LECTURE XXIII.

_Of Mercury._

Mercury is the most fusible of all the metals, not becoming solid but in

40 deg. below 0 in Fahrenheit's thermometer. It is then malleable. It is

heavier than any other metal except gold or platina. It is volatile in a

temperature much lower than that of boiling water, and in vacuo in the

common temperature of the atmosphere; and at six hundred it boils.

In a degree of heat in which it would rise easily in vapour, mercury

imbibes pure air, and becomes a red calx, called _precipitate per se_.

At a greater degree of heat it parts with that air, and is running

mercury again.

Mercury is not perceptibly altered by exposure to the air.

Mercury is acted upon by the vitriolic acid when hot. In this process

vitriolic acid air is procured, and the mercury is converted into a

white substance, which being dipped in water becomes yellow, called

_turbith mineral_, one third heavier than the mercury from which it was

made. By heat this substance parts with its pure air, and becomes

running mercury; but if the process be made in a clean earthen vessel,

there will remain a portion of _red calx_, which cannot be reduced by

any degree of heat, except in contact with some substance containing

phlogiston. If this be done with a burning lens, in inflammable air,

much of the air will be absorbed.

Mercury is dissolved most readily in the nitrous acid, when the purest

nitrous air is procured; and there remains a substance which is first

yellow, and by continuance red, called _red precipitate_. In a greater

degree of heat the dephlogisticated air will be recovered, and the

mercury be revived; but the substance yields nitrous air after it

becomes solid, and till it changes from yellow to red.

The precipitates of mercury from acids by means of alkalies possess the

property of exploding, when they are exposed to a gradual heat in an

iron spoon, after having been triturated with one sixth of their weight

of the flowers of sulphur. The residuum consists of a violet-coloured

powder, which, by sublimation, is converted into cinnabar.

It seems, therefore, as if the sulphur combined suddenly with the

mercury, and expelled the dephlogisticated air in an elastic state.

The marine acid seizes upon mercury dissolved in nitrous acid, and if

the acid be dephlogisticated, the precipitate is _corrosive sublimate_;

but with common marine acid, it is called _calomel_, or _mercurius

dulcis_. This preparation is generally made in the dry way, by

triturating equal parts of mercury, common salt and vitriol, and

exposing the whole to a moderate heat; when the corrosive sublimate

rises, and adheres to the upper part of the glass vessel in which the

process is made.

Mercury combines readily with sulphur by trituration, and with it forms

a black powder called _Ethiops mineral_. A more intimate combination of

mercury and sulphur is made by means of fire. This is called _cinnabar_,

about one third of which is sulphur. Vermillion is cinnabar reduced to

powder.

Mercury readily unites with oil, and with it forms a deep black or blue

compound, used in medicine.

It readily combines with most of the metals, and when it is used in a

sufficient quantity to make them soft, the mixture is called an

_amalgam_. It combines most readily with gold, silver, lead, tin,

bismuth, and zinc. Looking-glasses are covered on the back with an

amalgam of mercury and tin.

When mercury is united with lead or other metals, it is rendered less

brilliant and less fluid; but agitation in pure air converts the impure

metal into a calx, together with much of the mercury, in the form of a

black powder.

Heat recovers the pure air, and the mercury, leaving the calx of the

impure metal.

Much mercury is found native in a slaty kind of earth, or in masses of

clay or stone; but the greatest quantity is found combined with sulphur

in _native cinnabar_.

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