LIMESTONE.
A large part of the structure of the earth's crust is formed of a
substance called limestone. Ordinary limestone is a compound of common
lime and carbon dioxide, a gas that is found mixed with the air to a
very small degree. Carbon dioxide will be better known by the older
people as carbonic acid. It is a gas that is given off whenever wood and
coal are burned, or any substance containing carbon. It is composed of
one atom of carbon to two of oxygen. Every ton of coal that is burned
sends off three and two-thirds tons of this gas. The increase in weight
comes from the fact that every atom of carbon unites with two of oxygen,
which it takes from the air, and the oxygen is heavier than the carbon.
In comparing the relative weights of atoms (the smallest combinable
particle of a solid, liquid, or gas) we use the hydrogen atom as the
unit of comparison and call it "one," because it is the lightest of all
atoms. The carbon atom is twelve times heavier than the hydrogen atom,
and the oxygen atom is sixteen times heavier. Hence it will be seen
readily how a ton of coal will form two and two-thirds times its weight
of carbonic dioxide. Lime, having a strong affinity or attraction for
this gas, has absorbed it from the air and water, forming what is known
as carbonate of lime--which is the ordinary limestone. Chalk and the
various marbles are also carbonates of lime. Limestone strata in the
crust of the earth are found in all the periods of the earth's
formation. All forms of sea shells that were once the homes of animal
life are constructed of this compound; and in the later formations of
limestone, in the Secondary and Tertiary periods, we find this rock to
be made up almost entirely of marine shells, some of them microscopic in
size. The earlier or older formations of limestone that are found deeper
down in the earth's crust are less mingled with these marine shells.
This comes from the fact that the first deposition of limestone strata
occurred before the later forms of sea life had developed. Whatever
signs of life are found in these lower stratifications are of the very
lowest order. It is not to be understood that animal life is a necessary
factor in the formation of limestone, but it has been an incidental
feature which no doubt has been the chief means of gathering up from the
water this compound and precipitating it into the great limestone
strata that are everywhere found.
Carbonate of lime is found in solution in nearly, if not quite, all of
the mineral waters, and is also found in the water of the ocean. In
earlier times it must have been held in solution in much greater
quantities than at present. The myriads of sea animals that existed, and
that still exist, gathered from the water this substance, which formed
their shells, and served as a house in which they lived. New germs were
continually forming new shells, while the older ones ceased to live as
animals, and their houses in which they lived were precipitated to the
bottom of the ocean, where they were bound together as limestone rock.
These sea animals no doubt caused a much more rapid formation of
limestone than would or could have been the case without their
existence.
One can thus readily see what an important factor animal life has been
in the process of world-building. This process is still going on, but
probably not to the same extent as in former ages, because it is not
likely that there is so much carbonate of lime held in solution as there
was before these great limestone beds were formed. Limestone, however,
is easily disintegrated by the action of water. We find the spring water
impregnated with it as well as that of the small streams and rivers.
Pure water is a powerful solvent. When the rains fall upon the earth the
water percolates through it and through the limestone strata, which
gradually wears away the limestone and carries it back to the ocean, so
that the process of tearing down and building up is continually going
on. The great caves that are found everywhere in the limestone regions
were formed by the action of water. The great Mammoth Cave of Kentucky,
which is said to have 200 miles of underground passages, has been
entirely worn out by the action of running water.
Some years ago the writer visited this cave and had an opportunity to
study the wonderful eroding or gnawing-out effect of water on limestone.
At some period earlier in the history of the earth there was evidently
an underground river or large stream of water that found its way through
the crevices of the rocks, and gradually wore out a great bed for
itself, which was fed by lateral streams pouring into the main branch,
each one of which lateral branches cut its own channel. A plan view of
the Mammoth Cave presents a picture not unlike that of a great river
with numerous branches emptying into it, all of them showing the
windings such as we see in a river and its feeders upon the surface of
the earth. There are three sets of these channels, one above the other,
and we do not find the water till we get to the bottom of the third
underground story, so to speak. There is one place in this system of
underground channels where the dripping from the roof of the upper
channels has cut a great well hole many feet in diameter perpendicularly
down through the whole system to a great depth. The sides of this great
well hole are fluted into grooves caused by the constant downflow of the
water. Although the amount of water flowing down through this well hole
is very small, it is continually at work. Like interest on money, it
never rests, each minute that passes has eaten away some of the great
rock.
In other portions of the cave the dripping of the water is so gradual
that the carbonate of lime hardens and forms what are called
stalactites, that hang like icicles from the roof of the cave. Sometimes
the water runs down so slowly upon these stalactites that it evaporates
as fast as it appears, leaving behind its little load of carbonate of
lime. If, however, there is a drip, there are formations built also from
the lime in the dropping water on the floor of the cave, and these are
called stalagmites. In time the stalactites and the stalagmites will
meet, forming a great column reaching from floor to ceiling. Some of
these formations, when they are free from foreign substances, are very
beautiful. They are also very hard, giving off a metallic musical tone
when struck by any hard substance.
We have already stated that limestone is a compound of ordinary lime and
carbon dioxide, forming a carbonate of lime. This statement does not
give a complete analysis of all the elements entering into limestone. In
the first place lime itself is a compound formed of two elementary
substances, calcium and oxygen. The lime molecule is composed of one
atom of calcium and one of oxygen. Neither calcium nor lime is found
pure in nature. Inasmuch as carbon dioxide is composed of one atom of
carbon and two of oxygen, and lime is composed of one atom of calcium
and one of oxygen, when we have the two combined the molecule of
carbonate of lime, or, as it is technically called, calcic carbonate, is
composed of one atom of calcium, one of carbon and three of oxygen,
(lime plus carbon dioxide).
As before stated, lime is not found un-combined with other substances in
nature. And as it is of great economic importance, it will be profitable
to know how it is formed. Lime is produced from ordinary limestone by
burning it in kilns where it is subjected to a heat of a certain
temperature for a number of hours. The heat drives off the carbon
dioxide, which, as we have seen, has taken away from each molecule of
the compound all of the carbon and two atoms of the oxygen, while all
of the calcium is retained with one atom of oxygen, leaving ordinary
lime. Lime, then, is simply oxide of calcium.
As all know, it is used almost exclusively for making mortar for
building purposes. In order to do this we have to put it through the
process of "slacking," by pouring water upon it, and here another
chemical change takes place. The water unites with the lime, when
immediately the heat that was expended in throwing off the carbon
dioxide and was stored in the lime as energy is now given up again in
the form of heat. When a considerable bulk of lime is slacked very
rapidly the heat that is given off is so great that it will produce
combustion. Here is a beautiful illustration of what has been
erroneously called "latent heat." It is "heat stored as potential
energy," that is released by the combination of lime with water.
Slackened lime, then, is called calcic hydrate.
Very little of the limestone that we find is absolutely pure. It is
considered good when it does not contain over five or six per cent. of
foreign substance. When more than this is present the lime is considered
poor, and when it reaches fifteen per cent. or more of impurities it
assumes the property of hardening under water and is called cement.
Carbonate of lime is found in several other forms; for instance, the
various kinds of marble and chalk are carbonates of lime. The
composition of marble and chalk is exactly the same as that of
limestone. The difference is chiefly one of molecular rather than
chemical structure. Marble is what chemists would call an allotropic or
changed form of limestone; and, as before stated, the difference seems
to consist in the fact that the marble assumes a crystalline arrangement
of its atoms and will therefore take a high polish, which is not true of
ordinary limestone. Marble varies greatly in coloring and texture, all
of which differences are explainable under the one head of molecular
arrangement. Nearly pure carbon exists in three distinct forms--the
diamond, graphite, and charcoal. As is the case with marble, these
differences in the different forms of carbon are not chemical, but
molecular differences. The substances are the same, but their
infinitesimal particles are differently arranged.
Carbonate of lime--as it exists in its various forms, as limestone, from
which lime and cement are made, and marble, which is such an important
element in the arts--is a substance of great importance to man. We have
already noted some of the processes that nature uses in gathering up
these substances from the ocean by the employment of various forms of
animal life. Here is another. Whoever has visited the Bermudas has seen
an island wholly formed of what is called coral rock. Coral is a
structure produced by a peculiar form of sea animal that gathers up the
calcareous or lime-like matter floating in the sea water, and builds a
house of it in which to live during the little lifetime that is allotted
to him. When he dies his children do not occupy the old home, but build
a new one, which is a superstructure planted upon the old one as a
foundation. This process of growth sometimes takes the form of a tree or
plant, and coral trees grow upon trees and plants upon plants, until a
structure is erected having its foundation upon the bottom of the ocean,
that finally reaches up until it rises above the surface of the water;
and here--after through years the water has brought sea-weed and drift
to decay and form soil, and the birds have brought seeds and
fertilization, and vegetable life is prospering--another animal called
man builds his home upon it. The material that the coral is formed of is
substantially the same as that we find in the minute shells of the
limestone rocks.
The great chalk cliffs that are found on the coasts of the English
channel are the work of a sea animal microscopic in size. At one time it
was a question among scientists how these chalk cliffs were formed, but
when the microscope was invented this mystery, as well as many others,
was solved. The chemical components of chalk are precisely the same as
those of limestone. The microscope shows that chalk is almost wholly a
product of very small organized shells. The animals who are the
architects of the chalk cliffs are called "foraminifera"--bearing shells
perforated with little holes. The chief difference between chalk and
limestone seems to be in the size of the shells of which they are
respectively made up and in the manner of the bonding of these shells
together. The shells in a lump of chalk are held much more loosely than
those in a lump of limestone. These intrepid workers are still actively
changing the structure of the bottoms of seas and oceans, and forming
new islands, which in turn become the substructure that supports new
life, animal and vegetable. And when we consider the great part
performed by these microscopic architects and builders it is not a
misnomer to speak of the building of a world.