CHAPTER XX.

THE ATMOSPHERE.

The atmosphere or the air of our globe is the vast ocean of gaseous

matter at the bottom of which human beings, as well as other land

animals, dwell. While it is so thin that a vessel full of it is spoken

of in ordinary language as being empty, it yet possesses a reality

which it often displays in a very serious manner. Its presence is made

gently evident to human beings by the moderate resistance it offers to

them when they are in motion; but when itself is in motion with the

force of the hurricane or tornado, no solid matters can stand in its

path. Heavy railroad trains and massive buildings are hurled from their

positions and turned into miserable masses of wreckage, while even

strongly rooted forests are swept out of place by its vigorous breath.

The terribly destructive power of air at one moment and its mild and

subtle efficiency at another are very suggestive of the wonderful

adjustment of the forces residing in it. It is by the restrained action

of these forces that the atmospheric air is so admirably fitted to

perform its varied functions in connection with animal life. At the

same time it is so unobtrusive in its workings that its very existence

is at first scarcely noted. When at rest, it peacefully wraps the earth

about as in a gossamer veil, but when in angry agitation it scourges

country and city alike as with a whip of gigantic cables.

The height to which the atmospheric air extends above the earth is not

exactly known. But carefully devised experiments have shown that going

upward, its compactness or density diminishes very rapidly. Indeed

calculations based upon exact experiment show that at a height of fprty

miles, or thereabouts, from the surface of the earth, the air is so

highly rarified that practically it there comes to an end. In other

words, at this height a given bulk of space contains no more air than

exists in the so-called vacuum produced by a superior air-pump.

Weight of Air.

Notwithstanding the extreme tenuity of the gaseous medium in which

we live, it is capable of buoying up on its wings a multitude of

living beings of vast aggregate weight. It is firm enough to support

the millions of birds that sail in it, and the myriad of millions of

insects who yet more freely navigate it in search of food and warmth,

and in answer to the various needs of their existence.

One of the most striking evidences of the fact that air is indeed

a material substance is very easily discovered by showing that it

possesses weight. Thus suppose a properly constructed glass globe is

almost entirely emptied of air by the action of an efficient air-pump.

Suppose then that the globe is weighed. Next if it be connected with a

bell-glass containing ordinary atmospheric air over a pneumatic trough,

it may be readily seen that the air leaves the bell-glass in order to

pass into the globe. If this globe is now weighed again, it is found to

manifest a decided increase of weight. This increase is due to the air

it has received. By such means it may be easily shown that a cubic yard

of air weighs not far from two pounds.

Composition of Air.

The principal constituents of air are the two gases oxygen and

nitrogen; and of these the oxygen makes up about one-fifth and the

nitrogen about four-fifths of the whole. In addition to these principal

substances, however, certain others are always present, of which may be

specified vapor of water, carbon dioxide and ammonia gas; while more

minute quantities of a vast multitude of other gaseous substances find

a reservoir in the air. It is an unquestioned fact that the atmosphere

is likewise charged most of the time with still more minute quantities

of solid dust materials of various kinds. An example is found in the

common salt, blown up into the atmosphere from the ruffled surface of

the oceans. Now the oceans are spread over fully three-fourths of the

earth’s surface, and the winds, blowing upon the crested waves, not

only diffuse the salt over the oceans themselves but also carry it far

inland; accordingly spectrum analysis reveals the presence of salt in

almost all atmospheric air.

Just as the rivers of water flow to the ocean and bear along to

it debris of every kind—pulverized rock and earthy materials and

other washings from the soil, leaves of forests, impure products of

civilization thrown in from houses and manufacturing establishments—and

all these materials make their relatively minute contributions to the

impurities in the great ocean itself, so it is with the atmospheric

ocean. Thousands of millions of living animals pour out, with every

breath from the lungs, materials exhaled from their bodies. And so

wherever fuel is burned, or wherever manufacturing establishments

liberate gases or vapors, or even finely pulverized solids, these are

cast forth from the mouths of their reeking chimneys; and they all flow

into the great aerial sea. So then it is no unexpected circumstance

that the air should be a reservoir in which, in minute quantity, is

likely to exist every gaseous substance produced.

Offices of the Several Constituents of the Air.

The oxygen of the air is its most active constituent. This is the

substance that has already been described as essential for all

ordinary combustion and all animal respiration. By a great variety of

characteristics it is well fitted for these important offices.

The chief duty of the nitrogen appears to be to dilute the oxygen

and moderate the excessive activities that would be manifested if

the atmosphere consisted entirely of the active gas. Since iron and

other metals burn in pure oxygen, it is plain that in an atmosphere of

oxygen—containing no moderating gas like nitrogen—a fire once kindled

in a stove would not confine itself to its proper fuel, but would soon

spread to the metal of the stove itself, and so initiate conflagrations

that could hardly be restrained.

The _moisture_ in the air adds a number of wonderful and serviceable

characteristics to it. Thus it helps to retain the heat received from

the sun and so materially contributes to the sustenance of animal

and vegetable life. The heat of the sun penetrates our atmospheric

coverlet with great readiness and this heat is received by the surface

of the earth and thence is imparted to the layer of air immediately

upon it. Now the moisture contained in the atmosphere—and in principal

quantity in the portions of air closest to the earth—is one of the

chief agencies that prevent the immediate escape of that heat that the

solid earth has secured from the sun’s rays. And it is in the warm

layer of air so produced that animals and plants chiefly flourish.

Ascend a mountain’s side and a height is soon reached at which eternal

snow and cold prevail, where animal life cannot penetrate and even the

lowest forms of vegetable life can hardly make their residence. What

has thus far been said points out a valuable office of watery vapor

and one that is entirely in addition to that which this same material

performs as it floats in the clouds, ready to fall as beneficent

showers and then to proceed to the other steps in the progress of that

useful circulation which it performs as a liquid. But it may not be

out of place to mention here that the aqueous vapor in the atmosphere

appears to serve in another way for man’s pleasure, even though in this

particular no utility can be claimed. Thus the glories of sunrise and

sunset, which have delighted intelligent beings for so many ages, are

paintings upon the drapery of the firmament which the pencil of light

has been enabled to produce through the medium of the refractive power

of those gathering drops of water which float about in various forms

and combinations in the morning or the evening sky.

It has already been more than once declared that _carbon dioxide_

is poured out into the atmosphere by all the ordinary processes of

combustion. This is not only true of combustions such as those of coal

and wood and similar highly carbonaceous materials; it applies with

equal force to the animal body itself, which has been properly likened

to a furnace. The air taken into the lungs at each breath inspired,

supports during life a continual combustion, by reason of which,

minute fragments of the animal tissue are burned in all parts of the

system. One of the products of this burning is carbon dioxide, which

is carried to the lungs, thence to be exhaled as a waste product into

the atmosphere. It might at first be expected that this carbon dioxide

would accumulate and form a constantly increasing proportion of the

air. But it is one of the proper foods of vegetable life; for nature

has wonderfully provided that plants should thrive by the absorption

or inhalation of this particular gas. And so all the leaves in the

forest are continually cleansing the air of that carbon dioxide that

living animals have cast aside as a useless thing. And by a magnificent

alchemy, the result of a wonderful and beneficent plan, they turn this

waste matter of the animal frame into food for themselves, and they

cast out into the air as _their_ refuse that oxygen gas which living

animals demand. So then the two forms of living beings exist in a

harmonious partnership by reason of which each one is benefited.

An example similar to that just given with respect to carbon dioxide

is found in _ammonia gas_. This substance is one of the commonest

products of the decay and decomposition of animal matters. Wherever

animal waste is deposited upon the surface of the earth it quickly

evolves ammonia gas. This gas diffuses itself through the atmosphere

under the influence of conditions whereby it may perform an important

service; for it is always extremely soluble in water. And so as soon as

rain is condensed, whether in a gentle shower or in abundant torrents,

each drop in passing through the air gathers ammonia and carries it

down to the earth. Again, ammonia is one of the chief foods for plants.

And so the rain drops, charged with such ammonia as they have been

able to collect, bear it to the rootlets in the soil, as a valuable

and important food, and one which has been proved to have a most

stimulating influence upon their growth.

There is not opportunity here for a discussion of the offices and the

interplay of the other substances existing in atmospheric air; for they

are more local in their effects and more difficult to trace and to

describe.

The Air is not a Chemical Compound.

The importance of the atmosphere and its great abundance have naturally

led to most thorough scientific scrutiny of it. Thus the amounts of its

principal constituents have been studied with extreme care. One result

has been that the principal constituents—the oxygen and the nitrogen—

have been found to exist in air in proportions singularly constant in

amount. This fact indeed has suggested to some chemists the impression

that air is a true chemical compound. This latter suggestion appears

not to be sustained by the most rigid examinations that have been made.

In fact they give ample support to the opinion already declared—that

the air consists of a mass of merely mingled gases and that these gases

are uniformly maintained in their proper proportional amounts by the

beautiful interaction of the physical and chemical properties with

which they are endowed.

Fitness of Atmospheric Air for its Uses.

The statements already presented must have suggested to the reader

that the atmospheric air fulfils its offices in nature much as any

contrivance carefully devised by an intelligent framer would accomplish

the work for which it was planned. Beside those chemical adaptations

which have been the principal grounds upon which this line of thought

has been supported here, there are others which may be briefly

suggested.

By reason of the _mobility_ of air, as well as its tendencies to

expansion by heat, our atmosphere is necessarily in a state of most

intricate ebbing and flowing. One prominent effect of the motion thus

set up is to cause a transfer of warm air, and so a distribution of

heat, from more favored portions of the globe to the others.

This same result is also more completely attained by the influence of

the _specific heat_ of air. Atmospheric air has remarkable power, in

which it resembles to some extent water: to take up a very large amount

of _heat_ with but a slight rise in _temperature_; similarly a slight

fall of temperature is associated with a large evolution of heat.

By reason of these properties, air, like water, has an exceptional

storage power for heat. This contributes largely to the equalization of

climates.

The _elasticity_ of the atmosphere permits it to become a useful

servant of man in the transmission of sound. Thus human beings—and

with less distinctness most of the living creatures of the lower

orders—communicate their thoughts by means of spoken words through that

line of atmospheric air extending from them to their hearer or hearers.

Again the characteristics of the atmosphere are such that it _diffuses_

sunlight. By this is meant that in air, sunlight does not confine

itself to those strictly straight lines which it follows in empty

spaces. So then this property of air mitigates the blackness of shadows

and, for example, he who walks into a shady lane does not plunge into

absolute darkness, as he might if we were deprived of this beneficial

diffusing influence of the atmospheric air.

The two considerations last adduced contribute much towards making the

earth a cheerful home for human beings; for they aid materially in the

distribution of intelligible ideas. Moreover those properties of air by

virtue of which its undulating waves makes music possible, and further

those which permit the flight of light, and so allow of the existence

of the graphic arts, certainly make no mean contributions to the

happiness of man; and thus they help to furnish the earth as his place

of residence.

[Illustration: FIG. 53.—Display of fireworks on the Seine, Paris.]

Chemistry · 第 20 / 26 章