CHEMICAL CONTRADICTIONS.

Science, whose aim and end is to prove the harmony and “eternal fitness

of things,” also proves that we live in a world of paradoxes; and that

existence itself, is a whirl of contradictions. Light and darkness,

truth and falsehood, virtue and vice, the negative and positive poles of

galvanic or magnetic mysteries, are evidences of all-pervading

antitheses, which acting like the good and evil genii of Persian

Mythology, neutralise each other’s powers when they come into collision.

It is the office of science to solve these mysteries. The appropriate

symbol of the lecture-room is a Sphinx; for a scientific lecturer is but

a better sort of unraveller of riddles.

Who would suppose, for instance, that water—which everybody knows,

extinguishes fire—may, under certain circumstances, add fuel to flame,

so that the “coming man” who is to “set the Thames on fire,” may not be

far off. If we take some mystical grey-looking globules of potassium

(which is the metallic basis of common pearl-ash) and lay them upon

water, the water will instantly appear to ignite. The globules will swim

about in flames, reminding us of the “death-fires” described by the

Ancient Mariner, burning “like witches’ oil” on the surface of the

stagnant sea. Sometimes even, without any chemical ingredient being

added, Fire will appear to spring spontaneously from water; which is not

a simple element, as Thales imagined, when he speculated upon the origin

of the Creation, but two invisible gases—oxygen and hydrogen, chemically

combined. During the electrical changes of the atmosphere in a

thunder-storm, these gases frequently combine with explosive violence,

and it is this combination which takes place when “the big rain comes

dancing to the earth.” These fire-and-water phenomena are thus accounted

for; certain substances have peculiar affinities or attractions for one

another; the potassium has so inordinate a desire for oxygen, that the

moment it touches, it decomposes the water, abstracts all the oxygen,

and sets free the hydrogen or inflammable gas. The potassium, when

combined with the oxygen, forms that corrosive substance known as

caustic potash, and the heat disengaged during this process, ignites the

hydrogen. Here the mystery ends; and the contradictions are

solved;—Oxygen and hydrogen when combined, become water; when separated

the hydrogen gas burns with a pale lambent flame. Many of Nature’s most

delicate deceptions are accounted for by a knowledge of these laws.

Your analytical chemist sadly annihilates, with his scientific

machinations, all poetry. He bottles up at pleasure the Nine Muses, and

proves them—as the fisherman in the Arabian Nights did the Afrite—to be

all smoke. Even the Will o’ the Wisp cannot flit across its own morass

without being pursued, overtaken, and burnt out by this scientific

detective policeman. He claps an extinguisher upon Jack o’ Lanthorn

thus:—He says that a certain combination of phosphorus and hydrogen,

which rises from watery marshes, produces a gas called phosphuretted

hydrogen, which ignites spontaneously the moment it bubbles up to the

surface of the water and meets with atmospheric air. Here again, the

Ithuriel wand of science dispels all delusion, pointing out to us, that

in such places animal and vegetable substances are undergoing constant

decomposition; and as phosphorus exists under a variety of forms in

these bodies, as phosphate of lime, phosphate of soda, phosphate of

magnesia, &c., and as furthermore the decomposition of water itself is

the initiatory process in these changes, so we find that phosphorus and

hydrogen are supplied from these sources; and we may therefore easily

conceive the consequent formation of phosphuretted hydrogen. This gas

rises in a thin stream from its watery bed, and the moment it comes in

contact with the oxygen of the atmosphere, it bursts into a flame so

buoyant, that it flickers with every breath of air, and realises the

description of Goëthe’s Mephistopheles, that the course of

Jack-o’-lantern is generally “zig-zag.”

Who would suppose that absolute darkness may be derived from two rays of

light! Yet such is the fact. If two rays proceed from two luminous

points very close to each other, and are so directed as to cross at a

given point on a sheet of white paper in a dark room, their united light

will be twice as bright as either ray singly would produce. But if the

difference in the distance of the two points be diminished only one

half, the one light will extinguish the other, and produce absolute

darkness. The same curious result may be produced by viewing the flame

of a candle through two very fine slits near to each other in a card.

So, likewise, strange as it may appear, if two musical strings be so

made to vibrate, in a certain succession of degrees, as for the one to

gain half a vibration on the other, the two resulting sounds will

antagonise each other and produce an interval of perfect silence. How

are these mysteries to be explained? The Delphic Oracle of science must

again be consulted, and among the high priests who officiate at the

shrine, no one possesses more recondite knowledge, or can recal it more

instructively, than Sir David Brewster. “The explanation which

philosophers have given,” he observes, “of these remarkable phenomena,

is very satisfactory, and may easily be understood. When a wave is made

on the surface of a still pool of water by plunging a stone into it, the

wave advances along the surface, while the water itself is never carried

forward, but merely rises into a height and falls into a hollow, each

portion of the surface experiencing an elevation and a depression in its

turn. If we suppose two waves equal and similar, to be produced by two

separate stones, and if they reach the same spot at the same time, that

is, if the two elevations should exactly coincide, they would unite

their effects, and produce a wave twice the size of either; but if the

one wave should be put so far before the other, that the hollow of the

one coincided with the elevation of the other, and the elevation of the

one with the hollow of the other, the two waves would obliterate or

destroy one another; the elevation as it were of the one filling up half

the hollow of the other, and the hollow of the one taking away half the

elevation of the other, so as to reduce the surface to a level. These

effects may be exhibited by throwing two equal stones into a pool of

water; and also may be observed in the Port of Batsha, where the two

waves arriving by channels of different lengths actually obliterate each

other. Now, as light is supposed to be produced by waves or undulations

of an ethereal medium filling all nature, and occupying the pores of the

transparent bodies; and as sound is produced by undulations or waves in

the air: so the successive production of light and darkness by two

bright lights, and the production of sound and silence by two loud

sounds, may be explained in the very same manner as we have explained

the increase and obliteration of waves formed on the surface of water.”

The apparent contradictions in chemistry are, indeed, best exhibited in

the lecture-room, where they may be rendered visible and tangible, and

brought home to the general comprehension. The Professor of Analytical

Chemistry, J. H. Pepper, who demonstrates these things in the Royal

Polytechnic Institution, is an expert manipulator in such mysteries;

and, taking a leaf out of his own magic-book, we shall conjure him up

before us, standing behind his own laboratory, surrounded with all the

implements of his art. At our recent visit to this exhibition we

witnessed him perform, with much address, the following experiments:—He

placed before us a pair of tall glass vessels, each filled, apparently,

with water;—he then took two hen’s eggs, one of these he dropped into

one of the glass vessels, and, as might have been expected, it

immediately sank to the bottom. He then took the other egg, and dropped

it into the other vessel of water, but, instead of sinking as the other

had done, it descended only half way, and there remained suspended in

the midst of the transparent fluid. This, indeed, looked like magic—one

of Houdin’s sleight-of-hand performances—for what could interrupt its

progress? The water surrounding it appeared as pure below as around and

above the egg, yet there it still hung like Mahomet’s coffin, between

heaven and earth, contrary to all the well established laws of gravity.

The problem, however, was easily solved. Our modern Cagliostro had

dissolved in one half of the water in this vessel as much common salt as

it would take up, whereby the density of the fluid was so much augmented

that it opposed a resistance to the descent of the egg after it had

passed through the unadulterated water, which he had carefully poured

upon the briny solution, the transparency of which, remaining

unimpaired, did not for a moment suggest the suspicion of any such

impregnation. The good housewife, upon the same principle, uses an egg

to test the strength of her brine for pickling.

Every one has heard of the power which bleaching gas (chlorine)

possesses in taking away colour, so that a red rose held over its fumes

will become white. The lecturer, referring to this fact, exhibited two

pieces of paper; upon one was inscribed, in large letters, the word

“PROTEUS;” upon the other no writing was visible; although he assured us

the same word was there inscribed. He now dipped both pieces of paper in

a solution of bleaching-powder, when the word “Proteus” disappeared from

the paper upon which it was before visible; whilst the same word

instantly came out, sharp and distinct, upon the paper which was

previously a blank. Here there appeared another contradiction: the

chlorine in the one case obliterating, and in the other reviving the

written word; and how was this mystery explained? Easily enough! Our

ingenious philosopher, it seems, had used indigo in penning the one word

which had disappeared; and had inscribed the other with a solution of a

chemical substance, iodide of potassium and starch; and the action which

took place was simply this: the chlorine of the bleaching solution set

free the iodine from the potassium, which immediately combined with the

starch, and gave colour to the letters which were before invisible.

Again—a sheet of white paper was exhibited, which displayed a broad and

brilliant stripe of scarlet—(produced by a compound called the

bin-iodide of mercury)—when exposed to a slight heat the colour changed

immediately to a bright yellow, and, when this yellow stripe was crushed

by smartly rubbing the paper, the scarlet colour was restored, with all

its former brilliancy. This change of colour was effected entirely by

the alteration which the heat, in the one case, and the friction, in the

other, produced in the particles which reflected these different

colours;—and, upon the same principle, we may understand the change of

the colour in the lobster-shell, which burns from black to red in

boiling; because the action of the heat produces a new arrangement in

the particles which compose the shell.

With the assistance of water and fire, which have befriended the

magicians of every age, contradictions of a more marvellous character

may be exhibited, and even the secret art revealed of handling red hot

metals, and passing through the fiery ordeal. If we take a platinum

ladle, and hold it over a furnace until it becomes of a bright red heat,

and then project cold water into its bowl, we shall find that the water

will remain quiescent and give no sign of ebullition—not so much as a

single “fizz;” but, the moment the ladle begins to cool, it will boil up

and quickly evaporate. So also, if a mass of metal, heated to whiteness,

be plunged in a vessel of cold water, the surrounding fluid will remain

tranquil so long as the glowing white heat continues; but, the moment

the temperature falls, the water will boil briskly. Again—if water be

poured upon an iron sieve, the wires of which are made red hot, it will

not run through; but, on the sieve cooling, it will run through rapidly.

These contradictory effects are easily accounted for. The repelling

power of intense heat keeps the water from immediate contact with the

heated metal, and the particles of the water, collectively, retain their

globular form; but, when the vessel cools, the repulsive power

diminishes, and the water coming into closer contact with the heated

surface its particles can no longer retain their globular form, and

eventually expand into a state of vapour. This globular condition of the

particles of water will account for many very important phenomena;

perhaps it is best exhibited in the dew-drop, and so long as these

globules retain their form, water will retain its fluid properties. An

agglomeration of these globules will carry with them, under certain

circumstances, so much force that it is hardly a contradiction to call

water itself a solid. The water-hammer, as it is termed, illustrates

this apparent contradiction. If we introduce a certain quantity of water

into a long glass tube, when it is shaken, we shall hear the ordinary

splashing noise as in a bottle; but, if we exhaust the air, and again

shake the tube, we shall hear a loud ringing sound, as if the bottom of

the tube were struck by some hard substance—like metal or wood—which may

fearfully remind us of the blows which a ship’s side will receive from

the waves during a storm at sea, which will often carry away her

bulwarks.

It is now time to turn to something stronger than water for more

instances of chemical contradictions. The chemical action of certain

poisons (the most powerful of all agents,) upon the human frame, has

plunged the faculty into a maze of paradoxes; indeed there is actually a

system of medicine, advancing in reputation, which is founded on the

principle of contraries. The famous Doctor Hahnemann, who was born at

Massieu in Saxony, was the founder of it, and, strange to say, medical

men, who are notorious for entertaining contrary opinions, have not yet

agreed among themselves whether he was a very great quack or a very

great philosopher. Be this as it may, the founder of this system, which

is called HOMŒOPATHY, when translating an article upon bark in Dr.

Cullen’s Materia Medica, took some of this medicine, which had for many

years been justly celebrated for the cure of ague. He had not long taken

it, when he found himself attacked with agueish symptoms, and a light

now dawned upon his mind, and led him to the inference that medicines

which give rise to the symptoms of a disease, are those which will

specifically cure it, and however curious it may appear, several

illustrations in confirmation of this principle were speedily found. If

a limb be frost-bitten, we are directed to rub it with snow; if the

constitution of a man be impaired by the abuse of spirituous liquors,

and he be reduced to that miserable state of enervation when the limbs

tremble and totter, and the mind itself sinks into a state of low

muttering delirium, the physician to cure him must go again to the

bottle and administer stimulants and opiates.

It was an old Hippocratic aphorism that two diseases cannot co-exist in

the same body; wherefore, gout has actually been cured by the afflicted

person going into a fenny country and catching the ague. The fatality of

consumption is also said to be retarded by a common catarrh; and upon

this very principle depends the truth of the old saying, that ricketty

doors hang long on rusty hinges. In other words, the strength of the

constitution being impaired by one disease has less power to support the

morbid action of another.

We thus live in a world of apparent contradictions; they abound in every

department of science, and beset us even in the sanctuary of domestic

life. The progress of discovery has reconciled and explained the nature

of some of them; but many baffle our ingenuity, and still remain

involved in mystery. This much, however, is certain, that the most

opposed and conflicting elements so combine together as to produce

results, which are strictly in unison with the order and harmony of the

universe.

Household words, No. 25, September 14, 1850 · 第 11 / 17 题