If the block of stone is scratching, perhaps the appearance of the

finished panel may be less objectionable with the furrows in parallel

lines than in what engravers call “cross-hatching,” but if the rubbing

is properly done it is not easy to discover what difference it could

make whether the stone is moved in a straight line or a circle. As to

absorption, it cannot be distinguished in the finished panel between

the surface that was coated with liquid filler and that to which the

color was applied directly, except that cracking always occurs much

sooner in the former, and this will be found to be the case with

surfaces that have been coated with liquid filler and finished without

roughstuff. Among the pigments that may be used for roughstuff, and

there are half a dozen or more, any of which may be used with success,

there is no doubt but that known as “English filler” is best, but it is

not always to be had without delay and inconveniences.

Yellow ocher, Reno umber and Keystone filler are all suitable for

roughstuff, the ocher having been used many years for the purpose,

but, as already remarked, the English filler is best. This is the

rule for mixing given by Nobles and Hoare: Four pounds filler, 1

pound ground white lead, 1 pint gold size, 1 pint varnish and 1 1⁠/⁠4

pints turpentine, or 3⁠/⁠4 pint good size and 1⁠/⁠2 pint boiled oil

in lieu of the varnish. In regard to the use of white lead ground in

oil, it makes the rubbing more laborious, increases the liability

to scratching, and requires a much longer time to harden before the

scouring can be done, without in any appreciable manner improving the

quality of the surface when finished.

It may be remarked here that the addition of white lead, whether

ground in oil or added dry to the coarser pigment, increases the labor

of scouring just in proportion as it is used until sufficient may be

used to render the scouring process impossible; hence, it follows that

the mixing should be governed by the character of the job in hand. If

the job is of a cheap class the use of very little or no lead at all

is advisable, and the proportion of Japan and turpentine may also be

increased, with the result that a fairly good surface may be obtained

with much less labor than in the formula given.

The number of coats of filler required to effect the purpose in any

given case must depend upon how well the builder has done his part

of the work. If he has left the surface very uneven it follows, as a

matter of course, that more coats will be required to make it level,

and more of the roughstuff will remain after the leveling process than

if the woodwork had been more perfectly done. While the merits of a

system or method are not to be judged by its antiquity, there should be

a good reason to justify the substitution of a new method for one that

has given perfect satisfaction for generations and been used by the

best coach painters who ever handled a brush.

A well-known writer on paints says that the effect of a varnish is

usually attributed to the manner of its application and the quantity

of thinners used for diluting the melted gums, with the prepared oils

and the oxidizing agents used in its manufacture. While this has

undoubtedly much to do with the successful application of varnish,

there are other facts in this connection that should not be overlooked.

For example, varnish is sometimes acted on by the breaking up, or the

disintegration of the filling coats; which in turn is evidently acted

on by the wood itself, according to its nature. {774}

With the aid of the microscope in examining the component parts of

wood a cellular tissue is observed which varies in form according to

the species and the parts which are inspected. This cellular tissue is

made up of small cavities called pores or cells, which are filled with

a widely diversified matter and are covered with a hard and usually

brittle substance called _lignin_.

This diversified matter consists of mineral salts and various

organic substances, gelatinous in their nature and held in solution

by a viscous liquid and containing nitrogenous matter in different

combinations, the whole being designated by the general name of

albuminous substances. The older the wood the more viscous is the

matter; while wood of recent growth (sapwood) contains less viscous

matter holding these substances in solution. This albumen in wood acts

on substances like filler and varnish in one way or the other, good

or bad. The seasoning of wood does not dispose of these substances.

The water evaporates, leaving them adhering to the sides of the cells.

The drier these substances are the less action they exert on the

filler or whatever substance is coated on the surface. If the filler

disintegrates, it affects the varnish.

All albuminous substances, be they dry or in liquid form, are subject,

more or less, according to the protein they contain—which seems, or

rather is, the essential principle of all albuminous matter—to the

influence of caustic potash and soda. Thus, the albumen of an egg is

exactly like that contained in the composition of wood. As albumen in

wood becomes solid by drying, it is easily dissolved again, and will

then be acted on chemically by any extraneous substance with which it

comes in contact.

Some of the shellacs, substitutes for shellacs, and some of the liquid

fillers are manufactured from some of the following substances: Old

linseed oil, old varnish, old and hard driers, turpentine, benzine,

often gasoline, rosin, whiting, cornstarch flour, nulls, paint

skins, silica, and so on. The list is long. To these must be added a

large volume of potash, to bring it to and hold it in solution. There

must be an excess of potash which is not combined into a chemical

compound, which if it did, might mitigate its influence on the albumen

of the wood. But as there is potash in its pure state remaining in

the solution it necessarily attacks the albumen of the wood, causing

disintegration, which releases it from the wood, causing white, grayish

flakes, and the formation of a powder. This is not a conclusion drawn

from an inference but an established scientific fact resulting from

experiments with fillers the various compositions of which were known.

All alkalies act on albumen. No one would knowingly varnish over a

surface such as it would be were the white of an egg applied to it and

then washed with an alkali solution; but that is just what is done when

varnish is put over a wood surface filled with a filler which contains

an alkali.

Most of the combinations of material used in the painting trade are

mixtures; that is, each part remains the same—exerting the same

chemical action on another substance, or any other substance coming in

contact with a paint mixture will exert the same chemical action on any

part, or on any ingredient it contains, the same as if that part was by

itself.

We can now account for some of the numerous peculiarities of varnish.

We know that any alkali when coming in contact with albumen forms

a compound, which on drying is a white, brittle substance easily

disintegrated. This is why potash, sal soda, and kindred substances

will remove paint. The alkali attacks the albumen in the oil, softening

it, causing easy removal, whereas if it were allowed to dry, the

albumen in the oil would take on a grayish color quite brittle. Potash

or other alkalies in filler not only attack the albumen in the wood,

but also attack the albumen in the oil by forming a compound with it.

Probably this compound is very slight, only forming a compound in

part, enough, nevertheless, to start a destroying influence, which is

demonstrated by the following results of experiments. The reader has,

perhaps, some time in his career applied a rosin varnish over a potash

filler and has been surprised by the good results, a more permanent

effect being obtained than in other instances where the best of varnish

was used. This is accounted for by the rosin of the potash. Again, the

reader may have had occasion to remove varnish with potash and found

that potash would not touch it. This is because of its being a rosin

varnish. Potash in filler may be rendered somewhat inert, by reason

of its compounding with other parts of the filler, but owing to the

quantity used in some of the commercial fillers it is not possible that

all the alkali is rendered inert. Hence it will attack the albumen

wherever found, as all albumen is identical in its chemical composition.

Alkalies have but little effect on the {775} higher classes of gums,

because of their effect on the albumen in the wood and oil. All

alcohol varnishes or varnishes made by the aid of heat stand well over

an alkali filler. Varnishes which contain little oil seem to stand

well. This is accounted for by the fact that alcohol renders albumen

insoluble. Alkalies of all kinds readily attack shellac and several

other of the cheap gums, forming unstable compounds on which oil has

but little effect.

Close-grained wood contains less albumen and more lignin than

open-grained varieties, and consequently does not take so much filler,

which accounts for the finish invariably lasting longer than the same

kind used on an open-grained wood. Open-grained wood contains more sap

than close grained; consequently there is more albumen to adhere to the

sides of the cells. The more albumen, the more readily it is attacked

by the potash, and the more readily decomposed, or rather destroyed.

Alcohol renders albumen insoluble immediately on application. It

prevents it from compounding with any other substance, or any

other substance compounding with it. Hence, we must conclude that

an application of alcohol to wood before the filler is applied is

valuable, which is proven to be a fact by experiment. Wash one half of

a board with alcohol, then apply the potash filler over all. Again,

wash the portion of the board on which is the filler and apply a

heavy-bodied oil varnish. Expose to sunlight and air the same as a

finished door or the like, and wait for the result. At the end of a few

months a vast difference will be found in the two parts of the surface.

The one on which there is no alcohol will show the ravages of time and

the elements much sooner than the one on which it is.

Wood finishers demand a difference in the composition of fillers,

paste and liquid, for open- and close-grained wood, respectively; but

unfortunately they do not demand a difference between either kind

in themselves, according to the kind of wood. Paste fillers are used

indiscriminately for open-grained wood and liquid for close-grained

wood.

To find the fillers best adapted for a certain wood, and to classify

them in this respect will require a large amount of chemical work and

practical experiments; but that it should be done is evidenced by the

fact that both success and failure result from the use of the same

filler on different varieties of wood. After once being classified

(owing to the large number now on the market), they will not number

nearly so many in the aggregate as might be supposed; as it will be

found in many instances that two entirely different varieties of wood

resemble each other more closely in their vascular formation and cell

characteristics than do two other specimens of the same variety. It is

a recognized fact that paste fillers whose base is starch or the like

work better and give better results in certain instances, while those

whose base is mineral matter seem to do better in other cases.

It is noticed that rosewood as a finishing veneer is obsolete.

This is not because of its scarcity, but because it is so hard to

finish without having been seasoned for a long time. In these days,

manufacturers cannot wait. It takes longer for the sap of rosewood

to become inactive, or in trade parlance to “die,” than any other

wood. This is because it takes so long for the albumen in the sap

to coagulate. Rosewood has always been a source of trouble to piano

makers, on account of the action of the sap on the varnish. However,

if this wood, previously to filling, was washed with a weak solution

of phosphoric acid, and then with wood spirit, it might be more easily

finished. The phosphoric acid would coagulate the albumen on the

surface of the wood immediately, while alcohol would reduce it to an

insoluble state. The idea here is to destroy the activity of the sap,

on the same principle as sappy places and knot sap are destroyed by

alcohol-shellac before being painted.

Oak is another wood which gives the painter trouble to finish. This may

be accounted for as follows: Oak contains a sour acid principle called

tannic acid. It is a very active property. Wood during the growing

season contains more albumen; thus in the circulation of the sap a

large quantity of soft matter is deposited on the lignin which lines

the cells, which lignin, if it contains any acid matter, acts on the

material of the filler. Tannic acid has a deleterious effect on some

of the material of which a number of fillers are made. Starch and many

gums are susceptible to its influence, making some of them quite soft.

Oak, like most other timber cut at the season when the least sap is in

circulation, is the more easily finished.

The vascular formation may, and no doubt has, something to do with

wood finishing. Different species of wood differ materially in their

vascular and cellular formation. Wood finishers recognize a difference

in treatment of French burl walnut and the common American {776}

variety. Circassian and Italian walnut, although of the same species,

demand widely different treatment in finishing to get the best results.

The only way to find the best materials to use in certain cases is to

study and experiment with that end in view. If, by aid of a microscope,

a certain piece of wood shows the same cellular formation that another

piece did which was successfully finished by a certain process, it may

be regarded as safe to treat both alike. If observation on this line is

indulged in, it will not take the finisher very long to learn just what

treatment is best for the work in hand. How often it has been noticed

in something of two parts, like a door, that the panels when finished

will pit, run, or sag, while the sides will present a surface in every

way desirable and _vice versa_. This is due to the difference in the

cellular construction of the wood and to the cellulose, and cannot be

otherwise for the parts have been seasoned the same time and treated

exactly alike. The physiology of wood is imperfectly understood,

but enough is known to warrant us in saying with a certainty that

the chemicals in fillers do act upon the principles embodied in its

formation.

* * * * *

Some tried formulas follow:

I.—Make a paste to fill the cracks as follows: Old furniture polish:

Whiting, plaster of Paris, pumice stone, litharge, equal parts, Japan

drier, boiled linseed oil, turpentine, coloring matter, of each a

sufficient quantity.

Rub the solids intimately with a mixture of 1 part of the Japan, 2

parts of the linseed oil, and 3 parts of turpentine, coloring to suit

with vandyke brown or sienna. Lay the filling on with a brush, let it

set for about 20 minutes, and then rub off clean except where it is to

remain. In 2 days it will be hard enough to polish. After the surface

has been thus prepared, the application of a coat of first-class copal

varnish is in order. It is recommended that the varnish be applied in a

moderately warm room, as it is injured by becoming chilled in drying.

To get the best results in varnishing, some skill and experience are

required. The varnish must be kept in an evenly warm temperature, and

put on neither too plentifully nor too gingerly. After a satisfactorily

smooth and regular surface has been obtained, the polishing proper may

be done. This may be accomplished by manual labor and dexterity, or by

the application of a very thin, even coat of a very fine, transparent

varnish.

If the hand-polishing method be preferred, it may be pursued by rubbing

briskly and thoroughly with the following finishing polish:

Alcohol 8 ounces

Shellac 2 drachms

Gum benzoin 2 drachms

Best poppy oil 2 drachms

Dissolve the shellac and gum in the alcohol in a warm place, with

frequent agitation, and, when cold, add the poppy oil. This may be

applied on the end of a cylindrical rubber made by tightly rolling a

piece of flannel, which has been torn, not cut, into strips 4 to 6

inches wide. It should be borne in mind that the surface of the cabinet

work of a piano is generally veneered, and this being so, necessitates

the exercise of much skill and caution in polishing.

II.—Prepare a paste from fine starch flour and a thick solution of

brown shellac, with the spatula upon a grinding stone, and rub the

wooden object with this. After the drying, rub off with sandpaper and

polish lightly with a rag moistened with a thin shellac solution and a

few drops of oil. The ground thus prepared varnish once or twice and a

fine luster will be obtained. This method is well adapted for any wood

with large pores, such as oak.

«Removal of Heat Stains from Polished Wood.»—Fold a sheet of blotting

paper a couple of times (making 4 thicknesses of the paper), cover the

place with it, and put a hot smoothing iron thereon. Have ready at hand

some bits of flannel, also folded and made quite hot. As soon as the

iron has made the surface of the wood quite warm, remove the paper,

etc., and go over the spot with a piece of paraffine, rubbing it hard

enough to leave a coating of the substance. Now with one of the hot

pieces of flannel rub the injured surface. Continue the rubbing, using

freshly warmed cloths until the whiteness leaves the varnish or polish.

The operation may have to be repeated.

«PRESERVATION OF WOOD.»

I.—An excellent way of preserving wood is to cut it between August

and October. The branches are removed, leaving only the leaves at the

top. The trunks, carefully cut or sawn (so that their pores remain

open), are immediately placed upright, with the lower part immersed in

tanks three-quarters filled with water, into which 3 or 4 kilograms of

powdered cupric sulphate per hectoliter have been introduced. The mass

of {777} leaves left at the extremity of each trunk is sufficient to

cause the ascent of the liquid by means of the capillary force and a

reserve of energy in the sap.

II.—Wood which can be well preserved may be obtained by making a

circular incision in the bark of the trees a certain time before

cutting them down. The woodcutters employed in the immense teak forests

of Siam have adopted in an empirical way a similar process, which has

been productive of good results. The tree is bled, making around the

trunk, at the height of 4 feet above ground, a circular incision 8

inches wide and 4 inches deep, at the time when it is in bloom and the

sap rising. Sometimes the tree is left standing for 3 years after this

operation. Frequently, also, a deep incision reaching the heart is made

on two opposite sides, and then it takes sometimes only 6 months to

extract the sap.

It is probable that it is partly in consequence of this method that the

teakwood acquires its exceptional resistance to various destructive

agents.

III.—A good preservation of piles, stakes, and palisades is obtained

by leaving the wood in a bath of cupric sulphate of 4° of the ordinary

acidimeter for a time which may vary from 8 to 15 days, according to

greater or less dryness of the wood and its size. After they are half

dried they are immersed in a bath of lime water; this forms with the

sulphate an insoluble compound, preventing the rain from dissolving the

sulphate which has penetrated the wood. This process is particularly

useful for vine props and the wood of white poplars.

A good way to prevent the decay of stakes would be to plant them upside

down; that is, to bury the upper extremity of the branch in the ground.

In this way, the capillary tubes do not so easily absorb the moisture

which is the cause of decay. It frequently happens that for one or

another reason, the impregnation of woods designed to be planted in

the ground, such as masts, posts, and supports has been neglected. It

would be impracticable, after they are placed, to take up these pieces

in order to coat them with carbolineum or tar, especially if they are

fixed in a wall, masonry, or other structure. Recourse must be had to

other means. Near the point where the piece rises from the ground,

a hole about one centimeter in width is made in a downward slanting

direction, filled with carbolineum, and closed with a wooden plug.

It depends upon the consistency of the wood whether the liquid will

be absorbed in 1 or 2 days. The hole is filled again for a week. The

carbolineum replaces by degrees the water contained in the wood. When

it is well impregnated, the hole is definitely closed with a plug

of wood, which is sawn level with the opening. The wood will thus

be preserved quite as well as if it had been previously coated with

carbolineum.

IV.—Wooden objects remaining in the open air may be effectually

protected against the inclemency of the weather by means of the

following coating: Finely powdered zinc oxide is worked into a paste

with water and serves for whitewashing walls, garden fences, benches,

and other wooden objects. After drying, probably at the end of 2 or

3 hours, the objects must be whitewashed again with a very dilute

solution of zinc chloride in glue or water. Zinc oxide and zinc

chloride form a brilliant, solid compound, which resists the inclemency

of the weather.

As a paint for boards, planks for covering greenhouses, garden-frames,

etc., Inspector Lucas, of Reutlingen (Würtemberg), has recommended the

following coating: Take fresh cement of the best quality, which has

been kept in a cool place, work it up with milk on a stone until it is

of the consistency of oil paint. The wood designed to receive it must

not be smooth, but left rough after sawing. Two or 3 coats are also a

protection from fire. Wood to be thus treated must be very dry.

V.—Wood treated with creosote resists the attacks of marine animals,

such as the teredo. Elm, beech, and fir absorb creosote very readily,

provided the wood is sound and dry. Beechwood absorbs it the best. In

fir the penetration is complete, when the wood is of a species of rapid

growth, and of rather compact grain. Besides, with the aid of pressure

it is always possible to force the creosote into the wood. Pieces of

wood treated with creosote have resisted for 10 or 11 years under

conditions in which oak wood not treated in this way would have been

completely destroyed.

The prepared wood must remain in store at least 6 months before use.

The creosote becomes denser during this time and causes a greater

cohesion in the fibers. In certain woods, as pitch pine, the injection

is impossible, even under pressure, on account of the presence of rosin

in the capillary vessels.

VI.—M. Zironi advises heating the wood {778} _in vacuo_. The sap

is eliminated in this way. Then the receiver is filled with rosin

in solution with a hydrocarbide. The saturation takes place in two

hours, when the liquid is allowed to run off, and a jet of vapor is

introduced, which carries off the solvent, whole the rosin remains in

the pores of the wood, increasing its weight considerably.

VII.—Wood can be well preserved by impregnating it with a solution of

tannate of ferric protoxide. This method is due to Hazfeld.

VIII.—The Hasselmann process (xylolized wood), which consists in

immersing the wood in a saline solution kept boiling under moderate

pressure, the liquid containing copper and iron sulphates (20 per cent

of the first and 80 per cent of the second), as well as aluminum and

kainit, a substance until recently used only as a fertilizer, is now

much employed on the railways in Germany.

IX.—Recently the discovery has been made that wood may be preserved

with dissolved betuline, a vegetable product of the consistency of

paste, called also birchwood rosin. Betuline must first be dissolved.

It is procurable in the crude state at a low price. The wood is

immersed for about 12 hours in the solution, at a temperature of from

57° to 60° F.

Henley's Twentieth Century Formulas, Recipes and Processes · 第 132 / 139 段