ĊaS⃛, calcium sulphate; F̋e, iron disulphide

This form of notation was quite extensively employed for a time,

especially by mineralogists, but it was entirely abandoned later.

It is interesting to notice that Dalton, who lived until 1844, to reach

the age of 78, differed from other chemists in refusing to accept the

letter-symbols of Berzelius. In a letter written to Graham in 1837 he

said: “Berzelius’s symbols are horrifying. A young student in chemistry

might as soon learn Hebrew as to make himself acquainted with them. They

appear like a chaos of atoms ... and to equally perplex the adepts of

science, to discourage the learner, as well as to cloud the beauty and

simplicity of the atomic theory.”

This forcibly expressed opinion was apparently tinged with self-esteem,

but there is no doubt that Dalton was sincere in believing that the

atoms were best represented by his circular symbols, because, as is well

known, he thought that all the atoms were spherical in form, and it is

evident that circles give the proper picture of spherical objects. At

the present time some insight as to the structure of atoms is being

gained, and it appears possible that the time may come when pictures of

their external appearance that are not wholly imaginary may be made.

_Changes in Formulas._—Even before the year 1826, Berzelius displayed

great skill in arriving at many formulas that agree with our present

ones, for example, H_{2}O for water, ZnCl_{2} for zinc chloride,

N_{2}O_{5} for nitric acid (anhydride), CaO for calcium oxide, CO and

CO_{2} for the oxides of carbon, and many others. But at the same period

other authorities, especially Gay-Lussac in France and Gmelin in

Germany, on account of a lack of appreciation for Avogadro’s principle

and for other reasons, such as the use of symbols to represent combining

weights rather than atoms, were using different formulas for some of

these compounds, such as HO, ZnCl and NO_{5}, so that their formulas for

many of the compounds of hydrogen, chlorine, nitrogen and several other

elements differed from those of Berzelius. The employment of different

formulas involved the use of different atomic or combining weights. For

example, with the formula H_{2}O for water the composition by weight

requires the ratio 1 to 16 for the weights of the hydrogen and oxygen

atoms, while with HO the ratio is 1 to 8.

Berzelius attempted to bring about greater uniformity in formulas and

atomic weights by making changes in his table of atomic weights

published in 1826. He practically doubled the relative atomic weights of

hydrogen, chlorine, nitrogen, and of the other elements that gave twice

as many atoms in his formulas as in those of others, and at the same

time he wrote the symbols of these elements with a bar across them to

indicate that they represented double atoms. For example, he wrote:

H̶O ZnC̶l N̶O_{5},

instead of

A century of science in America · 第 31 / 45 题