1. Sulphur almost chemically pure, of a very bright and yellow color.

_Second Best._--Slightly inferior to the first quality; bright and

yellow.

_Second Good._--Contains 4 to 5 per cent. of earthy matter, but is of

a bright yellow.

_Second Current._--Dirty yellow, containing more earthy matter than

that last named.

_Third Best._--Brownish yellow; this tint depends on the amount of

bitumen which it contains.

_Third Good._--Light brown, containing much extraneous matter.

_Third Current._--Brown and coarse.

These qualities are decided by color, not by test. The difference of

price is from 3 to 10 francs per ton. Manufacturers prefer the third

best, because of its containing more sulphuric acid and costing less

than the sulphur of better quality.

Sulphur is conveyed to the seaboard by rail, in carts, or on mules or

donkeys. Conveyance by cart, mule, or donkey is only resorted to when

the distance is short or from mines to railroad stations. The tariff

in the latter case is understood to be 1 lire per ton per mile. The

railroad tariff is 0.12 per ton per kilometer; but it is contemplated,

it is understood, to reduce this to 7 centimes in a short time. The

price per ton of sulphur is as follows:

At Porto At At

Grade. Empedocle. Licata. Catania.

Lire. Lire. Lire.

Second best 86.60 87.00 90.70

Second good 84.42 84.50 90.30

Second current 83.90 83.90 88.40

Third best 79.00 79.90 86.90

Third good 77.80 77.80 83.00

Third current 76.80 76.70

Sulphur free on board, brokerage, shipment, export duty, and all other

expenses included, costs 20 lire per ton in excess of the above

prices. Nearly all the sulphur exported from Palermo emanates from the

Lercara mines, in the province of Palermo, the price per ton being as

follows: first quality, 91.60 lire; second quality, 88.40. Sulphur is

usually conveyed in steamers to foreign countries from Sicilian ports.

The average freight per ton to New York is about as follows: From

Palermo, 8.70 lire; from Catania, 13.50 lire; from Girgenti, 16 lire.

An additional charge of 2.50 lire is made when the sulphur may be

destined for other ports in the United States.

Liebig once said that the degree of civilization of a nation and its

wealth could be seen in its consumption of sulphuric acid. Now,

although Italy produces immense quantities of sulphur, it cannot, on

account of the scarcity of fuel, and other obvious reasons perhaps,

compete with certain other countries in the manufacture and

consumption of sulphuric acid.

Sulphur is employed in the manufacture of sulphuric acid, and the

latter serves in the manufacture of sulphate of soda, chloridic acid,

carbonate of soda, azodic acid, ether, stearine candles, purification

of oils in connection with precious metals and electric batteries.

Nordhausen's sulphuric acid is employed in the manufacture of indigo.

Sulphate of soda is employed in the manufacture of artificial soda,

glassware, cold mixtures, and medicines. Carbonate of soda is used in

the manufacture of soap, bleaching wool, coloring and painting

tissues, and in the manufacture of fine crystal ware and the

preparation of borax. Chloric acid is used in the preparation of

chlorides with bioxide of manganese, and with chlorides in the

preparation of hypochlorides of lime, known in commerce under the name

of bleaching powder, and improperly called chloride of lime, which is

used as a disinfectant in contagious diseases, in bleaching stuffs,

and in the manufacture of paper from vegetable fibers, and in the

manufacture of gelatine extracted from bones, as well as in fermenting

molasses and in the manufacture of sugar from beet root. Sulphur is

also used in the preparation of gunpowder and oil of vitriol, and in

the manufacture of matches and cultivation of the vine.

In the year 1838 the Neapolitan government granted a monopoly to a

French company for the trade in sulphur. By the terms of the agreement

the producers were required to sell their sulphur to the company at

certain fixed prices, and the latter paid the government the sum of

$350,000 annually in consideration of this requirement. This, however,

was not a success, and tended to curtail the sulphur industry, and the

government, discovering the agreement to be against its interests,

annulled it, and established a free system of production, charging an

export tax per ton only. At that time sulphuric acid was derived

exclusively from sulphur. Hence the demand from all countries was

great, and the prices paid for sulphur were high. It was about this

period that the sulphur industry was at its zenith. The monopoly

having been abolished, every mine did its utmost to produce as much

sulphur as possible, and from the export duty exacted by the

government there accrued to it a much larger revenue than that which

it received during the period of the monopoly. The progress of science

has, however, modified the state of things since then, as sulphur can

now be obtained from pyrite or pyrite of iron. This discovery

immediately caused the price of sulphur to fall, and the great demand

therefore correspondingly ceased. In England, at the present time, it

is understood that two-thirds of the sulphuric acid used is

manufactured from pyrites. The decrease in prices caused many of the

mines to suspend operations, and as a result the sulphur remained idle

in stock. In 1884 an association was formed at Catania with a view to

buying up sulphur thus stored away at the mines and various ports at

low prices, and store it away until a favorable opportunity should

present itself for the sale thereof. This had the effect of increasing

the prices of sulphur in Sicily for some time, and the producers,

discovering that the methods of the association increased the foreign

demand for their produce as well as its prices, exported it directly

themselves, thus breaking up the association referred to, as it was no

longer a profitable concern.

The railroad system, which in later years has placed the most

important parts of Sicily in communication with the seaboard, has been

most beneficial to the sulphur industry. A great saving has been made

in transporting it to the ports. This was formerly (as stated)

accomplished by carts drawn by mules at an enormous expense, as the

roads were wretched, and unless some person of distinction

contemplated passing over them, repairs were unknown.

Palermo, March 20, 1888.

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Scientific American Supplement, No. 647, May 26, 1888 · 第 26 / 59 题