Thus, if [lambda] = 1/4000, R = 1/10, we find

f1 = 800 inches.

The image of the sun thrown upon a screen at a distance exceeding 66

ft., through a hole 1/5 in. in diameter, is therefore at least as well

defined as that seen direct.

As the minimum focal length increases with the square of the aperture,

a quite impracticable distance would be required to rival the

resolving power of a modern telescope. Even for an aperture of 4 in.,

f1 would have to be 5 miles.

A similar argument may be applied to find at what point an achromatic

lens becomes sensibly superior to a single one. The question is

whether, when the adjustment of focus is correct for the central rays

of the spectrum, the error of phase for the most extreme rays (which

it is necessary to consider) amounts to a quarter of a wave-length. If

not, the substitution of an achromatic lens will be of no advantage.

Calculation shows that, if the aperture be 1/5 in., an achromatic lens

has no sensible advantage if the focal length be greater than about 11

in. If we suppose the focal length to be 66 ft., a single lens is

practically perfect up to an aperture of 1.7 in.

Another obvious inference from the necessary imperfection of optical

images is the uselessness of attempting anything like an absolute

destruction of spherical aberration. An admissible error of phase of

1/4[lambda] will correspond to an error of 1/8[lambda] in a reflecting

and 1/2[lambda] in a (glass) refracting surface, the incidence in both

cases being perpendicular. If we inquire what is the greatest

admissible longitudinal aberration ([delta]f) in an object-glass

according to the above rule, we find

[delta]f = [lambda][alpha]^-2 (2),

[alpha] being the angular semi-aperture.

In the case of a single lens of glass with the most favourable

curvatures, [delta]f is about equal to [alpha]^2f, so that [alpha]^4

must not exceed [lambda]/f. For a lens of 3 ft. focus this condition

is satisfied if the aperture does not exceed 2 in.

When parallel rays fall directly upon a spherical mirror the

longitudinal aberration is only about one-eighth as great as for the

most favourably shaped single lens of equal focal length and aperture.

Hence a spherical mirror of 3 ft. focus might have an aperture of 21/2

in., and the image would not suffer materially from aberration.

On the same principle we may estimate the least visible displacement

of the eye-piece of a telescope focused upon a distant object, a

question of interest in connexion with range-finders. It appears

(_Phil. Mag._, 1885, 20, p. 354) that a displacement [delta]f from the

true focus will not sensibly impair definition, provided

[delta]f < f^2[lambda]/R^2 (3),

2R being the diameter of aperture. The linear accuracy required is

thus a function of the _ratio_ of aperture to focal length. The

formula agrees well with experiment.

The principle gives an instantaneous solution of the question of the

ultimate optical efficiency in the method of "mirror-reading," as

commonly practised in various physical observations. A rotation by

which one edge of the mirror advances 1/4[lambda] (while the other edge

retreats to a like amount) introduces a phase-discrepancy of a whole

period where before the rotation there was complete agreement. A

rotation of this amount should therefore be easily visible, but the

limits of resolving power are being approached; and the conclusion is

independent of the focal length of the mirror, and of the employment

of a telescope, provided of course that the reflected image is seen in

focus, and that the full width of the mirror is utilized.

A comparison with the method of a material pointer, attached to the

parts whose rotation is under observation, and viewed through a

microscope, is of interest. The limiting efficiency of the microscope

is attained when the angular aperture amounts to 180 deg.; and it is

evident that a lateral displacement of the point under observation

through 1/2[lambda] entails (at the old image) a phase-discrepancy of a

whole period, one extreme ray being accelerated and the other retarded

by half that amount. We may infer that the limits of efficiency in the

two methods are the same when the length of the pointer is equal to

the width of the mirror.

[Illustraton: FIG. 5.]

We have seen that in perpendicular reflection a surface error not

exceeding 1/8[lambda] may be admissible. In the case of oblique

reflection at an angle [phi], the error of retardation due to an

elevation BD (fig. 5) is

QQ' - QS = BD sec [phi](1 - cos SQQ') = BD sec [phi] (1 + cos 2[phi]) = 2BD cos [phi];

from which it follows that an error of given magnitude in the figure

of a surface is less important in oblique than in perpendicular

reflection. It must, however, be borne in mind that errors can

sometimes be compensated by altering adjustments. If a surface

intended to be flat is affected with a slight general curvature, a

remedy may be found in an alteration of focus, and the remedy is the

less complete as the reflection is more oblique.

The formula expressing the optical power of prismatic spectroscopes

may readily be investigated upon the principles of the wave theory.

Let A0B0 be a plane wave-surface of the light before it falls upon the

prisms, AB the corresponding wave-surface for a particular part of the

spectrum after the light has passed the prisms, or after it has passed

the eye-piece of the observing telescope. The path of a ray from the

wave-surface A0B0 to A or B is determined by the condition that the

optical distance, [int] [mu]ds, is a minimum; and, as AB is by

supposition a wave-surface, this optical distance is the same for both

points. Thus

_ _

/ /

| [mu]ds (for A) = | [mu]ds (for B) (4).

_/ _/

We have now to consider the behaviour of light belonging to a

neighbouring part of the spectrum. The path of a ray from the

wave-surface A0B0 to the point A is changed; but in virtue of the

minimum property the change may be neglected in calculating the

optical distance, as it influences the result by quantities of the

second order only in the changes of refrangibility. Accordingly, the

optical distance from A0B0 to A is represented by [int]([mu] +

[delta][mu])ds, the integration being along the original path A0 ...

A; and similarly the optical distance between A0B0 and B is

represented by [int] ([mu] + [delta][mu])ds, the integration being

along B0 ... B. In virtue of (4) the difference of the optical

distances to A and B is

_ _

/ /

| [delta][mu]ds (along B0 ... B) - | [delta][mu]ds (along A0 ... A) (5).

_/ _/

The new wave-surface is formed in such a position that the optical

distance is constant; and therefore the _dispersion_, or the angle

through which the wave-surface is turned by the change of

refrangibility, is found simply by dividing (5) by the distance AB.

If, as in common flint-glass spectroscopes, there is only one

dispersing substance, [int] [delta][mu] ds = [delta][mu].s, where s is

simply the thickness traversed by the ray. If t2 and t1 be the

thicknesses traversed by the extreme rays, and a denote the width of

the emergent beam, the dispersion [theta] is given by

[theta] = [delta][mu](t2 - t1)/a,

or, if t1 be negligible,

[theta] = [delta][mu]t/a (6).

The condition of resolution of a double line whose components subtend

an angle [theta] is that [theta] must exceed [lambda]/a. Hence, in

order that a double line may be resolved whose components have indices

[mu] and [mu] + [delta][mu], it is necessary that t should exceed the

value given by the following equation:--

t = [lambda]/[delta][mu] (7).

8. _Diffraction Gratings._--Under the heading "Colours of Striated

Surfaces," Thomas Young (_Phil. Trans._, 1802) in his usual summary

fashion gave a general explanation of these colours, including the law

of sines, the striations being supposed to be straight, parallel and

equidistant. Later, in his article "Chromatics" in the supplement to the

5th edition of this encyclopaedia, he shows that the colours "lose the

mixed character of periodical colours, and resemble much more the

ordinary prismatic spectrum, with intervals completely dark interposed,"

and explains it by the consideration that any phase-difference which may

arise at neighbouring striae is multiplied in proportion to the total

number of striae.

The theory was further developed by A. J. Fresnel (1815), who gave a

formula equivalent to (5) below. But it is to J. von Fraunhofer that we

owe most of our knowledge upon this subject. His recent discovery of the

"fixed lines" allowed a precision of observation previously impossible.

He constructed gratings up to 340 periods to the inch by straining fine

wire over screws. Subsequently he ruled gratings on a layer of gold-leaf

attached to glass, or on a layer of grease similarly supported, and

again by attacking the glass itself with a diamond point. The best

gratings were obtained by the last method, but a suitable diamond point

was hard to find, and to preserve. Observing through a telescope with

light perpendicularly incident, he showed that the position of any ray

was dependent only upon the grating interval, viz. the distance from the

centre of one wire or line to the centre of the next, and not otherwise

upon the thickness of the wire and the magnitude of the interspace. In

different gratings the lengths of the spectra and their distances from

the axis were inversely proportional to the grating interval, while with

a given grating the distances of the various spectra from the axis were

as 1, 2, 3, &c. To Fraunhofer we owe the first accurate measurements of

wave-lengths, and the method of separating the overlapping spectra by a

prism dispersing in the perpendicular direction. He described also the

complicated patterns seen when a point of light is viewed through two

superposed gratings, whose lines cross one another perpendicularly or

obliquely. The above observations relate to transmitted light, but

Fraunhofer extended his inquiry to the light _reflected_. To eliminate

the light returned from the hinder surface of an engraved grating, he

covered it with a black varnish. It then appeared that under certain

angles of incidence parts of the resulting spectra were _completely

polarized_. These remarkable researches of Fraunhofer, carried out in

the years 1817-1823, are republished in his _Collected Writings_

(Munich, 1888).

The principle underlying the action of gratings is identical with that

discussed in S 2, and exemplified in J. L. Soret's "zone plates." The

alternate Fresnel's zones are blocked out or otherwise modified; in

this way the original compensation is upset and a revival of light

occurs in unusual directions. If the source be a point or a line, and

a collimating lens be used, the incident waves may be regarded as

plane. If, further, on leaving the grating the light be received by a

focusing lens, e.g. the object-glass of a telescope, the Fresnel's

zones are reduced to parallel and equidistant straight strips, which

at certain angles coincide with the ruling. The directions of the

lateral spectra are such that the passage from one element of the

grating to the corresponding point of the next implies a retardation

of an integral number of wave-lengths. If the grating be composed of

alternate transparent and opaque parts, the question may be treated by

means of the general integrals (S 3) by merely limiting the

integration to the transparent parts of the aperture. For an

investigation upon these lines the reader is referred to Airy's

_Tracts_, to Verdet's _Lecons_, or to R. W. Wood's _Physical Optics_.

If, however, we assume the theory of a simple rectangular aperture (S

3); the results of the ruling can be inferred by elementary methods,

which are perhaps more instructive.

Apart from the ruling, we know that the image of a mathematical line

will be a series of narrow bands, of which the central one is by far

the brightest. At the middle of this band there is complete agreement

of phase among the secondary waves. The dark lines which separate the

bands are the places at which the phases of the secondary wave range

over an integral number of periods. If now we suppose the aperture AB

to be covered by a great number of opaque strips or bars of width d,

separated by transparent intervals of width a, the condition of things

in the directions just spoken of is not materially changed. At the

central point there is still complete agreement of phase; but the

amplitude is diminished in the ratio of a : a + d. In another

direction, making a small angle with the last, such that the

projection of AB upon it amounts to a few wave-lengths, it is easy to

see that the mode of interference is the same as if there were no

ruling. For example, when the direction is such that the projection of

AB upon it amounts to one wave-length, the elementary components

neutralize one another, because their phases are distributed

symmetrically, though discontinuously, round the entire period. The

only effect of the ruling is to diminish the amplitude in the ratio a

: a + d; and, except for the difference in illumination, the

appearance of a line of light is the same as if the aperture were

perfectly free.

The lateral (spectral) images occur in such directions that the

projection of the element (a + d) of the grating upon them is an exact

multiple of [lambda]. The effect of each of the n elements of the

grating is then the same; and, unless this vanishes on account of a

particular adjustment of the ratio a : d, the resultant amplitude

becomes comparatively very great. These directions, in which the

retardation between A and B is exactly mn[lambda], may be called the

principal directions. On either side of any one of them the

illumination is distributed according to the same law as for the

central image (m = 0), vanishing, for example, when the retardation

amounts to (mn [+-] 1)[lambda]. In considering the relative brightnesses

of the different spectra, it is therefore sufficient to attend merely

to the principal directions, provided that the whole deviation be not

so great that its cosine differs considerably from unity.

We have now to consider the amplitude due to a single element, which

we may conveniently regard as composed of a transparent part a bounded

by two opaque parts of width 1/2d. The phase of the resultant effect is

by symmetry that of the component which comes from the middle of a.

The fact that the other components have phases differing from this by

amounts ranging between [+-] am[pi]/(a + d) causes the resultant

amplitude to be less than for the central image (where there is

complete phase agreement). If Bm denote the brightness of the m^th

lateral image, and B0 that of the central image, we have

_ _+ am[pi]/(a + d) _

| / 2am[pi] |^2 /a + d \^2 am[pi]

B_m : B0 = | | cosx dx :- ------- | = ( ------ ) sin^2 ------ (1).

|_ _/ a + d _| \am[pi]/ a + d

-am[pi]/(a + d)

If B denotes the brightness of the central image when the whole of the

space occupied by the grating is transparent, we have

B0 : B = a^2 : (a + d)^2,

and thus

1 am[pi]

Bm : B = --------- sin^2 ------ (2).

m^2[pi]^2 a + d

The sine of an angle can never be greater than unity; and consequently

under the most favourable circumstances only 1/m^2[pi]^2 of the original

light can be obtained in the m^th spectrum. We conclude that, with a

grating composed of transparent and opaque parts, the utmost light

obtainable in any one spectrum is in the first, and there amounts to

1/[pi]^2, or about 1/10, and that for this purpose a and d must be

equal. When d = a the general formula becomes

sin^2 1/2m[pi]

Bm : B = ------------- (3),

m^2[pi]^2

showing that, when m is even, Bm vanishes, and that, when m is odd,

Bm : B = 1/m^2[pi]^2.

The third spectrum has thus only 1/9 of the brilliancy of the first.

Another particular case of interest is obtained by supposing a small

relatively to (a + d). Unless the spectrum be of very high order, we

have simply

Bm : B = a/(a + d)^2 (4);

so that the brightnesses of all the spectra are the same.

The light stopped by the opaque parts of the grating, together with

that distributed in the central image and lateral spectra, ought to

make up the brightness that would be found in the central image, were

all the apertures transparent. Thus, if a = d, we should have

1 1 2 / 1 1 \

1 = - + - + ------ ( 1 + - + -- + ... ),

2 4 [pi]^2 \ 9 25 /

which is true by a known theorem. In the general case

___m=[oo]

a / a \^2 2 \ 1 /m[pi]a\

----- = ( ----- ) + ------ > -- sin^2( ------ ),

a + d \a + d/ [pi]^2 /__ m^2 \ a + d/

m=1

a formula which may be verified by Fourier's theorem.

According to a general principle formulated by J. Babinet, the

brightness of a lateral spectrum is not affected by an interchange of

the transparent and opaque parts of the grating. The vibrations

corresponding to the two parts are precisely antagonistic, since if

both were operative the resultant would be zero. So far as the

application to gratings is concerned, the same conclusion may be

derived from (2).

[Illustration: FIG. 6.]

From the value of Bm : B0 we see that no lateral spectrum can surpass

the central image in brightness; but this result depends upon the

hypothesis that the ruling acts by opacity, which is generally very

far from being the case in practice. In an engraved glass grating

there is no opaque material present by which light could be absorbed,

and the effect depends upon a difference of retardation in passing the

alternate parts. It is possible to prepare gratings which give a

lateral spectrum brighter than the central image, and the explanation

is easy. For if the alternate parts were equal and alike transparent,

but so constituted as to give a relative retardation of 1/2[lambda], it

is evident that the central image would be entirely extinguished,

while the first spectrum would be four times as bright as if the

alternate parts were opaque. If it were possible to introduce at every

part of the aperture of the grating an arbitrary retardation, all the

light might be concentrated in any desired spectrum. By supposing the

retardation to vary uniformly and continuously we fall upon the case

of an ordinary prism: but there is then no diffraction spectrum in the

usual sense. To obtain such it would be necessary that the retardation

should gradually alter by a wave-length in passing over any element of

the grating, and then fall back to its previous value, thus springing

suddenly over a wave-length (_Phil. Mag._, 1874, 47, p. 193). It is

not likely that such a result will ever be fully attained in practice;

but the case is worth stating, in order to show that there is no

theoretical limit to the concentration of light of assigned

wave-length in one spectrum, and as illustrating the frequently

observed unsymmetrical character of the spectra on the two sides of

the central image.[4]

We have hitherto supposed that the light is incident perpendicularly

upon the grating; but the theory is easily extended. If the incident

rays make an angle [theta] with the normal (fig. 6), and the

diffracted rays make an angle [phi] (upon the same side), the relative

retardation from each element of width (a + d) to the next is (a + d)

(sin[theta] + sin[phi]); and this is the quantity which is to be

equated to m[lambda]. Thus

sin[theta] + sin[phi] = 2 sin 1/2([theta] + [phi]) cos 1/2([theta] - [phi]) = m[lambda]/(a + d) (5).

The "deviation" is ([theta] + [phi]), and is therefore a minimum when

[theta] = [phi], i.e. when the grating is so situated that the angles

of incidence and diffraction are equal.

In the case of a reflection grating the same method applies. If

[theta] and [phi] denote the angles with the normal made by the

incident and diffracted rays, the formula (5) still holds, and, if the

deviation be reckoned from the direction of the regularly reflected

rays, it is expressed as before by ([theta] + [phi]), and is a minimum

when [theta] = [phi], that is, when the diffracted rays return upon

the course of the incident rays.

[Illustration: FIG. 7.]

In either case (as also with a prism) the position of minimum

deviation leaves the width of the beam unaltered, i.e. neither

magnifies nor diminishes the angular width of the object under view.

From (5) we see that, when the light falls perpendicularly upon a

grating ([theta] = 0), there is no spectrum formed (the image

corresponding to m = 0 not being counted as a spectrum), if the

grating interval [sigma] or (a + d) is less than [lambda]. Under these

circumstances, if the material of the grating be completely

transparent, the whole of the light must appear in the direct image,

and the ruling is not perceptible. From the absence of spectra

Fraunhofer argued that there must be a microscopic limit represented

by [lambda]; and the inference is plausible, to say the least (_Phil.

Mag._, 1886). Fraunhofer should, however, have fixed the microscopic

limit at 1/2[lambda], as appears from (5), when we suppose [theta] =

1/2[pi], [phi] = 1/2[pi].

[Illustration: FIG. 8.]

We will now consider the important subject of the resolving power of

gratings, as dependent upon the number of lines (n) and the order of

the spectrum observed (m). Let BP (fig. 8) be the direction of the

principal maximum (middle of central band) for the wave-length

[lambda] in the m^th spectrum. Then the relative retardation of the

extreme rays (corresponding to the edges A, B of the grating) is

mn[lambda]. If BQ be the direction for the first minimum (the darkness

between the central and first lateral band), the relative retardation

of the extreme rays is (mn + 1)[lambda]. Suppose now that [lambda] +

[delta][lambda] is the wave-length for which BQ gives the principal

maximum, then

(mn + 1)[lambda] = mn([lambda] + [delta][lambda]);

whence

[delta][lambda]/[lambda] = 1/mn (6).

According to our former standard, this gives the smallest difference

of wave-lengths in a double line which can be just resolved; and we

conclude that the resolving power of a grating depends only upon the

total number of lines, and upon the order of the spectrum, without

regard to any other considerations. It is here of course assumed that

the n lines are really utilized.

In the case of the D lines the value of [delta][lambda]/[lambda] is

about 1/1000; so that to resolve this double line in the first

spectrum requires 1000 lines, in the second spectrum 500, and so on.

It is especially to be noticed that the resolving power does not

depend directly upon the closeness of the ruling. Let us take the case

of a grating 1 in. broad, and containing 1000 lines, and consider the

effect of interpolating an additional 1000 lines, so as to bisect the

former intervals. There will be destruction by interference of the

first, third and odd spectra generally; while the advantage gained in

the spectra of even order is not in dispersion, nor in resolving

power, but simply in brilliancy, which is increased four times. If we

now suppose half the grating cut away, so as to leave 1000 lines in

half an inch, the dispersion will not be altered, while the brightness

and resolving power are halved.

There is clearly no theoretical limit to the resolving power of

gratings, even in spectra of given order. But it is possible that, as

suggested by Rowland,[5] the structure of natural spectra may be too

coarse to give opportunity for resolving powers much higher than those

now in use. However this may be, it would always be possible, with the

aid of a grating of given resolving power, to construct artificially

from white light mixtures of slightly different wave-length whose

resolution or otherwise would discriminate between powers inferior and

superior to the given one.[6]

If we define as the "dispersion" in a particular part of the spectrum

the ratio of the angular interval d[theta] to the corresponding

increment of wave-length d[lambda], we may express it by a very simple

formula. For the alteration of wave-length entails, at the two limits

of a diffracted wave-front, a relative retardation equal to

mnd[lambda]. Hence, if a be the width of the diffracted beam, and

d[theta] the angle through which the wave-front is turned,

ad[theta] = mn d[lambda],

or dispersion = mn/a (7).

The resolving power and the width of the emergent beam fix the optical

character of the instrument. The latter element must eventually be

decreased until less than the diameter of the pupil of the eye. Hence

a wide beam demands treatment with further apparatus (usually a

telescope) of high magnifying power.

In the above discussion it has been supposed that the ruling is

accurate, and we have seen that by increase of m a high resolving

power is attainable with a moderate number of lines. But this

procedure (apart from the question of illumination) is open to the

objection that it makes excessive demands upon accuracy. According to

the principle already laid down it can make but little difference in

the principal direction corresponding to the first spectrum, provided

each line lie within a quarter of an interval (a + d) from its

theoretical position. But, to obtain an equally good result in the

m^th spectrum, the error must be less than 1/m of the above amount.[7]

There are certain errors of a systematic character which demand

special consideration. The spacing is usually effected by means of a

screw, to each revolution of which corresponds a large number (e.g.

one hundred) of lines. In this way it may happen that although there

is almost perfect periodicity with each revolution of the screw after

(say) 100 lines, yet the 100 lines themselves are not equally spaced.

The "ghosts" thus arising were first described by G. H. Quincke

(_Pogg. Ann._, 1872, 146, p. 1), and have been elaborately

investigated by C. S. Peirce (_Ann. Journ. Math._, 1879, 2, p. 330),

both theoretically and experimentally. The general nature of the

effects to be expected in such a case may be made clear by means of an

illustration already employed for another purpose. Suppose two similar

and accurately ruled transparent gratings to be superposed in such a

manner that the lines are parallel. If the one set of lines exactly

bisect the intervals between the others, the grating interval is

practically halved, and the previously existing spectra of odd order

vanish. But a very slight relative displacement will cause the

apparition of the odd spectra. In this case there is approximate

periodicity in the half interval, but complete periodicity only after

the whole interval. The advantage of approximate bisection lies in the

superior brilliancy of the surviving spectra; but in any case the

compound grating may be considered to be perfect in the longer

interval, and the definition is as good as if the bisection were

accurate.

[Illustration:

| | | | | ( ( ( | | | | ) | (

FIG. 9.--x^2. FIG. 10.--y^2. FIG. 11.--x^3. FIG. 12.--xy^2.

/ / /

\ | | / | \ | | | |

/ / /

Encyclopaedia Britannica, 11th Edition, "Diameter" to "Dinarchus" Volume 8, Slice 4 · 第 62 / 86 题