CHAPTER I.

[Illustration]

COLLOTYPE

AND

PHOTO-LITHOGRAPHY

PRACTICALLY ELABORATED BY

DR. JULIUS SCHNAUSS,

Member of the Imperial German Academy of Naturalists, &c.

TRANSLATED, WITH THE AUTHOR’S SANCTION AND ASSISTANCE,

BY

EDWIN C. MIDDLETON.

TOGETHER WITH AN APPENDIX ON

STEAM PRESSES,

BY THE TRANSLATOR.

LONDON:

ILIFFE AND SON, 3, ST. BRIDE STREET, LUDGATE CIRCUS,

1889.

PRINTED BY ILIFFE AND SON, 3, ST. BRIDE STREET, LUDGATE CIRCUS,

LONDON, E.C. WORKS: COVENTRY.

CONTENTS.

CHAPTER. PAGE.

I. Introductory 9

II. Bichromates in Conjunction with Organic

Substances 12

III. Summary of the more important Printing

Processes with Chromated Gelatine 18

IV. Collotype Apparatus 25

V. Chemicals and Materials for Collotype 46

VI. Preparation of the Collotype Plate 59

VII. Negatives suitable for Collotype 72

VIII. Printing in the Press 88

IX. Finishing and Varnishing Collotype Prints 96

X. Other Collotype Processes 102

XI. Failures in Collotype: In the Preparation of

the Plates 107

XII. Investigations on Collotype 114

XIII. Collotype in Natural Colours 119

XIV. Magic Prints 122

XV. Photo “Glass” Printing 124

XVI. Allgeyer’s Collotype Process 127

XVII. Practice of Photo-Lithography 130

XVIII. Autography 135

XIX. Negatives for Photo-Lithography 149

XX. Application of the Carbon Process to

Photo-Lithography 155

APPENDIX.

Steam Presses 162

TRANSLATOR’S PREFACE.

The impossibility of obtaining any work in the English language on

the subject of Collotype first led to my translation of the German

work of Dr. Schnauss, and the fact that no work has hitherto appeared

fully dealing with the matter is the excuse I offer for the present

publication. The translation is necessarily one of considerable

freedom, but it is offered as containing all the information to be

found in the original, and in addition, considerable extensions, made

with the author’s consent. The omission of the chapter dealing at

length with the steam machine was necessitated by the fact that the

rotary machine there described is no longer manufactured.

Without pointing to the frontispiece in any sense as a high-class work,

it may serve to show that I have made some practical acquaintance with

the subject. The illustration, printed on ordinary paper, was produced

from the instructions found in this work, and I may add that at the

time of writing I have printed over 500 impressions from the first

plate, and it still remains in fair working condition.

EDWIN C. MIDDLETON.

STANMORE ROAD,

BIRMINGHAM.

COLLOTYPE AND PHOTO-LITHOGRAPHY.

CHAPTER I.

INTRODUCTORY.

The observation by Mungo Ponton of the sensitiveness to light of

bichromate of potassium in conjunction with organic substances is but

little more recent than the discovery of photography itself. If sized

paper is saturated with an aqueous solution of this salt and then

exposed under any transparent design, the latter will be reproduced

as a negative of a brown colour on a yellow ground. If the exposed

paper is placed in water, the bichromate salt will be removed from

the unexposed, and consequently unaltered portions; the image will

remain brown after this treatment, though somewhat bleached. The

sensitiveness to light is proportionately increased by the addition of

larger quantities of organic substances, as starch, paste, glue, sugar

or gum, as first observed by Becquerel. This arises in consequence of

the organic matter being oxidised by the chromic acid, a corresponding

decomposition and reduction of the chromate salt to chromate of

chromium taking place.

In the year 1853 an Englishman—Fox-Talbot, the gifted discoverer of

calotype (_i.e._, the production of photographic negatives on paper

by means of silver salts)—followed up the lines of these important

observations, and discovered that the mixture of bichromate of

potassium and glue entirely lost its solubility and power of swelling

in cold water after exposure to light, and on this he based his process

(heliography) of etching on metal plates. The plate, after receiving a

coating of the chromated gelatine solution, was dried, exposed under

a positive, and afterwards developed or washed out in warm water, all

unexposed and consequently soluble portions being removed, while the

exposed and therefore insoluble portions covered as a negative[A]

the metal plate, and so protected it in those parts from the etching

mordant employed, usually chloride of potassium or perchloride of

iron. His successor in these researches was a Frenchman, Poitevin, who

invested these processes with even greater practical importance. He,

however, worked chiefly on paper with the bichromate mixed with albumen

or gelatine, and attained results which were the first practical steps

towards photo-lithography and carbon or pigment printing. Further on

we shall return with more detail to these subjects. In the hands of

Tessié du Motay and Marechal, of Metz, the discoveries of Poitevin

derived further practical value, and to them we are indebted for the

first advances in collotype, they in their practice using metal plates

as a support. Joseph Albert, of Munich, followed, and introduced

further and considerable modifications, amongst others utilising glass

plates as a foundation. The want of adhesiveness of the chromated

gelatine layer to its support was a source of great trouble to the

earlier experimentalists, and was a matter giving rise to innumerable

difficulties, which were, however, finally surmounted by the researches

of Husnik, Albert, and Obernetter.

[A] For the production of an intaglio plate the impression on the

chromated gelatine must be printed from a positive, which will

naturally give a negative on the copper plate.

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