78 shales 253 sandstones 345 limestones

SiO₂ 58.11 78.31 5.19

Al₃O₂ 15.40 4.76 .81

Fe₂O₃ 4.02 1.08 .54

FeO 2.45 .30

MnO 2.44 1.16 7.89

CaO 3.10 5.50 42.57

Na₃O 1.30 .45 .05

K₂O 3.24 1.32 .33

H₂O+ 3.66 1.32 .56

H₂O- 1.33 .31 .21

CO₂ 2.63 5.04 41.54

TiO₃ .65 .25 .06

P₃O₅ .17 .08 .04

SO₃ .65 .07 .05

Organic carbon .80 — —

(100.) (100.) approx. (100.)

Many persons upon learning that average shale, and even “clay dirt,” may

contain 15% alumina, Al₂O₃ (equivalent to almost 8% metallic aluminum),

become thoughtlessly and erroneously enthusiastic about aluminum ore

possibilities on their farms or properties. The aluminum is there all

right, but it is so securely combined with silica and other elements

that the cost of extraction is now greater than the price of aluminum

obtained from less abundant ores. Until chemists find a method of

extraction of the metal from ordinary clay or shale that can be carried

out at considerably less expense than is now possible, the vast

quantities of clay and shale on the earth’s surface must be considered a

distant reserve of a prohibitively high cost aluminum.

Missouri possesses a little bauxitic clay in the southeastern part of

the state but unfortunately does not contain deposits of high grade

bauxite, the chief ore of aluminum, and so does not contribute to the

aluminum production of the United States (see the discussion under

DIASPORE CLAY). Arkansas is a leading producer of bauxite, but the

geological conditions present in that bauxite locality are so different

from Missouri geology that little hope is held for finding bauxite in

Missouri, except possibly in the extreme southeastern part.

The Common Rocks and Minerals of Missouri · 第 15 / 73 题