CHAPTER X

SOLID SOLUTIONS. MIXED CRYSTALS 175

General, 175. Solution of gases in solids, 176. Palladium

and hydrogen, 178. Solutions of solids in solids. Mixed

crystals, 180. Formation of mixed crystals of isomorphous

substances, 182. I. The two components can form an unbroken

series of mixed crystals. (_a_) _The freezing points of all mixtures

lie between the freezing points of the pure components._ Examples,

183. Melting-point curve, 183. (_b_) _The freezing-point curve passes

through a maximum._ Example, 186. (_c_) _The freezing-point

curve passes through a minimum._ Example, 188. Fractional

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crystallization of mixed crystals, 188. II. The two components

do not form a continuous series of mixed crystals. (_a_) _The

freezing-point curve exhibits a transition point_, 190. Example,

190. (_b_) _The freezing-point curve exhibits a eutectic point_, 191.

Examples, 192. Changes in mixed crystals with the temperature,

192.

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