SPICES
MUSTARD
Mustard is often adulterated with mustard hulls, wheat, and rice. And
when white-colored flour of any kind is used, turmeric, Martius yellow,
or a coal-tar color is employed to give the mixture the color of
mustard. Cayenne pepper is occasionally used to impart pungency to
diluted mustard.
FLOUR
Boil 2 grams of the mustard in 4 or 5 cc. of distilled water for about
10 minutes. After it is cool, add a few drops of iodin solution slowly,
avoiding a large excess though having a little uncombined iodin. If a
blue color is produced, some starchy matter has been added to the
mustard. The intensity of the reaction is an indication of the amount of
starchy matter used. Pure mustard contains no starch and hence gives no
reaction with iodin.
COLORING MATTER
Pure mustard is a very light dull yellow, and whenever the sample is
bright yellow, there is good grounds for suspecting the presence of some
artificial coloring matter.
TURMERIC
Add strong ammonium hydroxid to the mustard, and if turmeric is present
an orange-red color is usually produced.
Make an alcoholic extract of the sample and dip a piece of filter paper
in it, and when dry draw it through a cold, saturated solution of boric
acid in water. An orange or red-brown tint produced on the paper
indicates the presence of turmeric.
Thoroughly mix 2 or 3 grams of the mustard with castor oil and filter.
If turmeric is present the filtrate will appear fluorescent.
Extract a portion of the sample with 3 times its weight of wood alcohol
and filter. Evaporate one half of the solution to dryness and add a
little hydrochloric acid to the residue. This will turn red whenever
turmeric is present, and if an excess of alkali be added it will change
to a greenish blue. Evaporate the other half to dryness and moisten with
a solution of boric acid and dry on a steam bath. A cherry-red color
indicates turmeric.
MARTIUS YELLOW OR ANALOGOUS COAL-TAR COLORING MATTER
Extract the slightly acidified sample with 95 per cent alcohol and dye
wool as directed under “Vegetables.” The wool will be dyed a bright
yellow.
_Allen’s Test._--Treat a portion of the sample with cold alcohol, and
shake vigorously for 5 minutes, then filter and evaporate the filtrate
to dryness; add enough water to take up the residue and dye some white
wool in this liquid as in the last test. When the dyed wool is wrapped
in white paper and heated to 120° in an air bath, part of the coloring
matter will be transferred to the paper. The coloring matter dissolves
readily in dilute ammonia or hot water, and on the addition of
hydrochloric acid the solution is decolorized and a yellow precipitate
formed. This distinguishes it from picric acid.
CAYENNE PEPPER
_Allen’s Test._--Boil 1 gram of the mustard for a few minutes with
alcohol, filter, and evaporate to dryness at about 100°. Taste the
residue and cayenne may be recognized by its pungency. Or heat a portion
of the extract, and smell the fumes. Irritation of the lungs and
coughing will surely follow if cayenne pepper is present.
PEPPER
Pepper may be adulterated with wheat, buckwheat, pepper husks, ground
olive stones, spent ginger. Cayenne pepper is sometimes added to
adulterated pepper to give it the normal pungency. Many of these
adulterants can be detected only by the aid of the microscope.
_Neuss’s Test._--True pepper turns an intense yellow when covered with
strong hydrochloric acid. Any adulteration can be detected at once by
the color.
GROUND OLIVE STONES OR “POIVRETTE”
Make a paste of the pepper with caustic alkali. Dilute with a large
quantity of water and wash by decantation. Olive stones will be colored
a bright yellow; pepper-husks will appear dark.
_Jumeau’s Test._--Dissolve 5 grams of iodin in a mixture of 50 cc. of
ether and 50 cc. of alcohol. Cover the bottom of a porcelain capsule
with the finely ground pepper, and add just enough of the iodin mixture
to wet the entire mass, and mix well till it has the same consistency
throughout. Let dry in the air, then powder and examine it, and if olive
stones are present they will be colored yellow. Pure pepper would have a
deep brown color.
Aniline acetate, one part aniline in 3 parts acetic acid, colors pure
pepper gray or white and olive stones yellowish brown.
CAYENNE
Heat some of the red particles found in the pepper and their
characteristic vapor is produced. Dissolve the particles in alcohol or
ether and the same vapors are produced.