_Of Heat._
Heat is an affection of bodies well known by the sensation that it
excites. It is produced by friction or compression, as by the striking
of flint against steel, and the hammering of iron, by the reflection or
refraction of light, and by the combustion of inflammable substances.
It has been long disputed, whether the cause of heat be properly a
_substance_, or some particular affection of the particles that compose
the substance that is heated. But be it a substance, or a principle of
any other kind, it is capable of being transferred from one body to
another, and the communication of it is attended with the following
circumstances. All substances are expanded by heat, but some in a
greater degree than others; as metals more than earthy substances, and
charcoal more than wood. Also some receive and transmit heat through
their substance more readily than others; metals more so than earths,
and of the metals, copper more readily than iron. Instruments contrived
to ascertain the expansion of substances by heat, are called
_pyrometers_, and are of various constructions.
As a standard to measure the degrees of heat, mercury is in general
preferable to any other substance, on account of its readily receiving,
and communicating, heat through its whole mass. _Thermometers_,
therefore, or instruments to measure the degrees of heat, are generally
constructed of it, though, as it is subject to become solid in a great
degree of cold, ardent spirit, which will not freeze at all, is more
proper in that particular case.
The graduation of thermometers is arbitrary. In that of Fahrenheit,
which is chiefly used in England, the freezing point of water is 32 deg.,
and the boiling point 212 deg. In that of Reaumur, which is chiefly used
abroad, the freezing point of water is 0, and the boiling point 80. To
measure the degrees of heat above ignition, Mr. Wedgwood has happily
contrived to use pieces of clay, which contract in the fire; and he has
also been able to find the coincidence of the degrees in mercurial
thermometers with those of his own.
To measure the degrees of heat and cold during a person's absence, Lord
George Cavendish contrived an instrument, in which a small bason
received the mercury, that was raised higher than the place for which it
was regulated by heat or cold, without a power of returning. But Mr. Six
has lately hit upon a better method, viz. introducing into the tube of
his thermometer a small piece of iron, which is raised by the ascent of
the mercury, and prevented from descending by a small spring; but which
may be brought back to its former place by a magnet acting through the
glass.
Heat, like light, is propagated in right lines; and what is more
remarkable, cold observes the same laws. For if the substance emitting
heat without light, as iron below ignition, be placed in the focus of a
burning mirror, a thermometer in the focus of a similar mirror, placed
parallel to it, though at a considerable distance, will be heated by it,
and if a piece of ice be placed there, the mercury will fall.
Heat assists the solvent power of almost all menstrua; so that many
substances will unite in a certain degree of heat, which will form no
union at all without it, as dephlogisticated and inflammable air.
If substances be of the same kind, they will receive heat from one
another, in proportion to their masses. Thus, if a quantity of water
heated to 40 deg. be mixed with another equal quantity of water heated to
20 deg., the whole mass will be heated to 30 deg. But if the substances be of
different kinds, they will receive heat from each other in different
proportions, according to their _capacity_ (as it is called) of
receiving heat. Thus, if a pint of mercury of the temperature of 136 be
mixed with a pint of water of the temperature of 50, the temperature of
the two after mixture will not be a medium between those two numbers,
viz. 93, but 76; consequently the mercury was cooled 60 deg., while the
water was heated only 26; so that 26 degrees of heat in water correspond
to 60 in mercury. But mercury is about 13 times specifically heavier
than water, so that an equal weight of mercury would contain only one
thirtieth part of this heat; and dividing 26 by 13, the quotient is 2.
If _weight_, therefore, be considered, the heat discovered by water
should be reckoned as 2 instead of 60; and consequently when water
receives 2 degrees of heat, an equal weight of mercury will receive 60 deg.;
and dividing both the numbers by 2, if the heat of water be 1, that of
the mercury will be 30. Or since they receive equal degrees of heat,
whether they discover it or not (and the less they discover, the more
they retain in a latent state) a pound of mercury contains no more than
one thirtieth part of the heat actually existing in a pound of water of
the same temperature. Water, therefore, is said to have a greater
capacity for receiving and retaining heat, without discovering it, than
mercury, in the proportion of 30 to 1, if weight be considered, or of
60 to 26, that is of 30 to 13; if _bulk_ be the standard, though,
according to some, it is as 3 to 2.
The capacity of receiving heat in the substance is greatest in a state
of vapour, and least in that of a solid; so that when ice is converted
into water, heat is absorbed, and more still when it is converted into
vapour; and on the contrary, when vapour is converted into water, it
gives out the heat which it had imbibed, and when it becomes ice it
gives out still more.
If equal quantities of ice and water be exposed to heat at the
temperature of 32 deg., the ice will only become water, without receiving
any additional sensible heat; but an equal quantity of water in the same
situation would be raised to 178 deg., so that 146 degrees of heat will be
imbibed, and remain in latent in the water, in consequence of its
passing from a state of ice: and heat communicated by a given weight of
vapour will raise an equal weight of a nonevaporable substance, of the
same capacity with water, 943 degrees; so that much more heat is latent
in steam, than in the water from which it was formed.
This doctrine of latent heat explains a great variety of phaenomena in
nature; as that of cooling bodies by evaporation, the vapour of water,
or any other fluid substance, absorbing and carrying off the heat they
had before.
Water, perfectly at rest, will fall considerably below the freezing
point, and yet continue fluid: but on the slightest agitation, the
congelation of the whole, or part of it, takes place instantly, and if
the whole be not solid, it will instantly rise to 32 deg., the freezing
point. From whatever cause, some motion seems necessary to the
commencement of congelation, at least in a moderate temperature; but
whenever any part of the water becomes solid, it gives out some of the
heat it had before, and that heat which was before latent becoming
sensible, and being diffused through the whole mass, raises its
temperature.
On the same principle, when water heated higher than the boiling point
in a digester is suddenly permitted to escape in the form of steam, the
remainder is instantly reduced to the common boiling point, the heat
above that point being carried off in a latent state by the steam.
Had it not been for this wise provision in nature, the whole of any
quantity of water would, in all cases of freezing, have become solid at
once; and also the whole of any quantity that was heated to the point of
boiling, would have been converted into steam at once; circumstances
which would have been extremely inconvenient, and often fatal.
This doctrine also explains the effect of freezing mixtures, as that of
salt and snow. These solid substances, on being mixed, become fluid, and
that fluid absorbing much heat, deprives all the neighbouring bodies of
part of what they had. But if the temperature at which the mixture is
made be as low as that to which this mixture would have brought it, it
has no effect, and in a lower temperature this new fluid would become
solid; for that mixture has only a certain determinate capacity for
heat, and if the neighbouring bodies have less heat, they will take
from it.
It has been observed, that the comparative heat of bodies containing
phlogiston is increased by calcination or combustion; so that the calx
of iron has a greater capacity for heat, and therefore contains more
latent heat, than the metal.
In general it is not found, that the same substances have their capacity
for receiving heat increased by an increase of temperature; but this is
said to be the case with a mixture of ardent spirit and water, and also
that of spirit of vitriol and water.
Since all substances contain a greater or less quantity of heat, and in
consequence of being deprived of it become colder and colder, it is a
question of some curiosity to determine the extent to which this can go,
or at what degree in the scale of a thermometer any substance would be
absolutely cold, or deprived of all heat; and an attempt has been made
to solve this problem in the following manner. Comparing the capacity of
water with that of ice, by means of a third substance, viz. mercury, it
has been found, that if that of ice be 9 deg., that of water is 10 deg.; so that
water in becoming ice gives out one tenth part of its whole quantity of
heat. But it has been shown, that ice in becoming water absorbs 146
degrees of heat. This, therefore, being one tenth part of the whole heat
of water, it must have contained 1460 degrees; so that taking 32
degrees, which is the freezing point, from that number, the point of
absolute cold will be 1426 below 0 of Fahrenheit's scale.
By a computation, made by means of the heat of inflammable and
dephlogisticated air, at the temperature of 50, Dr. Crawford finds, that
it contains nearly 1550 degrees of heat; so that the point of absolute
cold will be 1500 below 0. But more experiments are wanted to solve this
curious problem to entire satisfaction.