3.--MINERALS CONTAINING CARBON.

THEO. F. BROOKINS, B. S., Principal Au Sable Forks Union Free School

and Academy, New York.

Among minerals of economic importance carbon minerals hold the unique

position of being at the same time of the most common and the most rare

occurrence. As far as external appearance indicates, a piece of common

coal and the most brilliant diamond are widely separated; with regard

to chemical composition they are closely related. Intermediate between

the coal of the stoke furnace and the "brilliant" of the jewelry

shop is still another well-known form of carbon, the graphite of the

lead pencil. These three substances comprise the far greater part of

carbon-containing minerals.

In so far as our mind's picture of a mineral is that of an aggregation

of crystals of fairly perfect form our consideration of coal as a

mineral is erroneous. We must yield to a broader interpretation of the

essential characteristics of a mineral and modify our idea so as to

include any homogeneous substance (solid, with the single exception of

mercury) of fairly definite chemical composition "occurring in nature

but not of apparent organic origin." Organic substances are those that

are alive or have lived.

Vegetation is, undoubtedly, the origin of all coal, but often much more

than a cursory examination is necessary to prove such origin. In the

less altered coals the vegetable origin is readily proved by the actual

presence of seeds, plant fibers, and other equally apparent organic

remains. A microscopic study is necessary for finding the presence

of woody fiber in the more metamorphosed form. The word metamorphose

comes from the Greek; _meta_ means after or over; _morphe_ is form. A

metamorphosis is a change of form or a forming over.

The history of the discovery of the value of coal as a means of

producing heat and of the development of the coal-mining industry

covers a comparatively recent period. Coal occurs in such quantities

near the surface of the earth's crust and its outcrops are so numerous

that it cannot have failed to attract the attention of the most ancient

of peoples. Indeed, that coal could be used as a fuel is mentioned by

a writer, Theophrastus, who lived 300 years B. C. The ancient Celts of

Britain are reputed to have evidenced knowledge of the industrial value

of coal. It was not until near the middle of the thirteenth century,

however, that coal became so important an economic product as to result

in statutes granting to certain places the privilege of mining it.

After a long period of trial in England the superiority of coal over

other fuels was recognized, and stone coal, as the harder form was

commonly known, came into general use. In America bituminous, or soft

coal, was mined to a slight extent in the latter half of the eighteenth

century. The form now commonly used in house-heating furnaces,

anthracite, for a long time baffled the colonists in their efforts to

make it burn. The knowledge that an anthracite fire is most effective

if not continually poked is said to have been acquired generally by

accident.

Europe and the United States to-day produce practically all the coal of

the world. In Europe, Great Britain, Germany, France, Austria-Hungary,

and Belgium are the main sources of supply. Several important coal

areas exist in our own country, notably that of the New England basin,

with an area of 500 square miles; the Appalachian district, with an

area of 65,000 square miles; the northern area, in Michigan, covering

7,000 square miles; the central area, comprising parts of Illinois,

Indiana and Kentucky, and including 48,000 square miles; the scattered

western area, with a total of 98,000 square miles; the indefinite

Rocky Mountain area, and the Pacific coast region, including parts of

California, Oregon, and Washington. Coal mining is yet an undeveloped

industry in our territorial possessions. Alaska has an abundant supply

of coal, and lesser quantities are found in Cuba and Porto Rico.

Mention has already been made of the two common kinds of coal,

bituminous and anthracite. These two kinds mark different stages in

the transformation from plant organism to mineral product. As the

biologist traces the successive steps in the evolution of an individual

of a species from germ to adult, so the geologist unfolds before us

the wonderful history of a piece of coal from its first appearance

on the earth to the time when it is thrown into our fire grate as

fuel. Coal is the metamorphosed product of vegetable growths, changed

by atmospheric agencies and the internal forces of the earth acting

through a total period of perhaps millions of years. In the remote

past, ages before man had appeared on the earth, the atmosphere or our

globe was highly charged with carbon gases. Vegetation flourished in

luxuriance. Great swamps were common. The ocean alternately covered

and receded from verdure-clothed land areas. Ponds were transformed

to morasses and swamps. In the swamps thus formed, the accumulated

sediment of centuries upon centuries covered alternate layers of

decayed plant organisms, until finally beds of peat were formed.

Great masses above pressed on those underneath; the internal heat of

the earth reached up and transformed the densely packed masses of

peat until the beds became hard and brown, the product of the partial

metamorphism being what we know as lignite, or brown coal. With the

continued action of the forces of metamorphism, the lignite turned

still darker, and as more gases were driven off, became heavier, until

the bituminous stage was reached, which, in turn, was succeeded by the

anthracite stage.

Graphite, or black lead, is a mineral containing not more than five

per cent of impurities, and is generally supposed to have originated

as did mineral coal, and to represent a still more advanced stage of

development. It occurs in various localities both in the vicinity of

coal measures and far removed from them. The chief part of the world's

supply comes from Ceylon, though Germany and the United States produce

quantities of graphite of excellent quality. In the Laurentian rocks of

Canada, and of course with as ancient origin, extensive deposits are

found. This presence of graphite in strata in which as yet no certain

traces of organic life have been found has led some to believe that

this form of carbon mineral may have another than organic origin.

Various uses are served by graphite. The chemist finds it of great

value in making his crucibles; the engineer uses it, finely powdered,

as a lubricant; the housekeeper polishes stoves with it; the

electrician uses it in his arc lights; all civilized nations use it

in the lead of lead pencils. The stem, _grapho_ (to write), on which

so many of our words, as geography, telegraph, graphophone, etc., are

formed, suggests also the origin of the name, graphite. The finest

quality lead pencils are those made from graphite occurring in a state

sufficiently pure to allow the cutting and grinding of pieces to the

size needed. In the case of the medium and poorer grade pencils, the

graphite has first been finely powdered and then pressed into the

requisite shape and size.

The purest form of carbon found in nature is the diamond. The rare

occurrence of diamonds indicates that the essential conditions in

nature for causing the transformation of some less pure form of

carbon into diamond are seldom present. While diamonds have actually

been produced in the laboratory by far-seeing and indefatigable

chemists, yet the cost of such products is so great as to preclude the

possibility of the most precious of gems becoming at all common. The

diamond is the hardest of all known substances, and will scratch any

other mineral across which it may be drawn.

Three localities have successively furnished the main part of the

world's stock of diamonds. A century and a half ago, practically all

the diamonds came from India, where at one time 60,000 persons were

employed in diamond digging. Toward the middle of the eighteenth

century, when the diamondiferous districts of India were becoming

exhausted, the discovery of the precious gem in Brazilian deposits

was made. At present, the supply of diamonds from Brazil has much

diminished, and the diamond fields of South Africa, where is located

the famous Kimberley mine, produce the larger part of the world's

output of diamonds.

Among famous diamonds of the world should be mentioned the Koh-i-noor

of the British crown, which, Hindu legend relates, was worn five

thousand years ago by one of their national heroes. The largest known

diamond, weighing three hundred sixty-seven carats, was found in

Borneo, and is now owned by the Rajah of Matan.

Birds and All Nature, Vol 7, No. 2, February 1900 Illustrated by Color Photography · 第 36 / 44 题