." "These conditions are due solely to
the cooling, and persist only while the low temperature lasts."
If this increased strength and hardness of a contracted metal are
what one would expect on molecular principles, the decreased chemical
activity at low temperatures is no less natural-seeming, when one
reflects how generally chemical phenomena are facilitated by the
application of heat. In point of fact, it has been found that at the
temperature of liquid hydrogen practically all chemical activity
is abolished, the unruly fluorine making the only exception. The
explanation hinges on the fact that every atom, of any kind, has
power to unite with only a limited number of other atoms. When the
"affinities" of an atom are satisfied, no more atoms can enter into the
union unless some atoms already there be displaced. Such displacement
takes place constantly, under ordinary conditions of temperature,
because the vibrating atoms tend to throw themselves apart, and other
atoms may spring in to take the places just vacated--such interchange,
in fact, constituting the essence of chemical activity. But when the
temperature is reduced the heat-vibration becomes insufficient to
throw the atoms apart, hence any unions they chance to have made are
permanent, so long as the low temperature is maintained. Thus it is that
substances which attack one another eagerly at ordinary temperatures
will lie side by side, utterly inert, at the temperature of liquid air.
Under certain conditions, however, most interesting chemical experiments
have been made in which the liquefied gases, particularly oxygen, are
utilized. Thus Olzewski found that a bit of wood lighted and thrust into
liquid oxygen burns as it would in gaseous oxygen, and a red-hot iron
wire thrust into the liquid burns and spreads sparks of iron. But more
novel still was Dewar's experiment of inserting a small jet of ignited
hydrogen into the vessel of liquid oxygen; for the jet continued to
burn, forming water, of course, which was carried away as snow. The idea
of a gas-jet burning within a liquid, and having snow for smoke, is
not the least anomalous of the many strange conceptions that the
low-temperature work has made familiar.
PRACTICAL RESULTS AND ANTICIPATIONS
Such are some of the strictly scientific results of the low-temperature
work. But there are other results of a more directly practical
kind--neither more important nor more interesting on that account, to
be sure, but more directly appealing to the generality of the
non-scientific public. Of these applications, the most patent and the
first to be made available was the one forecast by Davy from the very
first--namely, the use of liquefied gases in the refrigeration of
foods. Long before the more resistant gases had been liquefied, the more
manageable ones, such as ammonia and sulphurous acid, had been utilized
on a commercial scale for refrigerating purposes. To-day every
brewery and every large cold-storage warehouse is supplied with such
a refrigerator plant, the temperature being thus regulated as is not
otherwise practicable. Many large halls are cooled in a similar manner,
and thus made comfortable in the summer. Ships carrying perishables
have the safety of their cargoes insured by a refrigerator plant. In all
large cities there are ice manufactories using the same method, and of
late even relatively small establishments, hotels, and apartment houses
have their ice-machine. It seems probable that before long all such
buildings and many private dwellings will be provided with a cooling
apparatus as regularly as they are now equipped with a heating
apparatus.
The exact details of the various refrigerator machines of course vary,
but all of them utilize the principles that the laboratory workers first
established. Indeed, the entire refrigerator industry, now assuming
significant proportions, may be said to be a direct outgrowth of that
technical work which Davy and Faraday inaugurated and prosecuted at the
Royal Institution--a result which would have been most gratifying to the
founder of the institution could he have forecast it. The usual means
of distributing the cooling fluids in the commercial plants is by
the familiar iron pipes, not dissimilar in appearance (when not in
operation) to the familiar gas, water, and steam pipes. When operating,
however, the pipes themselves are soon hidden from view by the thick
coating of frost which forms over them. In a moist beer-cellar
this coating is often several inches in thickness, giving a very
characteristic and unmistakable appearance.
Another commercial use to which refrigerator machines are now put is in
the manufacture of various drugs, where absolute purity is desirable.
As different substances congeal at different temperatures, but the same
substances at uniform pressure always at the same temperature, a
means is afforded of freeing a drug from impurities by freezing, where
sometimes the same result cannot be accomplished with like thoroughness
by any other practicable means. Indeed, by this means impurities have
been detected where not previously suspected. And Professor Ramsay has
detected some new elementary substances even, as constituents of the
air, which had previously not been dissociated from the nitrogen with
which they are usually mixed.
Such applications of the refrigerator principles as these, however,
though of vast commercial importance, are held by many enthusiasts to
be but a bagatelle compared with other uses to which liquefied gases
may some time be put. Their expectations are based upon the enormous
potentialities that are demonstrably stored in even a tiny portion of,
say, liquefied air. These are, indeed, truly appalling. Consider, for
example, a portion of air at a temperature above its critical point, to
which, as in Thilorier's experiments, a pressure of thirty-one tons to
the square inch of the encompassing wall is being applied. Recall that
action and reaction are equal, and it is apparent that the gas itself is
pushing back--struggling against being compressed, if you will--with an
equal power. Suppose the bulk of the gas is such that at this pressure
it occupies a cubical space six inches on a side--something like the
bulk of a child's toy balloon, let us say. Then the total outward
pressure which that tiny bulk of gas exerts, in its desperate molecular
struggle, is little less than five thousand tons. It would support an
enormous building without budging a hair's-breadth. If the building
weighed less than five thousand tons it would be lifted by the gas; if
much less it would be thrown high into the air as the gas expanded. It
gives one a new sense of the power of numbers to feel that infinitesimal
atoms, merely by vibrating in unison, could accomplish such a result.
But now suppose our portion of gas, instead of being placed under our
hypothetical building, is plunged into a cold medium, which will permit
its heat-vibrations to exhaust themselves without being correspondingly
restored. Then, presently, the temperature is lowered below the critical
point, and, presto! the mad struggle ceases, the atoms lie amicably
together, and the gas has become a liquid. What a transformed thing
it is now. Instead of pressing out with that enormous force, it has
voluntarily contracted as the five thousand tons pressure could not
make it do; and it lies there now, limpid and harmless-seeming, in the
receptacle, for all the world like so much water.
And, indeed, the comparison with water is more than superficial, for
in a cup of water also there are wonderful potentialities, as every
steam-engine attests. But an enormous difference, not in principle but
in practical applications, exists in the fact that the potentialities
of the water cannot be utilized until relatively high temperatures are
reached. Costly fuel must be burned and the heat applied to the water
before it can avail to do its work. But suppose we were to place our
portion of liquid air, limpid and water-like, in the cylinder of a
locomotive, where the steam of water ordinarily enters. Then, though no
fuel were burned--though the entire engine stood embedded in the snow
of an arctic winter--it would be but a few moments before the liquid air
would absorb even from this cold medium heat enough to bring it above
its critical temperature; and, its atoms now dancing apart once more and
re-exerting that enormous pressure, the piston of the engine would be
driven back and then the entire cylinder burst into fragments as the
gas sought exit. In a word, then, a portion of liquid air has a store
of potential energy which can be made kinetic merely by drawing upon
the boundless and free supply of heat which is everywhere stored in the
atmosphere we breathe and in every substance about us. The difficulty
is, not to find fuel with which to vaporize it, as in case of water,
but to keep the fuel from finding it whether or no. Were liquid air in
sufficient quantities available, the fuel problem would cease to
have any significance. But of course liquid air is not indefinitely
available, and exactly here comes the difficulty with the calculations
of many enthusiasts who hail liquefied gas as the motive power of the
near future. For of course in liquefying the air power has been applied,
for the moment wasted, and unless we can get out of the liquid more
energy than we have applied to it, there is no economy of power in
the transaction. Now the simplest study of the conditions, with the
mechanical theory of matter in mind, makes it clear that this is
precisely what one can never hope to accomplish. Action and reaction are
equal and in opposite directions at all stages of the manipulation, and
hence, under the most ideal conditions, we must expect to waste as much
work in condensing a gas (in actual practice more) as the condensed
substance can do in expanding to the original volume. Those enthusiasts
who have thought otherwise, and who have been on the point of perfecting
an apparatus which will readily and cheaply produce liquid air after
the first portion is produced, are really but following the old
perpetual-motion-machine will-o'-the-wisp.
It does not at all follow from this, however, that the energies of
liquefied air may not be utilized with enormous advantage. It is not
always the cheapest form of power-transformer that is the best for all
purposes, as the use of the electrical storage battery shows. And so it
is quite within the possibilities that a multitude of uses may be
found for the employment of liquid air as a motive power, in which its
condensed form, its transportability or other properties will give
it precedence over steam or electricity. It has been suggested, for
example, that liquefied gas would seem to afford the motive power par
excellence for the flying-machine, once that elusive vehicle is well in
harness, since one of the greatest problems here is to reduce the weight
of the motor apparatus. In a less degree the same problem enters into
the calculations of ships, particularly ships of war; and with them also
it may come to pass that a store of liquid air (or other gas) may come
to take the place of a far heavier store of coal. It is even within the
possibilities that the explosive powers of the same liquid may take the
place of the great magazines of powder now carried on war-ships; for,
under certain conditions, the liquefied gas will expand with explosive
suddenness and violence, an "explosion" being in any case only a very
sudden expansion of a confined gas. The use of the compressed air in the
dynamite guns, as demonstrated in the Cuban campaign, is a step in this
direction. And, indeed, the use of compressed air in many commercial
fields already competing with steam and electricity is a step towards
the use of air still further compressed, and cooled, meantime, to a
condition of liquidity. The enormous advantages of the air actually
liquefied, and so for the moment quiescent, over the air merely
compressed, and hence requiring a powerful retort to hold it, are patent
at a glance. But, on the other hand, the difficulty of keeping it liquid
is a disadvantage that is equally patent. How the balance will be struck
between these contending advantages and disadvantages it remains for
the practical engineering inventors of the future--the near future,
probably--to demonstrate.
Meantime there is another line of application of the ideas which the
low-temperature work has brought into prominence which has a peculiar
interest in the present connection because of its singularly Rumfordian
cast, so to speak, I mean the idea of the insulation of cooled or heated
objects in the ordinary affairs of life, as, for example, in cooking.
The subject was a veritable hobby with the founder of the Royal
Institution all his life. He studied the heat-transmitting and
heat-reflecting properties of various substances, including such
directly practical applications as rough surfaces _versus_ smooth
surfaces for stoves, the best color for clothing in summer and in
winter, and the like. He promulgated his ideas far and wide, and
demonstrated all over Europe the extreme wastefulness of current methods
of using fuel. To a certain extent his ideas were adopted everywhere,
yet on the whole the public proved singularly apathetic; and, especially
in America, an astounding wastefulness in the use of fuel is the general
custom now as it was a century ago. A French cook will prepare an
entire dinner with a splinter of wood, a handful of charcoal, and a
half-shovelful of coke, while the same fuel would barely suffice to
kindle the fire in an American cook-stove. Even more wonderful is the
German stove, with its great bulk of brick and mortar and its glazed
tile surface, in which, by keeping the heat in the room instead of
sending it up the chimney, a few bits of compressed coal do the work of
a hodful.
It is one merit of the low-temperature work, I repeat, to have called
attention to the possibilities of heat insulation in application to "the
useful purposes of life." If Professor Dewar's vacuum vessel can reduce
the heat-transmitting capacity of a vessel by almost ninety-seven per
cent., why should not the same principle, in modified form, be applied
to various household appliances--to ice-boxes, for example, and
to cooking utensils, even to ovens and cook-stoves? Even in the
construction of the walls of houses the principles of heat insulation
might advantageously be given far more attention than is usual at
present; and no doubt will be so soon as the European sense of economy
shall be brought home to the people of the land of progress and
inventions. The principles to be applied are already clearly to hand,
thanks largely to the technical workers with low temperatures. It
remains now for the practical inventors to make the "application to the
useful purposes of life." The technical scientists, ignoring the example
which Rumford and a few others have set, have usually no concern with
such uninteresting concerns.
For the technical scientists themselves, however, the low-temperature
field is still full of inviting possibilities of a strictly technical
kind. The last gas has indeed been liquefied, but that by no means
implies the last stage of discovery. With the successive conquest of
this gas and of that, lower and lower levels of temperature have been
reached, but the final goal still lies well beyond. This is the north
pole of the physicist's world, the absolute zero of temperature--the
point at which the heat-vibrations of matter are supposed to be
absolutely stilled. Theoretically this point lies 2720 below the
Centigrade zero. With the liquefaction of hydrogen, a temperature of
about -253 deg or -254 deg Centigrade has been reached. So the gap
seems not so very great. But like the gap that separated Nansen from the
geographical pole, it is a very hard road to travel. How to compass it
will be the study of all the low-temperature explorers in the immediate
future. Who will first reach it, and when, and how, are questions for
the future to decide.
And when the goal is reached, what will be revealed? That is a question
as full of fascination for the physicist as the north-pole mystery
has ever been for the generality of mankind. In the one case as in
the other, any attempt to answer it to-day must partake largely of the
nature of a guess, yet certain forecasts may be made with reasonable
probability. Thus it can hardly be doubted that at the absolute zero all
matter will have the form which we term solid; and, moreover, a degree
of solidity, of tenacity and compactness greater than ever otherwise
attained. All chemical activity will presumably have ceased, and any
existing compound will retain unaltered its chemical composition so
long as absolute zero pertains; though in many, if not in all cases,
the tangible properties of the substance--its color, for example, and
perhaps its crystalline texture--will be so altered as to be no longer
recognizable by ordinary standards, any more than one would ordinarily
recognize a mass of snowlike crystals as air.
It has, indeed, been suggested that at absolute zero all matter may take
the form of an impalpable powder, the forces of cohesion being destroyed
with the vibrations of heat. But experiment seems to give no warrant to
this forecast, since cohesion seems to increase exactly in proportion
to the decrease of the heat-vibrations. The solidity of the meteorites
which come to the earth out of the depths of space, where something
approaching the zero temperature is supposed to prevail, also
contradicts this assumption. Still less warrant is there for a visionary
forecast at one time entertained that at absolute zero matter will
utterly disappear. This idea was suggested by the observation, which
first gave a clew to the existence of the absolute zero, that a gas at
ordinary temperatures and at uniform pressure contracts by 1-27 2d of
its own bulk with each successive degree of lowered temperature. If this
law held true for all temperatures, the gas would apparently contract to
nothingness when the last degree of temperature was reached, or at least
to a bulk so insignificant that it would be inappreciable by standards
of sense. But it was soon found by the low-temperature experimenters
that the law does not hold exactly at extreme temperatures, nor does it
apply at all to the rate of contraction which the substance shows after
it assumes the liquid and solid conditions. So the conception of the
disappearance of matter at zero falls quite to the ground.
But one cannot answer with so much confidence the suggestion that at
zero matter may take on properties hitherto quite unknown, and making
it, perhaps, differ as much from the conventional solid as the solid
differs from the liquid, or this from the gas. The form of vibration
which produces the phenomena of temperature has, clearly, a determining
share in the disposal of molecular relations which records itself to our
senses as a condition of gaseousness, liquidity, or solidity; hence it
would be rash to predict just what inter-molecular relations may not
become possible when the heat-vibration is altogether in abeyance. That
certain other forms of activity may be able to assert themselves in
unwonted measure seems clearly forecast in the phenomena of increased
magnetism, and of phosphorescence at low temperatures above outlined.
Whether still more novel phenomena may put in an appearance at the
absolute zero, and if so, what may be their nature, are questions that
must await the verdict of experiment. But the possibility that this may
occur, together with the utter novelty of the entire subject, gives
the low-temperature work precedence over almost every other subject
now before the world for investigation (possible exceptions being
radio-activity and bacteriology). The quest of the geographical pole is
but a child's pursuit compared with the quest of the absolute zero. In
vital interest the one falls as far short of the other as the cold of
frozen water falls short of the cold of frozen air.
Where, when, and by whom the absolute zero will be first reached are
questions that may be answered from the most unexpected quarter. But it
is interesting to know that great preparations are being made today in
the laboratories of the Royal Institution for a further attack upon the
problem. Already the research equipment there is the best in the world
in this field, and recently this has been completely overhauled and
still further perfected. It would not be strange, then, in view of past
triumphs, if the final goal of the low-temperature workers should be
first reached in the same laboratory where the outer territories of
the unknown land were first penetrated three-quarters of a century ago.
There would seem to be a poetic fitness in the trend of events should it
so transpire. But of course poetic fitness does not always rule in the
land of science.
IV. SOME PHYSICAL LABORATORIES AND PHYSICAL PROBLEMS
SIR NORMAN LOCKYER AND SOLAR CHEMISTRY