HERBA MENTHÆ PIPERITÆ.

_Peppermint_; F. _Menthe poivrée_; G. _Pfefferminze_.

=Botanical Origin=—_Mentha piperita_ Hudson (non Linn.), an erect

usually glabrous perennial, much resembling the Common Spearmint of the

gardens, but differing from it in having the leaves all stalked, the

flowers larger, the upper whorls of flowers somewhat crowded together,

and the lower separate. In the opinion of Bentham it is possibly a mere

variety of _M. hirsuta_ L., with which it can be connected by numerous

intermediate forms.

Peppermint rapidly propagates itself by runners, and is now found in

wet places in several parts of England, as well as on the Continent. It

is cultivated on the large scale in England, France, Germany, and North

America.

=History=—_Mentha piperita_ was first observed in Hertfordshire by

Dr. Eales, and communicated to Ray, who in the second edition of his

_Synopsis Stirpium Britannicarum_, 1696, noticed it under the name

of _Mentha spicis brevioribus et habitioribus, foliis Menthæ fuscæ,

sapore fervido piperis_; and in his _Historia Plantarum_[1763] as

“_Mentha palustris_ ... _Peper-Mint_.”[1764] Dale, who found the plant

in the adjoining county of Essex, states[1765] that it is esteemed a

specific in renal and vesical calculus; and Ray, in the third edition

of his _Synopsis_, declares it superior to all other mints as a remedy

for weakness of the stomach and for diarrhœa. Peppermint was admitted

to the London Pharmacopœia in 1721, under the designation of _Mentha

piperitis sapore_.

[1759] _Philosophical Magazine_, xiii. (1838) 444.

[1760] _Journ. of Chemical Society_, ii. (1854) 11.

[1761] Flückiger, _Pharm. Journ._ vii. (1876) 75.

[1762] Price from 1824 to 1839, 40_s._ to 48_s._ per lb.

[1763] Tomus iii. (1704) 284.

[1764] I have examined the original specimen still preserved among

Ray’s plants in the British Museum and find it to agree perfectly with

the plant now in cultivation.—D. H.

[1765] _Pharmacologiæ Supplementum_, Lond. 1705. 117.

The cultivation of peppermint at Mitcham in Surrey dates from about

1750,[1766] at which period only a few acres of ground were there

devoted to medicinal plants. At the end of the last century, above 100

acres were cropped with peppermint. But so late as 1805 there were no

stills at Mitcham, and the herb had to be carried to London for the

extraction of the oil. Of late years the cultivation has diminished in

extent, by reason of the increased value of land and the competition of

foreign oil of peppermint.

On the Continent Mentha Piperitis was grown as early as 1771 at

Utrecht; Gaubius[1767] appears to have been the first to notice

“_Camphora Europæa Menthæ Piperitidis_,” i.e. Menthol (see page 483).

In Germany peppermint became practically known in the latter half of

the last century, especially through the recommendation of Knigge.[1768]

=Description=—The rootstock of peppermint is perennial, throwing out

runners. The stem is erect, 3 to 4 feet high, when luxuriant somewhat

branched below with erecto-patent branches, firm, quadrangular,

slightly hairy, often tinged with purple. Leaves all stalked, the

stalks of the lower ½ to ¾ of an inch long, naked or nearly so, the

leaf lanceolate, narrowed or rather rounded towards the base, the

point narrowed out and acute, the lowest 2 to 3 inches long by about

¾ of an inch broad, naked and dull green above, paler and glandular

all over, but only slightly hairy upon the veins beneath; the teeth

sharp, fine, and erecto-patent. Inflorescence in a loose lanceolate

or acutely conical spike, 2 to 3 inches long by about ¾ of an inch

broad at the base, the lowest whorls separate, and usually the lowest

bracts leaf-like. Bracteoles lanceolate-acuminate, about equalling

the expanded flowers, slightly ciliated. Pedicels 1 to 1½ lines long,

purplish, glandular but not hairy. Calyx often purplish, the tube about

1 line long and the teeth ½ a line, the tube campanulate-cylindrical,

purplish, not hairy, but dotted over with prominent glands; the teeth

lanceolate subulate, furnished with short erecto-patent hairs. Corolla

reddish-purple about twice as long as the calyx, naked both within and

without. Nut smooth[1769] (_rugose_, according to our observation). The

odour and taste are strongly aromatic.

In var. 2. _vulgaris_ of Sole, _M. piperita_ β. Smith, the plant is

more hairy, with the spikes broader and shorter, or even bluntly

capitate. colourless, pale yellow, or greenish liquid, of sp. gr.

varying from 0·84 to 0·92. We learn from information kindly supplied

by Messrs. Schimmel and Co., Leipzig, that the best peppermint grown

in Germany, carefully dried, affords from 1 to 1·25 per cent. of oil.

It has a strong and agreeable odour, with a powerful aromatic taste,

followed by a sensation of cold when air is drawn into the mouth. We

find that the Mitcham oil examined by polarized light in a column 50

mm. long, deviates from 14°·2 to 10°·7 to the left, American oil 4°·3.

=Chemical Composition=—The constituent for the sake of which peppermint

is cultivated is the essential oil, _Oleum Menthæ piperitæ_, a

coloureless, pale yellow or greenish liquid, of sp. gr. varying from

0·84 to 0·92. We learn from information kindly supplied by Messrs.

Schimmel and Co., Leipzig, that the best peppermint grown in

Germany, carefully dried from 1 to 1·25 per cent of oil. It has

a strong and agreeable odour, with a powerful aromatic taste, followed

by a sensation of cold when air is drawn into the mouth. We find that

the Mitcham oil examined by polarized light in a column 50 mm. long,

deviates from 14·2° to 10·7° to the left, American oil 4·2°.

[1766] Lysons, _Environs of London_, i. (1800) 254.

[1767] _Adversariorum varii argumenti liber unus_, Leidae, 1771. 99.

[1768] _De Menthâ Piperitide Commentatio_, Erlangæ, 1780.

[1769] This description is borrowed from Mr. Baker’s paper on the

English Mints, referred to at page 480, note 1.

When oil of peppermint is cooled to -4° C., it sometimes deposits

colourless hexagonal crystals of _Peppermint Camphor_, C₁₀H₁₉OH,

called also _Menthol_. We have never observed it, nor are we aware

that menthol has been noticed in America, but it is largely afforded

by eastern mints, and found in commerce under the name of _Chinese_

or _Japanese Oil of Peppermint_,[1770] either liquid, and easily

depositing the camphor, or also forming a crystalline mass impregnated

with the liquid oil.

Pure menthol has the exquisite odour and taste of peppermint; it

forms hexagonal crystals, melting at 42° C., and boiling at 212°

C. By distilling menthol with P₂O₅ it yields menthene, C₁₀H₁₈, a

levogyrate liquid, boiling at 163°, the peculiar odour of which reminds

of peppermint.[1771] The Chinese crystallized oil of peppermint has

sometimes a bitterish after-taste and an odour similar to that of

spearmint, but by recrystallization it assumes the pure flavour.

The liquid part of the oil of peppermint has not yet been thoroughly

investigated; it appears to consist chiefly of the compound C₁₀H₁₈O.

Upon the liquid portions depend the remarkable colorations which the

oil of peppermint is capable of assuming. If 50 to 70 drops of the

crude oil are shaken with one drop of nitric acid, sp. gr. about 1·2,

the mixture changes from faintly yellowish to brownish, and, after

an hour or two, exhibits a bluish, violet or greenish colour; in

reflected light, it appears reddish and not transparent. The colour

thus produced lasts a fortnight. We have thus examined the various

samples of peppermint oil at our command, and may state that the finest

among them assume the most beautiful coloration and fluorescence,

which, however, shows very appreciable differences. An inferior oil

of American origin was not coloured; and a very old sample of an

originally excellent English oil was likewise not coloured by the test.

Menthol is not altered when similarly treated.[1772] The nitric acid

test is not capable of revealing adulterations of peppermint oil, for

the coloration takes place with an oil to which a considerable quantity

of oil of turpentine has been added.

[1770] The Chinese oil is distilled at Canton, and was exported from

Canton in 1872 to the extent of 800 lbs.; it was valued at about 30s.

per lb.—See also Flückiger in _Pharm. Journ._ Oct. 14, 1871. 321. As to

Japan we are informed that there are large plantations of peppermint;

the oil “Hakano Abura” is exported from Hiogo and Osaka, but frequently

adulterated. Mr. Holmes informed me (1879) that he found the mother

plant coming nearest to _Mentha canadensis_.—F. A. F..

[1771] On Japanese Peppermint Camphor see Beckett and Alder Wright,

_Yearbook of Pharm._ 1875. 605.

[1772] _Pharm. Journ._ Feb. 25, 1871. 682.

Remarkable colorations of a different hue are also displayed by the

various kinds of oil of peppermint if other chemical agents are

mixed with it. Thus green or brownish tints are produced by means

of _anhydrous_ chloral; the oil becomes bluish or greenish or

rose-coloured if shaken with a concentrated solution of bisulphite

of sodium. It is worthy of note that oils of different origin, which

cannot be distinguished by means of nitric acid, exhibit totally

different colorations if mixed with either of the liquids just named,

or with vapour of bromine. This behaviour may be of some use in the

examination of commercial sorts of peppermint oil.

As to bisulphite of sodium, it yields a solid compound with certain

kinds of peppermint oil, which we have not yet examined.

=Production and Commerce=—In several parts of Europe, as well as in

the United States, peppermint is cultivated on the large scale as a

medicinal plant.

In England the culture is carried on in the neighbourhood of Mitcham

in Surrey, near Wisebeach in Cambridgeshire, Market Deeping in

Lincolnshire, and Hitchin in Hertfordshire.

At Mitcham in 1850 there were about 500 acres under cultivation; in

1864 only about 219 acres.[1773] At Market Deeping there were in 1871

about 150 acres cropped with peppermint. The usual produce in oil

may be reckoned at 8 to 12 lb. per acre. The fields of peppermint

at Mitcham are level, with a rich, friable soil, well manured and

naturally retentive of moisture. The ground is kept free from weeds,

and in other respects is carefully tilled. The crop is cut in August,

and the herb is usually allowed to dry on the ground before it is

consigned to the stills. These are of large size, holding 1000 to

2000 gallons, and heated by coal; each still is furnished with a

condensing worm of the usual character, which passes out into a small

iron cage secured by a padlock, in which stands the oil separator. The

distillation is conducted at the lowest possible temperature. The water

that comes over with the oil is not distilled with another lot of herb,

but is for the most part allowed to run away, a very little only being

reserved as a perquisite of the workmen. The produce is very variable,

and no facilities exist for estimating it with accuracy.[1774] It is

however stated that a ton of dried peppermint yields from 2½ to 3½

pounds of oil, which equals 0·11 to 0·15 per cent. But we have been

assured by a grower at Mitcham that the yield is as much as 6 pounds

from a ton, or 0·26 per cent.

At Mitcham and its neighbourhood two varieties of peppermint are at

present recognized, the one being known as _White Mint_, the other as

_Black Mint_, but the differences between the two are very slight. The

Black Mint has _purple_ stems; the White Mint, _green_ stems, and as

we have observed, leaves rather more coarsely serrated than those of

the Black. The Black Mint is more prolific in essential oil than the

White, and hence more generally cultivated; but the oil of the latter

is superior in delicacy of odour and commands a higher price. White

Mint is said to be principally grown for drying in bundles, or as it is

termed “_bunching_.”

[1773] _Pharm. Journ._ x. (1851) 297. 340; also Warren in _Pharm.

Journ._ vi. (1865) 257. To these papers and to personal inquiries we

are indebted for most of the particulars relating to peppermint culture

at Mitcham.

[1774] Only the larger growers have stills. These they let to smaller

cultivators who pay so much for distilling a charge, _i.e._ whatever

the still can be made to contain, without reference to weight. Hence

the dried herb is preferred to the fresh, as a larger quantity can be

distilled at one time.

Peppermint is grown on a vastly larger scale in America, the localities

where the cultivation is carried on being Southern Michigan, Western

New York, and Ohio. In Michigan where the plant was introduced in

1855, there were in 1858 about 2100 acres devoted to its growth, all

with the exception of about 100 acres being in the county of St.

Joseph, where there are about 100 distilleries. The average produce

of this district was estimated in 1858 at 15,000 lb.; but the yield

fluctuates enormously, and in the exceptionally fine season of 1855 it

was reckoned at 30,000 lb. We must suppose that it is sometimes much

larger, for we have been informed by Mr. H. G. Hotchkiss, of Lyons,

Wayne County, State of New York, one of the most well-known dealers, in

a letter under date Oct. 10, 1871, that the quantity sent out by him

in the previous year reached the enormous amount of 57,365 lb. It is

further stated by the official statistics of Hamburg for the year 1876

that this port received 25,840 lb. of peppermint oil from the United

States and 14,890 lb. from Great Britain.

From the statistics quoted by Stearns[1775] it would appear that the

produce of oil per acre is somewhat higher in America than in England,

but from various causes information on this head cannot be very

reliable.

Peppermint is cultivated at Sens in the department of the Yonne in

France[1776] and in Germany in the environs of Leipzig, where the

little town of Cölleda produces annually as much as 40,000 cwts. of the

herb.

The annual crop of the world is supposed to yield 90,000 lb. of

peppermint oil.[1777]

Peppermint oil varies greatly in commercial value, that of Mitcham

commanding twice or three times as high a price as the finest American.

Even the oil of Mitcham is by no means uniform in quality, certain

plots of ground affording a product of superior fragrance. A damp

situation or badly drained ground is well known to be unfavourable to

the quantity and quality of oil.

The presence of weeds among the peppermint is an important cause of

deterioration to the oil, and at Mitcham some growers give a gratuity

to their labourers to induce them to be careful in throwing out other

plants when cutting the herb for distillation. One grower of peppermint

known to us was compelled to abandon the cultivation, owing to the

enormous increase of _Mentha arvensis_ L. which could not be separated,

and which when distilled with the peppermint ruined the flavour of

the latter. In America great detriment is occasioned by the growth of

_Erigeron canadensis_ L. Newly cleared ground planted with peppermint

is liable to the intrusion of another plant of the order Compositæ,

_Erechtites hieracifolia_ Raf., which is also highly injurious to the

quality of the oil.[1778]

=Uses=—A watery or spirituous solution of oil of peppermint is a

grateful stimulant, and is a frequent adjunct to other medicines. Oil

of peppermint is extensively consumed for flavouring and cordials.

[1775] To whose paper _On the Peppermint Plantations of Michigan_ in

the _Proceedings of the Americ. Pharm. Assoc._ for 1858, we owe the

few particulars for which we can here afford space.—To be farther

consulted, same _Proceedings_, 1876. 828.

[1776] _Journ. de Pharm._ viii. (1868) 130.—Abstract from Roze, _La

Menthe poivrée, sa culture en France, ses produits, falsifications de

l’essence et moyens de les reconnaître_, Paris, 1868. 43 pages.

[1777] Todd, _Proceedings Am. Ph. Ass._ 1876, 828.

[1778] Maisch, _American Journ. of Pharm._ March 1870. 120.

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