CHAPTER XIII.

ON THE SECONDARY, PURPLE.

Purple, the third and last of the secondary colours, is composed of

_red_ and _blue_, in the proportions of five of the former to eight of

the latter; proportions which constitute a perfect purple, or one of

such a hue as will neutralize and best contrast a perfect yellow, in the

ratio of thirteen to three, either of surface or intensity. When mixed

with its co-secondary colour, green, purple forms the tertiary _olive_;

and, when compounded with the remaining secondary, orange, it

constitutes in like manner the tertiary _russet_. Of the three secondary

colours it is the coolest, as well as the nearest in relation to _black_

or shade; in which respect, and in never being a warm colour, it

resembles blue. In other respects also, purple partakes of the

properties of blue, which is its archeus, or ruling colour; hence it is

to the eye a retiring colour, that reflects light little, and loses

rapidly in power in a declining light, and according to the distance at

which it is viewed. By reason of its being the mean between black and

blue it becomes the most retiring of all positive colours. Nature

employs this hue beautifully in landscape, as a sub-dominant, in

harmonizing the broad shadows of a bright sunshine ere the light sinks

into deep orange or red. Girtin, who saw Nature as she is, and painted

what he saw, delighted in this effect of sunlight and shadow. As a

ruling colour, whether in flesh or otherwise, purple is commonly too

cold, or verges on ghastliness, a fault which is to be as much avoided

as the opposite extreme of viciousness in colouring, stigmatized as

foxiness.

Yet, next to green, purple is the most generally pleasing of the

consonant colours; and has been celebrated as a regal or imperial

colour, as much perhaps from its rarity in a pure state, as from its

individual beauty. Romulus wore it in his trabea or royal mantle, and

Tullus Hostilius, after having subdued the Tuscans, assumed the pretexta

or long robe, broadly striped with purple. Under the Roman emperors, it

became the peculiar emblem or symbol of majesty, and the wearing of it

by any who were not of the Imperial family, was deemed a "treasonable

usurpation," punishable by death. At the decline of the empire, the

Tyrian purple was an important article of commerce, and got to be common

in the clothing of the people. Pliny says, "Nepos Cornelius, who died in

the reign of Augustus Cæsar, when I was a young man, assured me that

the light violet purple had been formerly in great request, and that a

pound of it usually fetched 100 denaria (about £4 sterling): that soon

after the tarentine or reddish purple came into fashion; and that this

was followed by the Tyrian dibapha, which could not be bought for less

than 1000 denaria (nearly £40 sterling) the pound; which was its price

when P. Lentulus Spinter was Ædile, Cicero being then Consul. But

afterwards, the double-dyed purple became less rare, &c." The Tyrian

purple alluded to was obtained from the purpuræ, a species of shell-fish

adhering to rocks and large stones in the sea adjoining Tyre. On

account, probably, of its extreme costliness, it was frequently the

custom to dye the cloth with a ground of kermes or alkanet, previous to

applying the Tyrian purple. This imparted to the latter a crimson hue,

and explains doubtless the term, double-dyed. The Greeks feigned the

ancient purple to be the discovery of Hercules Tyrius, whose dog, eating

by chance of the fish from which it was produced, returned to him with

his mouth tinged with the dye. Alexander the Great is said to have found

in the royal treasury, at the taking of Susa, purple to the enormous

value of 5000 talents,[A] which had lain there one hundred and

ninety-two years, and still preserved its freshness and beauty.

When inclining to red, purple takes the name of _crimson_, &c.; and when

leaning to blue, the names of _violet_, _lilac_, _mauve_, _&c._ Blue is

a colour which it serves to mellow, or follows well into shade. The

contrast or harmonizing colour of purple is yellow on the side of light

and the primaries; while purple itself is the harmonizing contrast of

the tertiary _citrine_ on the side of shade, and less perfectly so of

the semi-neutral _brown_. As the extreme primaries, blue and yellow,

when either compounded or opposed, afford, though not the most perfect

harmony, yet the most pleasing consonance of the primary colours; so the

extremes, purple and orange, yield the most pleasing of the secondary

consonances. This analogy extends likewise to the extreme tertiary and

semi-neutral colours, while the mean or middle colours furnish the most

agreeable contrasts or harmonies.

In nature pure purple is not a common colour, and on the palette purple

pigments are singularly few. They lie under a peculiar disadvantage as

to apparent durability and beauty of colour, owing to the neutralizing

power of yellowness in the grounds upon which they are laid; as well as

to the general warm colour of light, and the yellow tendency of almost

all vehicles and varnishes, by which the colour of purple is subdued.

208. BURNT CARMINE

is the carmine of cochineal partially charred till it resembles in

colour the purple of gold, for which, in miniature and water-painting,

it is substituted. It is a magnificent reddish purple of extreme

richness and depth, eligible in flower-painting and the shadow of

draperies. As it is generally impossible, however, to alter the nature

of a pigment by merely changing its colour, burnt carmine is scarcely

more permanent than the carmine from which it is produced. If used,

therefore, it should be in body, and not in thin washes or as a glaze.

Durable pigments are admissible in any form; but semi-stable pigments

(gamboge excepted) should only be employed in body.

209. BURNT LAKE

holds the same relation to crimson lake as burnt carmine to ordinary

carmine; and is hence a weaker variety of the preceding, with less

richness, and likewise less permanence.

210. INDIAN PURPLE

is prepared by precipitating an extract of cochineal with sulphate of

copper. It is a very deep-toned but rather cold and subdued purple,

neither so red nor so brilliant as burnt carmine; and is chiefly of

service in draperies. It is apt to lose its purple colour in a great

measure on exposure to light and air, and assume an inky blackness; a

defect which becomes less apparent when the pigment is used in bulk.

211. MARS VIOLET,

_Violet de Mars_, _Purple Ochre_, or _Mineral Purple_, is a dark ochre,

native of the Forest of Dean in Gloucestershire. It is of a murrey or

chocolate colour, and forms cool tints of a purple hue with white. It is

of a darker colour than Indian red, which has also been classed among

purples, but has a similar body and opacity, and generally resembles

that pigment. It may be prepared artificially, and some natural red

ochres burn to this colour. Being difficult and sometimes impossible to

procure, Mars violet is often compounded; in which case it is liable to

vary both in hue and stability. As, however, Indian red is always taken

for its basis, the mixture is never wholly fugitive, nor exhibits any

very glaring contrast on exposure.

212. MIXED PURPLE.

Purple being a secondary colour, composed of _blue_ and _red_, it

follows of course that any blue and red pigments, which are not

chemically at variance, may be employed in producing mixed purples of

any required hue, either by compounding or grinding them together ready

for use, or by combining them in the various modes of operation in

painting. In such compounding, the more perfect and permanent the

original colours are, the more perfect and permanent will be the purple

obtained. To produce a pure purple, neither the red nor the blue must

contain or incline to yellow; while to compound a durable purple, both

the red and the blue must be durable also. Ultramarine and the reds of

madder yield beautiful and excellent purples, equally stable in water or

oil, in glazing or tint, whether under the influence of light or impure

air. Cobalt blue and madder red likewise afford good purples; and some

of the finest and most delicate purples in ancient paintings appear to

have been composed of ultramarine and vermilion, which furnish tints

equally permanent, but less transparent than the above, and less easily

compounded. Facility of use, and other advantages, are obtained at too

great a sacrifice by the employment of perishable mixtures, such as the

lakes of cochineal with indigo.

PERMANENT REDS. | PERMANENT BLUES.

|

Cadmium Red. | Cerulian Blue.

Liquid Rubiate. | Cobalt Blue.

Madder Carmine. | Genuine Ultramarine.

Rose Madder. | Brilliant Ultramarine.

Mars Red. | French Ultramarine.

Ochres. | New Blue.

Vermilions. | Permanent Blue.

It should be noted that all the above reds do not afford pure purples

with blue; those which contain more or less yellow, as cadmium red and

orange vermilion, furnish purples partaking more or less of olive, which

is a compound of purple and green. To those reds may be added the russet

Rubens Madder and the marrone Madder Brown, two pigments which are alike

eligible for mixed purple and mixed orange. No purple, it will be

remarked, equal in gorgeous richness to that produced from crimson lake

and Prussian blue is obtainable from the colours given; just as no mixed

green is of such depth and power if that blue be wanting as a

constituent. But, as our compound tints are given rather as examples of

durability than beauty, all semi-stable or fugitive mixtures are of

necessity ignored.

213. PURPLE MADDER,

_Field's Purple_, or _Purple Rubiate_, is the only durable organic

purple the palette possesses. Marked by a soft subdued richness rather

than by brilliancy, it leans somewhat towards marrone, and affords the

greatest depth of shadow without coldness of tint. Unfortunately, in the

whole range of artistic pigments there is no colour obtainable in such

small quantity as madder purple; hence its scarcity and high price cause

it to be confined to water-colour painting, in which the clearness and

beauty of its delicate tones render it invaluable in every stage of a

drawing. With raw Sienna and indigo or Prussian blue, subdued by black,

it gives beautiful shadow tints, and will be found useful in sky and

other effects compounded with cobalt, rose madder, French blue and

sepia, yellow ochre and cobalt, lamp black and cobalt, light red,

Vandyke brown, burnt Sienna, or aureolin. With great transparency, body,

and depth, it is pure and permanent in its tints, neither gives nor

sustains injury on admixture, dries and glazes well in oil, works well,

and is altogether most perfect and eligible. For fresco it is admirably

adapted, being quite uninjured by lime.

There is a lighter and slightly brighter sort, containing less colouring

matter and more base, which has all the properties of the above with

less intensity of colour. For the sake of cheapness, the purple is

sometimes compounded in oil, generally of brown madder and a blue.

Provided the latter be stable, transparent, and mix kindly, no greater

objection can be taken to this than to the neutral orange of brown

madder and yellow ochre.

214. VIOLET CARMINE

is a brilliant bluish purple of much richness, employed in draperies and

the like. It is prepared by precipitating an alcoholic extract of the

root of the _Anchusa tinctoria_, commonly known as alkanet, a plant

growing in the Levant, and some other warm countries. It was used by the

ancients as a dye, or as a groundwork to those stuffs which were to be

dyed purplish-red: the ladies in ancient times also employed it as a

paint. Its colouring matter or _anchusin_ has the character of a resin,

and is dark-red, softened by heat, insoluble in water, soluble in

alcohol and alkalis, and freely so in ether, fats, and volatile oils, to

all of which it imparts a brilliant red hue. To obtain anchusin, all the

soluble matters are first abstracted from the bruised root by water: it

is then digested in a solution of carbonate of potash, from which it may

be readily precipitated by an acid. Its alcoholic solution yields with

different reagents crimson, flesh-coloured, blue, and violet

precipitates, none of which, however, can be classed as durable. The

variety under notice, violet carmine, resembles the other colours

afforded by alkanet in not being able to withstand the action of light.

On continued exposure, it loses its beauty and brightness, together with

much of its colour, and, like Indian purple, assumes an inky blackness.

Hence it is unsuited to permanently pure effects, and should only be

used in body.

* * * * *

215. _Archil Purple._

Archil may be regarded as the English, cudbear as the Scotch, and litmus

as the Dutch name for one and the same substance, extracted from

several species of lichens by various processes. These lichens, which

are principally collected on rocks adjacent to the sea, are cleaned and

ground into a pulp with water, treated from time to time with ammoniacal

liquor, and exposed with frequent agitation to the action of the

atmosphere. Peculiar principles existing in the lichens are, by the

joint instrumentality of the air, water, and ammonia, so changed as to

generate colouring matter, which, when perfect, is expressed. Soluble in

water and alcohol, this colouring principle yields by precipitation with

chloride of calcium a compound known as 'Solid French Purple', a pigment

more stable than the archil colours generally, but all too fugitive for

the palette.

216. _Bismuth Purple._

A purple powder is capable of being produced from bismuth by passing

chlorine gas through the hydrated oxide suspended in a saturated

solution of potash. As soon as the oxide becomes brown-red, the mixture

is boiled and the liquid decanted off at once, the residue being

immediately washed first with alcohol and then with water. On the whole,

the result is not, for an artistic pigment, worth the trouble involved

in the preparation.

217. _Burnt Madder_

is obtained by carefully charring madder carmine until it becomes of the

hue required. Bearing the same relation to madder carmine as burnt

carmine to the carmine of cochineal, burnt madder is a permanent and

perfectly unexceptionable pigment. By reason, probably, of its great

price, it is not mentioned in trade catalogues, and must be held as

commercially unknown.

218. _Cobalt Purples_

are obtainable ranging from the richest crimson purple to the most

delicate violet. We have produced them by wet and dry methods, varying

in brilliancy and beauty, but characterised generally by want of body,

and frequently by a smalt-like grittiness. Chemically, good and stable

colours, they are not received with favour on the palette, and certainly

may be very well replaced by mixtures of cobalt blue and madder red.

When a permanent compound is obtainable equal in colour to an original

pigment, and superior in its physical attributes, no objection can

fairly be taken to its artistic preference. There are other things to be

considered in a pigment besides permanence, or even permanence and

colour combined. The two together do not constitute a perfect pigment,

that is, a material of practical utility and value. In the last

chapter, allusion was made to a green which possesses both the one and

the other, and yet is--at present, at least--quite unfitted for artistic

use. Hence, with a strong partiality for simple original pigments, we

are bound to confess there are cases where mixtures are justifiably

preferred. All we contend for is, that each constituent of such mixtures

should be stable, and neither give nor receive injury by being

compounded.

219. _Gold Purple_,

Purple of Cassius, or Cassius's Purple Precipitate, was discovered in

1683 by Cassius of Leyden. It is a compound of tin and gold, best formed

by mixing aqueous perchloride of iron with aqueous protochloride of tin,

till the colour of the liquid has a shade of green, and then adding this

liquid, drop by drop, to a solution of perchloride of gold, which is

free from nitric acid and very dilute: after twenty-four hours the

purple is deposited. When recently prepared, the colour is brightened by

boiling nitric acid. Not brilliant, but rich and powerful, this purple

varies in hue according to the mode of manufacture from deep crimson to

murrey or dark purple: it also differs in degrees of transparency.

Working well in water, it is an excellent though costly pigment, once

popular in miniatures, but at present rarely, if ever used, as purple

madder is cheaper, and perfectly well supplies its place. Retaining its

colour at a high red heat, it is now confined to enamel and porcelain

painting, and to tinging glass of a fine red. If, whilst in its hydrated

state, it be washed with ammonia, a bright purple liquid results, from

which a violet colour, somewhat less expensive, can be produced, by

combining the gold purple with alumina, and calcining the product in the

same way that is practised with cobalt. This compound may be exposed to

the action of the sun's rays for a year without being sensibly affected.

220. _Prussian Purple._

A prussiate of iron is obtainable of a violet hue, affording good shadow

tints and clear pale washes. It has not, however, been introduced as a

pigment, as ordinary Prussian blue tinged with red furnishes a similar

colour.

221. _Sandal Wood Purple._

Sandal wood contains about 16 per cent. of colouring matter, soluble

with difficultly in water, but readily dissolved by alcohol. From the

latter solution, chloride of tin throws down a purple, and sulphate of

iron a deep violet precipitate; neither of which is remarkable for

permanence.

222. _Tin Violet._

By heating chromate of stannic oxide to bright redness, a dark violet

mass is obtained, which is better adapted to enamel painting than to the

palette. It communicates in glazings a variety of tints, from rose-red

to violet.

* * * * *

So scant is the number of good purples in common use, that there are but

two which can be classed as durable, namely, purple madder and the true

Mars violet.

Foremost in the second group stands burnt carmine. As there are

different degrees both of permanence and fugacity, so are there

different degrees of semi-stability. Burnt carmine, burnt lake, Indian

purple, and violet carmine, all belong to this division; but the first

certainly is more permanent than the rest.

Rich and beautiful as it is, purple madder cannot be called brilliant;

while Mars violet is, of course, ochrous. Unlike green and orange,

therefore, purple can point to no original pigment at once vivid and

durable: as regards purple, brilliancy implies a semi-stability that

borders more or less closely on fugacity. Until the advent of a perfect

palette, however, brilliancy and semi-stability will doubtless hold

their own. Their present popularity may be seen by a glance at the lists

of artist-colours--lists compiled, be it remembered, in obedience to

the law of demand and supply. If art were really so much honoured as

some of its disciples pretend, none but durable colours would be

employed. In our opinion, if a picture be worth painting at all, it is

worth painting with permanent pigments; but many evidently think

otherwise. Deploring an error neither flattering to the craft they

practise nor to themselves, we would urge such to bear in mind this

axiom, semi-stable pigments become fugitive when used in thin washes.

Even in body they do not preserve their primitive hue, but in glazing

and the like, their colour altogether flies or is wholly destroyed.

It is this semi-stability, recommended to the thoughtless and

indifferent by the beauty which generally accompanies it, that is the

bane of modern art. Even our greatest painters have yielded to its

fascination. Who has not gazed upon one of Turner's fading pictures with

still more of sadness than enjoyment, that anything so grand, so

beautiful, so true, should slowly but surely be passing away? A feeling

akin to pity is conjured up at the sight of the helpless wreck,

abandoned amid the treacherous materials employed, and sinking deeper

and deeper. Mournful, indeed, is that mighty ruin of mind amid matter;

mournful the thought that in years to come, the monument sought for will

not be found.

FOOTNOTES:

[A] A talent of money, _i.e._, a talent's weight of silver, was equal to

nearly £244.

Field's Chromatography or Treatise on Colours and Pigments as Used by Artists · 第 9 / 17 章