LUMINOUS PAINT.

The sun is evidently going out of fashion, and is more and more

excluded from “good society” as our modern substitute for civilization

advances. “Serve him right!” many will say, for behaving so badly

during the last two summers. The old saw, which says something about

“early to bed and early to rise” is forgotten: we take “luncheon”

at dinner-time, dine at supper-time, make “morning” calls and go to

“morning” concerts, etc., late in the afternoon, say “Good morning”

until 6 or 7 P.M.; and thus, by sleeping through the bright hours of

the morning, and waking up fully only a little before sunset, the

demand for artificial light becomes almost overwhelming. Not only do we

require this during a longer period each day, but we insist upon more

and more, and still more yet, during that period.

The rushlight of our forefathers was superseded by an exotic

luxury, the big-flame candle made of Russian tallow, with a wick

of Transatlantic cotton. Presently this luxurious innovation was

superseded by the “mould candle;” the dip was consigned to the kitchen,

and the bloated aristocrats of the period indulged in a _pair_ of

candlesticks, alarming their grandmothers by the extravagance of

burning two candles on one table. Presently the mould candle was

snuffed out by the composite; then came the translucent pearly paraffin

candle, gas light, solar lamps, moderator lamps, and paraffin lamps.

Even these, with their brilliant white flame from a single wick, are

now insufficient, and we have duplex and even triplex wicks to satisfy

our demand for glaring mockeries of the departed sun.

Some are still living who remember the oil lamps in Cheapside and

Piccadilly, and the excitement caused by the brilliancy of the new gas

lamps; but now we are dissatisfied with these, and demand electric

lights for common thoroughfares, or some extravagant combination of

concentric or multiplex gas-jets to rival it.

The latest novelty is a device to render darkness visible by capturing

the sunbeams during the day, holding them as prisoners until after

sunset, and then setting them free in the night. The principle

is not a new discovery; the novelty lies in the application and

some improvements of detail. In the “Boy’s Own Book,” or “Endless

Amusement,” of thirty or forty years ago, are descriptions of “Canton’s

phosphorus,” or “solar phosphori,” and recipes for making them. Burnt

oyster-shells or oyster-shells burnt with sulphur, was one of these.

Various other methods of effecting combination between lime or baryta

with sulphur are described in old books, the result being the formation

of more or less of what modern chemists call calcium sulphide and

barium sulphide (or otherwise sulphide of calcium or sulphide of

barium). These compounds, when exposed to the sun, are mysteriously

acted upon by the solar rays, and put into such a condition that their

atoms or molecules, or whatever else constitutes their substance,

are set in motion—in that sort of motion which communicates to the

surrounding medium the wavy tremor which agitates our optic nerve and

produces the sensation of light.

Until lately, this property has served no other purpose than puzzling

philosophers, and amusing that class of boys who burn their fingers,

spoil their clothes, and make holes in their mothers’ table-covers,

with sulphuric acid, nitric acid, and other noxious chemicals. The

first idea of turning it to practical account was that of making a sort

of enamel of one or the other of these sulphides, and using it as a

coating for clock-faces. A surface thus coated and exposed to the light

during the day becomes faintly luminous at night.

Anybody desirous of seeing the sort of light which it emits, may do so

very easily by purchasing an unwashed smelt from the fishmonger, and

allowing it to dry with its natural slime upon it, then looking at it

in the dark. A sole or almost any other fish will answer the purpose,

but I name the smelt from having found it the most reliable in the

course of my own experiments. It emits a dull, ghostly light, with very

little penetrating power, which shows the shape of the fish, but casts

no perceptible light on objects around.

Thus the phosphorescent parish-clock face, with non-phosphorescent

figures and hands, would look like a pale ghost of the moon with dark

figures round it, and dark hands stretching across, by which the

time of the night might possibly be discovered there or thereabouts.

This invention has already appeared in a great many paragraphs, but,

hitherto, upon very few clock-faces.

Recently it has assumed a more ambitions form—patented, of course. The

patentees claim an improved phosphorescent powder, which is capable

of being worked up with the medium of paints and varnishes, and thus

applied, not merely to clock-faces, but to the whole of the walls and

ceilings of any apartment. In this case the faintness of the light will

be in some degree compensated by the extent of phosphorescent surface,

and it is just possible that the sum total of the light emitted from

walls and ceiling may be nearly equal to that of one mould candle. If

so, it will have some value as a means of lighting powder magazines

and places for storage of inflammable compounds. It is stated that one

of the London Dock companies is about to use it for its spirit vaults;

also that the Admiralty has already tried the paint at Whitehall, and

has ordered two compartments of the _Comus_ to be painted with it, in

order to test its capability of lighting the dark regions of ironclad

ships.

This application can, however, only be limited to those parts which

receive a fair amount of light during the day, for unless the

composition first receives light, it is not able afterwards to emit it,

and this emission or phosphorescence only continues a few hours after

the daylight has passed away; five or six hours is the time stated.

A theatrical manager is said to be negotiating for the exclusive right

to employ this weird illumination for scenic purposes. The sepulchre

scene in “Robert le Diable,” or the incantation in “Der Freischutz,” or

“The Sorcerer,” might be made especially effective by its ghostly aid.

The name-plates of streets, and buoys at sea might be advantageously

coated with such a composition; and many other uses suggest themselves.

There are rival inventors, as a matter of course. The French patentees

claim the use of cuttle-fish bones, various sea-shells, etc., mixed

with pure lime, sulphur, and calcined sea-salt, besides sulphides of

calcium, barium, strontium, uranium, magnesium, or aluminium. They

also add phosphorus itself, though for what purpose is questionable,

seeing that this substance is only luminous during the course of its

oxidation or slow combustion, and after this has ended the resultant

phosphoric acid is no more luminous than linseed oil or turpentine. An

admixture of phosphorus might temporarily increase the luminosity of a

_sample_, but any conclusions based upon this would be quite delusive.

They also assert that electrical discharges passed through the paint

increase its luminosity. According to some enthusiasts, electricity

is to do everything; but these ladies and gentlemen omit to calculate

the cost of rousing and feeding this omnipotent giant. In this case

electrical machinery for stimulating the paint for anything outside of

lecture-table experiments or theatrical and other sensational displays,

would be a commercial absurdity.

The Americans, of course, are re-inventing in this direction, but Mr.

Edison has not yet appeared on the luminous-paint scene. If he does we

shall doubtless hear of something very brilliant, even though we never

see it. In the meantime we may safely hope that this application of an

old scientific plaything to useful purposes may become of considerable

utility, as it evidently opens a wide field for further investigation

and progressive improvement, by the application of the enlarged powers

which modern science places at the disposal of ingenious inventors. We

hope, for the sake of all concerned, that it will not fall into the

hands of professional prospectus manufacturers and joint-stock-company

mongers, and that the story of its triumphs will be told without any

newspaper exaggerations.

Since the above was written—in February, 1880—I have tested

this luminous paint (Balmain’s patent). Practically, I find it

unsatisfactory. In the first place, its endurance is far shorter

than is stated. It begins to fade almost immediately the light is

withdrawn, and in the course of an hour or two it is, for all practical

use—though not absolutely—extinguished. Besides this it emits a very

unpleasant odor painfully resembling sewage and sulphureted hydrogen.

This is doubtless due to the sulphur compound, but is, I have no doubt,

quite harmless in spite of its suggestions.

Science in Short Chapters · 第 86 / 116 题