CHAPTER I

Transcriber Note

Text emphasis denoted as _Italics_ and =Bold=. Whole and fractional

numbers as 123-4/5.

The Cambridge Manuals of Science

and Literature

ROCKS AND THEIR ORIGINS

CAMBRIDGE UNIVERSITY PRESS

=London:= FETTER LANE, E.C.

C. F. CLAY, Manager

[Illustration]

=Edinburgh:= 100, PRINCES STREET

=London:= WILLIAM WESLEY & SON, 28, ESSEX STREET, STRAND

=Berlin:= A. ASHER AND CO.

=Leipzig:= F. A. BROCKHAUS

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_All rights reserved_

ROCKS AND THEIR

ORIGINS

BY

GRENVILLE A. J. COLE

Professor of Geology in the Royal

College of Science for Ireland

Cambridge:

at the University Press

1912

=Cambridge:=

PRINTED BY JOHN CLAY, M.A.

AT THE UNIVERSITY PRESS

_With the exception of the coat of arms at

the foot, the design on the title page is a

reproduction of one used by the earliest known

Cambridge printer, John Siberch, 1521_

PREFACE

This little book is intended for those who are not specialists in

geology, and it may perhaps be accepted as a contribution for the

general reader. To all who are interested in the earth, the study of

rocks is an important branch of natural history. If detailed works

on petrology are to be consulted later, F. W. Clarke's _Data of

Geochemistry_ (Bulletin, U.S. Geological Survey, ed. 2, 1911) must

on no account be overlooked. Its numerous references to published

papers, and the attention given to rock-origins, make it a worthy

companion to C. Doelter's _Petrogenesis_. Many things have perforce

been omitted from the present essay. It seemed unnecessary to review

the Carbonaceous rocks, since the most important of these have been

admirably dealt with in E. A. N. Arber's _Natural History of Coal_,

published as a volume in this series. I should like to have described

occurrences of rock-salt, of massive gypsum, and other products of

arid lands, where "black alkali" poisons the surface, and the casual

pools are fringed with white and crumbling crusts. Rock-taluses, and

all the varied alluvium carried seaward as the outwash of continental

land, well deserve a chapter to themselves. But there is really no end

to the subject, which embraces all the accumulative processes of the

earth. A few vacation-journeys, judiciously planned out, teach us that

text-books are merely signposts to set us on what is believed to be

the way. When the path enters the great forest, or rises above green

lakelets to the crags, we find there those who went before us, pointing

to unconquered lands.

G. A. J. C.

Royal College of Science

for Ireland, Dublin.

_February 1912._

CONTENTS

CHAP. PAGE

List of Illustrations viii

I. On Rocks in General 1

List of the common Minerals that form Rocks 8

II. The Limestones 12

III. The Sandstones 56

IV. Clays, Shales, and Slates 78

V. Igneous Rocks 103

VI. Metamorphic Rocks 143

References 162

Table of Stratigraphical Systems 189

Index 170

LIST OF ILLUSTRATIONS

FIG. PAGE

1 Surface of Limestone plateau, Causse du Larzac, Aveyron 45

2 Ravine in Limestone, Cañon of the Dourbie, Aveyron 47

3 Waterworn cliff of Limestone, Millersdale 49

4 Limestone country dissected by ravines, Hercegovina 51

5 Sand developing from Sandstone, Cape of Good Hope 59

6 Siliceous Conglomerate, Co. Waterford 75

7 Quartzite Cone, Croagh Patrick 77

8 Shrinkage-cracks in Clay, Spitsbergen 81

9 Landslide of Limestone over Shale, Drôme 93

10 Weathering of Shale, Isère 95

11 Boulder-clay, Crich, Derbyshire (_Phot._ H. A. Bemrose) 97

12 Nordenskiöld Glacier, Spitsbergen 99

13 Sefström Glacier, Spitsbergen 101

14 Ash-layer of 1906 on Vesuvius 111

15 Puy de la Vache, Puy-de-Dôme 113

16 Granite invading Mica-schist, Cape Town 121

17 Weathering granite, Lundy Island 139

18 Granite weathering under tropical conditions, Matopo Hills 141

19 Composite Gneiss, Co. Donegal 153

20 Composite Gneiss, Ängnö, Sweden 155

(Figs. 11 and 17 are reproduced from the Cambridge County Geographies

of _Derbyshire_ and _Devonshire_ respectively; the rest of the

illustrations are from photographs by the author.)

CHAPTER I

ON ROCKS IN GENERAL

The description of rocks has fallen very much into the hands of lovers

of analysis and classification, and attention has been diverted, even

among geologists, from their fundamental importance as parts of the

earth's crust. The geographer or the general traveller may often wish

for closer acquaintance with the units that build up the scenery around

him. The characters of rocks again and again control the features of

the landscape. When studied more nearly, these same characters imply

conditions of deposition or solidification, and lead the mind back to

still older landscapes, and to the meeting of oceans and continents on

long-forgotten shores. Petrology, indeed, involves the understanding

of how rocks "come to be where we find them when we try"; but the

classification of hand-specimens was from the first easier than

field-investigation, and in later times the science was threatened

with the description of isolated microscopic slides. Fortunately, a

certain amount of feeling for natural history has been imported again

into the subject, and evolutionary principles and sequences have been

discussed. Experimental work, moreover, has been brought to bear on the

question of the origins of rocks, with more success than might have

been expected, since it is very difficult to realise in a laboratory,

or even in the mind, the conditions that prevail in the lower parts of

the earth's crust.

Rocks, we have to remember, are in themselves considerable masses, and

have relations with others far away. The coarseness of a sandstone at

one point, or even over square miles of country, implies the deposition

of finer material somewhere else. The lava-flow implies the existence

of mysterious cauldrons in the crust. It is, however, fortunate that

the primary classification of rocks was promulgated without regard for

theories of rock-origins. The work was done by men who were masters

and pioneers in mineralogy. At a time when a powerful school regarded

basalt as of sedimentary origin, and when granite was generally

believed to be the most ancient component of the crust, rock-masses

were taken in hand as aggregates of certain minerals, and were reduced

to an orderly scheme for arrangement in the cabinets of the curious.

Any system based on ideal relationships would have been fatal at that

time to petrology as a science.

Alexandre Brongniart, in 1813, thus saw objections to the

classification of rocks that had been proposed by Werner. In his "Essai

d'une classification minéralogique des Roches mélangées," he showed the

impossibility of determining the age of a rock in relation to others

before assigning to it a name, and the absurdity of separating similar

rocks on account of differences in their geological age. Brongniart

was thus forced to rely, firstly, upon the prevalence of certain

mineral constituents, and, secondly, on the structure of the mass. He

developed this scheme in 1827, in his "Classification et caractères

minéralogiques des Roches homogènes et hétérogènes"; but it is clear

that, even in such a system, considerations of natural history and of

origin will ultimately predominate. Brongniart was much influenced by

Karl von Leonhard's "Charakteristik der Felsarten," published in 1823,

and these two authors have been regarded as the founders of petrography.

The difficulty of distinguishing between rocks laid down as true

sediments on the earth's surface and those that have consolidated from

a state of fusion has been very largely removed. The assistance of the

microscope can now be called on to elucidate the minute structure of

fine-grained masses, which appeared homogeneous to earlier workers.

The pioneer in microscopic methods was Pierre Louis Antoine Cordier,

who knew rocks as a traveller knows them in the field. In 1798, as

a young man of twenty-one, he had gone to Egypt with the famous

expedition under General Bonaparte. Déodat de Dolomieu had charge of

the geological observations, and Cordier went through the hardships of

the campaign as his assistant. When Bonaparte abandoned the army and

withdrew to Paris, Cordier might well have been lost to Europe.

However, he successfully brought home the knowledge acquired in the

field, and set himself, in those agitating years, to solve the problem

of the compact groundwork of igneous rocks. He argued that this

groundwork probably consisted of minerals, and that these minerals

were probably similar to those occurring as visible constituents of

the mass. He examined the powder of these larger crystals under the

microscope, and made himself familiar with their aspect in a fractured

form. He then powdered the compact material of his rocks, washed

away the dust, and was able to recognise in the coarser residue the

minerals that he had previously studied. He used the magnet to extract

the iron ore; he determined the fusibility of the particles with the

blowpipe; and he even discovered in volcanic lavas a residual glass

associated with the crystalline material[1]. To this day, when a

particular mineral has to be determined in a rock, it is often best to

follow Cordier's method, and to extract the actual crystals, however

small. Various modes of separation, especially those involving the use

of dense liquids, have been devised since Cordier's time, and the

specific gravity of a single crystal can now be determined, although it

may be so small as to require looking for in the dense liquid with a

lens[2].

Between 1836 and 1838, Christian Gottfried Ehrenberg, Professor of

Medicine at Berlin, made an immense step forward in the study of rocks.

Being keenly interested in microscopic forms of life, he wished to

determine their importance as constituents of rocks. Using a microscope

magnifying 300 diameters, he showed the presence of organisms in

flint and limestone, and found in 1838 that a thin slice of chalk

coated over with Canada balsam became practically transparent. In

his "Mikrogeologie," published in 1854, he gives drawings of thin

sections of several flints, seen by transmitted light, which are thus

rock-sections in the modern petrological sense. His method could not

have been generally known until his book appeared in 1854. Meanwhile,

Henry Clifton Sorby, about 1845, found the naturalist W. C. Williamson

making thin sections of fossil plants and bones. He promptly perceived

the importance of the method as applied to rocks in general, and

introduced it to the Geological Society of London in 1850, in a paper

on the Calcareous Grit of Scarborough. Seven years later, he read

his memorable paper on "The Microscopical Structure of Crystals[3],"

in which he made use of slices of granite and of Vesuvian and other

lavas. Ferdinand von Zirkel met Sorby by chance at Bonn in 1862, and,

learning his methods, proceeded to systematise the examination of

rock-specimens with the microscope. Such studies, rapidly appreciated

by Michel Lévy, Rosenbusch, Judd, and others, naturally led to advances

of the first importance in petrology. They enabled workers to ascertain

the relations of the rock-constituents one to another, and the order

of consolidation of minerals from an igneous magma. The broad division

of rocks into those of sedimentary and those of igneous origin has

been further emphasised. The rocks styled metamorphic still afford the

greatest difficulty, even after prolonged enquiry in the field.

Seeing that some rocks are merely massive minerals, that is, large

masses formed of one mineral species, while others consist of crystals

or fragments of a variety of minerals, it may be well to remind

ourselves of the distinction between minerals and rocks. We may define

a _mineral_ as a natural substance formed by inorganic action; its

chemical composition is constant; under favourable circumstances, it

assumes a characteristic crystalline form.

Like all definitions of natural objects, the above requires some

qualification. In many cases the chemical composition of a mineral

varies by a well-defined series of atomic replacements, and we

cannot feel called upon to establish a new species for every step

away from the rigid type. Sodium thus replaces potassium to some

extent in orthoclase felspar. The crystalline form, again, may not be

specifically characteristic, as, for instance, in the members of the

garnet series, which crystallise in the cubic system. The homogeneity

of molecular structure throughout the individual may be regarded as the

most essential feature of what we style a mineral species; that is to

say, the molecules contain the same elements in the same proportions,

and are arranged on the same physical plan.

A _rock_, on the other hand, is a mere aggregate of mineral particles,

or of molecules that, under proper conditions, would group themselves

to form mineral species. It may consist entirely of granules or

crystals of one species; but the structures in these have no common

orientation, as they would have in a single large continuous crystal.

The rock itself has no crystalline form, and any structures that

simulate such forms will be found on measurement to have none of the

regularity that characterises genuine crystals. A rock, moreover,

formed of several mineral species in association will by no means

possess a constant chemical composition, and the variations from point

to point form a feature of especial interest in the study of igneous

masses, of sediments deposited on a shore, or of alluvium in a valley

stretching far between the hills.

In the pages that follow we hope, then, to bear in mind the relations

of rocks to the earth and to ourselves. Like the ancient Romans, we

build our cities with huge blocks and slabs brought from crystalline

masses oversea. We now tunnel, for our commercial highways, through the

complex cores of mountain-chains. Everywhere rocks are our foundations,

throughout our travels or in our settled homes. They rise as obstacles

against us, or they spread before us fields of fertile soil. Some

knowledge of them is part of the general body of culture that makes us,

in the best sense, citizens of the world.

LIST OF THE COMMON MINERALS THAT FORM ROCKS

=Actinolite.= See Amphiboles.

=Albite.= See Felspars.

=Amphiboles.= A series of silicates with the general formula

RSiO_{3}, where R is magnesium, iron or calcium; in many,

such as the common species _Hornblende_, molecules occur in

addition in which aluminium and triad iron are introduced.

Hornblende thus consists of _m_ (Mg, Fe″, Ca) SiO_{3}.

_n_ (Mg, Fe″) (Al, Fe‴)_{2} SiO_{6}. _Actinolite_ is a

non-aluminous amphibole occurring in needle-like prisms. The

amphiboles crystallise in prisms having angles of about 56°

and 124°. See Pyroxenes.

=Anatase.= See Rutile.

=Andalusite.= Aluminium silicate, Al_{2}SiO_{5}, crystallising

in the rhombic system. _Sillimanite_ consists also of

Al_{2}SiO_{5} and is rhombic, but crystallises with different

fundamental angles.

=Anorthite.= See Felspars.

=Apatite.= Calcium phosphate, with fluorine, or sometimes

chlorine, (CaF)Ca_{4}(PO_{4})_{3} = 3Ca_{3}(PO_{4})_{2}.

CaF_{2}.

=Aragonite.= Calcium carbonate, CaCO_{3}, crystallising in the

rhombic system, with a specific gravity of 2·93. See Calcite.

=Augite.= See Pyroxenes.

=Biotite.= See Micas.

=Calcite.= Calcium carbonate, CaCO_{3}, crystallising in the

trigonal system, with a specific gravity of 2·72. See

Aragonite.

=Chalcedony.= Crystalline silica, SiO_{2}, in fibrous and often

mammillated forms. _Flint_ or _Chert_ is a concretionary form,

in which some interstitial opal may be present.

=Chert.= See Chalcedony.

=Chlorites.= Hydrous aluminium magnesium iron silicates,

resembling green micas, but softer and with non-elastic plates.

=Chromite.= Iron chromium oxide, FeCr_{2}O_{4}. Magnesium may

replace part of the dyad iron, and aluminium and triad iron

some of the chromium.

=Diallage.= An altered augite with a shimmery submetallic lustre.

=Diopside.= See Pyroxenes.

=Dolomite.= Magnesium calcium carbonate, MgCa(CO_{3})_{2}.

=Enstatite.= See Pyroxenes.

=Epidote.= Calcium aluminium iron silicate,

Ca_{2}(AlOH)(Al, Fe‴)_{2}(SiO_{4})_{3}.

=Felspars.= A series of silicates of aluminium with potassium

or sodium or calcium, or all of these. _Orthoclase_,

KAlSi_{3}O_{8}, and the corresponding sodium form, _Albite_,

NaAlSi_{3}O_{8}, lie at one end of the series, and the calcium

felspar _Anorthite_, CaAl_{2}(SiO_{4})_{2}, at the other.

While Orthoclase crystallises in the monoclinic system, a

triclinic form, _Microcline_, with the same composition, is

also common. All the other felspars are triclinic, and, with

microcline, are often styled _plagioclases_. The principal

felspars between Albite and Anorthite are _Oligoclase_,

the "soda-lime felspar," and _Labradorite_, the "lime-soda

felspar."

=Flint.= See Chalcedony.

=Garnets.= A series of silicates with the general composition

of R_{3}″R_{2}‴(SiO_{3})_{4}, R″ being Ca, Fe″, or Mn, and

R‴ being Al or Fe‴. The common red garnet in mica-schists is

_Almandine_, Fe_{3}Al_{2}(SiO_{3})_{4}, while that in altered

limestones is _Grossularite_, Ca_{3}Al_{2}(SiO_{3})_{4}.

=Glauconite.= A hydrous iron potassium silicate, with some

aluminium, magnesium, and calcium, formed in marine deposits.

=Gypsum.= Hydrous calcium sulphate, CaSO_{4} + 2 H_{2}O.

=Hornblende.= See Amphiboles.

=Hypersthene.= See Pyroxenes.

=Ilmenite.= Titanium iron oxide, _m_ FeTiO_{3} + _n_ Fe_{2}O_{3}.

=Iron Pyrites.= Iron disulphide, FeS_{2}. A cubic species,

_Pyrite_, and a less common rhombic species, _Marcasite_,

occur.

=Kaolin.= Hydrous aluminium silicate, H_{4}Al_{2}Si_{2}O_{9}.

=Kyanite.= Aluminium silicate, Al_{2}SiO_{5}, crystallised in the

triclinic system. See Andalusite.

=Labradorite.= See Felspars.

=Leucite.= Potassium aluminium silicate, KAl(SiO_{3})_{2}.

=Limonite.= Hydrous iron oxide. H_{6}Fe_{4}O_{9}.

=Magnetite.= Magnetic iron oxide, Fe_{3}O_{4}.

=Marcasite.= See Iron Pyrites.

=Micas.= A series of aluminium silicates, with potassium,

magnesium, or iron, or all of these. Lithium and sodium

sometimes occur. The two marked types are _Muscovite_, rich

in aluminium and potassium, the common "alkali mica,"

H_{2}KAl_{3}(SiO_{4})_{3}, with a silvery aspect, and

_Biotite_, the common dark "ferromagnesian" mica, (H,

K)_{2}(Mg, Fe″)_{2}(Al, Fe‴)_{2}(SiO_{4})_{3}.

=Microcline.= See Felspars.

=Muscovite.= See Micas.

=Nepheline.= Sodium aluminium silicate, with some potassium, the

pure sodium type being NaAlSiO_{4}; the types with potassium

contain slightly more silica.

=Oligoclase.= See Felspars.

=Olivine.= Magnesium iron silicate, (Mg, Fe)_{2}SiO_{4}.

=Opal.= Uncrystallised silica, SiO_{2}, with some water.

=Orthoclase.= See Felspars.

=Pyrite.= See Iron Pyrites.

=Pyroxenes.= A series of silicates corresponding in composition

to the Amphiboles, but crystallising in prisms which have

angles of about 87° and 93°. On the whole, the pyroxenes

are richer in calcium than the amphiboles. The formula of

_Wollastonite_ is CaSiO_{3}. _Diopside_ consists of Ca(Mg,

Fe)(SiO_{3})_{2}. _Augite_, the commonest form, is aluminous,

corresponding to Hornblende among the amphiboles; but the

change from Augite into Hornblende, which often occurs, may

imply a loss of calcium. _Enstatite_ and _Hypersthene_ are

species crystallising in the rhombic system; the former

consists of MgSiO_{3}, while in Hypersthene iron replaces some

of the magnesium.

=Quartz.= Silica, SiO_{2}, crystallised in the trigonal system.

=Rock-Salt.= Sodium chloride, NaCl.

=Rutile.= Titanium dioxide, TiO_{2}, crystallised in the

tetragonal system. _Anatase_ has the same composition, and is

tetragonal, but has different fundamental angles.

=Serpentine.= Hydrous magnesium iron silicate, H_{4}(Mg,

Fe)_{3}Si_{2}O_{9}.

=Siderite.= Iron carbonate, FeCO_{3}.

=Sillimanite.= See Andalusite.

=Talc.= Hydrous magnesium silicate, H_{2}Mg_{3}(SiO_{3})_{4}.

=Tourmaline.= A borosilicate of aluminium with various other

elements, R′_{9}Al_{3}(BOH)_{2}Si_{4}O_{19}. R represents H,

Na, Al, Mg, Fe.

=Tridymite.= Silica, SiO_{2}, crystallised in doubly refracting

six-sided plates. Its specific gravity is 2·3, that of Quartz

being 2·65.

=Wollastonite.= See Pyroxenes.

=Zeolites.= A series of hydrous aluminium silicates, with

potassium, sodium, calcium, and sometimes barium.

=Zircon.= Zirconium silicate, ZrSiO_{4}.

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