T1 = T2 = T'12;

and T12 = 0, as it should do.

Laplace does not treat systematically the question of interfacial

tension, but he gives incidentally in terms of his quantity H a relation

analogous to (47).

If 2T'12 > T1 + T2, T12 would be negative, so that the interface would

of itself tend to increase. In this case the fluids must mix.

Conversely, if two fluids mix, it would seem that T'12 must exceed the

mean of T1 and T2; otherwise work would have to be _expended_ to effect

a close alternate stratification of the two bodies, such as we may

suppose to constitute a first step in the process of mixture (Dupre,

_Theorie mecanique de la chaleur_, p. 372; Kelvin, _Popular Lectures_,

p. 53).

Encyclopaedia Britannica, 11th Edition, "Capefigue" to "Carneades" Volume 5, Slice 3 · 第 25 / 74 题