QUARTZ FIBERS.[1]

[Footnote 1: Lecture delivered at the Royal Institution, on

Friday, June 14, by Mr. C. V. Boys, F.R.S.--_Nature._]

In almost all investigations which the physicist carries out in the

laboratory, he has to deal with and to measure with accuracy those

subtile and to our senses inappreciable forces to which the so-called

laws of nature give rise. Whether he is observing by an electrometer

the behavior of electricity at rest or by a galvanometer the action of

electricity in motion, whether in the tube of Crookes he is

investigating the power of radiant matter, or with the famous

experiment of Cavendish he is finding the mass of the earth--in these

and in a host of other cases he is bound to measure with certainty and

accuracy forces so small that in no ordinary way could their existence

be detected, while disturbing causes which might seem to be of no

particular consequence must be eliminated if his experiments are to

have any value. It is not too much to say that the very existence of

the physicist depends upon the power which he possesses of producing

at will and by artificial means forces against which he balances those

that he wishes to measure.

I had better perhaps at once indicate in a general way the magnitude

of the forces with which we have to deal.

The weight of a single grain is not to our senses appreciable, while

the weight of a ton is sufficient to crush the life out of any one in

a moment. A ton is about 15,000,000 grains. It is quite possible to

measure with unfailing accuracy forces which bear the same relation to

the weight of a grain that a grain bears to a ton.

To show how the torsion of wires or threads is made use of in

measuring forces, I have arranged what I can hardly dignify by the

name of an experiment. It is simply a straw hung horizontally by a

piece of wire. Resting on the straw is a fragment of sheet iron

weighing ten grains. A magnet so weak that it cannot lift the iron yet

is able to pull the straw round through an angle so great that the

existence of the feeble attraction is evident to every one in the

room.

Now it is clear that if, instead of a straw moving over the table

simply, we had here an arm in a glass case and a mirror to read the

motion of the arm, it would be easy to observe a movement a hundred or

a thousand times less than that just produced, and therefore to

measure a force a hundred or a thousand times less than that exerted

by this feeble magnet.

Again, if instead of wire as thick as an ordinary pin I had used the

finest wire that can be obtained, it would have opposed the movement

of the straw with a far less force. It is possible to obtain wire ten

times finer than this stubborn material, but wire ten times finer is

much more than ten times more easily twisted. It is ten thousand times

more easily twisted. This is because the torsion varies as the fourth

power of the diameter. So we say 10 × 10 = 100, 100 × 100 = 10,000.

Therefore, with the finest wire, forces 10,000 times feebler still

could be observed.

It is therefore evident how great is the advantage of reducing the

size of a torsion wire. Even if it is only halved, the torsion is

reduced sixteenfold. To give a better idea of the actual sizes of such

wires and fibers as are in use, I shall show upon the screen a series

of such photographs taken by Mr. Chapman, on each of which a scale of

thousandths of an inch has been printed.

[Illustration: Scale of 1000ths of an inch for Figs. 1 to 7. The scale

of Figs. 8 and 9 is much finer.]

[Illustration: FIG. 1.]

[Illustration: FIG. 2.]

[Illustration: FIG. 3.]

The first photograph (Fig. 1) is an ordinary hair--a sufficiently

familiar object, and one that is generally spoken of as if it were

rather fine. Much finer than this is the specimen of copper wire now

on the screen (Fig. 2), which I recently obtained from Messrs. Nalder

Brothers. It is only a little over one-thousandth of an inch in

diameter. Ordinary spun glass, a most beautiful material, is about

one-thousandth of an inch in diameter, and this would appear to be an

ideal torsion thread (Fig. 3). Owing to its fineness, its torsion

would be extremely small, and the more so because glass is more easily

deformed than metals. Owing to its very great strength, it can carry

heavier loads than would be expected of it. I imagine many physicists

must have turned to this material in their endeavor to find a really

delicate torsion thread. I have so turned only to be disappointed. It

has every good quality but one, and that is its imperfect elasticity.

For instance, a mirror hung by a piece of spun glass is casting an

image of a spot of light on the scale. If I turn the mirror, by means

of a fork, twice to the right, and then turn it back again, the light

does not come back to its old point of rest, but oscillates about a

point on one side, which, however, is slowly changing, so that it is

impossible to say what the point of rest really is. Further, if the

glass is twisted one way first and then the other way, the point of

rest moves in a manner which shows that it is not influenced by the

last deflection alone: the glass remembers what was done to it

previously. For this reason spun glass is quite unsuitable as a

torsion thread; it is impossible to say what the twist is at any time,

and therefore what is the force developed.

[Illustration: FIG. 4.]

So great has the difficulty been in finding a fine torsion thread that

the attempt has been given up, and in all the most exact instruments

silk has been used. The natural cocoon fibers, as shown on the screen

(Fig. 4), consist of two irregular lines gummed together, each about

one two-thousandth of an inch in diameter. These fibers must be

separated from one another and washed. Then each component will,

according to the experiment of Gray, carry nearly 60 grains before

breaking, and can be safely loaded with 15 grains. Silk is therefore

very strong, carrying at the rate of from 10 to 20 tons to the square

inch. It is further valuable in that its torsion is far less than that

of a fiber of the same size of metal or even of glass, if such could

be produced. The torsion of silk, though exceedingly small, is quite

sufficient to upset the working of any delicate instrument, because it

is never constant. At one time the fiber twists one way and another

time in another, and the evil effect can only be mitigated by using

large apparatus in which strong forces are developed. Any attempt that

may be made to increase the delicacy of apparatus by reducing their

dimensions is at once prevented by the relatively great importance of

the vagaries of the silk suspension.

The result, then, is this. The smallness, the length of period, and

therefore delicacy, of the instruments at the physicist's disposal

have until lately been simply limited by the behavior of silk. A more

perfect suspension means still more perfect instruments, and therefore

advance in knowledge.

It was in this way that some improvements that I was making in an

instrument for measuring radiant heat came to a deadlock about two

years ago. I would not use silk, and I could not find anything else

that would do. Spun glass, even, was far too coarse for my purpose, it

was a thousand times too stiff.

[Illustration: FIG. 5.]

There is a material invented by Wollaston long ago, which, however, I

did not try because it is so easily broken. It is platinum wire which

has been drawn in silver, and finally separated by the action of

nitric acid. A specimen about the size of a single line of silk is now

on the screen, showing the silver coating at one end (Fig. 5).

As nothing that I knew of could be obtained that would be of use to

me, I was driven to the necessity of trying by experiment to find some

new material. The result of these experiments was the development of a

process of almost ridiculous simplicity which it may be of interest

for me to show.

The apparatus consists of a small crossbow, and an arrow made of straw

with a needle point. To the tail of the arrow is attached a fine rod

of quartz which has been melted and drawn out in the oxyhydrogen jet.

I have a piece of the same material in my hand, and now after melting

their ends and joining them together, an operation which produces a

beautiful and dazzling light, all I have to do is to liberate the

string of the bow by pulling the trigger with one foot, and then if

all is well a fiber will have been drawn by the arrow, the existence

of which can be made evident by fastening to it a piece of stamp

paper.

In this way threads can be produced of great length, of almost any

degree of fineness, of extraordinary uniformity, and of enormous

strength. I do not believe, if any experimentalist had been promised

by a good fairy that he might have anything he desired, that he would

have ventured to ask for any one thing with so many valuable

properties as these fibers possess. I hope in the course of this

evening to show that I am not exaggerating their merits.

[Illustration: FIG. 6.]

[Illustration: FIG. 7.]

In the first place, let me say something about the degree of fineness

to which they can be drawn. There is now projected upon the screen a

quartz fiber one five-thousandth of an inch in diameter (Fig. 6). This

is one which I had in constant use in an instrument loaded with about

30 grains. It has a section only one-sixth of that of a single line of

silk, and it is just as strong. Not being organic, it is in no way

affected by changes of moisture and temperature, and so it is free

from the vagaries of silk which give so much trouble. The piece used

in the instrument was about 16 inches long. Had it been necessary to

employ spun glass, which hitherto was the finest torsion material,

then, instead of 16 inches, I should have required a piece 1,000 feet

long, and an instrument as high as the Eiffel tower to put it in.

There is no difficulty in obtaining pieces as fine as this yards long

if required, or in spinning it very much finer. There is upon the

screen a single line made by the small garden spider, and the size of

this is perfectly evident (Fig. 7). You now see a quartz fiber far

finer than this, or, rather, you see a diffraction phenomenon, for no

true image is formed at all; but even this is a conspicuous object in

comparison with the tapering ends, which it is absolutely impossible

to trace in a microscope. The next two photographs, taken by Mr.

Nelson, whose skill and resources are so famous, represent the extreme

end of a tail of quartz, and, though the scale is a great deal larger

than that used in the other photographs, the end will be visible only

to a few. Mr. Nelson has photographed here what it is absolutely

impossible to see. What the size of these ends may be, I have no means

of telling. Dr. Royston Piggott has estimated some of them at less

than one-millionth of an inch, but, whatever they are, they supply for

the first time objects of extreme smallness the form of which is

certainly known, and, therefore, I cannot help looking upon them as

more satisfactory tests for the microscope than diatoms and other

things of the real shape of which we know nothing whatever.

Since figures as large as a million cannot be realized properly, it

may be worth while to give an illustration of what is meant by a fiber

one-millionth of an inch in diameter.

A piece of quartz an inch long and an inch in diameter would, if drawn

out to this degree of fineness, be sufficient to go all the way round

the world 658 times; or a grain of sand just visible--that is,

one-hundredth of an inch long and one hundredth of an inch in

diameter--would make one thousand miles of such thread. Further, the

pressure inside such a thread due to a surface tension equal to that

of water would be 60 atmospheres.

Going back to such threads as can be used in instruments, I have made

use of fibers one ten-thousandth of an inch in diameter, and in these

the torsion is 10,000 times less than that of spun glass.

As these fibers are made finer their strength increases in proportion

to their size, and surpasses that of ordinary bar steel, reaching, to

use the language of engineers, as high a figure as 80 tons to the

inch. Fibers of ordinary size have a strength of 50 tons to the inch.

While it is evident that these fibers give us the means of producing

an exceedingly small torsion, and one that is not affected by weather,

it is not yet evident that they may not show the same fatigue that

makes spun glass useless. I have, therefore, a duplicate apparatus

with a quartz fiber, and you will see that the spot of light comes

back to its true place on the screen after the mirror has been twisted

round twice.

I shall now for a moment draw your attention to that peculiar property

of melted quartz that makes threads such as I have been describing a

possibility. A liquid cylinder, as Plateau has so beautifully shown,

is an unstable form. It can no more exist than can a pencil stand on

its point. It immediately breaks up into a series of spheres. This is

well illustrated in that very ancient experiment of shooting threads

of resin electrically. When the resin is hot, the liquid cylinders,

which are projected in all directions, break up into spheres, as you

see now upon the screen. As the resin cools, they begin to develop

tails; and when it is cool enough, i.e., sufficiently viscous, the

tails thicken and the beads become less, and at last uniform threads

are the result. The series of photographs show this well.

[Illustration: FIG. 8.]

[Illustration: FIG. 9.]

There is a far more perfect illustration which we have only to go into

the garden to find. There we may see in abundance what is now upon the

screen--the webs of those beautiful geometrical spiders. The radial

threads are smooth like the one you saw a few minutes ago, but the

threads that go round and round are beaded. The spider draws these

webs slowly, and at the same time pours upon them a liquid, and still

further to obtain the effect of launching a liquid cylinder in space

he, or rather she, pulls it out like the string of a bow, and lets it

go with a jerk. The liquid cylinder cannot exist, and the result is

what you now see upon the screen (Fig. 8). A more perfect illustration

of the regular breaking up of a liquid cylinder it would be impossible

to find. The beads are, as Plateau showed they ought to be,

alternately large and small, and their regularity is marvelous.

Sometimes two still smaller beads are developed, as may be seen in the

second photograph, thus completely agreeing with the results of

Plateau's investigations.

I have heard it maintained that the spider goes round her web and

places these beads there afterward. But since a web with about 360,000

beads is completed in an hour--that is at the rate of about 100 a

second--this does not seem likely. That what I have said is true, is

made more probable by the photograph of a beaded web that I have made

myself by simply stroking a quartz fiber with a straw wetted with

castor oil (Fig. 9); it is rather larger than a spider line; but I

have made beaded threads, using a fine fiber, quite indistinguishable

from a real spider web, and they have the further similarity that they

are just as good for catching flies.

Now, going back to the melted quartz, it is evident that if it ever

became perfectly liquid, it could not exist as a fiber for an instant.

It is the extreme viscosity of quartz, at the heat even of an electric

arc, that makes these fibers possible. The only difference between

quartz in the oxyhydrogen jet and quartz in the arc is that in the

first you make threads and in the second are blown bubbles. I have in

my hand some microscopic bubbles of quartz showing all the perfection

of form and color that we are familiar with in the soap bubble.

An invaluable property of quartz is its power of insulating perfectly,

even in an atmosphere saturated with water. The gold leaves now

diverging were charged some time before the lecture, and hardly show

any change, yet the insulator is a rod of quartz only three-quarters

of an inch long, and the air is kept moist by a dish of water. The

quartz may even be dipped in the water and replaced with the water

upon it without any difference in the insulation being observed.

Not only can fibers be made of extreme fineness, but they are

wonderfully uniform in diameter. So uniform are they that they

perfectly stand an optical test so severe that irregularities

invisible in any microscope would immediately be made apparent. Every

one must have noticed when the sun is shining upon a border of flowers

and shrubs how the lines which spiders use as railways to travel from

place to place glisten with brilliant colors. These colors are only

produced when the fibers are sufficiently fine. If you take one of

these webs and examine it in the sunlight, you will find that the

colors are variegated, and the effect, consequently, is one of great

beauty.

A quartz fiber of about the same size shows colors in the same way,

but the tint is perfectly uniform on the fiber. If the color of the

fiber is examined with a prism, the spectrum is found to consist of

alternate bright and dark bands. Upon the screen are photographs

taken by Mr. Briscoe, a student in the laboratory at South Kensington,

of the spectra of some of these fibers at different angles of

incidence. It will be seen that coarse fibers have more bands than

fine, and that the number increases with the angle of incidence of the

light. There are peculiarities in the march of the bands as the angle

increases which I cannot describe now. I may only say that they appear

to move not uniformly, but in waves, presenting very much the

appearance of a caterpillar walking.

So uniform are the quartz fibers that the spectrum from end to end

consists of parallel bands. Occasionally a fiber is found which

presents a slight irregularity here and there. A spider line is so

irregular that these bands are hardly observable; but, as the

photograph on the screen shows, it is possible to trace them running

up and down the spectrum when you know what to look for.

To show that these longitudinal bands are due to the irregularities, I

have drawn a taper piece of quartz by hand, in which the two edges

make with one another an almost imperceptible angle, and the spectrum

of this shows the gradual change of diameter by the very steep angle

at which the bands run up the spectrum.

Into the theory of the development of these bands I am unable to

enter; that is a subject on which your professor of natural philosophy

is best able to speak. Perhaps I may venture to express the hope, as

the experimental investigation of this subject is now rendered

possible, that he may be induced to carry out a research for which he

is so eminently fitted.

Though this is a subject which is altogether beyond me, I have been

able to use the results in a practical way. When it is required to

place into an instrument a fiber of any particular size, all that has

to be done is to hold the frame of fibers toward a bright and distant

light, and look at them through a low-angled prism. The banded spectra

are then visible, and it is the work of a moment to pick out one with

the number of bands that has been found to be given by a fiber of the

desired size. A coarse fiber may have a dozen or more, while such

fibers as I find most useful have only two dark bands. Much finer ones

exist, showing the colors of the first order with one dark band; and

fibers so fine as to correspond to the white or even the gray of

Newton's scale are easily produced.

Passing now from the most scientific test of the uniformity of these

fibers, I shall next refer to one more homely. It is simply this: The

common garden spider, except when very young, cannot climb up one of

the same size as the web on which she displays such activity. She is

perfectly helpless, and slips down with a run. After vainly trying to

make any headway, she finally puts her hands (or feet) into her mouth

and then tries again, with no better success. I may mention that a

male of the same species is able to run up one of these with the

greatest ease, a feat which may perhaps save the lives of a few of

these unprotected creatures when quartz fibers are more common.

It is possible to make any quantity of very fine quartz fiber without

a bow and arrow at all, by simply drawing out a rod of quartz over and

over again in a strong oxyhydrogen jet. Then, if a stand of any sort

has been placed a few feet in front of the jet, it will be found

covered with a maze of thread, of which the photograph on the screen

represents a sample. This is hardly distinguishable from the web spun

by this magnificent spider in corners of greenhouses and such places.

By regulating the jet and the manipulation, anything from one of these

stranded cables to a single ultro-microscope line may be developed.

And now that I have explained that these fibers have such valuable

properties, it will no doubt be expected that I should perform some

feat with their aid which, up to the present time, has been considered

impossible, and this I intend to do.

Of all experiments, the one which has most excited my admiration is

the famous experiment of Cavendish, of which I have a full size model

before you. The object of this experiment is to weigh the earth by

comparing directly the force with which it attracts things with that

due to large masses of lead. As is shown by the model, any attraction

which these large balls exert on the small ones will tend to deflect

this 6 ft. beam in one direction, and then if the balls are reversed

in position, the deflection will be in the other direction. Now, when

it is considered how enormously greater the earth is than these balls,

it will be evident that the attraction due to them must be in

comparison excessively small. To make this evident, the enormous

apparatus you see had to be constructed, and then, using a fine

torsion wire, a perfectly certain but small effect was produced. The

experiment, however, could only be successfully carried out in cellars

and underground places, because changes of temperature produced

effects greater than those due to gravity.[2]

[Footnote 2: Dr. Lodge has been able, by an elaborate

arrangement of screens, to make this attraction just evident to

an audience.--C. V. B.]

Now I have in a hole in the wall an instrument no bigger than a

galvanometer, of which a model is on the table. The balls of the

Cavendish apparatus, weighing several hundredweight each, are replaced

by balls weighing 1¾ pounds only. The smaller balls of 1¾ pounds are

replaced by little weights of 15 grains each. The 6 foot beam is

replaced by one that will swing round freely in a tube three-quarters

of an inch in diameter. The beam is, of course, suspended by a quartz

fiber. With this microscopic apparatus, not only is the very feeble

attraction observable, but I can actually obtain an effect eighteen

times as great as that given by the apparatus of Cavendish, and what

is more important, the accuracy of observation is enormously

increased.

The light from a lamp passes through a telescope lens, and falls on

the mirror of the instrument. It is reflected back to the table, and

thence by a fixed mirror to the scale on the wall, where it comes to a

focus. If the mirror on the table were plane, the whole movement of

the light would be only about eight inches, but the mirror is convex,

and this magnifies the motion nearly eight times. At the present

moment the attracting weights are in one extreme position, and the

line of light is quiet. I will now move them to the other position,

and you will see the result--the light slowly begins to move, and

slowly increases in movement. In forty seconds it will have acquired

its highest velocity, and in forty more it will have stopped at 5

feet 8½ inches from the starting point, after which it will slowly

move back again, oscillating about its new position of rest.

It is not possible at this hour to enter into any calculations; I will

only say that the motion you have seen is the effect of a force of

less than one ten-millionth of the weight of a grain, and that with

this apparatus I can detect a force two thousand times smaller still.

There would be no difficulty even in showing the attraction between

two No. 5 shot.

And now, in conclusion, I would only say that if there is anything

that is good in the experiments to which I have this evening directed

your attention, experiments conducted largely with sticks, and string,

and straw and sealing wax, I may perhaps be pardoned if I express my

conviction that in these days we are too apt to depart from the simple

ways of our fathers, and instead of following them, to fall down and

worship the brazen image which the instrument maker hath set up.

* * * * *

Scientific American Supplement, No. 717, September 28, 1889 · 第 12 / 38 题