CHAPTER VII.

FARMYARD MANURE

Farmyard manure is the oldest, and is still undoubtedly the most

popular, of all manures. It has stood the test of long experience, and

has proved its position as one of the most important of all our

fertilisers. It is highly desirable, therefore, to make a somewhat

detailed examination of its composition, and to see on what the

variation in this depends; and, finally, to examine into the mode of its

action as a manure.

That it should prove a valuable manure is scarcely to be wondered at, as

it is originally formed from vegetable substance, and as it therefore

contains all the elements present in the plant itself.

Its composition is very variable, and probably no two samples would

yield exactly similar analyses. In this fact lies one of the chief

difficulties of the treatment of the subject, and all statements made

in the following pages as to its chemical composition must be taken as

only _approximate_.

We may divide its constituents into three classes.

1. That portion due to _solid excreta_.

2. The liquid portion, largely made up of dilute _urine_.

3. The _straw_, or other material, which is used as litter.

The composition of the manure will vary according to the proportion in

which these three substances are present, as well as according to the

composition of the substances themselves. It will consequently tend to a

clearer apprehension of the subject if we first examine briefly the

chemical composition of the solid excreta and urine of the farm animals.

1. _Solid Excreta._

The manurial value of the solid excreta of animals--_i.e._, the

proportion they contain of _nitrogen_, _phosphoric acid_, and

_potash_--depends on a variety of conditions.

The solid excreta of horses, sheep, cows, and pigs, are well known to

possess different properties, as well as to vary in their composition.

What, however, has a still greater influence is the nature of the food.

This is owing to the fact that the solid excreta are made up of

undigested food. We can scarcely expect the same quality of solid

excreta from an animal fed on poor diet as from an animal fed on very

much richer diet. Again, the percentage of the food voided in the solid

excreta varies in the case of different animals.[131]

Another consideration which enters into the question is the age, as well

as the treatment, of the animal. A young animal, during the period of

its growth, absorbs from its food into its system a larger quantity of

the three fertilising substances, nitrogen, phosphoric acid, and potash,

than is the case with an adult animal whose weight is neither increasing

nor diminishing. A working horse, similarly, will return more of the

nitrogen, phosphates, and potash in its dung than one not at work and

which is permitted to gain in weight. The nature of the composition of

the solid excreta, therefore, will depend on the nature of the _food_,

_age_, _breed_, _condition_, and _treatment_ of the animal.

Let us now investigate shortly the influence of the above

considerations. The solid excrements of the common farm animals are

generally distinguished from one another according to the rate at which

they decompose or ferment on keeping. Thus horse-dung is generally known

as a "hot" dung; while cow-dung, on the other hand, is known as "cool."

Why this should be so is not absolutely clear. Probably it is owing to

the fact that the former contains less water, as well as to the fact

(and this probably has more to do with it) that it contains a larger

percentage of fertilising matter, especially nitrogen, thus affording

conditions more favourable for rapid fermentation than in the case of

the more moist and less rich cow-dung.

The composition of the solid excreta of various animals, as we have just

said, varies with the nature of their food; so that it is impossible to

take any analyses as absolutely representing its composition. It may be

interesting, however, to compare the analyses of samples of horse-dung

with those of some other of the commoner farm animals, with a view to

obtaining an _approximate_ idea of this difference.

Stoeckhardt has found that in 1000 lb. of the fresh solid excreta of the

animals below mentioned, there were the following amounts of _nitrogen_,

_phosphoric acid_, and _alkalies_:--

-----------------------+----------+-------------+-------------+-----------

| | | PHOSPHORIC |

| | NITROGEN. | ACID. | ALKALIES.

| WATER. |-----+-------+-----+-------+---+-------

| | |Reduced| |Reduced| |Reduced

| | | to | | to | | to

-----------------------+----+-----+-----+-------+-----+-------+---+-------

|lb. | per | lb. | per | lb. | per |lb.| per

| |cent.| | cent. | | cent. | | cent.

Horses (winter food) |760 |76 |5 | .50 |3-1/2| .35 | 3 | .30

Cows (winter food) |840 |84 |3 | .30 |2-1/2| .25 | 1 | .10

Swine (winter food) |800 |80 |6 | .60 |4-1/2| .45 | 5 | .50

Sheep (2 lb. hay per | | | | | | | |

diem) |580 |58 |7-1/2| .75 |6 | .6 | 3 | .30

-----------------------+----+-----+-----+-------+-----+-------+---+-------

From the above table it will be seen that the sheep's dung contains the

least percentage of _water_, and is richer in _nitrogen_ and _phosphoric

acid_ than any of the other three. The percentage of alkalies, of which

the most important is potash, is, however, not so large. This may be

accounted for by the interesting and well-known fact that a large

percentage of potash is to be found in the wool of sheep.[132]

The solid excrement of the sheep is, therefore, weight for weight, the

most valuable as a manure, as it contains more nitrogen and phosphates

than the others, and at the same time is much drier.

If, however, we compare the composition of the solid excreta in a dry

state, we shall find that the following are the results (basing our

calculation on Stoeckhardt's analyses):--

Nitrogen, Phosphoric acid, Alkalies,

per cent. per cent. per cent.

Horse 2.08 1.45 1.25

Cow 1.87 1.56 0.62

Pig 3.00 2.25 2.50

Sheep 1.78 1.42 0.71

It will be seen from the above that the dry substance of the solid

excreta of the pig is richest in fertilising substances. Too much

stress, however, as has already been pointed out, must not be put on any

single analysis, as so much depends on various conditions, especially

the food.[133] The most reliable method of studying this question,

therefore, is to study it in its relation to the food consumed. Wolff

has calculated from numerous investigations that, with regard to the

amount of solid excreta produced by the food, the following percentage

of _organic matter_, _nitrogen_, and _mineral substances_, originally

present in the dry matter of the food, is voided in the dung:--

Cow. Ox. Sheep. Horse. Average.

Organic matter 39.5 42.5 44.0 44.1 42.5

Nitrogen 47.5 33.9 46.7 32.4 40.1

Mineral substances 53.9 64.6 57.9 62.5 59.7

There is one fact to be borne in mind in estimating the manurial value

of the dung of different animals--viz., that the quantity of dung voided

by one animal is much greater than that voided by another. Thus the

amount voided by the cow, for example, is much greater than that voided

by the horse; so that, in this way, the inferior quality of the former

is, to some extent, compensated for by its greater quantity.

2. _Urine._

The solid excreta possess, however, very much less manurial value than

the urine. The former, as already stated, are undigested

food-substances: any fertilising matters which they contain are such as

have failed to be digested or absorbed into the animal system. The

urine, on the other hand, contains those fertilising substances which

have been digested.

The amount of nitrogen and mineral matter, however, in the urine, does

not represent necessarily the total amount of these substances. Thus, in

the case of a growing or fattening animal, there is always a certain

amount of these substances being absorbed to build up the animal tissue

and put on flesh.

In this respect it will be seen that the composition of urine will vary

in the same way as that of the dung. In the case of the urine, however,

there is a compensating influence to be taken into account. Urine is a

waste product, and there is more waste in a young than in an adult

animal.

Another very important condition which determines the composition of

urine is the nature of the food, especially the quantity of water drunk.

This, of course, is obvious: the more water drunk, the poorer must the

composition of the urine be. But here again, as in the case of the dung,

this is largely compensated for by the total quantity voided--the more

dilute the urine, the larger will its quantity be; so that the inferior

quality is in this way made up for by its increased quantity.

Keeping in mind, then, the fact we have just stated--viz., that the

composition of urine will vary according to different conditions--we may

obtain an approximate idea of what its composition is from the following

results of analyses by Stoeckhardt. In 1000 parts the following

quantities of _water_, _nitrogen_, _phosphoric acid_, and _alkalies_

were found to be present.

From the following table it will be seen that the urine of swine

(containing 97 per cent of water) is much poorer in nitrogen and

alkalies than is the case with the urine of the sheep, horse, or

cow.[134] While this is the case, the amount of phosphoric acid it

contains is greater than that contained in the sheep's urine.

-------------------+------------+-------------------------+------------

| | | Phosphoric |

| Water. | Nitrogen. | Acid. | Alkalies.

+------+-----+------+-----+------+-----+------+-----

| Per | Per | Per | Per | Per | Per | Per | Per

| 1000 |cent.| 1000 |cent.| 1000 |cent.| 1000 |cent.

|parts.| |parts.| |parts.| |parts.|

-------------------+------+-----+------+-----+------+-----+------+-----

Sheep (2 lb. hay }| 865 | 86.5| 14 | 1.4 | .5 | .050| 20 | 2.0

per diem) }| | | | | | | |

| | | | | | | |

Swine (winter food)| 975 | 97.5| 3 | .3 | 1.25 | .125| 2 | .2

| | | | | | | |

Horses (hay and }| 890 | 89.0| 12 | 1.2 | - | - | 15 | 1.5

oats) }| | | | | | | |

| | | | | | | |

Cows (hay and }| 920 | 92.0| 8 | .8 | - | - | 14 | 1.4

potatoes) }| | | | | | | |

-------------------+------+-----+------+-----+------+-----+------+-----

Phosphoric acid is present in the urine of the farm animals in the most

minute traces: practically, it may be considered to be wanting in the

urine of the horse and the cow, and is present only in small quantities

in sheep's urine. The pig's urine, indeed, contains it in larger

quantities; but the percentage is still so small as to justify the

statement that the urine of the common farm animals is not a complete

manure, and must be supplemented by phosphates, if it is to be used

alone. The incomplete nature of urine as a manure constitutes a strong

argument in favour of its being applied along with the solid excreta,

which contain, as we have seen, considerable quantities of phosphoric

acid. It is on this account that the drainings of rotten manure-heaps

are more valuable, from a manurial point of view, than urine itself,

since these contain the soluble portion of the phosphates in the solid

excreta.[135] The urine of all animals, however, is not equally poor in

phosphates. In the case of flesh-eating animals, such as the dog, the

urine is found to contain them in considerable quantities.

The above tables show that the most valuable urine, weight for weight,

is that of the sheep, as it contains the largest amount of alkalies

(including potash) and nitrogen; that the urine of the horse comes next;

then that of the cow; while, as has already been pointed out, that of

the pig is the poorest.

In order to make our survey of the composition of urine uniform with

that of the dung, let us see how the urine of the common farm animals

compares in the matter of the composition of its dry substance. The

following results (basing our calculations on Stoeckhardt's figures,

previously given) show this:--

Nitrogen, Phosphoric acid, Alkalies,

per cent. per cent. per cent.

Pig 12.0 5 8

Horse 10.9 trace 13.6

Sheep 10.4 3.7 14.9

Cow 10.0 trace 17.5

From these figures we see that the dry substance of the urine of the pig

is richest in nitrogen and phosphoric acid, but poorest in alkalies, of

the four common farm animals; that of the horse comes next in the amount

of nitrogen it contains, but that, on the whole, there is very little

difference between the horse, cow, and sheep in this respect.[136]

As in the case of the dung, this subject is best studied in relation to

the food consumed. We are again indebted to Wolff's investigations for

valuable information on this point. He has found that the following

percentages of _organic matter_, _nitrogen_, and _mineral substances_,

originally present in the dry matter of the food, are voided in the

urine:--

Cow. Ox. Sheep. Horse. Average

Organic matter 4.0 4.4 2.0 3.3 3.4

Nitrogen 31.0 54.8 42.3 60.7 47.2

Mineral substances 43.1 34.3 41.0 37.5 39.0[137]

We have now considered briefly the composition of the solid excrements

and urine of the common farm animals, and have also enumerated some of

the principal causes of the variation in their composition.

The solid excreta consist, as we have seen, of _undigested_ food, while

the urine contains the manurial ingredients of the food which have been

_digested_ by the animal system.[138] The latter is, weight for weight,

as a rule, very much more valuable as a manure than the former. From

the table given in the Appendix[139] it will be seen that the

proportions of the nitrogen and ash-constituents originally present in

the food consumed, which are voided in the excrements, vary with

different circumstances. Wolff, in summarising his results, points out

that, as a rule, the solid and liquid excrements will contain about 46

per cent of the organic matter, 87.3 of the nitrogen, and 98.7 of

mineral matter; while the experiments of Lawes and Gilbert at Rothamsted

show that, with fattening oxen and sheep and with horses, more than 95

per cent of the nitrogen and 96 per cent or more of the ash-constituents

are voided in the manure. The pig retains a larger proportion of the

nitrogen--about 85 per cent appearing in the manure--while in the

milking-cow only about 75 per cent is returned in the excrements.

Generally speaking, we may say that the nitrogen originally present in

the food suffers very little loss in passing through the animal system,

and that, practically speaking, the ash-constituents suffer no loss

whatever.

As to the distribution of the manurial ingredients, much will depend on

the nature of the food. Almost invariably more than a _half_ of the

total nitrogen excreted will be found in the urine, in many cases very

much more.[140] Of the mineral constituents, about a third on the

average may be said to be excreted in the urine. Of this mineral matter

it may be noted that nearly all the alkalies (potash and soda), or about

98 per cent, are found in the urine. Of phosphoric acid and lime, on the

other hand, there are the merest traces in the urine. Horse-urine,

however, is an exception with regard to lime, as it contains about 60

per cent of the lime consumed in the food. For information on the

subject of pig-manure the reader is referred to Appendix, Note V.[141]

Before passing from this part of the subject, it may be desirable to

place before our readers the composition of the dung and urine taken

together, so that we may be able to form some idea of their relative

value, weight for weight. As the nitrogen constitutes by far the most

valuable portion of the manurial ingredients, it will be sufficient if

we compare them as to their percentage of this ingredient.

Water, Nitrogen, Calculated on

per cent. per cent. dry substance, Analyses by

per cent.

Sheep 67 .91 2.7 Juergensen.

Horse 76 .65 2.7 Boussingault.

Pig 82 .61 3.4 Boussingault.

Cow 86 .36 2.6 Boussingault.

From these figures we see that, in their natural condition, the excreta

of the sheep are the most valuable; those of the horse and pig coming

next; while those of the cow are the poorest, containing one-third as

much nitrogen as those of the sheep, and one-half as much as those of

the horse and pig. This difference, however, is due almost entirely to

the different percentage of water the excreta of the various animals

contain in their natural state; for in the dry state they are seen to

contain, with the single exception of the pig, practically the same

amount.

In conclusion, then, the important points to be noticed are--

1. That in the passage of the food through the system of the common farm

animals, only a very small percentage of the fertilising substances,

nitrogen, phosphoric acid, and potash, is assimilated and retained in

the animal body; and that, therefore, theoretically at least, the

excreta should contain nearly the same amount of fertilising matter as

the food originally did.

2. That even in the case of a fattening animal, the loss of fertilising

matter sustained by the food in passing through the system is not great.

3. That with regard to the total amount of solid excreta and urine

voided, the latter contains, as a rule, more nitrogen than the former;

the nitrogen in the urine, further, being more valuable, as it is in a

soluble condition.

4. That as regards the distribution of the ash-constituents, _lime_,

_phosphoric acid_, and _magnesia_ are almost entirely found in the solid

excrements; while the urine contains nearly all the _potash_.

5. That the best results can be expected only when the liquid and solid

excreta are used together as a manure.

As the composition of the manure depends so largely on the nature of the

food, a table will be found in the Appendix, Note VI.,[142] containing

the manurial composition of some of the commoner feeding-stuffs.

3. _Litter._

We have now to consider the third constituent of farmyard manure--viz.,

the _litter_, which generally consists of straw.

The uses of the litter, in addition to providing a dry and comfortable

bed for the animal, may be briefly summed up as follows:--

1. To absorb and retain the liquid portion of the excreta.

2. To increase the quantity of the manure, and thus secure its more

equal distribution when applied to the field than could otherwise be

done.

3. To add to its value as a manure, both physically and chemically.

4. To retard and regulate the decomposition of the excreta.

Of course litter also performs a very useful function sanitarily,

inasmuch as it serves to keep the stall or byre fresher and cleaner, and

more free from noxious gases, which it absorbs, than would otherwise be

the case.

_Straw_ is almost universally used for this purpose. Besides being one

of the bye-products of the farm, it is admirably suited in many ways,

both owing to its peculiar shape--its tubular structure being

excellently adapted for this purpose--as well as on account of its

composition, being largely composed of cellulose, a very absorptive

substance. Straw thus possesses considerable absorptive power. In

manurial ingredients it is not very rich; for, of the various parts of

the ripened plant, straw contains the least percentage of nitrogen and

phosphates. This is due to the fact that, as the straw ripens, a

considerable proportion of these ingredients passes up from the stalk to

the seeds, where they are retained.

Generally speaking, straw may be said to contain not more than _a half

per cent_ of nitrogen--_i.e._, 11.2 lb. per ton. Its percentage of

nitrogen varies, of course; the recorded analyses[143] for wheat-straw

ranging from .22 to .81 per cent, or furnishing an average of .48 per

cent--_i.e._, 10.75 lb. per ton. Barley-straw is somewhat richer in

nitrogen, the recorded analyses ranging from .41 to .85 per cent, or

giving an average of .57 per cent--_i.e._, 12.76 lb. per ton; while

oat-straw is the richest of the commoner straws, ranging from .32 to

1.12 per cent, an average of .72 per cent--_i.e._, 16.12 lb per ton.

Of mineral matter, however, straw contains a very much larger

percentage, proportionally, than of nitrogen; for, with the exception of

phosphates, there is a considerable quantity of inorganic fertilising

matter, in the shape of potash, lime, &c., present in

Composition of Straw.[144]

-----------------+---------------+------------------------+--------

| Ash. | Composition of Ash. |

+------+--------+------------------------+

| | | Lb. per ton. |

| | Lb. |-------+----------+-----| Number

| Per | per |Potash.|Phosphoric|Lime.| of

| cent.| ton. | | Acid | |Analyses

-----------------+------+--------+-------+----------+-----+--------

Wheat (winter) | 5.54 | 124.09 | 18.61 | 5.05 | 7.18| 8

Wheat (summer) | 5.14 | 115.13 | 25.76 | 6.47 | 7.12| 6

Rye (winter) | 5.33 | 119.39 | 20.61 | 5.89 | 9.73| 8

Rye (summer) | 6.14 | 137.53 | 42.41 | 6.73 |10.53| 1

Barley | 4.90 | 109.76 | 26.83 | 5.75 | 8.73| 8

Oats | 5.09 | 114.01 | 26.22 | 4.17 | 9.12| 4

-----------------+------+--------+-------+----------+-----+--------

it. Of total ash ingredients, on an average, there are generally about 5

per cent--or 112 lb. per ton. The largest percentage of the fertilising

matter in this 5 per cent is potash, which varies in the ashes of the

straws of the commoner crops from 30 to 15 per cent. The above table

will show the variation in composition of the straws of some of the

commoner farm crops, and may be valuable for purposes of reference. The

crops are wheat (winter and summer), barley, oats, and rye (winter and

summer), and the amount is also calculated in lb. per ton. The results

represent the average of a number of analyses.[145] From the table it

will be seen that the percentage of phosphates is, as has already been

noticed, very small.

But while straw is well adapted for the purposes for which litter is

used, it is not the only substance. Its almost exclusive use as litter

is largely owing to the fact that it is a bye-product of the farm.

_Loam as Litter._--Generally speaking, any substance which has great

absorptive as well as retentive powers for nitrogen and the soluble

fertilising matters present in farmyard manure, and whose price is

nominal, is well suited for acting as litter. Ordinary loamy soil

possesses the above qualifications, and is, besides, a substance to be

had for nothing, and, under certain circumstances and in certain

countries, is actually used for this purpose, often along with straw. A

great objection against loam, however, is that it forms a dirty litter.

Moreover, it possesses a very small percentage of fertilising matter.

The tendency, consequently, in using ordinary loam, would be to dilute

the manure too much, besides retarding fermentation to an undesirable

extent. Except, therefore, under very exceptional circumstances, loam is

not to be regarded as a good litter.

_Peat as Litter._--Some kinds of soil, however, are well suited for this

purpose. Of these, the best are those rich in organic matter, the

so-called peaty soils. Peat, when dried and freed from any earthy

matter, forms an excellent absorbent of the liquid portion of the

manure, surpassing in this respect straw itself. It is, further,

generally very much richer in nitrogen--some peats having been found to

contain between 4 and 5 per cent of nitrogen. In some thirty samples of

peat analysed by Professor S. W. Johnson, the percentage of nitrogen

varied from .4 to 2.9, giving an average of 1.5 per cent.

While it has a very great capacity for absorbing liquids, it possesses

in an unequalled degree the power of retaining the soluble nitrogen

compounds. This is undoubtedly one of the most important properties

which recommend peat for the purposes of litter.[146]

Some interesting experiments on the value of peat-moss as a litter have

been recently carried out by Dr Bernard Dyer.[147] From these

experiments Mr Dyer has found that both its liquid-absorbing and

liquid-retaining powers are very much greater than those of straw. While

straw was only able to absorb three times its weight of water, peat-moss

was found to absorb nearly ten times its weight. With regard to its

water-retaining power, this was also found to be in excess of that of

straw. Both these properties are, it need scarcely be pointed out, of

very great value in a litter. Another point of interest in these

experiments was the respective amounts of nitrogen absorbed and retained

by the peat-moss and the straw. It was found that, in this respect, the

peat-moss had again an advantage over the straw. Lastly, the manure

produced by the peat-moss was shown to be richer in fertilising matter

than that produced by the use of straw.[148] These experiments are

interesting as demonstrating the fact that in peat-moss we have a

substance which is capable of acting as an excellent substitute for the

more costly straw, and which might increasingly be used as a fodder with

great benefit to the farmer.

Another substance which has been suggested as an excellent litter is the

common _bracken-fern_. According to some analyses made by Mr John

Hughes, the bracken, especially if cut in a young state, is a substance

of considerable manurial value. When dried, it is very much richer in

nitrogen, potash, and lime than straw. Its absorbent properties,

however, are probably not so great. Where it can easily and cheaply be

had, as in many parts of Scotland and Ireland, it might well be used for

littering purposes.[149]

_Dried leaves_ have also been used as a litter. Autumn leaves, however,

contain a very small percentage of fertilising matter. This is due to

the fact that the most of their potash, phosphoric acid, and nitrogen

pass into the body of the trees at the approach of winter. According to

Professor Storer, dried leaves only contain from .1 to .5 per cent

potash,.006 to .3 per cent phosphoric acid, and about .75 per cent of

nitrogen. Leaves, however, besides being poor in manurial ingredients,

make a bad litter, as they ferment but slowly. There is in this

fermentation a large quantity of cold sour humic acid formed, which

seriously impairs the value of the manure.[150]

Having now considered the composition of the three separate ingredients

of farmyard manure--viz., the _dung_ or _solid excreta_, the _urine_,

and the _litter_--we are in a position to consider the composition of

farmyard manure. In this connection it will be well to consider

separately the manures produced by the different farm animals.

1. _Horse-manure._

The composition of horse-manure is perhaps the most uniform of all the

manures produced by the different farm animals. This is due to the fact

that the food of the horse is generally of the same kind, consisting of

oats, hay, and straw.

The total excrements voided by a horse in a day have been calculated,

according to the average of experiments by Boussingault and Hofmeister,

at 28.11 lb., of which only 6.37 lb. consisted of dry matter.[151] These

28.11 lb. contained .18 lb. of nitrogen and .92 lb. of mineral matter.

The amount of straw necessary to absorb this amount of excrement may be

stated at from 4 to 6 lb. The amounts of nitrogen and mineral matter in

4 lb. of straw are .01 and .23 lb. respectively. The total amount of

nitrogen and ash, therefore, in the farmyard manure produced by a horse

in one day, would be .19 lb. nitrogen and 1.15 lb. mineral matter; or,

if we take the larger quantity of straw, somewhat more.

Taking these figures, we find that the amount of manure produced by a

horse in a year will be from 11,720 to 12,450 lb. (_i.e._, from 5-1/4

to 5-1/2 tons),[152] containing from 69 to 73 lb. nitrogen, and from 420

to 460 lb. mineral matter.[153]

A word or two may be of value regarding the treatment in the stable of

horse-manure. The great object to be aimed at is the prevention of loss

of valuable fertilising constituents. This loss may be due to two

causes. It may be, in the first place, caused by drainage of the soluble

matter of the manure; or secondly, it may be due to volatilisation of

the volatile constituents.

The first of these two sources of loss depends on the precautions taken

in the way of providing a proper impervious flooring to the stable. This

source of loss is extremely difficult to prevent, inasmuch as nearly all

materials used for flooring absorb a certain percentage of urine. The

judicious use of litter, however, will minimise this loss to within a

trifling extent.

Dr Heiden states that the amount of straw used as litter for the horse

in Germany is from 4 to 6 lb. per day. The quantity should be regulated

according to the percentage of water the excreta contain; the more

watery excreta requiring naturally a larger quantity of litter. The most

eminent authorities on this subject recommend that the amount of litter

should equal one-fourth of the food in its natural state, or about

one-third of its dry substance.

The second source of loss, which is due to volatilisation of the

volatile ingredients, may be largely prevented by the use of certain

preservatives.

Horse-dung being, comparatively speaking, of a dry nature, it is

extremely difficult to effect its thorough mixture with the litter. For

this reason the manure formed from horse excreta is particularly liable

to rapid fermentation.[154] In the process of fermentation, as will be

seen more in detail further on, the nitrogen is converted into carbonate

of ammonia. As nitrogen in this form is of an extremely volatile nature,

the risks of loss from this source are considerable. As illustrating

this fact, it may be mentioned that Boussingault has found by experiment

that the total percentage of nitrogen contained by fresh horse-manure

might be reduced in the process of fermentation to one-half of its

original amount by loss from this source.

The preservatives used to prevent this volatilisation are technically

known as "fixers." This they do by chemically combining with the

volatile ammonia and forming non-volatile compounds with it.

Of the acid fixers, hydrochloric and sulphuric acids have been

recommended. The former, however, is not well suited for this purpose.

It is a strongly fuming acid, and when brought into contact with

ammonia forms dense white fumes. The use of sulphuric acid is not open

to this objection. Sulphate of ammonia, the salt formed in this case, is

one of the most stable (or least volatile) of the compounds of ammonia.

If used, it should be largely diluted with water, and the whole mixed

with sand. Such a mixture, when sprinkled over the stable-floor in even

very small quantities, has been found to effectually prevent any loss of

the volatile carbonate of ammonia.

It is not, however, on the whole advisable to use an acid substance as a

fixer, since such a substance may act deleteriously on the horses'

hoofs.

Such substances as _gypsum_, _copperas_, and _sulphate of magnesia_,

while equally efficient, are not open to this objection. The

above-mentioned substances owe their efficacy to the fact that they are

compounds of sulphuric acid, which, by combining with the volatile

ammonia and forming sulphate of ammonia, prevent its escape.

Gypsum, or sulphate of lime, although, comparatively speaking, an

insoluble substance, when brought in contact with carbonate of ammonia

has been proved to effect the conversion of the ammonia into sulphate of

ammonia. It is also believed to retard the decomposition of the

manure.[155] Copperas, or ferrous sulphate, while a soluble salt, and

while thus acting in a more speedy manner in fixing the ammonia, is not

so well suited, owing to the hurtful influence it is well known to

possess on plant-life. It is only right to remember that there may be

circumstances in which copperas may, in small quantities, act even

beneficially as a manure, as Griffiths' experiments would seem to

indicate. The above objection, however, cannot be urged against sulphate

of magnesia. In addition to fixing the ammonia, sulphate of magnesia may

very probably fix the soluble phosphoric acid. Kainit, which consists of

a mixture of sulphates and chlorides of potassium and magnesium, has

also been suggested for this purpose. By using such a fixer, the value

of the resulting manure would be much enhanced. In conclusion, it must

be remembered that all the above-named fixers act very much in the same

way--viz., by converting the volatile carbonate of ammonia into sulphate

of ammonia.[156]

2. _Cow-manure._

The composition of the manure formed from the excrementitious matter of

the cow is very much less constant than is the case in the horse-manure.

An average statement of that composition is therefore very much more

difficult to obtain. The number of analyses available for the purpose of

forming this average is, however, very large. The manure produced by

cows contains a large percentage of water. This is due to the large

quantity of water they drink. It has been estimated that milch-cows

drink along with their winter food, for every pound of dry substance, 4

lb. of water, and in summer about 6 lb.

According to some experiments by Boussingault, the excrements of a cow

in a day amounted to 73.23 lb., of which only 9.92 lb. were dry

matter.[157] These excrements contained .256 lb. of nitrogen and 1.725

lb. of mineral matter. The amount of straw necessary to use as litter

for this amount of excrements may be taken at 6 to 10 lb. The manure,

therefore, formed by a cow per day, would contain from .274 to .286 lb.

of nitrogen, and from 2.046 to 2.278 lb. of mineral matter. In a year

this would amount to from 100 to 104.4 lb. of nitrogen, and from 746.8

lb. to 831.5 lb. of mineral matter; or from 6 cwt. 75 lb. to 7 cwt. 47

lb.

Cow-dung is, owing to its more watery nature and poorer quality, very

much slower in its fermentation than horse-dung. When applied alone,

cow-manure is very slow in its action, and makes its influence felt for

at least three or four years. It is difficult to spread it evenly over

the soil, owing to the fact that, when somewhat dried, it has a tendency

to form hard masses, which, when buried in the soil, may resist

decomposition for a very long period. The cause of this is due to the

presence of a considerable amount of mucilaginous and resinous matter in

the solid excreta, which prevents the entrance of moisture and air into

the centre of the mass. This tendency of cow-manure to resist

decomposition will be greatly lessened in the case of the excrements of

a cow richly fed.

The risks of loss of volatile ammonia are, therefore, in its case not so

great as we have seen them to be in the case of the "hot" horse-dung.

Notwithstanding this fact, much of what has been said on the use of

preservatives for horse-manure may be also applied to the cow-dung. This

is owing to the fact that the dung is allowed to accumulate in the court

for some time. The amount of straw it is advisable to use as litter

varies, as has been said, from 6 to 10 lb. per day. The best method of

calculating this amount, according to Dr Heiden, is by taking one-third

of the total weight of the dry substance of the food. The above

authority also recommends that the straw is best applied in blocks of

about one foot in length; and this for the following reasons:--

1. The strewing of it is more convenient.

2. The absorption of the fluid portion is more complete.

3. The cleaning out of the manure from the byre is easier.

4. The manure is more easily distributed when applied to the field.

Among the advantages incidental to allowing the manure to accumulate in

the court may be mentioned the following:--

1. The more thorough absorption of the urine by the straw, and,

consequently, the more uniform mixture which will be thus effected of

the more valuable urine with the less valuable solid excreta.

2. A certain retardation of decomposition effected by the treading under

foot of the manure.

3. The protection of the manure from rain and wind, and the securing of

a uniform temperature.

Against those advantages must be placed the risk of seriously affecting

the health of the animal. Although this is a point of very great

importance, it scarcely falls within the scope of this work. It may be

pointed out, however, that the judicious use of some of the chemical

fixers previously referred to may do much to keep the air of the byre or

court free of noxious gases.[158]

3. _Pig-manure._

The food of the pig is so very variable in its character that it is

wellnigh impossible to obtain anything like an average analysis of its

excrements. When the food of the pig is rich, then the manure may be

quite equal in quality to the other manures. According to Boussingault,

the total amount of excrements, on an average, voided by a pig in

twenty-four hours is about 8.32 lb., of which 1.5 lb. is dry

matter.[159] The amount of nitrogen these excrements contain is only .05

lb., and of mineral ingredients .313 lb. If we take the amount of straw

most suitable for absorbing this quantity of excrementitious matter at

from 4 to 8 lb., then we shall find that the manure produced by a pig

will contain from .06 to .074 lb. nitrogen and .545 to .772 lb. mineral

matter. These quantities, calculated for a year, give from 22 to 27 lb.

of nitrogen, and from 1 cwt. 87 lb. to 2 cwt. 57 lb. of mineral matter.

That is about as much nitrogen as would be contained in 1-1/4 to 1-1/2

cwt. of nitrate of soda (95 per cent purity); or from slightly less than

1 cwt. to slightly over 1 cwt. of sulphate of ammonia (97 per cent

purity).

As has already been pointed out, the excrements of the pig are, as a

rule, very poor in nitrogen. This accounts for the fact that pig-manure

is a "cold" manure, slow in fermenting.[160]

4. _Sheep-manure._

The dung and the urine of the sheep, as we have already seen, are,

weight for weight, the most valuable of any of the common farm animals.

The total weight of the excrements voided by a sheep in a day may be

taken, on an average,[161] at 3.78 lb., of which .97 lb. is dry matter.

These excrements contain .038 lb. of nitrogen and .223 lb. mineral

matter. Taking the amount of straw most suitable for absorbing this

quantity of excrementitious matter at three-fifths of a pound, then the

manure produced by a sheep in a day will contain .0429 lb. nitrogen and

.264 lb. mineral matter. That is, in a year the quantities of nitrogen

and mineral matter in the manure produced by a sheep would be 15.66 lb.

of nitrogen and 96.36 lb. of mineral matter.

From its richness in nitrogen, and from its dry condition, sheep-dung is

peculiarly liable to ferment. While richer in fertilising substances

than horse-manure, it is not so rapid in its fermentation. This is due

to the harder and more compact physical character of the solid excreta.

The risks of loss of volatile ammonia are, in its case, exceptionally

great. The use of artificial "fixers" is therefore to be strongly

recommended.[162]

_Fermentation of Farmyard Manure._

Having now considered the nature of the different manures produced by

the four common farm animals separately, it is of importance to consider

the exact nature of the fermentation, decomposition, or putrefaction

which takes place in the manure-heap.

It is now more than thirty years since Pasteur showed that the

fermentation which ensued on keeping a sample of urine was due to the

action of a minute organism, for the propagation of which a certain

amount of warmth, air, and moisture, as well as the presence of certain

food-constituents, especially nitrogenous bodies, were necessary.

Subsequent researches by Pasteur and others have conclusively

demonstrated that the micro-organic life instrumental in effecting the

putrefaction or decay of organic matter of any kind, may be divided into

two great classes:--

1. Those which require a plentiful supply of oxygen for their

development, and which, when bereft of oxygen, die--known as _aerobies_.

2. Those which, on the contrary, develop in the complete absence of

oxygen, and which, when exposed to oxygen, die--known as _anaerobies_.

In the fermentation of the manure-heap, therefore, we must conceive of

the two classes of organisms as the active agents. In the interior

portion of the manure-heap, where the supply of oxygen is necessarily

limited, the fermentation going on there is effected by means of the

anaerobic organism--_i.e._, the organism which does not require oxygen;

while on the surface portion, which is exposed to the air, the aerobic

(or oxygen-requiring) organism is similarly active. Gradually, as decay

progresses, the aerobic organisms increase in number. It is through

their instrumentality that the final products of decomposition are

largely produced. The functions of the anaerobic organisms may be, on

the contrary, regarded as largely preparatory in their nature. By

breaking up the complex organic substances in the manure into new and

simpler forms, they advance the process of putrefaction through the

initial stages; and when this is accomplished, they die and give place

to the aerobic, which, as we have just seen, effect the final

transformation of the organic matter into such simple substances as

_water_ and _carbonic acid gas_.

The conditions influencing the fermentation of farmyard manure may be

summed up as follows:[163]--

1. _Temperature._--The higher the temperature the more rapidly will the

manure decay.

2. _Openness to the Air._--Of course it will be seen that the effect of

exposing the manure to the action of the air is to induce the

development of the aerobic type of organism, and thus to promote more

rapid fermentation. If, on the other hand, the manure be impacted, the

slower but more regular fermentation, due to the anaerobic type of

organism, will be chiefly promoted. It must be remembered that in the

proper rotting of farmyard manure both kinds of fermentation should be

fostered. It is, in fact, on the careful regulation of the two classes

of fermentation that the successful rotting of the manure depends. It

must further be remembered that, even with a certain amount of openness

in a manure-heap, anaerobic fermentation may take place. This is due to

the fact that the evolution of carbonic acid gas, in such a case, is so

great as to exclude the access of the atmospheric oxygen into the pores

of the heap.

3. The _dampness_ of the manure-heap is another important influence.

This, of course, will act in two ways. First, by lowering the

temperature. Where the manure-heap is found to be suffering from

"fire-fang," the common method in practice is to lower the temperature

by moistening the heap with water. Secondly, it acts as a retarder of

fermentation by limiting the supply of atmospheric oxygen, and thus

preventing, as we have just seen, aerobic fermentation.

4. The fourth chief influence in regulating fermentation of the

manure-heap is its _composition_, and more especially the amount of

nitrogen it contains in a soluble form. The rate at which fermentation

takes place in any organic substance may be said chiefly to depend on

the percentage of soluble nitrogenous matter it contains: the greater

this is in amount, the more quickly does fermentation go on. There are

always a number of soluble nitrogenous bodies in farmyard manure. These

are chiefly found in the urine, such as _urea_, _uric_ and _hippuric

acids_, and _ammonia_ salts.

_Products of Decomposition of Farmyard Manure._

The most important of the changes which take place in the rotting of

farmyard manure may be briefly enumerated as follows:--

1. The gradual conversion into gases of a large portion of the organic

elements in the manure. Of these gaseous products the most abundant is

_carbonic acid gas_ (CO_2). It is in this form that the carbonaceous

matter which constitutes the chief portion of the manure escapes into

the air. Carbon also escapes into the air, combined with hydrogen, in

the form of _carburetted hydrogen_ or _marsh-gas_ (CH_4), a product of

the decomposition of organic matter in the presence of a large quantity

of water. This gas is consequently found bubbling up through stagnant

water. Next to carbonic acid gas, _water_ (H_2O) is the most abundant

gaseous product of decomposition. The nitrogen present in the manure, in

different forms, is converted by the process of decomposition chiefly

into _ammonia_, which, combining with the carbonic acid, forms carbonate

of ammonia, a very volatile salt. It is to this fact that one of the

great sources of loss in the decomposition of farmyard manure is due. If

the temperature of the manure-heap be permitted to rise too high, the

carbonate of ammonia volatilises. It is probable, also, that a not

inconsiderable portion of the nitrogen escapes into the air in the free

state. The last of the most important gaseous products of decomposition

are _sulphuretted_ and _phosphoretted hydrogen_. It is to these gases

that much of the smell of rotting farmyard manure is due.

2. The second class of substances formed are _soluble organic acids_,

such as _humic_ and _ulmic acids_. The function performed by these acids

is a very important one. They unite with the ammonia and the alkali

substances in the mineral portion of the manure, forming humates and

ulmates of ammonia, potash, &c. It is these ulmates that form the black

liquor which oozes out from the manure-heap.

In very rotten farmyard manure traces of _nitric acid_ may be found; but

it must be remembered that the formation of nitrates is practically

impossible under the ordinary conditions of active fermentation of

farmyard manure, except perhaps in its very last stages.

3. The third class of changes taking place have to do with the mineral

portion of the manure. The result of the formation of so much carbonic

and other organic acids is to increase the amount of _soluble_ mineral

matter very considerably.

_Analyses of Farmyard Manure._

It is chiefly to the valuable researches of the late Dr Augustus

Voelcker that we owe our knowledge of the composition of old and fresh

farmyard manure. All interested in this important question should peruse

the original papers on this subject contributed to the 'Journal of the

Royal Agricultural Society' by Dr Voelcker. Typical analyses

illustrating the variation in the composition of farmyard manure at

different stages of decomposition will be found in the Appendix.[164]

From what has been already said, it is obvious chat the composition of

farmyard manure is of a very variable nature.

The quantity of moisture naturally varies most, and this variation will

depend on the age of the manure, and the conditions under which it is

permitted to decay. It may be taken at from a minimum of 65 per cent in

fresh to 80 per cent in well-rotted manure. The total organic matter may

be taken at from 13 to 14 per cent, containing nitrogen .4 to .65 per

cent. The total mineral matter will range from about 4 to 6.5 per cent,

containing of potash from .4 to .7 per cent, and of phosphoric acid from

.2 to .4 per cent.[165]

As Mr Warington[166] has pointed out, one ton of farmyard manure would

thus contain 9 to 15 lb. of nitrogen, about the same quantity of potash,

and 4 to 9 lb. of phosphoric acid. These quantities of nitrogen and

phosphoric acid, calculated to (95 per cent) nitrate of soda, and (97

per cent) sulphate of ammonia, and (25 per cent) superphosphate, give

respectively 57.25 to 96 lb. nitrate of soda, 45 to 75 lb. sulphate of

ammonia, and 35 to 79 lb. superphosphate. That is, in order to apply as

much nitrogen to the soil as is contained in one ton of nitrate of soda,

we should require to use from 23 to 41 tons of farmyard manure:

similarly one ton of sulphate of ammonia contains as much nitrogen as 30

to 50 tons farmyard manure. In the same way one ton of superphosphate

of lime contains as much phosphoric acid as 28 to 64 tons farmyard

manure.

The value of rotten manure is, weight for weight, greater than that of

fresh manure. This is due to the fact that, while the water increases in

amount, the loss of organic matter of a non-nitrogenous nature more than

counterbalances the increase in water. The manure, therefore, becomes

more concentrated in quality. The loss on the total weight, according to

Wolff, in the rotting of farmyard manure, should not exceed in two or

three months' time 16 to 20 per cent--viz., a sixth to a fifth of its

entire weight. Not only, however, does the manure become richer in

manurial ingredients, but the forms in which the manurial ingredients

are present in rotten manure are more valuable, as they are more

soluble. These statements must not be taken as proving that it is more

economical to apply farmyard manure in a rotten condition than in a

fresh one. The distinction must not be lost sight of which exists

between relative increase--increase in the percentage of valuable

constituents--and absolute increase. The increase in the value of the

manure by the changes of the manurial ingredients from the insoluble to

the soluble condition may be effected at the expense of a considerable

amount of absolute loss of these valuable ingredients. This is a point

which is probably too often left out of account in discussing the

relative merits of fresh and rotten farmyard manure; and it is

important that it should be clearly understood. In the words of the late

Dr Voelcker: "Direct experiments have shown that 100 cwt. of fresh

farmyard manure are reduced to 80 cwt. if allowed to lie till the straw

is half rotten; 100 cwt. of fresh farmyard manure are reduced to 60 cwt.

if allowed to ferment till it becomes 'fat or cheesy'; 100 cwt. of fresh

farmyard manure are reduced to 40-50 cwt. if completely decomposed. This

loss not only affects the water and other less valuable constituents of

farmyard manure, but also its most fertilising ingredients. Chemical

analysis has shown that 100 cwt. of common farmyard manure contain about

40 lb. of nitrogen, and that during fermentation in the first period 5

lb. of nitrogen are dissipated in the form of volatile ammonia; in the

second, 10 lb.; in the third, 20 lb. Completely decomposed common manure

has thus lost about one-half of its most valuable constituent."[167]

While, of course, a very great amount of absolute loss of the valuable

constituents--the nitrogen and ash-constituents--of farmyard manure may

take place through volatilisation and drainage, by taking requisite

precautions this loss may be very much minimised. As regards the total

loss, this, in two or three months' time, should only amount to 16 to 20

per cent--or one-sixth to one-fifth of the weight.[168] The use of

fixers, to which reference has already been made, will greatly minimise

this loss. The application of fixers is best made to the manure when

still in the stall or byre. The health of the animal benefits by so

doing, while the manure is at once guarded against loss from this

source.

As to the relative merits of covered and uncovered manure-heaps, much

difference of opinion exists. It is one of those questions which does

not admit of final decision one way or another, as it depends so largely

on the individual circumstances of each case. That manure produced under

cover is more valuable than manure made in the open is readily granted.

The question, however, is as to whether the increase in its value is

sufficiently great to warrant the extra expense involved in building

covered courts. This depends on the individual circumstances of each

case, and cannot be decided in a general way. For experiments on the

relative value of manure made under cover and in the open, see

Appendix.[169]

The method of applying farmyard manure to the field is a question which

belongs more to the practical farmer than, to the scientist, and must be

largely decided by economic considerations. There is an aspect, however,

of the question which may well be treated here. The first point in the

production of good manure is in connection with its even distribution.

It is of great importance that the excrements of the different farm

animals be thoroughly mixed together. By the intimate incorporation of

the "hot" horse-dung with the "cold" cow and pig dung, uniform

fermentation is secured. Fire-fang--or too rapid fermentation--may occur

from this not being properly done, and from the manure becoming too dry.

It is important, also, as we shall see immediately, to have the manure

uniform in quality when applied to the field. The manure ought to be

firmly trodden down, to moderate the rate of fermentation. Where the

manure-heap is exposed to rain, the quantity of water it will naturally

receive will probably be quite sufficient, if indeed not too much, to

ensure a proper rate of fermentation--except, perhaps, in very warm

weather. The great point to be aimed at is to ensure regular

fermentation. What has to be especially avoided is any sudden exposure

of the manure to large quantities of water. The result of such a

washing-out of the soluble nitrogen is to retard fermentation, besides

incurring the risk of great actual loss by drainage.[170]

_Application of Farmyard Manure to the Field._

In applying the manure to the field, and before ploughing it in, two

methods of procedure may be pursued. First, the manure may be set out in

heaps, larger or smaller, over the field, and be allowed to remain in

these heaps some time before being spread; and secondly, it may be

directly spread broadcast over the field, and thus allowed to lie for

some time. Lastly, the manure may be ploughed in immediately; and it may

be stated that such a method is, where circumstances permit, the safest

and most economical method.[171]

In discussing the merits and demerits of these two methods, Dr Heiden

points out, first, with regard to the distribution of the manure in

small heaps over the field, that this is not to be recommended, on the

following grounds:--

1. Because the chances of loss by volatilisation are thereby increased.

The manure is distributed several times instead of only once or twice.

2. It is apt to ensure unequal distribution. The separate heaps run the

risk of losing their soluble nitrogenous matter, which soaks into the

ground beneath the heaps. The other portions of the field not covered by

the manure-heaps are thus manured with washed-out farmyard manure,

bereft of its most valuable constituents. The result is, that while

certain portions of the field are too strongly manured, other portions

are too weakly manured.

3. The proper fermentation of the manure is apt to be interfered with by

the loss of that which is its most important agent--viz., the soluble

nitrogenous matter--and also by the drying action of the wind.

The same objections hold good to a large extent with regard to the

setting out in the fields of the manure in large heaps. The risks of

loss, in one respect, may be said to be less, owing to the smaller

surface presented. On the other hand, they may be greater, owing to

fermentation taking place more quickly. Agricultural practice, however,

often renders this custom necessary; and if precautions are taken not to

let the heap lie too long, and to cover it over with earth, the risk of

serious loss may be rendered inconsiderable.

With regard to the second method of procedure--viz., the spreading of

the manure broadcast over the field, and allowing it thus to lie--Dr

Heiden is of opinion that this should only be done when the field is

level. In the case of uneven ground the risks are, of course, obvious.

It has been affirmed that, by allowing farmyard manure thus to lie

exposed for some time, an important loss of volatile ammonia--carbonate

of ammonia--is apt to take place. This could only take place where the

former treatment of the farmyard manure had been bad. Hellriegel has

shown that in the case of properly prepared farmyard manure there is no

danger of loss in this way. The absorptive power of the soil for

ammonia, it must be remembered, is very great, and the amount of

volatile ammonia in farmyard manure is relatively so small that it is

scarcely possible that any could escape in this way. Hellriegel's

experiments have demonstrated this in a very striking way. He has found

that in the case of a chalky soil, and during the summer and autumn

months, practically no loss of ammonia takes place. The following

considerations may be further urged in support of this method of

application, as against immediately ploughing in the manure, viz.:--

1. That fermentation takes place more quickly.

2. That it results in a more equable distribution of the manurial

constituents in the dung, by gradually and thoroughly incorporating the

liquid portion of the manure with the soil-particles.

Against, however, these undoubted advantages, one serious disadvantage

may be urged--viz., that the manure, before being ploughed in, becomes

robbed to a large extent of its soluble nitrogenous compounds, which, as

we have repeatedly observed, are so necessary for fermentation; and

that, therefore, when it is ploughed in, it does not so readily ferment.

This being so, it is highly advisable, in the case of light or sandy

soils, not to follow such a practice, but to plough the manure directly

in.

As to the depth to which it is advisable to plough the manure in, it may

be here noticed that it should not be too deep, so as to permit of the

access of sufficient moisture to ensure proper fermentation, and to

prevent rapid washing down of nitrates to the drains. Lastly, it need

scarcely be pointed out that it is highly important to have the manure

evenly and thoroughly incorporated with the soil-particles. Where the

manure is permitted to cake together in lumps, it may successfully

resist the action of fermentation for several years.

_Value and Function of Farmyard Manure._

Practical experience has long demonstrated the fact that farmyard manure

is, taking it all round, the most valuable, and admits of the most

universal application, of all manures; and science has done much to

explain the reason of this. The influence of farmyard manure is so

many-sided that it is difficult even to enumerate its different

functions. As has already been pointed out, its indirect value as a

manure is probably as great as, if indeed even not greater than, its

direct value. In concluding our study of farmyard manure, we shall

endeavour to summarise, in as brief a manner as possible, its chief

properties.

First, as to its value as a supplier of the necessary elements of

plant-food. This, there can be little doubt, has been, and still is,

grossly exaggerated by the ordinary farmer. Much has been claimed for it

as a "general" manure. How far it merits pre-eminence on this score

among other manures will be seen in the sequel. It is true that, since

it is composed of vegetable matter, it contains all the necessary plant

ingredients.[172] As has been shown in the Introduction, there is

practically in the case of most soils no necessity to add to a manure

any more than the three ingredients, _nitrogen_, _phosphoric acid_, and

_potash_. Its value, then, as a direct manure, must depend on the

quantity and proportion in which these three ingredients are present.

These substances, as we have already seen, it contains only in very

small quantities. It is, judged from this point of view, a comparatively

poor manure. Furthermore, only a certain percentage of these substances

is in a soluble or immediately available condition,--in this respect the

rotten manure being very much more valuable than the fresh manure.

Again, a point of great importance in a universal manure is the

proportion in which the necessary plant-foods are present. If it be

asked, Are the nitrogen, phosphoric acid, and potash in farmyard manure

present in the proportion in which crops require these constituents? the

answer must be in the negative. Heiden[173] has very strikingly

illustrated this point, in so far as the relations between the two ash

ingredients are concerned, by some computations as to the amount which

would be removed from the soil in the course of different

rotations.[174] In the case of five different rotations it was found

that the ratio between the potash and phosphoric acid removed was as

follows:[175] (1) 2.96 to 1; (2) 2.76 to 1; (3) 2.95 to 1; (4) 4.13 to

1; (5) 3.78 to 1. This would give a mean of 3.32 to 1. This is not the

ratio in which these ingredients are generally present in farmyard

manure. Farmyard manure may be said to be much richer in the mineral

constituents of plants than in nitrogen. Professor Heiden found that in

the case of a farm at Waldau, the crops in the course of ten years

removed from a _morgen_ (.631 of an acre) the following quantities:--

lb.

Nitrogen 329

Potash 263

Phosphoric acid 121

In order to supply these amounts the following quantities of manure

would require to be supplied:--

1. For the nitrogen, 26 or 27 tons (manure containing .606 per cent

nitrogen).

2. For the potash, 20 to 25 tons (manure containing .672 per cent

potash).

3. For the phosphoric acid, 13 to 19 tons (manure containing .315 per

cent phosphoric acid).

From the above it will be seen that farmyard manure contains too little

nitrogen in proportion to its ash ingredients.

It is not merely the amount of fertilising ingredients removed by the

crop we have to take into account in estimating the value of certain

manurial ingredients for the different crops. Two other considerations

have to be remembered--viz., the amount of the constituents already

present in the soil, and the ability of the different crops to obtain

the ingredients from the soil. If we take into account these two

considerations in estimating the value of farmyard manure as a general

manure, we shall find that they accentuate the inadequacy of the ratio

existing between the nitrogen and the mineral ingredients. Messrs Lawes

and Gilbert have found in the Rothamsted experiments with farmyard

manure, that while it restored the mineral ingredients, it was

inadequate as a sufficient source of nitrogen. Nitrogen is, of all

manurial ingredients, in least abundance in soils. It is consequently

found that the ingredient in which farmyard manure requires to be

reinforced is nitrogen. With regard to phosphoric acid and potash, it

has already been shown that the ratio between them is probably greater

than that in a good average manure. We should, arguing from this alone,

be inclined to think that farmyard manure would be best reinforced with

potash. The reverse is the case, however, as every farmer knows. This is

due, first, to the fact that the potash, unlike the phosphoric acid, is

entirely of a soluble nature, and therefore immediately available for

the plant's needs; and secondly, to the fact that the necessity for the

application of potash as a manure is generally not nearly so great as in

the case of phosphoric acid. The result is, that farmyard manure will

be, as a rule, more valuably supplemented by phosphoric acid than by

potash.

Another point of great importance, in estimating the value of farmyard

manure as a chemical manure, is the inferior value possessed by much of

the nitrogen it contains, as compared with the nitrogen in such

artificial manures as nitrate of soda and sulphate of ammonia. According

to the Rothamsted experiments, weight for weight, the nitrogen in

farmyard manure is not half so valuable as it is in sulphate of ammonia.

Much of the nitrogen becomes only very slowly available; not a little of

it perhaps actually takes years to be converted into nitrates.[176]

Thus, with regard to the direct value of farmyard manure as a manure, we

have seen--

1. That it contains a very small quantity of the three fertilising

ingredients.

2. That the proportion in which these three ingredients are present is

not the best proportion for the requirements of crops.

3. That the form in which a portion of these ingredients--nitrogen and

phosphoric acid--is present is not of the most valuable kind.

It is consequently not as a direct chemical manure that farmyard manure

is pre-eminently valuable. We must seek for perhaps its most valuable

properties in its indirect influence.

It adds to the soil a large quantity of organic matter. Most soils are

improved by the addition of _humus_. The water-absorbing and retaining

powers of a soil are increased by this addition of _humus_, while it

enables the soil to attract an increased amount of moisture from the

air. This is often of great importance, as in the period of germination

of seed.[177] The influence it exerts on the texture of the soil in the

process of fermentation is also very great. This is especially so in

soils whose texture is too close, such as heavy clayey soils. It opens

up their pores to the air, and renders them more friable. Where such an

influence is most required, as in clayey soils, the manure ought to be

applied in a fresh condition, so that the maximum influence exerted by

the manure in this direction may be experienced. On light soils, on the

contrary, whose friability and openness are already too great, and which

do not require to be increased, the manure will be best applied in a

rotten condition. It adds, further, greatly to the heat of the soils by

its decomposition. Thus on cold damp soils it effects one very marked

benefit. The influence it exerts in its decomposition upon the

fertilising ingredients present in the soil is also by no means

inconsiderable. In the process of its fermentation large quantities of

carbonic acid gas are generated. This carbonic acid probably acts in a

double capacity. It will, in the first place, greatly increase the

solvent power of the soil-water, and thus enable it to set free an

increased amount of mineral plant-food; and secondly, it will help to

conserve a certain quantity of the soil-nitrogen, by preventing its

conversion into nitrates.

As its indirect and mechanical properties are greatest when in its fresh

condition, it will be better to apply it in that condition to soils most

lacking in these mechanical properties. We may therefore say that

farmyard manure is best applied in a rotted condition to light sandy

soils, and to soils in a high state of cultivation, where its mechanical

properties are not so much required.

An important point still remains to be discussed--viz., the rate at

which the farmyard manure should be applied. This, of course, should

naturally depend on a variety of circumstances--the amount of artificial

manures used as supplementary to the farmyard manure, the frequency of

its application, and the nature of the soil.

These considerations naturally vary so much, that the quantities of

farmyard manure it is advisable to apply in different cases are widely

different. There is a strong probability that the rate at which farmyard

manure has been applied in the past has been grossly in excess of what

could be profitably employed. Opinion is gaining ground among practical

farmers, that smaller and more frequent applications of farmyard manure

to the soil would be fraught with better results than the older custom

of applying a large dressing at a time. This is an opinion in the

support of which science can urge strong arguments. It is only of late

years that we have come to recognise sufficiently the various risks

which all fertilisers are subject to in the soil, and the importance,

therefore, of minimising these risks as much as possible by putting into

the soil at one time only as much manure as it is safely able to retain.

"The famous old German writer Thaer regarded 17 or 18 tons as an

abundant dressing; 14 tons he called good, and 8 or 9 tons light. Other

German authorities speak of 7 to 10 tons as light, 12 to 18 tons as

usual, 20 or more tons as heavy, and 30 tons as a very heavy

application."[178]

In the new edition of Stephens' 'Book of the Farm,'[179] from 8 to 12

tons per acre for roots, and from 15 to 20 tons for potatoes, along with

artificials, which may cost from 25s. to 60s. per acre additional, are

quoted as general dressings.

The majority of recent experiments with farmyard manure would seem to

indicate that, even in the case of what are considered small dressings,

the extra return in crop the first year after application is not such as

to cover the expense of the manure. Of course, as is commonly pointed

out, the effect of farmyard manure is of a lasting nature, and is

probably felt throughout the whole rotation, or even longer. This, to a

certain extent, is no doubt true; still it may be strongly doubted

whether farmyard manure is, after all, an economical manure, as compared

with artificial manures. The desirability of manuring the soil and not

the crop is, in this age of keen competition, no longer believed in; and

the Rothamsted experiments have shown that it is highly doubtful whether

even the soil benefits to anything like a commensurate extent by the

application of large quantities of farmyard manure. This is of course

assuming for farmyard manure the value that it would fetch when sold,

or, to put it rather differently, the price it would cost if the farmer

had to purchase it. Farmyard manure is a necessary bye-product of the

farm, and can scarcely be regarded, therefore, in the same light as the

artificial manures which the farmer buys.[180]

FOOTNOTES:

[131] See Appendix, Note I., p. 279.

[132] "The large amount of potash in unwashed wool is very remarkable: a

fleece must sometimes contain more potash than the whole body of the

shorn sheep."--Warington's 'Chemistry of the Farm,' p. 78.

[133] See Appendix, Note II., p. 279.

[134] The urine of the pig, from the nature of its food, is, as a

general rule, a very poor nitrogenous manure.

[135] See Appendix, Note XV., p. 290.

[136] See Appendix, Note III., p. 280.

[137] See Appendix, Note XVIII., p. 291.

[138] The nitrogen present in the urine, it may be well to point out, is

derived from the waste of nitrogenous tissue as well as from nitrogenous

matter of the food digested.

[139] Note IV., p. 281.

[140] Warington puts this matter admirably in the following words: "If

the food is nitrogenous and easily digested, the nitrogen in the urine

will greatly preponderate. If, on the other hand, the food is one

imperfectly digested, the nitrogen in the solid excrement may form the

larger quantity. When poor hay is given to horses, the nitrogen in the

solid excrement will exceed that contained in the urine. On the other

hand, corn, cake, and roots yield a large excess of nitrogen in the

urine." ('Chemistry of the Farm,' p. 137).

[141] See p. 281.

[142] See p. 282.

[143] See Heiden's 'Duengerlehre,' vol. ii. p. 58.

[144] Heiden's 'Duengerlehre,' vol. i. p. 404.

[145] The following quantities of nitrogen are found in rye, pea, and

bean straw:--

Ranging from Average Lb.

per cent. per cent. per ton.

Rye-straw .30 to .73 .57 12.76

Pea-straw .76 to 1.61 1.21 27.10

Bean-straw 1.15 to 2.62 1.92 43.00

[146] Dr J. M. H. Munro recommends the sprinkling of a little finely

sifted peat-powder in addition to straw, as an excellent means of

preventing loss of volatile ammonia in the fermentation of manure.

[147] See 'Mark Lane Express,' October 7, 1889, p. 475.

[148] See Appendix, Note VII., p. 283.

[149] For analyses see Appendix, Note VIII., p. 283.

[150] According to Storer, in a ton of autumn leaves of the best quality

there would be 6 lb. of potash, less than 3 lb. of phosphoric acid, and

10 or 15 lb. of nitrogen. Another substance that may be used as a litter

is sawdust. This substance is a good absorbent, but is of little value

as a manurial substance.

[151] Heiden's 'Duengerlehre,' vol. ii. pp. 34, 66. In Boussingault's

experiments the food consisted of 15 lb. _hay_, 4.54 lb. _oats_, and 32

lb. water; the total excrements amounting to 31.16 lb., containing 7.42

lb. dry matter. In Hofmeister's experiments the food consisted of 5.23

lb. _hay_, 6.18 lb. _oats_, 1 lb. _chopped straw_, and 25.57 lb. water;

the excrements amounting to 25.07 lb., containing 5.32 lb. dry matter.

[152] This is taking no account of the amount of water which the manure

will absorb, and which will probably double the quantity.

[153] See Appendix, Note IX., p. 283.

[154] The rapid fermentation of horse-manure is due to its mechanical as

well as its chemical nature. The horse does not reduce its food to such

small pieces, and its urine is rich in nitrogen.

[155] Schulze recommends one-third of a pound per day of sulphate of

lime for each horse.

[156] See Appendix, Note X., p. 284.

[157] The food consisted of 30 lb. _potatoes_, 15 lb. _hay_, and 120 lb.

_water_.

[158] For further analyses of cow-manure, see Appendix, Note XI., p.

286.

[159] This is for a pig of six to eight months old, and fed on potatoes.

[160] It has been asserted that the use of pig-manure, when applied

alone, is apt to give an unpleasant taste to the produce grown.

[161] Taken from a very large number of analyses by a number of

experimenters. See Heiden's 'Duengerlehre,' vol. i. p. 99.

[162] See Storer, 'Agricultural Chemistry,' vol. ii. p. 96.

A question of great importance is as to the amount of farmyard manure

produced on a farm in a year, and its value. This is a question which is

extremely difficult to satisfactorily deal with. Various methods of

calculating this amount have been resorted to. It may be well to state

these pretty fully. Some practical authorities estimate the amount by

calculating that every ton of straw should produce 4 tons of manure.

Another method consists in estimating the amount from the size of the

farm. Sir John Lawes has calculated the composition of farmyard manure

which should be produced in the case of a farm of 400 acres, farmed on

the four-course system. He assumes that half of the roots and 100 tons

of hay are consumed at the homestead; that the whole of the straw of the

corn crops is retained at home as food and litter; that twelve horses

have corn equal to 10 lb. of oats per head per day; and that about ten

shillings per acre are expended in the purchase of cake for feeding

stock. Under these conditions the amount of farmyard manure should be

855 tons (or an average of 8-1/2 tons for each of the 100 acres of

root-crop) of _fresh undecomposed dung_. (For composition, see Appendix,

Note XVII., p. 291.) Another method is by taking, as the data of

calculation, the number of cattle, horses, sheep, &c., producing the

manure. Lloyd considers that a fattening animal requires 3 tons of straw

in the year, and makes about 12 tons of manure. A farmer, therefore,

should make 8 tons of manure for every acre of that part of his land

which, in the four-course rotation, is put down to turnips.

The last method consists in taking as the data the amount of food

consumed and litter used in the production of the manure. Of these

methods Heiden considers the last as alone satisfactory and trustworthy.

Applying this method to the horse, he shows, from experiments, that a

little over 47 per cent of the dry matter of its food has been proved to

be voided in the solid and liquid excreta. Taking the average percentage

of water in the excreta as about 77.5, the percentage of dry matter in

the excreta will be 22.5. That is, every pound of dry matter in the food

eaten by the horse yields a little over 2 lb. of excrementitious matter.

To this of course must be added the amount of straw used as litter,

which may be taken at 6.5 lb.

From these data we may calculate the amount of manure produced in a year

by a horse, making certain assumptions as to the amount of work

performed. This Heiden does by assuming that a horse works 260 days, of

twelve hours each, in the course of a year, or 130 whole days, spending

235 days in the stall. Calculating from the above data, he estimates

that a well-fed working horse will produce about 50 lb. of manure in a

day, or 6.5 tons in a year. Of course this does not necessarily

represent all the manure actually produced by the horse, but how much of

the remaining portion of the manure actually finds its way to the farm

it is impossible to say. According to the 'Book of the Farm,' Division

III. p. 98, a farm-horse makes about 12 tons of manure in a year.

It has been calculated that cows void about 48 per cent of the dry

matter of their food in the solid and liquid excreta, which contain of

water, on an average, 87.5 per cent. That is, every pound of dry matter

will furnish 3.84 lb. of total excreta. By adding the necessary amount

of straw for litter (which may be taken at one-third the weight of the

dry matter of the fodder), Heiden calculates that an ox weighing 1000

lb. should produce 113 lb. of manure in a day, or 20 tons in a year. The

'Book of the Farm,' Division III. p. 98, gives the annual amount at from

10 to 14 tons. According to Wolff, one may assume that on an average the

fresh excrements (both liquid and solid) of the common farm animals

(with the exception of the pig) contain of every 100 lb. of dry matter

in the food consumed about 50 lb., or a half. Estimating the dry matter

in the litter used at equal to about 1/4 of the dry matter of the food,

this would mean that for every 100 lb. of dry matter consumed in food

there would be 75 lb. of dry manure (viz., 50 lb. dry excrements + 25

lb. dry litter), which would yield 300 lb. of farmyard manure in the wet

state--_i.e._, with 75 per cent water. The amount of food daily required

per every 1000 lb. of live-weight of the common farm animals may be

taken, roughly speaking, at 24 lb. dry food material and 6 lb. of straw

as litter. The daily production of manure for 1000 lb. of live-weight

would amount, therefore, to 18 lb. of dry, or 72 lb. wet manure. (See

Appendix, Note XVII., p. 291.) According to J. C. Morton and Evershed,

oxen feeding in boxes require 20 lb. of straw per head per day as

litter. An ox, therefore, will make 8 tons of fresh dung in six months,

using 32 cwt. of litter. This means that each ton of litter gives 5 tons

of fresh dung. It is calculated that nearly twice as much litter must be

used in open yards.

[163] It has been calculated that under ordinary circumstances

sheep-dung, when allowed to ferment by itself, should do so in about

four months, horse-dung in six months, and cow-dung in eight months.

[164] See Appendix, Note XII., p. 286.

[165] See Heiden's 'Duengerlehre,' vol. ii. p. 156.

[166] Warington, 'Chemistry of the Farm,' p. 33.

[167] Recent experiments by Muentz and Girard in France have shown that

the loss in sheep excreta from volatilisation of the carbonate of

ammonia amounted to over 50 per cent. By the use of straw litter this

was reduced to about a half less, and with earth litter one quarter

less.

[168] See Appendix, Note XIII., p. 288.

[169] See Appendix, Note XIV., p. 289.

[170] See Appendix, Note XV., p. 290.

[171] For spring application rotten farmyard manure is generally used,

because in this condition its fertilising matter is more quickly

available. On light land it is best to apply it in the rotten condition

shortly before it is likely to be used. (See p. 261.)

[172] The total amount of plant-food in a ton of farmyard manure is

together less than 1/20th of its total weight.

[173] See Heiden's 'Duengerlehre,' vol. ii. p. 171.

[174] For full details see Appendix, Note XVI., p. 290.

[175] Storer reproduces these results in his 'Agricultural Chemistry,'

vol. ii. p. 21.

[176] This aspect of farmyard manure has been ably stated by Mr F. J.

Cooke, a well-known Norfolk farmer. In commenting on the results of the

Rothamsted experiments, he says: "It is clear enough that the faith of

the farmer in the soil-enriching character of his home-made manure is

amply justified; the only question being, indeed, if this quality be not

too highly appreciated. It is not, after all, so much by the fattening

of our land as by the bounty of the crop grown upon it that we reap the

fruit of our exertions. The man of scientific mind keeps his purpose

fixed on the _production of good crops_ mainly, and the cheapest way to

grow them. The experiments under consideration show that richness of

land may be purchased much too dearly, and that richness of crop by no

means bears the necessary relation to richness of soil which has

sometimes been imagined. We may boast of the 'lasting qualities' of our

dung, but the answer of science by these experiments is, that so great

is the last that the life of one man may not be long enough to exhaust

it. In the extravagant use of dung, therefore, such considerations,

amongst many others, as length of purse, as well as length and character

of tenure, must clearly be taken into account."

[177] See paper on "Manurial Experiments with Turnips" by author, in

'Transactions of the Highland and Agricultural Society of Scotland;'

1891.

[178] Storer's 'Agricultural Chemistry,' vol. i. p. 498.

[179] Division III. p. 130.

[180] Mr F. J. Cooke, who has already been quoted, has kindly furnished

the author with his views on the peculiar functions of farmyard manure

as a manure. He says: "I look upon it, broadly speaking, as chiefly of

value in restoring to good land, after cropping, those particular

advantages which good land alone can give, and in helping better than

any other manure, when applied to poor land, to bring it up to the level

of good land in those particular merits which belong alone to fine

soils. I speak now of an inherent value in good soils, beyond that

attaching to them as mere reservoirs of abundant plant-food. For

instance, one may supply a poor soil by artificial manure with much more

food--and in a highly soluble condition--than is needed by the crop to

be grown upon it, and yet not get so good a crop as upon a naturally

richer but otherwise similar soil less abundantly filled with

immediately available food. This may arise from a more perfect

distribution of the plant-food in the rich soil, or from the steady way

in which it becomes available to the crop, as well as for other reasons.

But whatever the cause, there, I think, is the broad fact of the power

of farmyard manure to enrich poor soils, so to speak, more

naturally--that is, in a way which makes them more nearly correspond to

better soils than artificial manures can."

Hence the indirect benefit to the farmer from farmyard manure is

probably greater than its direct value as a mere manure. And the usual

provision and use of it amongst all straw-growing farmers is

sufficiently justified. The extent, however, to which that course may be

beneficially carried, is one of the most important of the many difficult

economic and scientific problems which the farmer has to face.

On the economic side must of course be considered the cost of

manufacture in individual instances, as ruled by the market value of the

straw, and the different circumstances and conditions under which the

various farm animals are kept and fed (I have the figures by me of one

well-known farmer, which show the cost to him of every ton of home-made

manure to be 20s. or more); the price the resultant crops may be

expected to command; the cost at the moment of artificial manures, &c.,

&c. Whilst on the scientific side must be considered the nature of the

soil, the particular rotation of crops, &c.

It was, amongst others, just these scientific and yet very definite and

practical problems we have tried to throw light on in the series of

field experiments conducted for several years by the Norfolk Chamber of

Agriculture. (See reprint of summary of same in last year's Report of

the Board of Agriculture.)

APPENDIX TO CHAPTER VII.

NOTE I. (p. 225).

DIFFERENCE IN AMOUNT OF EXCRETA VOIDED FOR FOOD CONSUMED.

With regard to the difference in the composition of the solid excreta

voided by different fattening animals fed on the same amount of food,

see Warington's 'Chemistry of the Farm,' p. 125, where it is shown that

for equal amount of live-weight, the sheep produces on the same weight

of dry food very much more manure than the pig, while the ox produces

even more than the sheep. Of course this does not refer to the total

amount of manure produced by the different animals, but only to the

amount of manure produced from the consumption of equal quantities of

food. This would seem to be owing to the greater capacity the pig has

for assimilating its food.

NOTE II. (p. 227).

SOLID EXCRETA VOIDED BY SHEEP, OXEN, AND COWS.

To contrast with the analyses given by Stoeckhardt, it may be well to

cite those based on Lawes and Gilbert's experiments, and quoted by

Warington ('Chemistry of the Farm,' p. 138):--

I.--SHEEP (fed on _meadow-hay_).

SOLID EXCREMENT.

Fresh. Dry.

Water 66.2 -

Organic matter 30.3 89.6

Ash 3.5 10.4

---- ----

Nitrogen .7 2.0

II.--OXEN (fed on _clover-hay_ and _oat-straw_, with 8 lb.

_beans_ per day).

Fresh. Dry.

Water 86.3 -

Organic matter 12.3 89.7

Ash 1.4 10.3

---- ----

Nitrogen .3 1.9

III.--COWS (fed on _mangels_ and _lucerne hay_).

Mangels. Lucerne hay.

Water 83.00 79.70

Nitrogen .33 .34

Phosphoric acid .24 .16

Potash .14 .23

NOTE III. (p. 232).

URINE VOIDED BY SHEEP, OXEN, AND COWS.

The following are the results for urine, the animals being fed as in

Note II.:--

Sheep. Oxen.

Fresh. Dry. Fresh. Dry.

Water 85.7 - 94.1 -

Organic matter 8.7 61.0 3.7 63.0

Ash 5.6 39.0 2.2 37.0

---- ---- ---- ----

Nitrogen 1.4 9.6 1.2 20.6

Cows.

Mangels. Lucerne hay.

Water 95.94 88.25

Nitrogen .12 1.54

Phosphoric acid .01 .006

Potash .59 1.69

NOTE IV. (p. 233).

PERCENTAGE OF FOOD VOIDED IN THE SOLID AND LIQUID EXCREMENTS.

According to Wolff, the following table shows the percentage of the dry

substance of the food which is voided in the solid and liquid excrements

of the cow, ox, sheep, and horse:--

Cow. Ox. Sheep. Horse. Average.

Solid excreta 38.0 44.0 42.6 46.7 42.8

Urine 5.8 6.3 6.8 5.7 6.2

---- ---- ---- ---- ----

Total 43.8 50.3 49.4 52.4 49.0

NOTE V. (p. 234).

PIG EXCREMENTS.

The excrements voided by pigs are poor in manurial constituents, because

the food on which they are fed is generally of a very poor nature. In

their case the urine is always very much richer in manurial ingredients

than the solid excreta. The relative composition of the solid excreta

and the urine will be best illustrated by quoting some experiments

carried out by Wolff on this subject. The experiments were carried out

with two pigs nine and a half months old, and each 121.9 kilogrammes (a

kilogramme is equal to about 2-1/4 lb.) in weight. The first consumed

daily 1000 grammes of barley, 5000 grammes of potatoes, and 2572 grammes

of sour-milk. The second one consumed the same quantities of potatoes

and sour-milk as the first, and 1000 grammes of peas. The following

table gives the results of excreta and urine daily voided, in grammes:--

Dry Nitrogen. Ash. Potash. Lime. Magnesia. Phosphoric

substance acid.

Solid { I. 217.7 8.7 28.6 7.3 4.4 3.0 10.3

excreta { II. 161.1 9.1 31.1 5.9 4.9 2.8 11.1

Urine { I. 112.8 19.3 56.2 33.0 0.4 0.9 6.7

{ II. 137.7 30.6 62.2 37.1 0.2 1.1 7.1

NOTE VI.(p. 236).

MANURIAL CONSTITUENTS IN 1000 PARTS OF ORDINARY FOODS.

Based on Lawes and Gilbert's Analyses.

(Warington's 'Chemistry of the Farm,' p. 139.)

-----------------------------+---------+-----------+---------+------------

| Dry | Nitrogen. | Potash. | Phosphoric

| matter. | | | acid.

-----------------------------+---------+-----------+---------+------------

Cotton-cake, decorticated | 918 | 70.4 | 15.8 | 30.5

Rape-cake | 887 | 50.5 | 13.0 | 20.0

Linseed-cake | 883 | 43.2 | 12.5 | 16.2

Cotton-cake, undecorticated | 878 | 33.3 | 20.0 | 22.7

Linseed | 882 | 32.8 | 10.0 | 13.5

Palm-kernel meal, English | 930 | 25.0 | 5.5 | 12.2

Beans | 855 | 40.8 | 12.9 | 12.1

Peas | 857 | 35.8 | 10.1 | 8.4

Malt-dust | 905 | 37.9 | 20.8 | 18.2

Bran | 860 | 23.2 | 15.3 | 26.9

Oats | 870 | 20.6 | 4.8 | 6.8

Rice-meal | 900 | 19.1 | 6.1 | 23.8

Wheat | 877 | 18.7 | 5.2 | 7.9

Rye | 857 | 17.6 | 5.8 | 8.5

Barley | 860 | 17.0 | 4.7 | 7.8

Maize | 890 | 16.6 | 3.7 | 5.7

Brewers' grains | 234 | 7.8 | 0.4 | 3.9

Clover-hay | 840 | 19.7 | 18.6 | 5.6

Meadow-hay | 857 | 15.5 | 16.0 | 4.3

Bean-straw | 840 | 13.0 | 19.4 | 2.9

Oat-straw | 857 | 6.4 | 16.3 | 2.8

Barley-straw | 857 | 5.6 | 10.7 | 1.9

Wheat-straw | 857 | 4.8 | 6.3 | 2.2

Potatoes | 250 | 3.4 | 5.8 | 1.6

Swedes | 107 | 2.2 | 2.0 | 0.6

Carrots | 140 | 2.1 | 3.0 | 1.1

Mangels | 120 | 1.8 | 4.6 | 0.7

Turnips | 80 | 1.6 | 2.9 | 0.8

-----------------------------+---------+-----------+---------+------------

NOTE VII. (p. 241).

ANALYSES OF STABLE-MANURE, MADE RESPECTIVELY WITH PEAT-MOSS LITTER

AND WHEAT-STRAW (by BERNARD DYER, B.Sc.)

Peat-moss litter. Wheat-straw.

Per cent. Per cent.

Total nitrogen 0.88 0.61

Equal to ammonia 1.07 0.74

Phosphoric acid 0.37 0.43

Equal to Tribasic phosphate of

lime (or Tricalcic phosphate) 0.80 0.94

Potash 1.02 0.59

NOTE VIII. (p. 242).

ANALYSES OF BRACKEN (by J. HUGHES, F.C.S.)

No. 1 No. 2

Young fern. Old fern.

Per cent. Per cent.

Water 11.66 14.90

* Organic matter 83.38 80.54

+ Mineral matter 4.96 4.56

------ ------

100.00 100.00

------ ------

Containing--

* Nitrogen 2.42 0.90

+ Silica 1.60 2.81

Potash 1.15 0.10

Soda 0.64 0.26

Lime 0.44 0.62

Magnesia 0.13 0.47

Phosphoric acid 0.60 0.30

NOTE IX. (p. 244).

ANALYSES OF HORSE-MANURE.

For a fuller discussion of this question, the reader is referred to

Heiden's 'Duengerlehre,' vol. ii. p. 185, and also to Storer's

'Agricultural Chemistry,' vol. i. p. 575. The statements in the

different text-books as to the quantity of manure produced by the horse

are such as naturally to perplex the student. This discrepancy is due,

however, to the different methods adopted by different writers of

calculating this amount. The subject is further discussed in the

footnote to p. 252. The following analyses of horse-manure may be

valuable for reference. They are taken from Storer's 'Agricultural

Chemistry,' vol. i. p. 496:--

----------------+-------+-------+-------+-------+-------+---------

| 1. | 2. | 3. | 4. | 5. | Average.

----------------+-------+-------+-------+-------+-------+---------

Water | 75.76 | 69.30 | 67.23 | 72.13 | 71.30 | 71.15

Dry matter | 24.24 | 24.82 | 32.72 | 27.87 | 28.70 | 27.67

Ash ingredients | 5.07 | 5.05 | 6.49 | 3.37 | 3.30 | 4.65

Potash | 0.51 | 0.63 | 0.22 | 0.59 | 0.53 | 0.49

Lime | 0.30 | 0.74 | 0.17 | 0.41 | 0.21 | 0.36

Magnesia | 0.19 | 0.29 | 0.20 | 0.17 | 0.14 | 0.20

Phosphoric acid | 0.41 | 0.67 | 0.35 | 0.12 | 0.28 | 0.36

Ammonia | 0.26 | 0.12 | 0.15 | 0.44 | - | 0.24

Total nitrogen | 0.53 | 0.69 | 0.47 | 0.67 | 0.58 | 0.59

----------------+-------+-------+-------+-------+-------+---------

NOTE X. (p. 247).

THE NATURE OF THE CHEMICAL REACTIONS OF AMMONIA "FIXERS."

For the student, the exact nature of the chemical reactions taking place

may be of interest.

In the first place, it must be distinctly understood that the form in

which ammonia escapes from the manure-heap is not, as is so commonly

erroneously stated in agricultural text-books, as "free" ammonia.

Whenever ammonia is brought into contact with carbonic acid, carbonate

of ammonia is formed. When it is remembered that carbonic acid is by far

the most abundant of the gaseous products of the decomposition of

organic matter, it will be at once seen that free ammonia could not

exist under such circumstances.

1. In the case of _hydrochloric acid_, the following chemical equation

will represent the nature of the reaction--

2HCl + (NH_{4})_{2}CO_{3} = 2NH_{4}Cl + H_{2}O+CO_{2}

(Hydrochloric (carbonate of ammonia,) (sal-ammoniac,) (carbonic acid.)

acid,)

2. In the case of _sulphuric acid_, the equation will be--

H_{2}SO_{4} + (NH_{4})_{2}CO_{3} = (NH_{4})_{2}SO_{4} + H_{2}O+CO_{2}

(Sulphuric (carbonate of (sulphate of ammonia,) (carbonic acid.)

acid,) ammonia,)

3. With _gypsum_ (CaSO_{4})--

CaSO_{4} + (NH_{4})_{2}CO_{3} = CaCO_{3} + (NH_{4})_{2}SO_{4}

(Gypsum,) (carbonate of (calcium (sulphate of ammonia.)

ammonia,) carbonate,)

4. With _copperas_ (FeSO_{4})--

FeSO_{4} + (NH_{4})_{2}CO_{3} = FeCO_{3} + (NH_{4})_{2}SO_{4}

(Sulphate of (carbonate of (ferrous (sulphate of ammonia.)

iron,) ammonia,) carbonate,)

5. With _sulphate of magnesia_ (MgSO_{4})--

MgSO_{4} + (NH_{4})_{2}CO_{3} = MgCO_{3} + (NH_{4})_{2}SO_{4}

(Sulphate of (carbonate of (carbonate of (sulphate of

magnesia,) ammonia,) magnesia,) ammonia.)

Reference has been made to the fact that magnesium sulphate may probably

not only fix the ammonia, but the phosphoric acid. When magnesium

sulphate, soluble phosphoric acid, and ammonia are brought in contact

with one another, the double insoluble phosphate of ammonium and

magnesium (MgNH_{4}PO_{4}6Aq) is formed. While such a reaction is

possible, it is highly improbable that it takes place to any extent. The

double phosphate is a crystalline salt which only separates after a

considerable time, and in the presence of a large excess of ammonia.

NOTE XI. (p. 250).

ANALYSES OF COW-MANURE.[181]

----------------+-------+-------+-------+-------+-------+-------+--------

| 1. | 2. | 3. | 4. | 5. | 6. |Average.

+-------+-------+-------+-------+-------+-------+--------

Water | 85.30 | 77.71 | 74.02 | 72.87 | 75.00 | 77.50 | 77.06

Dry matter | 14.70 | 22.30 | 25.98 | 27.13 | 25.00 | 22.50 | 22.93

Ash ingredients | 2.04 | 4.71 | 3.94 | 6.70 | 6.22 | 2.20 | 4.30

Potash | 0.36 | 0.46 | 0.56 | 1.69 | 0.39 | 0.40 | 0.64

Lime | 0.29 | 0.37 | 0.58 | 0.41 | 0.24 | 0.31 | 0.48

Magnesia | 0.19 | 0.11 | 0.13 | - | 0.18 | 0.11 | -

Phosphoric acid | 0.16 | 0.13 | 0.07 | 0.20 | 0.14 | 0.16 | 0.14

Ammonia | 0.06 | 0.16 | 0.07 | - | 0.27 | - | 0.14

Total nitrogen | 0.38 | 0.54 | 0.41 | 0.79 | 0.46 | 0.34 | 0.48

----------------+-------+-------+-------+-------+-------+-------+--------

NOTE XII. (p. 259).

COMPOSITION OF FRESH AND ROTTEN FARMYARD

MANURE (VOELCKER).

Composition of fresh manure, composed of horse, cow,

and pig dung, about fourteen days old:--

Water 66.17

* Soluble organic matter 2.48

Soluble inorganic matter 1.54

+ Insoluble organic matter 25.76

Insoluble inorganic matter 4.05

------

100.00

------

* Containing nitrogen .149

Equal to ammonia .181

+ Containing nitrogen .494

Equal to ammonia .599

Total percentage of nitrogen .643

Equal to ammonia .780

Ammonia in a volatile state .034

Ammonia in form of salts .088

Composition of the whole ash:--

Soluble in water, 27.55 per cent:--

Soluble silica 4.25

Phosphate of lime 5.35

Lime 1.10

Magnesia 0.20

Potash 10.26

Soda 0.92

Chloride of sodium 0.54

Sulphuric acid 0.22

Carbonic acid and loss 4.71

Insoluble in water, 72.45 per cent:--

Soluble silica 17.34

Insoluble silicious matter 10.04

Oxide of iron and alumina with phosphates 8.47

(Containing phosphoric acid, 3.18 per cent.)

(Equal to bone-earth, 6.88 per cent.)

Lime 20.21

Magnesia 2.56

Potash 1.78

Soda 0.38

Sulphuric acid 1.27

Carbonic acid and loss 10.40

------

100.00

-------

Composition of rotten dung, six months old, is as

follows:--

Water 75.42

* Soluble organic matter 3.71

Soluble inorganic matter 1.47

+ Insoluble organic matter 12.82

Insoluble inorganic matter 6.58

------

100.00

------

* Containing nitrogen .297

Equal to ammonia .360

+ Containing nitrogen .309

Equal to ammonia .375

Total amount of nitrogen .606

Equal to ammonia .735

Ammonia in a volatile state .046

Ammonia in form of salts .057

Composition of the whole ash:--

Soluble in water, 18.27 per cent:--

Soluble silica 3.16

Phosphate of lime 4.75

Lime 1.44

Magnesia 0.59

Potash 5.58

Soda 0.29

Chloride of sodium 0.46

Sulphuric acid 0.72

Carbonic acid and loss 1.28

Insoluble in water, 81.73 per cent:--

Soluble silica 17.69

Insoluble silica 12.54

Phosphate of lime -

Oxides of iron alumina with phosphates 11.76

(Containing phosphoric acid, 3.40 per cent.)

(Equal to bone-earth, 7.36 per cent.)

Lime 20.70

Magnesia 1.17

Potash 0.56

Soda 0.47

Chloride of sodium -

Sulphuric acid 0.79

Carbonic acid and loss 16.05

------

100.00

------

NOTE XIII. (p. 263).

COMPARISON OF FRESH AND ROTTEN MANURE (WOLFF).

Fresh. Moderately rotten

(Taking the quantity of dry matter

as the same.)

Dry matter 25.00 25.00

Ash 3.81 4.76

Nitrogen 0.39 0.49

Potash 0.45 0.56

Lime 0.49 0.61

Magnesia 0.12 0.15

Phosphoric acid 0.18 0.23

Sulphuric acid 0.10 0.13

Silica 0.86 1.08

NOTE XIV. (p. 263).

LORD KINNAIRD'S EXPERIMENTS.[182]

"Lord Kinnaird has given the particulars of a very careful experiment.

He tried to test the comparative value of manure kept in an open court

with that kept under cover. He selected the same kind of cattle, gave

them the same kind and quantity of food, and bedded them with the same

kind of straw. A field of 20 acres of uniform land was selected. This

having been equally divided, 2 acres out of each 10 gave the following

results:--

_Potatoes grown with Uncovered Manure._

Tons. cwt. lb.

First measurement--1 acre produced. 7 6 8

Second do. do. do. 7 18 99

_Potatoes grown with Covered Manure._

First measurement--1 acre produced. 11 17 56

Second do. do. do. 11 12 26

This shows an increase of about 4 tons of potatoes per acre with the

covered manure.

"The next year the weather was wet, grain soft and not in very good

order, but the following was the amount of produce:--

_Wheat grown with Uncovered Manure._

Weight per

Produce in grain. bushel. Produce in straw.

Acre. bushels. lb. lb. stones. lb.

First 41 19 61-1/2 152 of 22

Second 42 38 61-1/2 160 of 22

_Wheat grown with Covered Manure._

First 53 5 61 220 of 22

Second 53 47 61 210 of 22"

NOTE XV. (pp. 231, 264).

DRAININGS OF MANURE-HEAPS.

The importance of not separating the liquid portion from the solid

portion has already been pointed out in dealing with the composition of

the solid excreta and the urine. These two constituents of the manure

are complementary to one another, and the value of farmyard manure as a

general manure is very much impaired if the liquid portion is not

applied along with the solid. In one important respect do the drainings

of manure-heaps differ from urine--that is, in the percentage of

phosphates they contain, the latter being practically devoid of

phosphoric acid.

The following is an analysis of drainings from a manure-heap (Wolff):--

Dry substance 18.0 | Magnesia 0.4

Ash 10.7 | _Phosphoric acid_ 0.1

Nitrogen 1.5 | Sulphuric acid 0.7

Potash 4.9 | Silica 0.2

Lime 0.3 |

NOTE XVI. (p. 270).

AMOUNTS OF POTASH AND PHOSPHORIC ACID REMOVED BY THE FOLLOWING

ROTATIONS FROM A PRUSSIAN MORGEN (.631 ACRE).

Potash. Phosphoric acid.

lb. lb.

1. Wheat 16.40 10.67

Oats 10.47 4.59

Potatoes 66.41 18.33

Hay 39.54 11.32

------ -----

132.82 44.91

------ -----

The ratio of potash to phosphoric acid is 2.96 to 1.

2. Wheat 16.90 10.67

Barley 17.44 10.65

Potatoes 66.41 18.33

Hay 39.54 11.32

------ -----

140.29 50.97

------ -----

The ratio of potash to phosphoric acid is 2.76 to 1.

3. Rye 20.03 12.15

Oats 10.97 4.59

Potatoes 66.41 18.33

Hay 39.54 11.32

------ -----

136.95 46.39

------ -----

The ratio of potash to phosphoric acid is 2.95 to 1.

4. Wheat 16.90 10.67

Oats 10.97 4.59

Mangels 148.54 25.62

Hay 39.54 11.32

------ -----

215.95 52.20

------ -----

The ratio of potash to phosphoric acid is 4.13 to 1.

5. Rye 20.03 12.15

Barley 17.44 10.65

Mangels 148.54 25.62

Hay 39.54 11.32

------ -----

225.55 59.74

The ratio of potash to phosphoric acid is 3.78 to 1.

NOTE XVII. (pp. 253, 254).

COMPOSITION OF FARMYARD MANURE (FRESH), (calculated by SIR

JOHN LAWES).

Phosphoric acid

Total dry Total mineral calculated as Potash. Nitrogen.

matter. matter. phosphate of

lime.

Percent 30.0 2.77 .50 .53 .64

Per ton (in lb.) 67.2 62.0 11.1 12.0 14.3

NOTE XVIII. (p. 232).

THE URINE.

An important consideration we have omitted to take note of in the text

is the quantity of the urine voided. It is this consideration that

renders the urine so much more valuable than the solid excreta. In the

case of a man it has been estimated that the urine voided is fifteen

times as much, is twelve times as rich in nitrogen, three times in

potash, and two in phosphoric acid, as the solid excreta (Munro). The

relation of solid matter in the case of the farm animals is not exactly

similar. The urine of the ox is about twice the weight of its solid

excreta. Both the horse and the sheep, however, void as a rule more

solid excreta than urine. Munro, in his work on 'Soils and Manures,'

contrasts the composition of the urine and solid excreta of the

different farm animals by the following statement:--

1 ton of urine contains 1 ton of solid excreta

in lb.: contains in lb.:

Nitrogen. Potash. Nitrogen.

Cow 30 20 9

Horse 36 22 12

Sheep 38 30 16

FOOTNOTES:

[181] Storer's 'Agricultural Chemistry,' vol. I. p. 496.

[182] Scott's 'Manures and Manuring,' p. 19.

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