CHAPTER VII.

Quantitative Colour Nomenclature.

THE GLASS STANDARD SCALES.

At an early stage of the investigation, it was found that coloured

glass gave better results than coloured solutions, and that Red,

Yellow, and Blue, were the only colours suitable for systematic

work; it was also found that any colour could be produced by their

combination. As already described arbitrary scales were first used in

many colours, but were superseded by these three, which, when graded

into scales of equivalent value, were found to cover all daylight

colours.

Upon this evidence, scales of red, yellow and blue were constructed

of glass slips, each scale being all of one colour, with a regular

variation of intensity from 0·01 to 20·0 units, equal units of the

three scales being in equivalence with each other. The dimensions of

the unit are necessarily arbitrary, but the scales comply with the

essentials of a scientific standard, in that the divisions are equal,

and the unit recoverable. The equality of the unit divisions in the

scales, is demonstrated by a system of cross-checking. The test of

colour equivalence has already been described on pages 10 and 28.

The power of recovering the unit, is by co-relation to well-known

physical colour constants, such as is easily obtained by definite

intensities of percentage solutions, of selected pure chemical

compounds in distilled water, at standard temperatures. For example,

a one per cent. solution of pure crystallized copper sulphate

C_{2}SO_{4}5H_{2}O at 60° F. when viewed in the optical instrument in

a 1-inch stratum, must be matched by a combination of Yellow 1·58 and

Blue 1·55.

The inch of distilled water itself constitutes very little of this

colour; the colour of distilled water is remarkably uniform, and might

almost be taken as a colour constant, thus: A 2-foot stratum is matched

by Yellow 0·1 and Blue 0·34, a 4-foot stratum by Yellow 1·0 and Blue

1·45.

A one per cent. solution of _Nickel Sulphate NiSO_{4}7H_{2}O, tem._ 60°

F. in a 2-inch stratum must be matched by 2·2 Blue and 2·0 Yellow units.

A one per cent. solution of _Potassium Bichromate_ K_{2}Cr_{2}O, Tem.

60° and in a 2-inch stratum after being dulled by 0·5 neutral tint

units must be matched by 34·0 yellow and 9·6 red units.

METHOD OF DEVELOPING, MEASURING AND NAMING COLOUR.

The single sensation colours, Red, Yellow and Blue, are matchable by a

single glass from the corresponding colour scale; the depth of colour

is directly indicated by the value of the glass used.

The single sensation colours, Orange, Green and Violet, are matchable

by a combination of equal units, from two of the standard scales, the

depth of colour is directly indicated by the unit value of either of

the glasses, thus: 2·0 Blue + 2·0 Red develop 2·0 units Violet.

A given neutral grey is matchable by a combination of equal units from

the three standard scales, the depth of grey, is directly indicated by

the unit value on either of the glasses used, thus:--

3·0 Red + 3·0 yellow + 3·0 blue develop 3·0 units neutral tint.

The complex colour sensations, red and yellow oranges, yellow and

blue greens, blue and red violets are matchable by unequal glasses

from two of the standard scales; the colour developed is not directly

indicated by the unit value of the glasses, but is recorded by means of

an equation, the first half of which contains the separate values of

the glasses used, and the second half the names and the depth of the

colours they transmit. For instance--

The equation of a colour matched by 17·0 red and 2·6 blue units, is as

follows:--

Standard Glasses. Colour Developed.

Red. Blue. Violet. Red.

17·0 + 2·6 = 2·6 + 14·4

The colour developed is a red violet in these proportions.

A colour matched by

Standard Glasses. Colour Developed.

Red. Yellow. Orange. Red.

10·0 + 3·0 = 3·0 + 7·0

The colour developed is a red orange in these proportions.

A colour matched by

Standard Glasses. Colour Developed.

Yellow. Blue. Green. Yellow.

3·0 + 1·5 = 1·5 + 1·5

The colour developed is a yellow green in these proportions.

A colour matched by

Standard Glasses. Colour Developed.

Blue. Red. Blue. Violet.

6·0 + 1·8 = 4·2 + 1·8

The colour developed is a blue violet in these proportions.

The standard glass colours are necessarily of a given brightness, and

colours for measurement may be either brighter, or sadder than the

standards.

A given complex colour of less than glass standard brightness, is

matchable by unequal numbers from the three standard scales; the

smallest unit value always represents the “black,” or neutral unit

factor. The equation is as follows:--

A colour matched by

Standard Glasses. Colour Developed.

Red. Yellow. Blue. Neutral Tint. Green. Blue.

1·0 + 3·0 + 9·0 = 1·0 + 2·0 + 6·0

The colour is a blue green, in the proportion of six to two, saddened

by one of neutral tint.

A given complex colour of greater brightness than the glass standards,

is first dulled by the interception of neutral tint units, until

measurable in the manner described above; the intercepting glasses

represent the unit value of excess of brightness, and is shown in the

equation as light units, for instance--

Standard Glasses. Colour Developed.

Neutral Tint. Yellow. Blue. Light. Green. Yellow.

1·5 + 7·5 + 0·5 = 1·5 + 0·5 + 7·0

The colour is a yellow green in the proportions of 7·0 of yellow, to

0·5 of green, and 1·5 brighter than the standards.

Every daylight colour being thus measurable by a suitable combination

of standard glasses, with or without the addition of a Light, or a

Neutral Tint factor, it follows that any colour can be described both

qualitatively, and quantitatively, in terms of the colour sensations

yielded by the standard glasses and their combination. The distinct

colour sensations are those, which, by common consent are known as Red,

Yellow, Blue, Orange, Green and Violet, and they are yielded by single

glasses, or by pairs as already described; all colours therefore fall

into the following categories:--

_A._--Single colour sensations:--

1. Transmitted by single glass standards:

Red.

Yellow.

Blue.

2. Transmitted by equivalent pairs of standard glasses:

Orange.

Green.

Violet.

_B._--Double colour sensations transmitted by unequal pairs of standard

glasses.

Red orange, transmitted by unequal units of red and yellow, red

preponderating.

Yellow orange, transmitted by unequal units of red and yellow, yellow

preponderating.

Yellow green, transmitted by unequal units of yellow and blue, yellow

preponderating.

Blue green, transmitted by unequal units of yellow and blue, blue

preponderating.

Blue violet, transmitted by unequal units of blue and red, blue

preponderating.

Red violet, transmitted by unequal units of blue and red, red

preponderating.

_C._--Any of the above colours with the addition or subtraction of

neutral tint.

Neutral tint itself, is transmitted by a combination of equal units

of the standard glasses, thus three units red, yellow and blue, when

superposed, transmit three units neutral tint.

EXAMPLES.

Three units red, of standard brightness, completely describes a colour

matched by a red glass of three units, and is denoted

R. 3·0

Three units red saddened by one neutral tint, completely describes a

colour matched by a red glass standard of four units red, combined with

a blue and yellow of one unit each, and is denoted

R. 3·0 + N.T. 1·0

A given red of three units, which is one unit brighter than standards,

after having been saddened by one unit each of red, yellow and blue,

is matched by three units of red and is correctly described by

Red 3·0 + Light 1·0

Three units of violet, of standard brightness, is matched by a red and

a blue glass of three units, and is correctly described by

V. 3·0

Three units of orange, of standard brightness, is matched by a red and

a yellow glass of three units, and is correctly described by

O. 3·0

A binary red violet of standard brightness, in which red preponderates

by one unit, is matched by four units red, and a blue of three units,

and is correctly described by

R. 1·0 + V. 3·0

A binary red orange, of standard brightness, in which orange

preponderates by three units, is matched by red four and yellow three

units, and is correctly described by

R. 1·0 + O. 3·0

A red orange, of less than standard brightness by one unit, in which

orange preponderates by three units, is matched by a red five, yellow

four, blue one, and is correctly described by

R. 1·9 + O. 3·0 + N.T. 1·0

A red violet, in which red preponderates by one unit, and is one unit

brighter than standard, is first dulled by one unit red, yellow and

blue, and then matched by four red and three blue, and is correctly

described by

R. 1·0 + V. 3·0 + Light 1·0

A red orange, in which red preponderates by one unit, and is one unit

brighter than standard, is first dulled by one red, yellow and blue,

and then matched by four red, and three yellow, and is correctly

described by

R. 1·0 + O. 3·0 + Light 1·0

Light and Colour Theories, and their relation to light and colour standardization · 第 7 / 12 章