CHEMICAL CHARACTERISTICS OF GEMSTONES

Since gems are embraced in the mineral kingdom, and minerals are

naturally occurring chemical substances, it follows that all the

accepted terms of chemical description can be applied to them. When a

chemist learns that ruby is an impure aluminum oxide, he understands a

great deal about the nature, origin, and behavior of ruby. He can assign

to it the chemical formula Al₂O₃, symbolizing its basic composition as

two atoms of aluminum united with three of oxygen. Similarly, other

popular gemstones can be described chemically as follows:

Diamond Carbon C

Sapphire Aluminum oxide Al₂O₃

Quartz Silicon dioxide SiO₂

Emerald Beryllium aluminum silicate Be₃Al₂(SiO₃)₆

Spinel Magnesium aluminate Mg(AlO₂)₂

Significantly, ruby and sapphire are chemically identical, both being of

the mineral species corundum. As already explained, the difference in

color is due entirely to very slight traces of chemical impurities.

Frequently, the impurities are present in irregular patches that give

spotty color effects.

Some mineral species possess many of the desirable qualities of

gemstones yet cannot be used as gems because they are chemically active

and therefore are less durable. They undergo alteration and

decomposition when exposed to light or to one or another of such

substances as air, water, skin acids and oils.

3

THE SHAPING OF GEMSTONES

Gemstone crystals often have naturally brilliant, reflecting faces, but

rarely are they perfect and unblemished. Also, their natural shapes do

not provide the best expression of their luster, brilliance, dispersion,

color, and other inherent properties. In fashioning a gemstone, the

skilled artisan tries to develop these hidden assets and to otherwise

enhance the gemstone’s general beauty.

From ancient times until the 1600’s little was attempted in the way of

shaping gemstones other than to smooth or polish the natural form.

Although similarly smoothed, or _tumbled_, gemstones recently have

returned to fashion, the finest pieces of gem rough are now converted

mainly into _faceted_, or shaped, stones. Standard types of facets—the

flat faces that are ground and polished on the rough gem material—have

been given individual and group names. A typical example is the

_brilliant_ cut, which is most commonly used to best bring out the

qualities of a diamond.

[Illustration: The standard brilliant cut, with a pattern of many

facets, is commonly used for gemstones having a high refractive

index and, therefore, great brilliance.]

[Illustration: Characteristic of the standard brilliant cut are the

32 crown facets surrounding a relatively small, flat, table facet

and the 24 pavilion facets and culet at the bottom of the stone.]

[Illustration: Ideal proportions for the standard brilliant cut have

been carefully determined so that the maximum amount of light will

be reflected back out the top of the stone. Incorrect proportions

cause the light to be lost at the bottom of the stone.]

[Illustration: The step cut, often called the emerald cut,

frequently is used for colored stones because the large table

permits a good view of the color.]

[Illustration: The emerald or step cut provides a large table and a

full bottom for the stone. Although the number of crown and pavilion

facets may vary, the general pattern is maintained.]

[Illustration: The simplified English brilliant cut takes maximum

advantage of the strong dispersion of diamond, with its flashes of

fire, but the fewer facets provide less sparkle than the standard

brilliant cut.]

The diagram shows a brilliant-cut diamond with angles and facets

arranged to give the stone maximum internal reflection as well as to

make use of its strong dispersive ability. Certain of the light beams

passing into a brilliant-cut diamond produce colorless brilliance by

being reflected back out of the stone through the _table_ by which they

entered. Other light beams, emerging through inclined facets, are split

up by dispersion into the rainbow, or fire, effect so prized in

diamonds. A stone that has been cut too wide for its depth, with

incorrect facet angles, will look large for its weight but its

brilliance and fire will have been drastically reduced.

[Illustration: The English brilliant cut has 28 crown and pavilion

facets—28 fewer than the standard brilliant cut.]

[Illustration: The Dutch rose cut is a very simple one that is used

mainly for small diamonds in jewelry that features a larger, colored

stone. It is based on a form that originated in India and was

introduced through Venice.]

For other purposes and for other kinds of precious stones a number of

basic cuts have been developed. The _brilliant_ and _step_ cuts are by

far the commonest of these basic cuts, but modern jewelry design

frequently uses such fancy cuts as the baguette, cut-corner triangle,

epaulet, half moon, hexagon, keystone, kite, lozenge, marquise,

pentagon, square, trapeze, and triangle. Some of these are shown here.

[Illustration: Just as the English brilliant cut, because of its 28

fewer facets, has less sparkle than the standard brilliant cut, the

step brilliant, with its 20 additional facets, has greater sparkle.]

[Illustration: The step brilliant cut is a complicated modification

of the standard brilliant. With an additional 12 facets in the crown

and 8 in the pavilion, the step brilliant has 78 facets, compared

with the 58 of the standard.]

[Illustration: Various kinds of cuts have been devised for special

purposes in jewelry design. These include the pentagon (1), lozenge

(2), hexagon (3), cut-corner triangle (4), kite (5), keystone (6),

epaulet (7), baguette (8), trapeze (9) and square (10).]

[Illustration: With this typical trim saw, water is used as a

coolant for the rapidly rotating metal disk, which has a

diamond-impregnated rim. Here, the blade is cutting its way through

a piece of gem tourmaline.]

In general, there are three operations in preparing a gemstone from the

rough—sawing, grinding, and polishing. Sawing usually is accomplished by

using a thin, diamond-impregnated, rapidly rotating disk of soft iron or

bronze, with oil or water being used as a coolant. The very hard diamond

dust literally scratches its way through the stone. Once the stone is

sawed to shape, the facets are ground and polished on a rotating

horizontal disk by the use of various abrasives. For rough grinding,

silicon carbide—or sometimes diamond powder—is used. Scratches are

removed and a high polish is given by the use of tin oxide, pumice,

rouge, or other fine-grained abrasives. The thick disks, or laps, are

made of cast iron, copper, lead, pewter, wood, cloth, leather, and

certain other materials. Since each species of gemstone differs in its

characteristics, each must be treated somewhat differently as to sawing

and lapping speeds, kind of lap, and choice of abrasives. Because of the

greatly increased interest in gem cutting as a hobby and the large

number of amateur cutters, a substantial market has developed in the

United States for lapidary supplies and equipment. New kinds of

machinery, new abrasives, and new kinds of saws and laps are introduced

regularly. Fundamentally, however, the process still involves sawing,

grinding, and polishing.

[Illustration: The final step in preparing a gemstone from rough is

the applying of a high polish by pressing the stone against a

rotating disk that has an extremely fine abrasive on its surface.

Here, the disk is of felt, and the abrasive is tin oxide.]

[Illustration: The cabochon cut gets its name from the French word

“caboche,” meaning pate or knob, a reference to the rounded top of

the stone. Here, from top to bottom, beginning at left, are

cabochons of turquoise, agate, and petrified wood; jasper,

smithsonite, and williamsite; and amazonite, petoskey stone, and

carnelian. (Two-thirds actual size.)]

[Illustration: These exquisite bowls, measuring 2 to 3 inches

across, are part of a set of 35 carved by George Ashley of Pala,

Calif., from gem materials found in the United States. Left to

right: paisley agate from California, petrified wood from Arizona,

black jade from Wyoming, chrysocolla from Arizona, and variscite

from Utah. (One-third actual size.)]

Shaping of gemstones is not limited to geometric faceting. Many stones,

especially those which are opaque or which produce stars and cat’s-eyes,

are cut as _cabochons_. This ancient, and probably oldest, cutting style

consists merely of a raised and rounded form. When extended completely

around the stone, the cabochon form results in a bead that can be

drilled and strung. Many cabochons, especially those of less expensive

gem materials, are now cut in large quantities to standard sizes in

order to fit mass-produced gem mountings.

Sculpting in gemstones is a much more intricate, nongeometric kind of

shaping. Although tools differ in detail, and the gem sculptor must

possess an artistic eye as well as lapidary skill, the basic processes

of sawing, grinding, and polishing are the same.

[Illustration: This coral carving, 11 inches tall without the stand,

owes its thin, graceful, willowy shape to the skill of the artist in

following the contour of a natural coral branch.]

[Illustration: The contemporary sculptor Oskar III J. W. Hansen

visualized and created the likeness of a spirited stallion in this

4½-inch turquoise carving, a gift of George Gilmer.]

[Illustration: This world-famed crystal ball, given to the

Collection as a memorial to W. R. Warner by his widow, represents

another phase of the lapidary art. Cut from a block of Burmese

quartz estimated to weigh 1000 pounds, this extremely valuable,

flawless, colorless sphere has a diameter of 12⅝ inches and weighs

106¾ pounds.]

4

GEM SUBSTITUTES

Because of their rarity and relatively high cost, the number of real

gems used throughout recorded times must be insignificant compared to

the number of gem substitutes used. There are records of glass and

ceramic imitations of gems as early as 3000 B.C. Certainly, the world

gem markets today are flooded with man-made gems. There even has been

developed a laboratory process for growing a coating of synthetic

emerald on the surface of a faceted stone of natural colorless beryl.

The recut gem looks like a natural emerald, and it has natural

inclusions that totally synthetic emeralds lack.

In general, gem substitutes can be classified as imitation stones,

assembled stones, reconstructed and altered stones, and synthetic

stones.

Gems in the Smithsonian Institution · 第 4 / 22 题