THE ELECTRO-CHEMICAL EQUIVALENT OF SILVER.

A very careful and important determination of the electrochemical

equivalent of silver has been made at the observatory of the Physical

Institute of Würzbourg, and the results are that an ampere current

flowing for a second, or a coulomb of electricity deposits 1.1183

milligrammes of silver or 0.3281 milligramme of copper, and decomposes

0.09328 milligramme of water, a result agreeing closely with that of

Lord Rayleigh recently communicated to the Physical Society. An ampere

therefore deposits 4.0259 grammes of silver per hour; Kohlrausch's

value is 4.0824, a value hitherto accepted universally. This value is

so useful in measuring electric currents with accuracy, and free from

the disturbances of magnetism, etc., that it is eminently satisfactory

to find the German value agree with that of Lord Rayleigh, which will

probably be adopted by English electricians.

* * * * *

Scientific American Supplement, No. 441, June 14, 1884. · 第 44 / 60 题