ANALYSES OF NATURAL GAS.

--------------------+--------+--------+--------+--------+--------+--------+

| 1 | 2 | 3 | 4 | 5 | 6 |

--------------------+--------+--------+--------+--------+--------+--------+

When tested.........|10-28-84|10-29-84|11-24-84|12-4-84 |10-18-84|10-25-84|

| per ct.| per ct.| per ct.| per ct.| per ct.| per ct.|

Carbonic acid ......| 0.8 | 0.6 | Nil. | 0.4 | Nil. | 0.30|

Carbonic oxide......| 1.0 | 0.8 | .58 | 0.4 | 1.0 | 0.30|

Oxygen... ... ......| 1.1 | 0.8 | .78 | 0.8 | 2.10| 1.20|

Olefiant gas .......| 0.7 | 0.8 | 0.98| 0.6 | 0.80| 0.6 |

Ethylic hydride ....| 3.6 | 5.5 | 7.92| 12.30 | 5.20| 4.8 |

Marsh gas ..........| 72.18| 65.25| 60.70| 49.58 | 57.85| 75.16|

Hydrogen ...........| 20.02| 26.16| 29.03| 35.92 | 9.64| 14.45|

Nitrogen ...........| Nil. | Nil. | Nil. | Nil. | 23.41| 2.89|

Heat units .........|728,746 |698,852 |627,170 |745,813 |592,380 |745,591 |

--------------------+--------+--------+--------+--------+--------+--------+

"We will now show how the natural gas compares with coal, weight for

weight, or, in other words, how many cubic feet of natural gas contain as

many heat units as a given weight of coal, say a ton. In order to

accomplish this end we will be obliged, as I have said before, to assume

as a basis for our calculations what I consider a gas of an average

chemical composition, viz.:

Per cent.

Carbonic acid............................ 0.60

Carbonic oxide........................... 0.60

Oxygen................................... 0.80

Olefiant gas............................. 1.00

Ethylic hydride.......................... 5.00

Marsh gas............................... 67.00

Hydrogen................................ 22.00

Nitrogen................................. 3.00

"Now, by the specific gravity of these gases we find that 100 liters of

this gas will weigh 64.8585 grammes, thus:

Weight,

Liters. grammes.

Marsh gas................. 67.0 48.0256

Olefiant gas.............. 1.0 1.2534

Ethylic hydride........... 5.0 6.7200

Hydrogen.................. 22.0 1.9712

Nitrogen.................. 3.0 3.7632

Carbonic acid............. 0.6 1.2257

Carbonic oxide............ 0.6 0.7526

Oxygen.................... 0.8 1.1468

-------

Total................................... 64.8585

"Then, if we take the heat units of these gases, we will find:

Heat units

Grammes. contained.

Marsh gas................ 48.0256 627,358

Olefiant gas............. 1.2534 14,910

Ethylic hydride.......... 6.7200 77,679

Hydrogen................. 1.9712 67,929

Carbonic oxide........... 0.7526 1,808

Nitrogen................. 3.7630 -----

Carbonic acid............ 1.2257 -----

Oxygen................... 1.1468 -----

------- -------

Totals 64.8585 789,694

"64.8585 grammes are almost exactly 1,000 grains, and 1 cubic foot of

this gas will weigh 267.9 grains; then the 100 liters, or 64.8585

grammes, or 1,000 grains, are 3,761 cubic feet; 3,761 cubic feet of this

gas contains 789,694 heat units, and 1,000 cubic feet will contain

210,069,604 heat units. Now, 1,000 cubic feet of this gas will weigh

265,887 grains, or in round numbers 38 lb. avoirdupois. We find that

64.8585 grammes, or 1,000 grains, of carbon contain 523,046 heat units,

and 265,887 grains, or 38 lb., of carbon contain 139,398,896 heat units.

Then 57.25 lb. of carbon contain the same number of heat units as 1,000

cubic feet of the natural gas, viz., 210,069,604. Now, if we say that

coke contains in round numbers 90 per cent. carbon, then we will have

62.97 lb. of coke, equal in heat units to 1,000 cubic feet of natural

gas. Then, if a ton of coke, or 2,000 lb., cost 10s., 62.97 lb. will cost

4d., or 1,000 cubic feet of gas is worth 4d. for its heating power. We

will now compare the heating power of this gas with bituminous coal,

taking as a basis a coal slightly above the general average of the

Pittsburg coal, viz.:

Per cent.

Carbon................................... 82.75

Hydrogen................................. 5.31

Nitrogen................................. 1.04

Oxygen................................... 4.64

Ash...................................... 5.31

Sulphur.................................. 0.95

"We find that 38 lb. of this coal contains 146,903,820 heat units. The

64.4 lb. of this coal contains 210,069,640 heat units, or 54.4 lb. of

coal is equal in its heating power to 1,000 cubic feet of natural gas. If

our coal cost us 5s. per ton of 2,000 lb., then 54.4 lb. costs 1.632d.,

and 1,000 cubic feet of gas is worth for its heat units 1.632d. As the

price of coal increases or decreases, the value of the gas will naturally

vary in like proportions. Thus, with the price of coal at 10s. per ton

the gas will be worth 3.264d. per 1,000 cubic feet. If 54.4 lb. of coal

is equal to 1,000 cubic feet of gas, then one ton, or 2,000 lb., is equal

to 36,764 cubic feet, or 2,240 lb. of coal is equal to 40,768 cubic feet

of natural gas. If we compare this gas with anthracite coal, we find that

1,000 cubic feet of gas is equal to 58.4 lb. of this coal, and 2,000 lb.

of coal is equal to 34,246 cubic feet of natural gas. Then, if this coal

cost 26s. per ton, 1,000 cubic feet of natural gas is worth 9½d. for its

heating power. In collecting samples of this gas I have noticed some very

interesting deposits from the wells. Thus, in one well the pipe was

nearly filled up with a soft grayish-white material, which proved on

testing to be chloride of calcium. In another well, soon after the gas

vein had been struck, crystals of carbonate of ammonia were thrown out,

and upon testing the gas I found a considerable amount of that alkali,

and with this well no chloride of calcium was observed until about two

months after the gas had been struck. In these calculations of the

heating power of gas and coal no account is of course taken of the loss

of heat by radiation, etc. My object has been to compare these two fuels

merely as regards their actual value in heat units."

Bearing in mind that it is never wise to prophesy unless you know, I

hesitate to speak of the future; but considering the experience we have

had in regard to the productiveness of the oil territory, which is now

yielding 70,000 barrels of petroleum per day, and which has continued to

increase year after year for twenty years, I see no reason to doubt the

opinion of experts that the territory which has already been proved to

yield gas will suffice for at least the present generation in and about

Pittsburg.

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Scientific American Supplement, No. 520, December 19, 1885 · 第 15 / 40 题