magnesium powder is heated in an iron pipe (placed over a row of
gas burners as in the combustion furnace used for organic
analysis) in a stream of hydrogen. After being heated for 1/2 hour
the mixture is found to absorb hydrogen (it no longer passes over
the mixture, but is retained by it). The product, which is light
grey, and slightly coherent, disengages a mass of hydrogen when
water is poured over it, and burns when heated in air. The
resultant mass contains 33 per cent. CaH, about 28 per cent. CaO,
and about 38 per cent. MgO. Neither CaH nor any other MH has yet
been obtained in a pure state.
The acetylene derivatives of the metals of the alkaline earths
C_{2}M (Chapter VIII., Note 12 bis), for instance, C_{2}Ba,
obtained by Maquenne and Moissan, belong to the same class of
analogous compounds. It must here be remarked that the oxides MO
of the metals of the alkaline earths, although not reducible by
carbon at a furnace heat, yet under the action of the heat
attained in electrical furnaces, not only give up their oxygen to
carbon (probably partly owing to the action of the current), but
also combine with carbon. The resultant compounds, C_{2}M, evolve
acetylene, C_{2}H_{2}, with HCl, just as N_{2}M_{3} give ammonia.
We may remark moreover that the series of compounds of the metals
of the alkaline earths with hydrogen, nitrogen and carbon is a
discovery of recent years, and that probably further research will
give rise to similar unexpected compounds, and by extending our
knowledge of their reactions prove to be of great interest.
Thus the analogies and correlation of the metals of these two groups
are now clearly marked, not only in their behaviour towards oxygen,
chlorine, acids, &c., but also in their capability of combining with
nitrogen and hydrogen.
* * * * *
END OF THE FIRST VOLUME
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Transcriber's note:
The half-title has been deleted.
Obvious misprints were corrected.
Inconsistant hyphenation was kept as it is.