ACETYLENE FROM IODOFORM.

P. CAZENEUVE publishes in the _Comptes Rendus_ a new method for the

preparation of acetylene, which consists in mixing iodoform intimately

with moist and finely divided silver. An abundant evolution of acetylene

takes place without heating. The reaction is represented by the

following formula: 2CHI_{3} + 6Ag = C_{2}H_{2} + 6 AgI. The

decomposition of the iodoform is hastened if the silver is mixed with

finely divided copper, such as can be obtained by precipitating it from

its sulphate by means of zinc.

Cazeneuve also observed that most metals which have any affinity for

iodine will decompose iodoform in the presence of water, forming

acetylene and an iodide of the metal. By the use of zinc he obtained a

liquid having a pleasant ethereal odor, and a gas mixture that contained

besides acetylene an iodine compound which burned with a purple-edged,

fawn-colored flame.

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Scientific American Supplement, No. 433, April 19, 1884 · 第 37 / 69 题