A NEW SULPHATE OF COPPER PILE.

Some studies made of the telegraph service of the Railway Company of

the East (France) have resulted in a happy modification of the Callaud

pile, rendering it easier of maintenance and reducing the consumption

of the materials employed.

As well known, the Callaud pile, which is exclusively employed for

telegraphic purposes by certain railroad companies, consists of a glass

vessel, of a circular piece of zinc suspended by hooks from the upper

part of the vessel, and of a strip of copper resting on the bottom of

the latter. This copper strip is riveted to a rod of the same metal

which constitutes the positive electrode. In the bottom of the vessel

there is placed a saturated solution of sulphate of copper, so that its

level reaches to within a short distance of the lower part of the zinc,

and the vessel is then filled with pure water. The zinc being attacked,

there is formed a zinc sulphate, which always remains at the upper part

of the vessel by reason of the difference in density of the solutions

of sulphate of zinc and sulphate of copper, and the reduced copper

deposits upon the strip in the center. It has been found necessary to

cover the copper rod with a sheath of gutta-percha in order to keep it

from being cut at the line of intersection of the two liquids, and this

is the first inconvenience of the system. It is necessary, moreover,

to keep the solution of copper at a certain degree of concentration by

placing in the bottom of the vessel a supply of crystals of sulphate

of copper. Hence it happens that the solution, being increased,

eventually reaches the zinc, and the latter is thereupon attacked to no

purpose, with a pure loss of copper through reduction. This is a second

inconvenience, which can be remedied by introducing into the pile

only a simply saturated solution without excess of crystals. It will

be seen that, in this latter case, it is necessary to visit the pile

quite frequently, to empty it by means of siphons, and to confide its

maintenance to experienced persons only.

This is why, up to the present, railroad companies have preferred

the Daniell to the Callaud pile for alarm bells that control signal

disks, despite the serious advantages of the Callaud pile and the

inconvenience of the porous vessel that enters into the composition of

the other.

[Illustration: NEW SULPHATE OF COPPER PILE.]

The modified Callaud pile is exempt from the defects that we have just

pointed out. It differs from the old form in the substitution of a

leaden tube, open at its extremities and dipping into the liquid of the

pile, for the piece of copper or positive electrode. The lead, which

is not attacked, and may serve indefinitely, is held in a vertical

position by means of a foot made by cutting slits with a pair of

scissors in the bottom of the tube, and bending back the strips thus

formed. This foot also serves to prevent the tube from touching the

zinc, by holding it in equilibrium.

In order to charge the element thus constituted, it is only necessary

to fill the lead tube with crystals of sulphate of copper and to pour

water into the glass vessel until its level reaches within a centimeter

and a half of the upper edge of the zinc. In an hour the copper will

have dissolved sufficiently to allow the pile to begin its action.

Experience has demonstrated that, whatever be the supply of copper that

is put into the lead tube, the saturated solution _will never reach the

zinc_, even in an open circuit.

In sum, the new arrangement given to the Callaud element presents the

following advantages: (1) It permits of the maintenance being confided

to anybody, since this consists simply in the introduction into the

central tube of crystals of sulphate of copper when it is seen that

the blue tint of the lower liquid is disappearing. (2) It permits of

proportioning the expense to the work really effected.--_La Nature_.

[Illustration: Lodges, Portington Grange, Eastrington.

Walter Hanstock, Architect.

GROUND PLAN.

CHAMBER PLAN.

Scientific American, September 29, 1883 Supplement. No. 404 · 第 24 / 75 题