CASTING THE ALLOYS.

The Semito-Hamitic races made excellent castings at a very early date.

The Phoenicians may be mentioned as particularly skillful. It is

reported that there were two immense bronze pillars that stood before

the temple of Gades in the 11th century before Christ. The Tyrian

founders also made a pillar for Solomon's Temple, and a metallic basin

10 ells in diameter and 5 deep. Similar large basins have been dug up

in Assyria.

The art of casting statues is no less ancient. Small statuettes were

cast solid; larger ones consisted of several pieces which were riveted

together. In the later Grecian and old Roman days the art reached

a high stage of perfection. Many cities had thousands of bronzes;

gigantic pieces were constructed. The Colossus of Rhodes was 30 meters

high and stood with outstretched legs astride the entrance to the

smaller harbor. Ships could pass through it with sails extended. A

statue of Jupiter in Tarent was 20 meters high, and one of Nero was

erected in Pliny's time, 30 meters high, costing a million dollars.[18]

These facts give us a good idea of the technical ability of the old

founders of bronze.

Analyses of antique bronzes give us some idea of their art of mixing

and coloring. We presume that they soon abandoned the use of copper

and pure bronze; the former yields porous casts and of a poor color;

the latter material was, in later times, too costly. Lead was probably

used at first for its fusibility only, but afterward it was certainly

introduced for economical reasons. This cheap material was often added

in very considerable quantity until they learned that leaden bronzes

did not have a fine color either while fresh and clean, or when old and

covered with patina.

We have also seen that zinc, as well as lead, was often added. As the

color of zinc alloys was red to light golden yellow (red metal, brass),

they tried to dispense with tin entirely, as its price was higher

than that of zinc (cadmia, as it was called). But they soon became

convinced that for fine statues, at least, a small quantity of _tin was

a necessity_. Generally a zinc-brass was used for statues.

To prevent the metallic constituents from separating during fusion, the

mass was kept thick and pasty by putting in old scrap bronze that had

been often melted and contained oxides. The smelters also knew that the

metals, particularly the tin, grew smaller every time it was melted,

in consequence of oxidation, slagging, and evaporation.[19] The Romans

therefore added, besides the scrap bronze, an eighth part of "silver

lead," _i. e._, a mixture of tin and lead.

Finally, in regard to the color of the castings, the ancients collected

valuable experiences. Cadmia (zinc ore) was used to impart a golden

color to the bronze.[20] Alloys rich in tin were used for mirrors, and

arsenic was employed to make them white.[21]

The moulds originally employed were very primitive. For simple objects

a corresponding hole was dug in the sand or clay soil. Complicated

figures had to be formed in clay, and the metal was cast in the clay

mould. If the mould was to serve for several castings, it had to be

made of baked clay, stone, brick, or other durable material. Organic

substances were mixed with the clay to prevent uneven shrinkage and

cracking.

Hollow casting is more difficult; first a core is formed corresponding

to the hollow in the figure; over this the figure is formed, and over

that the mantle, _i. e._, the negative, or mould. The latter is taken

off, the figure taken away from the core, the mantle replaced, and

the metal poured into the space between the core and the mantle. In

this case it is difficult to take off the mantle so clean and put it

back so accurately that the parts will not be disturbed. To avoid this

difficulty a wax model may be built on the core, and the mantle formed

over this, and then when the mould is dry it can be heated and the wax

melted out.

The Phoenicians and Egyptians must have used one or the other of

these devices for their hollow castings.

The Greeks appear at first as pupils and imitators of the

Phoenicians, but they soon surpassed their teachers in forms as well

as skill. They knew how to make their moulds so perfect, and were able

to place their cores so near the mantles, that the castings were as

thin as cardboard. The master founders of to-day have not reached that

perfection.

Scientific American, September 29, 1883 Supplement. No. 404 · 第 51 / 75 题