CHAPTER III.

PHYSICAL PROPERTIES.

A--CRYSTALLINE STRUCTURE.

Before proceeding to the study of precious stones as individual gems,

certain physical properties common to all must be discussed, in order to

bring the gems into separate classes, not only because of some chemical

uniformity, but also because of the unity which exists between their

physical formation and properties.

The first consideration, therefore, may advisedly be that of their

crystals, since their crystalline structure forms a ready means for the

classification of stones, and indeed for that of a multitudinous variety

of substances.

It is one of the many marvellous phenomena of nature that mineral, as

well as many vegetable and animal substances, on entering into a state

of solidity, take upon themselves a definite form called a crystal.

These crystals build themselves round an axis or axes with wonderful

regularity, and it has been found, speaking broadly, that the same

substance gives the same crystal, no matter how its character may be

altered by colour or other means. Even when mixed with other

crystallisable substances, the resulting crystals may partake of the two

varieties and become a sort of composite, yet to the physicist they are

read like an open book, and when separated by analysis they at once

revert to their original form. On this property the analyst depends

largely for his results, for in such matters as food adulteration, etc.,

the microscope unerringly reveals impurities by means of the crystals

alone, apart from other evidences.

It is most curious, too, to note that no matter how large a crystal may

be, when reduced even to small size it will be found that the crystals

are still of the same shape. If this process is taken still further, and

the substance is ground to the finest impalpable powder, as fine as

floating dust, when placed under the microscope each speck, though

perhaps invisible to the naked eye, will be seen a perfect crystal, of

the identical shape as that from which it came, one so large maybe that

its planes and angles might have been measured and defined by rule and

compass. This shows how impossible it is to alter the shape of a

crystal. We may dissolve it, pour the solution into any shaped vessel or

mould we desire, recrystallise it and obtain a solid sphere, triangle,

square, or any other form; it is also possible, in many cases, to

squeeze the crystal by pressure into a tablet, or any form we choose,

but in each case we have merely altered the _arrangement_ of the

crystals, so as to produce a differently shaped _mass_, the crystals

themselves remaining individually as before. Such can be said to be one

of the laws of crystals, and as it is found that every substance has its

own form of crystal, a science, or branch of mineralogy, has arisen,

called "crystallography," and out of the conglomeration of confused

forms there have been evolved certain rules of comparison by which all

known crystals may be classed in certain groups.

This is not so laborious a matter as would appear, for if we take a

substance which crystallises in a cube we find it is possible to draw

nine symmetrical planes, these being called "planes of symmetry," the

intersections of one or more of which planes being called "axes of

symmetry." So that in the nine planes of symmetry of the cube we get

three axes, each running through to the opposite side of the cube. One

will be through the centre of a face to the opposite face; a second will

be through the centre of one edge diagonally; the third will be found in

a line running diagonally from one point to its opposite. On turning the

cube on these three axes--as, for example, a long needle running through

a cube of soap--we shall find that four of the six identical faces of

the cube are exposed to view during each revolution of the cube on the

needle or axis.

These faces are not necessarily, or always, planes, or flat, strictly

speaking, but are often more or less curved, according to the shape of

the crystal, taking certain characteristic forms, such as the square,

various forms of triangles, the rectangle, etc., and though the crystals

may be a combination of several forms, all the faces of any particular

form are similar.

All the crystals at present known exhibit differences in their planes,

axes and lines of symmetry, and on careful comparison many of them are

found to have some features in common; so that when they are sorted out

it is seen that they are capable of being classified into thirty-three

groups. Many of these groups are analogous, so that on analysing them

still further we find that all the known crystals may be classed in six

separate systems according to their planes of symmetry, and all stones

of the same class, no matter what their variety or complexity may be,

show forms of the same group. Beginning with the highest, we have--(1)

the cubic system, with nine planes of symmetry; (2) the hexagonal, with

seven planes; (3) the tetragonal, with five planes; (4) the rhombic,

with three planes; (5) the monoclinic, with one plane; (6) the

triclinic, with no plane of symmetry at all.

In the first, the cubic--called also the isometric, monometric, or

regular--there are, as we have seen, three axes, all at right angles,

all of them being equal.

The second, the hexagonal system--called also the rhombohedral--is

different from the others in having four axes, three of them equal and

in one plane and all at 120 deg. to each other; the fourth axis is not

always equal to these three. It may be, and often is, longer or shorter.

It passes through the intersecting point of the three others, and is

perpendicular or at right angles to them.

The third of the six systems enumerated above, the tetragonal--or the

quadratic, square prismatic, dimetric, or pyramidal--system has three

axes like the cubic, but, in this case, though they are all at right

angles, two only of them are equal, the third, consequently, unequal.

The vertical or principal axis is often much longer or shorter in this

group, but the other two are always equal and lie in the horizontal

plane, at right angles to each other, and at right angles to the

vertical axis.

The fourth system, the rhombic--or orthorhombic, or prismatic, or

trimetric--has, like the tetragonal, three axes; but in this case, none

of them are equal, though the two lateral axes are at right angles to

each other, and to the vertical axis, which may vary in length, more so

even than the other two.

The fifth, the monoclinic--or clinorhombic, monosymmetric, or

oblique--system, has also three axes, all of them unequal. The two

lateral axes are at right angles to each other, but the principal or

vertical axis, which passes through the point of intersection of the two

lateral axes, is only at right angles to one of them.

In the sixth and last system, the triclinic--or anorthic, or

asymmetric--the axes are again three, but in this case, none of them are

equal and none at right angles.

It is difficult to explain these various systems without drawings, and

the foregoing may seem unnecessarily technical. It is, however,

essential that these particulars should be clearly stated in order

thoroughly to understand how stones, especially uncut stones, are

classified. These various groups must also be referred to when dealing

with the action of light and other matters, for in one or other of them

most stones are placed, notwithstanding great differences in hue and

character; thus all stones exhibiting the same crystalline structure as

the diamond are placed in the same group. Further, when the methods of

testing come to be dealt with, it will be seen that these particulars of

grouping form a certain means of testing stones and of distinguishing

spurious from real. For if a stone is offered as a real gem (the true

stone being known to lie in the highest or cubic system), it follows

that should examination prove the stone to be in the sixth system, then,

no matter how coloured or cut, no matter how perfect the imitation, the

test of its crystalline structure stamps it readily as false beyond all

shadow of doubt--for as we have seen, no human means have as yet been

forthcoming by which the crystals can be changed in form, only in

arrangement, for a diamond crystal _is_ a diamond crystal, be it in a

large mass, like the brightest and largest gem so far discovered--the

great Cullinan diamond--or the tiniest grain of microscopic

diamond-dust, and so on with all precious stones. So that in future

references, to avoid repetition, these groups will be referred to as

group 1, 2, and so on, as detailed here.

The chemistry, properties and tests of precious stones · 第 3 / 8 章