CHAPTER VI.

TRACHYTE AND BASALT.—DISTRIBUTION OF VOLCANIC ISLES.

The sinking of crystals in fluid lava. Specific gravity of the

constituent parts of trachyte and of basalt, and their consequent

separation. Obsidian. Apparent non-separation of the elements of

plutonic rocks. Origin of trap-dikes in the plutonic series.

Distribution of volcanic islands; their prevalence in the great oceans.

They are generally arranged in lines. The central volcanoes of Von Buch

doubtful. Volcanic islands bordering continents. Antiquity of volcanic

islands, and their elevation in mass. Eruptions on parallel lines of

fissure within the same geological period.

ON THE SEPARATION OF THE CONSTITUENT MINERALS OF LAVA, ACCORDING TO

THEIR SPECIFIC GRAVITIES.

One side of Fresh-water Bay, in James Island, is formed by the wreck of

a large crater, mentioned in the last chapter, of which the interior

has been filled up by a pool of basalt, about two hundred feet in

thickness. This basalt is of a grey colour, and contains many crystals

of glassy albite, which become much more numerous in the lower,

scoriaceous part. This is contrary to what might have been expected,

for if the crystals had been originally disseminated in equal numbers,

the greater intumescence of this lower scoriaceous part would have made

them appear fewer in number. Von Buch has described a stream of

obsidian on the Peak of Teneriffe, in which the crystals of feldspar

become more and more numerous, as the depth or thickness increases, so

that near the lower surface of the stream the lava even resembles a

primary rock. (“Description des Isles Canaries” pages 190 and 191.) Von

Buch further states, that M. Dree, in his experiments in melting lava,

found that the crystals of feldspar always tended to precipitate

themselves to the bottom of the crucible. In these cases, I presume

there can be no doubt that the crystals sink from their weight. (In a

mass of molten iron, it is found (“Edinburgh New Philosophical Journal”

volume 24 page 66) that the substances, which have a closer affinity

for oxygen than iron has, rise from the interior of the mass to the

surface. But a similar cause can hardly apply to the separation of the

crystals of these lava-streams. The cooling of the surface of lava

seems, in some cases, to have affected its composition; for Dufrenoy

(“Mem. pour servir” tome 4 page 271) found that the interior parts of a

stream near Naples contained two-thirds of a mineral which was acted on

by acids, whilst the surface consisted chiefly of a mineral

unattackable by acids.) The specific gravity of feldspar varies from

2.4 to 2.58, whilst obsidian seems commonly to be from 2.3 to 2.4; and

in a fluidified state its specific gravity would probably be less,

which would facilitate the sinking of the crystals of feldspar. (I have

taken the specific gravities of the simple minerals from Von Kobell,

one of the latest and best authorities, and of the rocks from various

authorities. Obsidian, according to Phillips, is 2.35; and Jameson says

it never exceeds 2.4; but a specimen from Ascension, weighed by myself,

was 2.42.) At James Island, the crystals of albite, though no doubt of

less weight than the grey basalt, in the parts where compact, might

easily be of greater specific gravity than the scoriaceous mass, formed

of melted lava and bubbles of heated gas.

The sinking of crystals through a viscid substance like molten rock, as

is unequivocally shown to have been the case in the experiments of M.

Dree, is worthy of further consideration, as throwing light on the

separation of the trachytic and basaltic series of lavas. Mr. P. Scrope

has speculated on this subject; but he does not seem to have been aware

of any positive facts, such as those above given; and he has overlooked

one very necessary element, as it appears to me, in the

phenomenon—namely, the existence of either the lighter or heavier

mineral in globules or in crystals. In a substance of imperfect

fluidity, like molten rock, it is hardly credible, that the separate,

infinitely small atoms, whether of feldspar, augite, or of any other

mineral, would have power from their slightly different gravities to

overcome the friction caused by their movement; but if the atoms of any

one of these minerals became, whilst the others remained fluid, united

into crystals or granules, it is easy to perceive that from the

lessened friction, their sinking or floating power would be greatly

increased. On the other hand, if all the minerals became granulated at

the same time, it is scarcely possible, from their mutual resistance,

that any separation could take place. A valuable, practical discovery,

illustrating the effect of the granulation of one element in a fluid

mass, in aiding its separation, has lately been made: when lead

containing a small proportion of silver, is constantly stirred whilst

cooling, it becomes granulated, and the grains of imperfect crystals of

nearly pure lead sink to the bottom, leaving a residue of melted metal

much richer in silver; whereas if the mixture be left undisturbed,

although kept fluid for a length of time, the two metals show no signs

of separating. (A full and interesting account of this discovery, by

Mr. Pattinson, was read before the British Association in September

1838. In some alloys, according to Turner “Chemistry” page 210, the

heaviest metal sinks, and it appears that this takes place whilst both

metals are fluid. Where there is a considerable difference in gravity,

as between iron and the slag formed during the fusion of the ore, we

need not be surprised at the atoms separating, without either substance

being granulated.) The sole use of the stirring seems to be, the

formation of detached granules. The specific gravity of silver is 10.4,

and of lead 11.35: the granulated lead, which sinks, is never

absolutely pure, and the residual fluid metal contains, when richest,

only 1/119 part of silver. As the difference in specific gravity,

caused by the different proportions of the two metals, is so

exceedingly small, the separation is probably aided in a great degree

by the difference in gravity between the lead, when granular though

still hot, and when fluid.

In a body of liquified volcanic rock, left for some time without any

violent disturbance, we might expect, in accordance with the above

facts, that if one of the constituent minerals became aggregated into

crystals or granules, or had been enveloped in this state from some

previously existing mass, such crystals or granules would rise or sink,

according to their specific gravity. Now we have plain evidence of

crystals being embedded in many lavas, whilst the paste or basis has

continued fluid. I need only refer, as instances, to the several,

great, pseudo-porphyritic streams at the Galapagos Islands, and to the

trachytic streams in many parts of the world, in which we find crystals

of feldspar bent and broken by the movement of the surrounding,

semi-fluid matter. Lavas are chiefly composed of three varieties of

feldspar, varying in specific gravity from 2.4 to 2.74; of hornblende

and augite, varying from 3.0 to 3.4; of olivine, varying from 3.3 to

3.4; and lastly, of oxides of iron, with specific gravities from 4.8 to

5.2. Hence crystals of feldspar, enveloped in a mass of liquified, but

not highly vesicular lava, would tend to rise to the upper parts; and

crystals or granules of the other minerals, thus enveloped, would tend

to sink. We ought not, however, to expect any perfect degree of

separation in such viscid materials. Trachyte, which consists chiefly

of feldspar, with some hornblende and oxide of iron, has a specific

gravity of about 2.45; whilst basalt, composed chiefly of augite and

feldspar, often with much iron and olivine, has a gravity of about 3.0.

(Trachyte from Java was found by Von Buch to be 2.47; from Auvergne, by

De la Beche, it was 2.42; from Ascension, by myself, it was 2.42.

Jameson and other authors give to basalt a specific gravity of 3.0; but

specimens from Auvergne were found, by De la Beche, to be only 2.78;

and from the Giant’s Causeway, to be 2.91.) Accordingly we find, that

where both trachytic and basaltic streams have proceeded from the same

orifice, the trachytic streams have generally been first erupted owing,

as we must suppose, to the molten lava of this series having

accumulated in the upper parts of the volcanic focus. This order of

eruption has been observed by Beudant, Scrope, and by other authors;

three instances, also, have been given in this volume. As the later

eruptions, however, from most volcanic mountains, burst through their

basal parts, owing to the increased height and weight of the internal

column of molten rock, we see why, in most cases, only the lower flanks

of the central, trachytic masses, are enveloped by basaltic streams.

The separation of the ingredients of a mass of lava, would, perhaps,

sometimes take place within the body of a volcanic mountain, if lofty

and of great dimensions, instead of within the underground focus; in

which case, trachytic streams might be poured forth, almost

contemporaneously, or at short recurrent intervals, from its summit,

and basaltic streams from its base: this seems to have taken place at

Teneriffe. (Consult Von Buch’s well-known and admirable “Description

Physique” of this island, which might serve as a model of descriptive

geology.) I need only further remark, that from violent disturbances

the separation of the two series, even under otherwise favourable

conditions, would naturally often be prevented, and likewise their

usual order of eruption be inverted. From the high degree of fluidity

of most basaltic lavas, these perhaps, alone, would in many cases reach

the surface.

As we have seen that crystals of feldspar, in the instance described by

Von Buch, sink in obsidian, in accordance with their known greater

specific gravity, we might expect to find in every trachytic district,

where obsidian has flowed as lava, that it had proceeded from the upper

or highest orifices. This, according to Von Buch, holds good in a

remarkable manner both at the Lipari Islands and on the Peak of

Teneriffe; at this latter place obsidian has never flowed from a less

height than 9,200 feet. Obsidian, also, appears to have been erupted

from the loftiest peaks of the Peruvian Cordillera. I will only further

observe, that the specific gravity of quartz varies from 2.6 to 2.8;

and therefore, that when present in a volcanic focus, it would not tend

to sink with the basaltic bases; and this, perhaps, explains the

frequent presence, and the abundance of this mineral, in the lavas of

the trachytic series, as observed in previous parts of this volume.

An objection to the foregoing theory will, perhaps, be drawn from the

plutonic rocks not being separated into two evidently distinct series,

of different specific gravities; although, like the volcanic, they have

been liquified. In answer, it may first be remarked, that we have no

evidence of the atoms of any one of the constituent minerals in the

plutonic series having been aggregated, whilst the others remained

fluid, which we have endeavoured to show is an almost necessary

condition of their separation; on the contrary, the crystals have

generally impressed each other with their forms. (The crystalline paste

of phonolite is frequently penetrated by long needles of hornblende;

from which it appears that the hornblende, though the more fusible

mineral, has crystallised before, or at the same time with a more

refractory substance. Phonolite, as far as my observations serve, in

every instance appears to be an injected rock, like those of the

plutonic series; hence probably, like these latter, it has generally

been cooled without repeated and violent disturbances. Those geologists

who have doubted whether granite could have been formed by igneous

liquefaction, because minerals of different degrees of fusibility

impress each other with their forms, could not have been aware of the

fact of crystallised hornblende penetrating phonolite, a rock

undoubtedly of igneous origin. The viscidity, which it is now known,

that both feldspar and quartz retain at a temperature much below their

points of fusion, easily explains their mutual impressment. Consult on

this subject Mr. Horner’s paper on Bonn “Geolog. Transact.” volume 4

page 439; and “L’Institut” with respect to quartz 1839 page 161.)

In the second place, the perfect tranquillity, under which it is

probable that the plutonic masses, buried at profound depths, have

cooled, would, most likely, be highly unfavourable to the separation of

their constituent minerals; for, if the attractive force, which during

the progressive cooling draws together the molecules of the different

minerals, has power sufficient to keep them together, the friction

between such half-formed crystals or pasty globules would effectually

prevent the heavier ones from sinking, or the lighter ones from rising.

On the other hand, a small amount of disturbance, which would probably

occur in most volcanic foci, and which we have seen does not prevent

the separation of granules of lead from a mixture of molten lead and

silver, or crystals of feldspar from streams of lava, by breaking and

dissolving the less perfectly formed globules, would permit the more

perfect and therefore unbroken crystals, to sink or rise, according to

their specific gravity.

Although in plutonic rocks two distinct species, corresponding to the

trachytic and basaltic series, do not exist, I much suspect that a

certain amount of separation of their constituent parts has often taken

place. I suspect this from having observed how frequently dikes of

greenstone and basalt intersect widely extended formations of granite

and the allied metamorphic rocks. I have never examined a district in

an extensive granitic region without discovering dikes; I may instance

the numerous trap-dikes, in several districts of Brazil, Chile, and

Australia, and at the Cape of Good Hope: many dikes likewise occur in

the great granitic tracts of India, in the north of Europe, and in

other countries. Whence, then, has the greenstone and basalt, forming

these dikes, come? Are we to suppose, like some of the elder

geologists, that a zone of trap is uniformly spread out beneath the

granitic series, which composes, as far as we know, the foundations of

the earth’s crust? Is it not more probable, that these dikes have been

formed by fissures penetrating into partially cooled rocks of the

granitic and metamorphic series, and by their more fluid parts,

consisting chiefly of hornblende, oozing out, and being sucked into

such fissures? At Bahia, in Brazil, in a district composed of gneiss

and primitive greenstone, I saw many dikes, of a dark augitic (for one

crystal certainly was of this mineral) or hornblendic rock, which, as

several appearances clearly proved, either had been formed before the

surrounding mass had become solid, or had together with it been

afterwards thoroughly softened. (Portions of these dikes have been

broken off, and are now surrounded by the primary rocks, with their

laminae conformably winding round them. Dr. Hubbard also (“Silliman’s

Journal” volume 34 page 119), has described an interlacement of

trap-veins in the granite of the White Mountains, which he thinks must

have been formed when both rocks were soft.) On both sides of one of

these dikes, the gneiss was penetrated, to the distance of several

yards, by numerous, curvilinear threads or streaks of dark matter,

which resembled in form clouds of the class called cirrhi- comae; some

few of these threads could be traced to their junction with the dike.

When examining them, I doubted whether such hair-like and curvilinear

veins could have been injected, and I now suspect, that instead of

having been injected from the dike, they were its feeders. If the

foregoing views of the origin of trap-dikes in widely extended granitic

regions far from rocks of any other formation, be admitted as probable,

we may further admit, in the case of a great body of plutonic rock,

being impelled by repeated movements into the axis of a mountain-chain,

that its more liquid constituent parts might drain into deep and unseen

abysses; afterwards, perhaps, to be brought to the surface under the

form, either of injected masses of greenstone and augitic porphyry, or

of basaltic eruptions. (Mr. Phillips “Lardner’s Encyclop.” volume 2

page 115 quotes Von Buch’s statement, that augitic porphyry ranges

parallel to, and is found constantly at the base of, great chains of

mountains. Humboldt, also, has remarked the frequent occurrence of

trap-rock, in a similar position; of which fact I have observed many

examples at the foot of the Chilian Cordillera. The existence of

granite in the axes of great mountain chains is always probable, and I

am tempted to suppose, that the laterally injected masses of augitic

porphyry and of trap, bear nearly the same relation to the granitic

axes which basaltic lavas bear to the central trachytic masses, round

the flanks of which they have so frequently been erupted.) Much of the

difficulty which geologists have experienced when they have compared

the composition of volcanic with plutonic formations, will, I think, be

removed, if we may believe that most plutonic masses have been, to a

certain extent, drained of those comparatively weighty and easily

liquified elements, which compose the trappean and basaltic series of

rocks.

ON THE DISTRIBUTION OF VOLCANIC ISLANDS.

During my investigations on coral-reefs, I had occasion to consult the

works of many voyagers, and I was invariably struck with the fact, that

with rare exceptions, the innumerable islands scattered throughout the

Pacific, Indian, and Atlantic Oceans, were composed either of volcanic,

or of modern coral-rocks. It would be tedious to give a long catalogue

of all the volcanic islands; but the exceptions which I have found are

easily enumerated: in the Atlantic, we have St. Paul’s Rock, described

in this volume, and the Falkland Islands, composed of quartz and

clay-slate; but these latter islands are of considerable size, and lie

not very far from the South American coast (Judging from Forster’s

imperfect observation, perhaps Georgia is not volcanic. Dr. Allan is my

informant with regard to the Seychelles. I do not know of what

formation Rodriguez, in the Indian Ocean, is composed.): in the Indian

Ocean, the Seychelles (situated in a line prolonged from Madagascar)

consist of granite and quartz: in the Pacific Ocean, New Caledonia, an

island of large size, belongs (as far as is known) to the primary

class. New Zealand, which contains much volcanic rock and some active

volcanoes, from its size cannot be classed with the small islands,

which we are now considering. The presence of a small quantity of

non-volcanic rock, as of clay-slate on three of the Azores (This is

stated on the authority of Count V. de Bedemar, with respect to Flores

and Graciosa (Charlsworth “Magazine of Nat. Hist.” volume 1 page 557).

St. Maria has no volcanic rock, according to Captain Boyd (Von Buch

“Descript.” page 365). Chatham Island has been described by Dr.

Dieffenbach in the “Geographical Journal” 1841 page 201. As yet we have

received only imperfect notices on Kerguelen Land, from the Antarctic

Expedition.), or of tertiary limestone at Madeira, or of clay-slate at

Chatham Island in the Pacific, or of lignite at Kerguelen Land, ought

not to exclude such islands or archipelagoes, if formed chiefly of

erupted matter, from the volcanic class.

The composition of the numerous islands scattered through the great

oceans being with such rare exceptions volcanic, is evidently an

extension of that law, and the effect of those same causes, whether

chemical or mechanical, from which it results, that a vast majority of

the volcanoes now in action stand either as islands in the sea, or near

its shores. This fact of the ocean-islands being so generally volcanic

is also interesting in relation to the nature of the mountain-chains on

our continents, which are comparatively seldom volcanic; and yet we are

led to suppose that where our continents now stand an ocean once

extended. Do volcanic eruptions, we may ask, reach the surface more

readily through fissures formed during the first stages of the

conversion of the bed of the ocean into a tract of land?

Looking at the charts of the numerous volcanic archipelagoes, we see

that the islands are generally arranged either in single, double, or

triple rows, in lines which are frequently curved in a slight degree.

(Professors William and Henry Darwin Rogers have lately insisted much,

in a memoir read before the American Association, on the regularly

curved lines of elevation in parts of the Appalachian range.) Each

separate island is either rounded, or more generally elongated in the

same direction with the group in which it stands, but sometimes

transversely to it. Some of the groups which are not much elongated

present little symmetry in their forms; M. Virlet (“Bulletin de la Soc.

Geolog.” tome 3 page 110.) states that this is the case with the

Grecian Archipelago: in such groups I suspect (for I am aware how easy

it is to deceive oneself on these points), that the vents are generally

arranged on one line, or on a set of short parallel lines, intersecting

at nearly right angles another line, or set of lines. The Galapagos

Archipelago offers an example of this structure, for most of the

islands and the chief orifices on the largest island are so grouped as

to fall on a set of lines ranging about N.W. by N., and on another set

ranging about W.S.W.: in the Canary Archipelago we have a simpler

structure of the same kind: in the Cape de Verde group, which appears

to be the least symmetrical of any oceanic volcanic archipelago, a N.W.

and S.E. line formed by several islands, if prolonged, would intersect

at right angles a curved line, on which the remaining islands are

placed.

Von Buch (“Description des Isles Canaries” page 324.) has classed all

volcanoes under two heads, namely, CENTRAL VOLCANOES, round which

numerous eruptions have taken place on all sides, in a manner almost

regular, and VOLCANIC CHAINS. In the examples given of the first class,

as far as position is concerned, I can see no grounds for their being

called “central;” and the evidence of any difference in mineralogical

nature between CENTRAL VOLCANOES and VOLCANIC CHAINS appears slight. No

doubt some one island in most small volcanic archipelagoes is apt to be

considerably higher than the others; and in a similar manner, whatever

the cause may be, that on the same island one vent is generally higher

than all the others. Von Buch does not include in his class of volcanic

chains small archipelagoes, in which the islands are admitted by him,

as at the Azores, to be arranged in lines; but when viewing on a map of

the world how perfect a series exists from a few volcanic islands

placed in a row to a train of linear archipelagoes following each other

in a straight line, and so on to a great wall like the Cordillera of

America, it is difficult to believe that there exists any essential

difference between short and long volcanic chains. Von Buch (Idem page

393.) states that his volcanic chains surmount, or are closely

connected with, mountain-ranges of primary formation: but if trains of

linear archipelagoes are, in the course of time, by the long- continued

action of the elevatory and volcanic forces, converted into

mountain-ranges, it would naturally result that the inferior primary

rocks would often be uplifted and brought into view.

Some authors have remarked that volcanic islands occur scattered,

though at very unequal distances, along the shores of the great

continents, as if in some measure connected with them. In the case of

Juan Fernandez, situated 330 miles from the coast of Chile, there was

undoubtedly a connection between the volcanic forces acting under this

island and under the continent, as was shown during the earthquake of

1835. The islands, moreover, of some of the small volcanic groups which

thus border continents, are placed in lines, related to those along

which the adjoining shores of the continents trend; I may instance the

lines of intersection at the Galapagos, and at the Cape de Verde

Archipelagoes, and the best marked line of the Canary Islands. If these

facts be not merely accidental, we see that many scattered volcanic

islands and small groups are related not only by proximity, but in the

direction of the fissures of eruption to the neighbouring continents—a

relation, which Von Buch considers, characteristic of his great

volcanic chains.

In volcanic archipelagoes, the orifices are seldom in activity on more

than one island at a time; and the greater eruptions usually recur only

after long intervals. Observing the number of craters, that are usually

found on each island of a group, and the vast amount of matter which

has been erupted from them, one is led to attribute a high antiquity

even to those groups, which appear, like the Galapagos, to be of

comparatively recent origin. This conclusion accords with the

prodigious amount of degradation, by the slow action of the sea, which

their originally sloping coasts must have suffered, when they are worn

back, as is so often the case, into grand precipices. We ought not,

however, to suppose, in hardly any instance, that the whole body of

matter, forming a volcanic island, has been erupted at the level, on

which it now stands: the number of dikes, which seem invariably to

intersect the interior parts of every volcano, show, on the principles

explained by M. Elie de Beaumont, that the whole mass has been uplifted

and fissured. A connection, moreover, between volcanic eruptions and

contemporaneous elevations in mass has, I think, been shown to exist in

my work on Coral-Reefs, both from the frequent presence of upraised

organic remains, and from the structure of the accompanying

coral-reefs. (A similar conclusion is forced on us, by the phenomena,

which accompanied the earthquake of 1835, at Concepcion, and which are

detailed in my paper (volume 5 page 601) in the “Geological

Transactions.”) Finally, I may remark, that in the same Archipelago,

eruptions have taken place within the historical period on more than

one of the parallel lines of fissure: thus, at the Galapagos

Archipelago, eruptions have taken place from a vent on Narborough

Island, and from one on Albemarle Island, which vents do not fall on

the same line; at the Canary Islands, eruptions have taken place in

Teneriffe and Lanzarote; and at the Azores, on the three parallel lines

of Pico, St. Jorge, and Terceira. Believing that a mountain-axis

differs essentially from a volcano, only in plutonic rocks having been

injected, instead of volcanic matter having been ejected, this appears

to me an interesting circumstance; for we may infer from it as

probable, that in the elevation of a mountain-chain, two or more of the

parallel lines forming it may be upraised and injected within the same

geological period.

Volcanic Islands · 第 6 / 7 章