I must now make one more step in explaining this question of curvature.

Now that the cylinder and sphere are balanced I shall blow in more air,

making the sphere larger; what will happen to the cylinder? The cylinder

is, as you see, very short; will it become blown out too, or what will

happen? Now that I am blowing in air you see the sphere enlarging, thus

relieving the pressure; the cylinder develops a waist, it is no longer a

cylinder, the sides are curved inwards. As I go on blowing and enlarging

the sphere, they go on falling inwards, but not indefinitely. If I were

to blow the upper bubble till it was of an enormous size the pressure

would become extremely small. Let us make the pressure nothing at all at

once by simply breaking the upper bubble, thus allowing the air a free

passage from the inside to the outside of what was the cylinder. Let me

repeat this experiment on a larger scale. I have two large glass rings,

between which I can draw out a film of the same kind. Not only is the

outline of the soap-film curved inwards, but it is exactly the same as

the smaller one in shape (Fig. 26). As there is now no pressure there

ought to be no curvature, if what I have said is correct. But look at

the soap-film. Who would venture to say that that was not curved? and

yet we had satisfied ourselves that the pressure and the curvature rose

and fell together. We now seem to have come to an absurd conclusion.

Because the pressure is reduced to nothing we say the surface must have

no curvature, and yet a glance is sufficient to show that the film is so

far curved as to have a most elegant waist. Now look at the plaster

model on the table, which is a model of a mathematical figure which also

has a waist.

[Illustration: Fig. 26.]

Let us therefore examine this cast more in detail. I have a disc of card

which has exactly the same diameter as the waist of the cast. I now hold

this edgeways against the waist (Fig. 27), and though you can see that

it does not fit the whole curve, it fits the part close to the waist

perfectly. This then shows that this part of the cast would appear

curved inwards if you looked at it sideways, to the same extent that it

would appear curved outwards if you could see it from above. So

considering the waist only, it is curved both towards the inside and

also away from the inside according to the way you look at it, and to

the same extent. The curvature inwards would make the pressure inside

less, and the curvature outwards would make it more, and as they are

equal they just balance, and there is no pressure at all. If we could in

the same way examine the bubble with the waist, we should find that this

was true not only at the waist but at every part of it. Any curved

surface like this which at every point is equally curved opposite ways,

is called a surface of no curvature, and so what seemed an absurdity is

now explained. Now this surface, which is the only one of the kind

symmetrical about an axis, except a flat surface, is called a catenoid,

because it is like a chain, as you will see directly, and, as you know,

_catena_ is the Latin for a chain. I shall now hang a chain in a loop

from a level stick, and throw a strong light upon it, so that you can

see it well (Fig. 28). This is exactly the same shape as the side of a

bubble drawn out between two rings, and open at the end to the air.[1]

[Illustration: Fig. 27.]

[Illustration: Fig. 28.]

[Footnote 1: If the reader finds these geometrical relations too

difficult to follow, he or she should skip the next pages, and go on

again at "We have found...." p. 77.]

Let us now take two rings, and having placed a bubble between them,

gradually alter the pressure. You can tell what the pressure is by

looking at the part of the film which covers either ring, which I shall

call the cap. This must be part of a sphere, and we know that the

curvature of this and the pressure inside rise and fall together. I have

now adjusted the bubble so that it is a nearly perfect sphere. If I blow

in more air the caps become more curved, showing an increased pressure,

and the sides bulge out even more than those of a sphere (Fig. 29). I

have now brought the whole bubble back to the spherical form. A little

increased pressure, as shown by the increased curvature of the cap,

makes the sides bulge more; a little less pressure, as shown by the

flattening of the caps, makes the sides bulge less. Now the sides are

straight, and the cap, as we have already seen, forms part of a sphere

of twice the diameter of the cylinder. I am still further reducing the

pressure until the caps are plane, that is, not curved at all. There is

now no pressure inside, and therefore the sides have, as we have

already seen, taken the form of a hanging chain; and now, finally, the

pressure inside is less than that outside, as you can see by the caps

being drawn inwards, and the sides have even a smaller waist than the

catenoid. We have now seen seven curves as we gradually reduced the

pressure, namely--

1. Outside the sphere.

2. The sphere.

3. Between the sphere and the cylinder.

4. The cylinder.

5. Between the cylinder and the catenoid.

6. The catenoid.

7. Inside the catenoid.

[Illustration: Fig. 29.]

Now I am not going to say much more about all these curves, but I must

refer to the very curious properties that they possess. In the first

place, they must all of them have the same curvature in every part as

the portion of the sphere which forms the cap; in the second place, they

must all be the curves of the least possible surface which can enclose

the air and join the rings as well. And finally, since they pass

insensibly from one to the other as the pressure gradually changes,

though they are distinct curves there must be some curious and intimate

relation between them. This though it is a little difficult, I shall

explain. If I were to say that these curves are the roulettes of the

conic sections I suppose I should alarm you, and at the same time

explain nothing, so I shall not put it in that way; but instead, I shall

show you a simple experiment which will throw some light upon the

subject, which you can try for yourselves at home.

[Illustration: Fig. 30.]

I have here a common bedroom candlestick with a flat round base. Hold

the candlestick exactly upright near to a white wall, then you will see

the shadow of the base on the wall below, and the outline of the shadow

is a symmetrical curve, called a hyperbola. Gradually tilt the candle

away from the wall, you will then notice the sides of the shadow

gradually branch away less and less, and when you have so far tilted the

candle away from the wall that the flame is exactly above the edge of

the base,--and you will know when this is the case, because then the

falling grease will just fall on the edge of the candlestick and splash

on to the carpet,--I have it so now,--the sides of the shadow near the

floor will be almost parallel (Fig. 30), and the shape of the shadow

will have become a curve, known as a parabola; and now when the

candlestick is still more tilted, so that the grease misses the base

altogether and falls in a gentle stream upon the carpet, you will see

that the sides of the shadow have curled round and met on the wall, and

you now have a curve like an oval, except that the two ends are alike,

and this is called an ellipse. If you go on tilting the candlestick,

then when the candle is just level, and the grease pouring away, the

shadow will be almost a circle; it would be an exact circle if the flame

did not flare up. Now if you go on tilting the candle, until at last the

candlestick is upside down, the curves already obtained will be

reproduced in the reverse order, but above instead of below you.

You may well ask what all this has to do with a soap-bubble. You will

see in a moment. When you light a candle, the base of the candlestick

throws the space behind it into darkness, and the form of this dark

space, which is everywhere round like the base, and gets larger as you

get further from the flame, is a cone, like the wooden model on the

table. The shadow cast on the wall is of course the part of the wall

which is within this cone. It is the same shape that you would find if

you were to cut a cone through with a saw, and so these curves which I

have shown you are called conic sections. You can see some of them

already made in the wooden model on the table. If you look at the

diagram on the wall (Fig. 31), you will see a complete cone at first

upright (A), then being gradually tilted over into the positions that I

have specified. The black line in the upper part of the diagram shows

where the cone is cut through, and the shaded area below shows the true

shape of these shadows, or pieces cut off, which are called sections.

Now in each of these sections there are either one or two points, each

of which is called a focus, and these are indicated by conspicuous

dots. In the case of the circle (D Fig. 31), this point is also the

centre. Now if this circle is made to roll like a wheel along the

straight line drawn just below it, a pencil at the centre will rule the

straight line which is dotted in the lower part of the figure; but if we

were to make wheels of the shapes of any of the other sections, a pencil

at the focus would certainly not draw a straight line. What shape it

would draw is not at once evident. First consider any of the elliptic

sections (C, E, or F) which you see on either side of the circle. If

these were wheels, and were made to roll, the pencil as it moved along

would also move up and down, and the line it would draw is shown dotted

as before in the lower part of the figure. In the same way the other

curves, if made to roll along a straight line, would cause pencils at

their focal points to draw the other dotted lines.

[Illustration: Fig. 31.]

We are now almost able to see what the conic section has to do with a

soap-bubble. When a soap-bubble was blown between two rings, and the

pressure inside was varied, its outline went through a series of forms,

some of which are represented by the dotted lines in the lower part of

the figure, but in every case they could have been accurately drawn by a

pencil at the focus of a suitable conic section made to roll on a

straight line. I called one of the bubble forms, if you remember, by its

name, catenoid; this is produced when there is no pressure. The dotted

curve in the second figure B is this one; and to show that this catenary

can be so drawn, I shall roll upon a straight edge a board made into the

form of the corresponding section, which is called a parabola, and let

the chalk at its focus draw its curve upon the black board. There is the

curve, and it is as I said, exactly the curve that a chain makes when

hung by its two ends. Now that a chain is so hung you see that it

exactly lies over the chalk line.

All this is rather difficult to understand, but as these forms which a

soap-bubble takes afford a beautiful example of the most important

principle of continuity, I thought it would be a pity to pass it by. It

may be put in this way. A series of bubbles may be blown between a pair

of rings. If the pressures are different the curves must be different.

In blowing them the pressures slowly and _continuously_ change, and so

the curves cannot be altogether different in kind. Though they may be

different curves, they also must pass slowly and continuously one into

the other. We find the bubble curves can be drawn by rolling wheels made

in the shape of the conic sections on a straight line, and so the conic

sections, though distinct curves, must pass slowly and continuously one

into the other. This we saw was the case, because as the candle was

slowly tilted the curves did as a fact slowly and insensibly change from

one to the other. There was only one parabola, and that was formed when

the side of the cone was parallel to the plane of section, that is when

the falling grease just touched the edge of the candlestick; there is

only one bubble with no pressure, the catenoid, and this is drawn by

rolling the parabola. As the cone is gradually inclined more, so the

sections become at first long ellipses, which gradually become more and

more round until a circle is reached, after which they become more and

more narrow until a line is reached. The corresponding bubble curves are

produced by a gradually increasing pressure, and, as the diagram shows,

these bubble curves are at first wavy (C), then they become straight

when a cylinder is formed (D), then they become wavy again (E and F),

and at last, when the cutting plane, _i. e._ the black line in the upper

figure, passes through the vertex of the cone the waves become a series

of semicircles, indicating the ordinary spherical soap-bubble. Now if

the cone is inclined ever so little more a new shape of section is seen

(G), and this being rolled, draws a curious curve with a loop in it; but

how this is so it would take too long to explain. It would also take too

long to trace the further positions of the cone, and to trace the

corresponding sections and bubble curves got by rolling them. Careful

inspection of the diagram may be sufficient to enable you to work out

for yourselves what will happen in all cases. I should explain that the

bubble surfaces are obtained by spinning the dotted lines about the

straight line in the lower part of Fig. 31 as an axis.

As you will soon find out if you try, you cannot make with a soap-bubble

a great length of any of these curves at one time, but you may get

pieces of any of them with no more apparatus than a few wire rings, a

pipe, and a little soap and water. You can even see the whole of one of

the loops of the dotted curve of the first figure (A), which is called a

nodoid, not a complete ring, for that is unstable, but a part of such a

ring. Take a piece of wire or a match, and fasten one end to a piece of

lead, so that it will stand upright in a dish of soap water, and project

half an inch or so. Hold with one hand a sheet of glass resting on the

match in middle, and blow a bubble in the water against the match. As

soon as it touches the glass plate, which should be wetted with the soap

solution, it will become a cylinder, which will meet the glass plate in

a true circle. Now very slowly incline the plate. The bubble will at

once work round to the lowest side, and try to pull itself away from the

match stick, and in doing so it will develop a loop of the nodoid, which

would be exactly true in form if the match or wire were slightly bent,

so as to meet both the glass and the surface of the soap water at a

right angle. I have described this in detail, because it is not

generally known that a complete loop of the nodoid can be made with a

soap-bubble.

[Illustration: Fig. 32.]

[Illustration: Fig. 33.]

We have found that the pressure in a short cylinder gets less if it

begins to develop a waist, and greater if it begins to bulge. Let us

therefore try and balance one with a bulge against another with a waist.

Immediately that I open the tap and let the air pass, the one with a

bulge blows air round to the one with a waist and they both become

straight. In Fig. 32 the direction of the movement of the air and of the

sides of the bubble is indicated by arrows. Let us next try the same

experiment with a pair of rather longer cylinders, say about twice as

long as they are wide. They are now ready, one with a bulge and one with

a waist. Directly I open the tap, and let the air pass from one to the

other, the one with a waist blows out the other still more (Fig. 33),

until at last it has shut itself up. It therefore behaves exactly in the

opposite way that the short cylinder did. If you try pairs of cylinders

of different lengths you will find that the change occurs when they are

just over one and a half times as long as they are wide. Now if you

imagine one of these tubes joined on to the end of the other, you will

see that a cylinder more than about three times as long as it is wide

cannot last more than a moment; because if one end were to contract ever

so little the pressure there would increase, and the narrow end would

blow air into the wider end (Fig. 34), until the sides of the narrow end

met one another. The exact length of the longest cylinder that is

stable, is a little more than three diameters. The cylinder just becomes

unstable when its length is equal to its circumference, and this is

3-1/7 diameters almost exactly.

[Illustration: Fig. 34.]

I will gradually separate these rings, keeping up a supply of air, and

you will see that when the tube gets nearly three times as long as it is

wide it is getting very difficult to manage, and then suddenly it grows

a waist nearer one end than the other, and breaks off forming a pair of

separate and unequal bubbles.

If now you have a cylinder of liquid of great length suddenly formed and

left to itself, it clearly cannot retain that form. It must break up

into a series of drops. Unfortunately the changes go on so quickly in a

falling stream of water that no one by merely looking at it could follow

the movements of the separate drops, but I hope to be able to show to

you in two or three ways exactly what is happening. You may remember

that we were able to make a large drop of one liquid in another, because

in this way the effect of the weight was neutralized, and as large drops

oscillate or change their shape much more slowly than small, it is more

easy to see what is happening. I have in this glass box water coloured

blue on which is floating paraffin, made heavier by mixing with it a

bad-smelling and dangerous liquid called bisulphide of carbon.

[Sidenote: _See Diagram at the end of the Book._

Fig. 35.]

The water is only a very little heavier than the mixture. If I now dip a

pipe into the water and let it fill, I can then raise it and allow drops

to slowly form. Drops as large as a shilling are now forming, and when

each one has reached its full size, a neck forms above it, which is

drawn out by the falling drop into a little cylinder. You will notice

that the liquid of the neck has gathered itself into a little drop which

falls away just after the large drop. The action is now going on so

slowly that you can follow it. Fig. 35 contains forty-three consecutive

views of the growth and fall of the drop taken photographically at

intervals of one-twentieth of a second. For the use to which this figure

is to be put, see page 149. If I again fill the pipe with water, and

this time draw it rapidly out of the liquid, I shall leave behind a

cylinder which will break up into balls, as you can easily see (Fig.

36). I should like now to show you, as I have this apparatus in its

place, that you can blow bubbles of water containing paraffin in the

paraffin mixture, and you will see some which have other bubbles and

drops of one or other liquid inside again. One of these compound bubble

drops is now resting stationary on a heavier layer of liquid, so that

you can see it all the better (Fig. 37). If I rapidly draw the pipe out

of the box I shall leave a long cylindrical bubble of water containing

paraffin, and this, as was the case with the water-cylinder, slowly

breaks up into spherical bubbles.

[Illustration: Fig. 36.]

[Illustration: Fig. 37.]

[Illustration: Fig. 38.]

Having now shown that a very large liquid cylinder breaks up regularly

into drops, I shall next go the other extreme, and take as an example an

excessively fine cylinder. You see a photograph of a spider on her

geometrical web (Fig. 38). If I had time I should like to tell you how

the spider goes to work to make this beautiful structure, and a great

deal about these wonderful creatures, but I must do no more than show

you that there are two kinds of web--those that point outwards, which

are hard and smooth, and those that go round and round, which are very

elastic, and which are covered with beads of a sticky liquid. Now there

are in a good web over a quarter of a million of these beads which catch

the flies for the spider's dinner. A spider makes a whole web in an

hour, and generally has to make a new one every day. She would not be

able to go round and stick all these in place, even if she knew how,

because she would not have time. Instead of this she makes use of the

way that a liquid cylinder breaks up into beads as follows. She spins a

thread, and at the same time wets it with a sticky liquid, which of

course is at first a cylinder. This cannot remain a cylinder, but breaks

up into beads, as the photograph taken with a microscope from a real web

beautifully shows (Fig. 39). You see the alternate large and small

drops, and sometimes you even see extra small drops between these again.

In order that you may see exactly how large these beads really are, I

have placed alongside a scale of thousandths of an inch, which was

photographed at the same time. To prove to you that this is what

happens, I shall now show you a web that I have made myself by stroking

a quartz fibre with a straw dipped in castor-oil. The same alternate

large and small beads are again visible just as perfect as they were in

the spider's web. In fact it is impossible to distinguish between one of

my beaded webs and a spider's by looking at them. And there is this

additional similarity--my webs are just as good as a spider's for

catching flies. You might say that a large cylinder of water in oil, or

a microscopic cylinder on a thread, is not the same as an ordinary jet

of water, and that you would like to see if it behaves as I have

described. The next photograph (Fig. 40), taken by the light of an

instantaneous electric spark, and magnified three and a quarter times,

shows a fine column of water falling from a jet. You will now see that

it is at first a cylinder, that as it goes down necks and bulges begin

to form, and at last beads separate, and you can see the little drops as

well. The beads also vibrate, becoming alternately long and wide, and

there can be no doubt that the sparkling portion of a jet, though it

appears continuous, is really made up of beads which pass so rapidly

before the eye that it is impossible to follow them. (I should explain

that for a reason which will appear later, I made a loud note by

whistling into a key at the time that this photograph was taken.)

[Illustration: Fig. 39.]

[Illustration: Fig. 40.]

Lord Rayleigh has shown that in a stream of water one twenty-fifth of an

inch in diameter, necks impressed upon the stream, even though

imperceptible, develop a thousandfold in depth every fortieth of a

second, and thus it is not difficult to understand that in such a stream

the water is already broken through before it has fallen many inches. He

has also shown that free water drops vibrate at a rate which may be

found as follows. A drop two inches in diameter makes one complete

vibration in one second. If the diameter is reduced to one quarter of

its amount, the time of vibration will be reduced to one-eighth, or if

the diameter is reduced to one-hundredth, the time will be reduced to

one-thousandth, and so on. The same relation between the diameter and

the time of breaking up applies also to cylinders. We can at once see

how fast a bead of water the size of one of those in the spider's web

would vibrate if pulled out of shape, and let go suddenly. If we take

the diameter as being one eight-hundredth of an inch, and it is really

even finer, then the bead would have a diameter of one sixteen-hundredth

of a two-inch bead, which makes one vibration in one second. It will

therefore vibrate sixty-four thousand times as fast, or sixty-four

thousand times a second. Water-drops the size of the little beads, with

a diameter of rather less than one three-thousandth of an inch, would

vibrate half a million times a second, under the sole influence of the

feebly elastic skin of water! We thus see how powerful is the influence

of the feebly elastic water-skin on drops of water that are sufficiently

small.

I shall now cause a small fountain to play, and shall allow the water as

it falls to patter upon a sheet of paper. You can see both the fountain

itself and its shadow upon the screen. You will notice that the water

comes out of the nozzle as a smooth cylinder, that it presently begins

to glitter, and that the separate drops scatter over a great space (Fig.

41). Now why should the drops scatter? All the water comes out of the

jet at the same rate and starts in the same direction, and yet after a

short way the separate drops by no means follow the same paths. Now

instead of explaining this, and then showing experiments to test the

truth of the explanation, I shall reverse the usual order, and show one

or two experiments first, which I think you will all agree are so like

magic, so wonderful are they and yet so simple, that if they had been

performed a few hundred years ago, the rash person who showed them might

have run a serious risk of being burnt alive.

[Illustration: Fig. 41.]

[Illustration: Fig. 42.]

You now see the water of the jet scattering in all directions, and you

hear it making a pattering sound on the paper on which it falls. I take

out of my pocket a stick of sealing-wax and instantly all is changed,

even though I am some way off and can touch nothing. The water ceases

to scatter; it travels in one continuous line (Fig. 42), and falls upon

the paper making a loud rattling noise which must remind you of the rain

of a thunder-storm. I come a little nearer to the fountain and the water

scatters again, but this time in quite a different way. The falling

drops are much larger than they were before. Directly I hide the

sealing-wax the jet of water recovers its old appearance, and as soon

as the sealing-wax is taken out it travels in a single line again.

Soap-Bubbles and the Forces Which Mould Them · 第 2 / 6 段