It is impossible to make powder magazines too dry, and every care should

be taken to ventilate them as much as possible during dry weather, by

opening all doors, windows, loopholes, &c. Magazines are generally made

bomb-proof, and are furnished with lightning conductors. They are

divided into chambers, and these again divided by uprights into bays. At

Purfleet, which is the grand depôt for gunpowder in England, there are

five magazines capable of containing 9,600 whole barrels each. Each

magazine is divided into two chambers, and each chamber into 24 bays,

and in each bay is placed 200 whole, 400 half, or 800 quarter barrels of

powder. Total in the five Magazines, 48,000 barrels, equal to 4,800,000

pounds.

LIGHTNING CONDUCTORS.

_Principles and Instructions relative to their application to Powder

Magazines, by_ SIR W. SNOW HARRIS, F.R.S. _Extracted from Army List

for July, 1859._

1.--Thunder and lightning result from the operation of a peculiar

natural agency through an interval of the atmosphere contained between

the surface of a certain area of clouds, and a corresponding area of the

earth’s surface directly opposed to the clouds. It is always to be

remembered that the earth’s surface and the clouds are the terminating

planes of the action, and that buildings are only assailed by Lightning

because they are points, as it were, in, or form part of, the earth’s

surface, in which the whole action below finally vanishes. Hence

buildings, under any circumstances, will be always open to strokes of

Lightning, and no human power can prevent it, whether having Conductors

or not, or whether having metals about them or not, as experience shows.

2.--Whenever the peculiar agency, (whatever it may be), active in this

operation of nature, and characterized by the general term Electricity,

or Electric Fluid, is confined to substances which are found to resist

its progress, such, for example, as air, glass, resinous bodies, dry

wood, stones, &c., then an explosive form of action is the result,

attended by such an evolution of light and heat, and by such an enormous

expansive force, that the most compact and massive bodies are rent in

pieces, and inflammable matter ignited. Nothing appears to stand against

it. Granite rocks are split open, oak and other trees, of enormous size,

rent in shivers, and masonry of every kind frequently laid in ruins. The

lower masts of ships of the line, 3 feet in diameter, and 110 feet long,

bound with hoops of iron half an inch thick and 5 inches wide, the whole

weighing about 18 tons, have been, in many instances, torn asunder, and

the hoops of iron burst open and scattered on the decks. It is, in fact,

this terrible expansive power which we have to dread in cases of

buildings struck by Lightning, rather than the actual heat attendant on

the discharge itself.

3.--When, however, the electrical agency is confined to bodies, such as

the metals, which are found to oppose but small resistance to its

progress, then this violent expansive or disruptive action is either

greatly reduced, or avoided altogether. The explosive form of action we

term Lightning, vanishes, and becomes, as it were, transformed into a

sort of continuous current action, of a comparatively quiescent kind,

which, if the metallic substance it traverses be of certain known

dimensions, will not be productive of any damage to the metal. If,

however, it be of small capacity, as in the case of a small wire, it may

become heated and fused. In this case, the electrical agency, as before,

is so resisted in its course as to admit of its taking on a greater or

less degree of explosive and heating effect, as in the former case. It

is to be here observed, that all kinds of matter oppose some resistance

to the progress of what is termed the Electrical Discharge, but the

resistance through capacious metallic bodies is comparatively so small,

as to admit of being neglected under ordinary circumstances; hence it is

that such bodies have been termed Conductors of Electricity, whilst

bodies such as air, glass, &c., which are found to oppose very

considerable resistance to electrical action, are placed at the opposite

extremity of the scale, and termed Non-conductors or Insulators.

The resistance of a metallic copper wire to an ordinary electrical

discharge from a battery, was found so small, that the shock traversed

the wire at the rate of 576,000 miles in a second. The resistance

however, through a metallic line of Conduction, small as it be,

increases with the length, and diminishes with the area of the section

of the Conductor, or as the quantity of metal increases.

4.--It follows from these established facts, that if a building were

metallic in all its parts, an iron magazine for example, then no damage

could possibly arise to it from any stroke of Lightning which has come

within the experience of mankind; e.g., a man in armour is safe from

damage by Lightning; in fact, from the instant the electrical discharge

in breaking with disruptive and explosive violence through the resisting

air, seizes upon the mass in any point of it, from that instant the

explosive action vanishes, and the forces in operation are neutralized

upon the terminating planes of action, viz., the surface of the earth,

and opposed clouds.

5.--All this plainly teaches us, that in order to guard a building

effectually against damage by Lightning, we must endeavour to bring the

general structure as nearly as may be, into that passive or

non-resisting state it would assume, supposing the whole were a mass of

metal.

6.--To this end, one or more conducting channels of copper depending

upon the magnitude and extent of the building should be systematically

applied to the walls; these conducting channels should consist either of

double copper plates united in series one over the other, as in the

method of fixing such Conductors to the masts of Her Majesty’s Ships,

the plates being not less than 3¹⁄₂ inches wide, and of ¹⁄₁₆th and ¹⁄₈th

of an inch in thickness, or the Conductors may with advantage be

constructed of stout copper pipe not less than ³⁄₁₆ths of an inch thick,

and 1¹⁄₂ to 2 inches in diameter: in either case the Conductors should

be securely fixed to the walls of the building, either by braces, or

copper nails, or clamps; they should terminate in solid metal rods

above, projecting freely into the air, at a moderate and convenient

height above the point to which they are fixed, and below they should

terminate in one or two branches leading outward about a foot under the

surface of the earth; if possible, they should be connected with a

spring of water or other moist ground.

It would be proper in certain dry situations, to lead out in several

directions under the ground, old iron or other metallic chains, so as to

expose a large extent of metallic contact in the surface of the earth.

7.--All the metals in the roof and other parts of the building of

whatever kind, should so far as possible have metallic communication

with these Alarm Conductors, and in case of any prominent elevated

chimney, it would be desirable to lead a pointed conducting tube along

it to the metals of the roof; all of which satisfies the conditions

above specified.

8.--Remark 1.--It is now proved beyond all questions, that the

electrical discharge never leaves perfect conducting lines of small

resistance, in order to pass out upon bad conducting circuits, in which

the resistance is very great, that is an established law of nature;

hence a stroke of Lightning upon such conducting lines will be confined

to the Conductors as constituting a line of discharge of less resistance

than any other line of discharge through the building, which can be

assigned. The apprehension of “Lateral Discharge” therefore, from the

Conductor, is quite absurd; and is not countenanced by any fact

whatever; if any doubt could possibly exist, it would be now most

completely set at rest by the experience of the permanent Conductors,

applied to the masts of Her Majesty’s ships. In very many instances

furious discharges of Lightning have fallen on the masts with a crash as

if the ship’s broadside had been fired, and the solid point aloft has

been found melted; in all these cases electrical discharge robbed by the

Conductor of its explosive violence, has traversed the line of action to

the sea, through the ship, and through the copper bolts, driven through

the ship’s solid timbers, without the least damage to the surrounding

masses, whether metallic, as in the case of the massive iron hoops on

the lower masts, or not. Persons have either been close by or actually

leaning against the Conductors at the time, without experiencing any ill

consequence.

9.--Remark 2.--It has also been incontestably shown, that metallic

bodies have not any specific attractive force or affinity for the matter

of Lightning; metals are as little attractive of lightning as wood or

stone. All matter is equally indifferent to Electricity so far as

regards a specific attraction, hence the idea that metals attract or

invite Lightning is a popular but very unlearned error contradicted by

the most satisfactory evidence, and the whole course of experience; in

short, we find that Lightning falls indiscriminately upon trees, rocks,

and buildings, whether the buildings have metals about them or not.

10.--Remark 3.--A building that is hence clear, may be struck and

damaged by Lightning without having a particle of metal in its

construction; if there be metals in it, however, and they happen to be

in such situations as will enable them to facilitate the progress of the

electrical discharge, so far as they go, then the discharge will fall on

them in preference to other bodies offering more resistance, but not

otherwise; if metallic substances be not present, or if present, they

happen to occupy places in which they cannot be of any use in helping on

the discharge in the course it wants to go, then the electricity seizes

upon other bodies, which lie in that course, or which can help it,

however small their power of doing so, and in this attempt such bodies

are commonly, but not always, shattered in pieces. The great law of the

discharge is,--progress between the terminating planes of action,

viz:--the clouds and earth, and in such line or lines as upon the whole,

offer the least mechanical impediment or resistance to this operation,

just as water falling over the side of a hill in a rain storm, picks out

or selects as it were by the force of gravity, all the little furrows or

channels which lie convenient to its course, and avoids those which do

not. If in the case of Lightning you provide through the instrumentality

of efficient Conductors, a free and uninterrupted course for the

electrical discharge, then it will follow that course without damage to

the general structure; if you do not, then this irresistible agency will

find a course for itself through the edifice in some line or lines of

least resistance to it, and will shake all imperfect conducting matter

in pieces in doing so; moreover it is to be specially remarked in this

case, that the damage ensues, not where the metals are, but where they

cease to be continued, the more metal in a building therefore the

better, more especially when connected by an uninterrupted circuit with

any medium of communication with the earth.

Such is, in fact, the great condition to be satisfied in the application

of Lightning Conductors, which is virtually nothing more than the

perfecting a line or lines of small resistance in given directions, less

than the resistance in any other lines in the building, which can be

assigned in any other direction, and in which by a law of nature the

electrical agency will move in preference to any others.

11.--It follows from the foregoing principles, that a magazine

constructed entirely of iron or other metal, would be infinitely more

safe in Lightning storms than if built with masonry in the usual way;

metallic roofs for magazines, with capacious metallic Conductors to the

earth, would be unobjectionable, and a source of security.

Metallic gutters and ridges having continuous metallic connection with

the earth are also unobjectionable.

A good method of Conductors for magazines built of masonry, would be

such as already described, regard being had to the position of the

building, its extent, and most prominent points, also to the nature,

state, and condition of the soil, whether it be moist or dry, alluvial

calcareous, or of hard rock; we must also consider the extent,

disposition, and peculiar position of the metallic bodies entering into

the general structure of the building, whether the roof be flat,

pointed, or angular in various parts.

The pointed projecting extremities of the two Conductors, one or more as

the case may be, will be commonly sufficient; but, in buildings having

tall chimneys or other elevated prominent points, at a distance from the

Main Conductor, it will be requisite to guard such chimneys or other

parts, by a pointed rod, led along them to the metals of the roof, or

directly connected with the Main Conductors, by metallic connections.

12.--Pointed terminations of the Conductors in the air, are so far

important that they tend to break the force of a discharge of Lightning

when it falls on them. In fact, before the great shock actually takes

place, under the form of a dense explosion, a very large amount of the

discharge, which otherwise would be concentrated, runs off, as it were,

through the pointed Conductor; but they have no other influence.

With respect to these pointed terminations, no great care need be taken

about them, except that they should consist of solid copper rod, of

about three-quarters of an inch in diameter, and about a foot in length,

and be united by brazing to the conducting tube, elevated at such

convenient height above the walls of the building as the case may

suggest.

As a support to the Conductor, when raised above the wall, we may employ

a small staff or spar of wood fixed to the masonry.

13.--Copper linings to the doors and window shutters of magazines are

not objectionable, if requisite, as a precaution against fire; but they

are useless as a means of keeping out Lightning; on the other hand, it

is not easy to conceive a case in which the explosion of the gunpowder

is to be apprehended from the action of Lightning on the doors or

windows. Supposing, however, such metallic linings desirable as a

precaution against common cases of fire, then the masses of metal

should, according to the principles already laid down, have metallic

communication with the general system of conduction in the building and

the Main Conductor.

ON THE EXPLOSIVE FORCE OF GUNPOWDER.

~Advantages of Gunpowder~

The advantages of Gunpowder, as a propelling agent, over any other

explosive material are, the comparative safety attending its manufacture

and transport, and the gradual nature of its decomposition when compared

with those materials, such as fulminating gold, silver, mercury, &c. &c.

In gunpowder, the force resulting from the rapid evolution of gas in a

confined space has sufficient time to overcome the inertia of the

projectile, which is not the case with other explosive materials, the

conversion of which gaseous products is so instantaneous that nothing

can resist the intensity of their explosive action. Other advantages

suggest themselves in the use of Gunpowder, such as the comparative

cheapness of the ingredients composing it, and the ease with which they

may be obtained; for the sulphur and saltpetre are very abundant

productions of nature, and the charcoal can be manufactured cheaply and

with great facility, and if care is taken in the process of the

fabrication of powder, little deterioration will take place on its

exposure to heat or moisture.

~Air & Steam as propellants~

Condensed air and steam have been used as propelling agents; but the

great inconvenience attending their use quite preclude the possibility

of adapting them to war purposes.

~Force of Gunpowder.~

As the force and effect obtained from Gunpowder is the foundation of all

other particulars relating to Gunnery, we will briefly consider these

points.

~Upon what the action of powder depends.~

The action of Gunpowder is dependent upon a purely chemical process. Mr.

Robins proved that the force generated by the combustion of gunpowder,

was owing to an elastic gas which was suddenly disengaged from the

powder, when it was brought to a certain temperature, and further that

this disengaged gas had its elastic force greatly augmented by the heat

evolved by the chemical action.

~Ingredients are charged with a large volume of heated gas.~

The propelling power of Gunpowder is dependent on the rapid

decomposition of the nitre into its component parts; the oxygen forms

carbonic acid with the carbon in the charcoal, and the heat thus

generated by ignition changes both this and the nitrogen into a large

volume of heated gas. In a mixture of nitre and charcoal alone, the

oxidation proceeds with comparative slowness; by the addition of

sulphur, an augmentation of combustibility is gained, in consequence of

its igniting at a very low temperature; the sulphur, also, by its

presence, renders available for the oxidation of the carbon an

additional amount of oxygen, viz: that which is united with the

potassium, the latter being at once converted into sulphite upon

ignition of the powder.

~Weight of gas evolved.~

~Volume of gas evolved.~

~Heat of gas evolved.~

~Pressure of gas generated.~

~Strength of powder not affected by density of air, but by damp.~

It appears that the weight of gas generated is equal to three tenths of

the weight of the powder which yielded it, and that its bulk when cold,

and expanded to the rarity of Common air was 240 times that of the

powder; the barometer standing at about 30 inches. From this Robins

concluded that if the fluid occupied a space equal to the volume of the

gunpowder, its elastic force, when cold, would be 240 times the pressure

of the atmosphere, when the barometer stands as above. Mr. Robins also

considered that the heat evolved was at least equal to that of red hot

iron, and he found by experiments that air heated to this temperature

had its elasticity quadrupled, and therefore, that the force of gas from

powder is at least four times 240 = 960, or in round numbers 1,000 times

as great as the elasticity of the air measured by its pressure on an

equal extent of surface. From the height of the barometer it is known

that the pressure of the atmosphere is about 14³⁄₄lbs. upon the square

inch, so that the pressure of the elastic gas generated by the

combustion of the gunpowder upon the same area would be 14.75 by 1,000

or 14,750lbs. at the moment of explosion. He found that the strength of

Gunpowder was the same whatever might be the density of the atmosphere,

but that the moisture of the air effected it considerably, in fact that

the same quantity of powder which would give a bullet an initial

velocity of 1,700 feet per second on a day when the atmosphere was

comparatively dry, would upon a damp day give no more than 1,200 or

1,300 feet.

~Velocity of gas~

The velocity of the expansion of the gas is a most important point, upon

which depends, chiefly, the peculiar value of the substance as a

propelling agent. Many of the warlike machines of the Ancients produced

a momentum far surpassing that of our heaviest cannon, but the great

celerity given to the bodies projected from guns by gunpowder cannot be

in the least approached by any other means than by the sudden production

of an elastic gas. Mr. Robins found that the flame of gunpowder expanded

itself when at the muzzle of the gun with a velocity of 7,000 feet per

second.

~Dr. Hutton’s calculation as to:--_Volume, Temperature, Pressure_.~

~Temperature~

~Expansion.~

~How to calculate expansion~

~Absolute force of gunpowder cannot be determined.~

It has been calculated that one cubic inch of powder is converted into

250 cubic inches of gas at the temperature of the atmosphere, and Dr.

Hutton states that the increase of volume at the moment of ignition

cannot be less than eight times; therefore one inch of gunpowder, if

confined, at the time of explosion exerts a pressure of about 30,000lbs.

being 250 by 8 by 15 = 30,000lbs. on the cubic inch, or 5,000lbs. on the

square inch; and which at once accounts for its extraordinary power. The

value of the temperature to which the gases are raised, on the explosion

of the powder, has been variously estimated and it may be concluded to

rise as high as will melt copper, or 4,000° Fahrenheit. All gases expand

uniformly by heat, the expansion having been calculated with great

precision, to be ¹⁄₄₈₀th for each degree of Fahrenheit. If therefore we

take Dr. Hutton’s calculations of one volume of powder expanding into

250 volumes of gas at the temperature of the atmosphere, and if we

suppose 4,000° Fahrenheit to be the heat to which they are raised on

ignition, the expansion of gunpowder would be calculated. Thus, suppose

the gas to be at 60°, the temperature of the atmosphere, we must deduct

60° from 4,000°, which will give 3,940, being the number of degrees

remaining to which it is raised, hence

temp. vol. temp. vol. vol.

1 3940

1° : --- 3,940° : ---- = 8·2

480 480

that is, each volume of gas would at a temperature of 4000° be

increased 8·2 in volume. Gunpowder when at the temperature of the air

being expanded 250 times in volume; therefore 250 by 8·2 = 2,050 as the

increased expansion for each volume of gas generated by the explosion of

gunpowder at the temperature of 4,000° Fahrenheit. Lieut-Colonel Boxer

calculates that the heat generated by good dry powder is not under

3,000° Fahrenheit. It appears with our present knowledge, the absolute

value of the force of gunpowder cannot be determined. Still by careful

and extensive experiments no doubt a near approximation to the truth may

ultimately be arrived at, so that although much has already been done by

various eminent philosophers, there is still more to be accomplished;

and the importance of the subject ought to act as a stimulus to the

exertions of those belonging to a profession the most interested in the

question.

~Loss of velocity by windage.~

It has been found by experiments that in calculating the initial

velocity of a projectile, one third of the whole force was lost with a

windage of ¹⁄₁₀th inch with a shot of 1·96-in. and 1·86-in. in diameter.

The bore of the gun being 2·02-in.

~Definition of ignition and combustion.~

By ignition we understand the act of setting fire to a single grain, or

to a charge of gunpowder, and by combustion we mean the entire

consumption of a grain or of a charge.

~Quickness of combustion.~

Upon the quickness of combustion mainly depends the applicability of

gunpowder for Military purposes.

~Ignition by heat.~

Gunpowder may be inflamed in a variety of ways, but whatever be the

method, one portion of the substance must in the first instance be

raised to a temperature a little above that necessary to sublime the

sulphur, which can be removed from the other ingredients, by gradually

raising the compound to a heat sufficient to drive it off in a state of

vapour. The heat required for this purpose is between 600° and 680°

Fahrenheit.

~Progressive combustion.~

When a charge of powder is exploded in the bore of a gun, to all

appearance there would seem to be an instantaneous generation of the

whole force. But in fact it is not so, a certain time being necessary to

the complete combustion of the substance. This gradual firing is of the

utmost importance, for were it otherwise, the gun, unless of enormous

strength, must be shattered in pieces, as well as the projectile; for in

such a case, this great force being suddenly exerted upon one part only

of the material, there would not be time for the action to be

distributed over the particles, at any great distance, before those in

the immediate vicinity of the explosion, were forced out of the sphere

of action of the cohesive force, and consequently rupture must take

place.

~Substances which have a more violent action than powder.~

Class Book for the School of Musketry, Hythe Prepared for the Use of Officers · 第 3 / 17 段