LECTURE XIX.

_Of Solid Substances._

All solid substances are capable of becoming fluid by heat, and most of

them may thereby be reduced into a state of vapour, or air; and in

passing from a fluid into a solid state their component parts assume a

particular mode of arrangement, called _crystallization_, which differs

according to the nature of the substance; so that all solids, especially

if they be suffered to concrete slowly, may be called _crystals_.

Exclusive of _salts_, which have been considered already, as formed by

the union of acids and alkalis, solids in general have obtained the

names of _earths_, or _stones_, which differ only in their texture; and

they are distinguished into those that are _metallizable_, or those that

are not; the former being called _ores_, and the latter simply _earths_;

the principal of which are the _calcareous_, _siliceous_,

_argillaceous_, _magnesia_, _terra ponderosa_, and a few others which

have been discovered lately, but have not been much examined.

_Of Calcareous Earth._

Calcareous earth is found in the shells of fishes, the bones of animals,

chalk, lime-stone, marble, and gypsum: but all calcareous earth is

supposed to be of animal origin; and beds of chalk, lime-stone, or

marble, are thought to have been beds of shells formed in the sea, in

some pristine state of the earth.

The calcareous earth which is found in shells, lime-stone, and marble,

is combined with fixed air, discovered by effervescing with acids. To

obtain it perfectly pure, the earth must be pounded and washed with

water, in order to free it from any saline substance which may be

contained in it, then dissolved in distilled vinegar, and precipitated

by mild alkalies. Lime-stone exposed to heat loses about half its

weight, in fixed air and water, and the remainder, called _quick-lime_,

attracts water very powerfully, and their union is attended with much

heat, after which it dissolves into a fine powder called _slaked lime_.

If it be left exposed to the atmosphere, it will of itself, by gradually

imbibing moisture, fall into the state of powder.

Water dissolves about one seven hundredth part of its weight of

quick-lime, and is then called _lime-water_. Exposed to the air, a crust

will be formed on its surface, which is found to consist of calcareous

earth and fixed air.

Lime and water mixed with sand make _mortar_, by which means different

stones may be made to cohere as one mass, which is the most valuable

use of this kind of earth.

Calcareous earth, united with vitriolic acid, makes _gypsum_; and this

substance pounded and exposed to heat, parts with its water, and is then

called _plaister of Paris_. In this state, by imbibing water again, it

becomes a firm substance, and thus is useful in making moulds, &c.

The earth of animal bones is calcareous united to the phosphoric acid.

_Of Siliceous Earth._

Siliceous earth seems to be formed by nature from chalk, perhaps by the

introduction of some unknown acid, which the vitriolic acid is not able

to dislodge. It abounds in most substances which are hard enough to

strike fire with steel, as _flint_, _rock crystal_, and most _precious

stones_. It is not acted upon by any acid except the fluor and

phosphoric, but especially the former: but it is soluble in alkalies;

and being then dissolved in water, makes _liquor silicum_, from which

the purest siliceous earth may be precipitated by acids. For this

purpose about four times the weight of alkali must be made use of. With

about equal weights of alkali and siliceous sand is made _glass_, of so

great use in admitting light and excluding the weather from our houses,

as well as for making various useful utensils. To make glass perfectly

colourless, and at the same time more dense, commonly called _flint

glass_, manufacturers use a certain proportion of calx of lead and

manganese.

Siliceous earth is not affected by the strongest heat, except by means

of a burning lens, or dephlogisticated air.

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