RELATION OF PRESSURE, DENSITY, AND TEMPERATURE OF LIQUIDS

§ 5. _Units of Volume._--In practical calculations the cubic foot and

gallon are largely used, and in metric countries the litre and cubic

metre (= 1000 litres). The imperial gallon is now exclusively used in

England, but the United States have retained the old English wine

gallon.

1 cub. ft. = 6.236 imp. gallons = 7.481 U.S. gallons.

1 imp. gallon = 0.1605 cub. ft. = 1.200 U.S. gallons.

1 U.S. gallon = 0.1337 cub. ft. = 0.8333 imp. gallon.

1 litre = 0.2201 imp. gallon = 0.2641 U.S. gallon.

_Density of Water._--Water at 53° F. and ordinary pressure contains

62.4 lb. per cub. ft., or 10 lb. per imperial gallon at 62° F. The

litre contains one kilogram of water at 4° C. or 1000 kilograms per

cubic metre. River and spring water is not sensibly denser than pure

water. But average sea water weighs 64 lb. per cub. ft. at 53° F. The

weight of water per cubic unit will be denoted by G. Ice free from air

weighs 57.28 lb. per cub. ft. (Leduc).

§ 6. _Compressibility of Liquids._--The most accurate experiments show

that liquids are sensibly compressed by very great pressures, and that

up to a pressure of 65 atmospheres, or about 1000 lb. per sq. in., the

compression is proportional to the pressure. The chief results of

experiment are given in the following table. Let V1 be the volume of a

liquid in cubic feet under a pressure p1 lb. per sq. ft., and V2 its

volume under a pressure p2. Then the cubical compression is (V2 -

V1)/V1, and the ratio of the increase of pressure p2 - p1 to the

cubical compression is sensibly constant. That is, k = (p2 - p1)V1/(V2

- V1) is constant. This constant is termed the elasticity of volume.

With the notation of the differential calculus,

/ / dV \ dp

k = dp / ( - -- ) = - V --.

/ \ V / dV

_Elasticity of Volume of Liquids._

+-----------+------------+-----------+------------+------------+

| | Canton. | Oersted. | Colladon | Regnault. |

| | | | and Sturm. | |

+-----------+------------+-----------+------------+------------+

| Water | 45,990,000 | 45,900,000| 42,660,000 | 44,000,000 |

| Sea water | 52,900,000 | .. | | .. |

| Mercury |705,300,000 | .. |626,100,000 |604,500,000 |

| Oil | 44,090,000 | .. | | .. |

| Alcohol | 32,060,000 | .. | 23,100,000 | .. |

+-----------+------------+-----------+------------+------------+

According to the experiments of Grassi, the compressibility of water

diminishes as the temperature increases, while that of ether, alcohol

and chloroform is increased.

§ 7. _Change of Volume and Density of Water with Change of

Temperature._--Although the change of volume of water with change of

temperature is so small that it may generally be neglected in ordinary

hydraulic calculations, yet it should be noted that there is a change

of volume which should be allowed for in very exact calculations. The

values of [rho] in the following short table, which gives data enough

for hydraulic purposes, are taken from Professor Everett's _System of

Units_.

_Density of Water at Different Temperatures._

+-------------+----------+----------+

| | | G |

| Temperature.| [rho] |Weight of |

+-----+-------+Density of|1 cub. ft.|

|Cent.| Fahr. | Water. | in lb. |

+-----+-------+----------+----------+

| 0 | 32.0 | .999884 | 62.417 |

| 1 | 33.8 | .999941 | 62.420 |

| 2 | 35.6 | .999982 | 62.423 |

| 3 | 37.4 | 1.000004 | 62.424 |

| 4 | 39.2 | 1.000013 | 62.425 |

| 5 | 41.0 | 1.000003 | 62.424 |

| 6 | 42.8 | .999983 | 62.423 |

| 7 | 44.6 | .999946 | 62.421 |

| 8 | 46.4 | .999899 | 62.418 |

| 9 | 48.2 | .999837 | 62.414 |

| 10 | 50.0 | .999760 | 62.409 |

| 11 | 51.8 | .999668 | 62.403 |

| 12 | 53.6 | .999562 | 62.397 |

| 13 | 55.4 | .999443 | 62.389 |

| 14 | 57.2 | .999312 | 62.381 |

| 15 | 59.0 | .999173 | 62.373 |

| 16 | 60.8 | .999015 | 62.363 |

| 17 | 62.6 | .998854 | 62.353 |

| 18 | 64.4 | .998667 | 62.341 |

| 19 | 66.2 | .998473 | 62.329 |

| 20 | 68.0 | .998272 | 62.316 |

| 22 | 71.6 | .997839 | 62.289 |

| 24 | 75.2 | .997380 | 62.261 |

| 26 | 78.8 | .996879 | 62.229 |

| 28 | 82.4 | .996344 | 62.196 |

| 30 | 86 | .995778 | 62.161 |

| 35 | 95 | .99469 | 62.093 |

| 40 | 104 | .99236 | 61.947 |

| 45 | 113 | .99038 | 61.823 |

| 50 | 122 | .98821 | 61.688 |

| 55 | 131 | .98583 | 61.540 |

| 60 | 140 | .98339 | 61.387 |

| 65 | 149 | .98075 | 61.222 |

| 70 | 158 | .97795 | 61.048 |

| 75 | 167 | .97499 | 60.863 |

| 80 | 176 | .97195 | 60.674 |

| 85 | 185 | .96880 | 60.477 |

| 90 | 194 | .96557 | 60.275 |

|100 | 212 | .95866 | 59.844 |

+-----+-------+----------+----------+

The weight per cubic foot has been calculated from the values of

[rho], on the assumption that 1 cub. ft. of water at 39.2° Fahr. is

62.425 lb. For ordinary calculations in hydraulics, the density of

water (which will in future be designated by the symbol G) will be

taken at 62.4 lb. per cub. ft., which is its density at 53° Fahr. It

may be noted also that ice at 32° Fahr. contains 57.3 lb. per cub. ft.

The values of [rho] are the densities in grammes per cubic centimetre.

§ 8. _Pressure Column. Free Surface Level._--Suppose a small vertical

pipe introduced into a liquid at any point P (fig. 3). Then the liquid

will rise in the pipe to a level OO, such that the pressure due to the

column in the pipe exactly balances the pressure on its mouth. If the

fluid is in motion the mouth of the pipe must be supposed accurately

parallel to the direction of motion, or the impact of the liquid at

the mouth of the pipe will have an influence on the height of the

column. If this condition is complied with, the height h of the

column is a measure of the pressure at the point P. Let [omega] be the

area of section of the pipe, h the height of the pressure column, p

the intensity of pressure at P; then

p[omega] = Gh[omega] lb.,

p/G = h;

that is, h is the height due to the pressure at p. The level OO will

be termed the free surface level corresponding to the pressure at P.

Encyclopaedia Britannica, 11th Edition, "Husband" to "Hydrolysis" Volume 14, Slice 1 · 第 29 / 207 题