brain; nothing is more common than inflammation of the _tunica
arachnoides_ that covers it. 2d. Oftentimes one membrane of the
eye only is affected, the others preserving their ordinary degree of
vitality. 3d. In convulsions or paralysis of the muscles of the larynx,
the mucous surface is unaffected; and on the other hand, the muscles
perform their functions as usual in catarrhs of this surface. Both
these affections are foreign to the cartilages, and _vice versa_.
4th. We observe a variety of different alterations in the texture
of the pericardium, but hardly ever in that of the heart itself; it
remains sound while the other is inflamed. The ossification of the
common membrane of the red blood does not extend to the neighboring
textures. 5th. When the membrane of the bronchia is the seat of
catarrh, the pleura is hardly affected at all, and reciprocally in
pleurisy the first is scarcely ever altered. In peripneumonia, when an
enormous infiltration in the dead body shows the excessive inflammation
that has existed during life in the pulmonary texture, the serous and
mucous surfaces often appear not to have been affected. Those who open
dead know that they are frequently healthy in incipient phthisis.
6th. We speak of a bad stomach, a weak stomach; this most commonly
should be understood as applying to the mucous surface only. Whilst
this secretes with difficulty the nutritive juices, without which
digestion is impaired, the serous surface exhales as usual its fluid,
the muscular coat continues to contract, etc. In ascites, in which
the serous surface exhales more lymph than in a natural state, the
mucous oftentimes performs its functions perfectly well, etc. 7th.
All authors have said much of the inflammation of the stomach, the
intestines, the bladder, etc. For myself, I believe that this disease
rarely ever affects at first the whole of any of these organs, except
in the case where poison or some other deleterious substance acts upon
them. There are for the mucous surface of the stomach and intestines,
acute and chronic catarrhs; for the peritoneum serous inflammations;
perhaps even for the layer of organic muscles that separates the two
membranes, there is a particular kind of inflammation, though we have
as yet hardly anything certain upon this point; but the stomach, the
intestines, and the bladder are not suddenly affected with these
three diseases. A diseased texture can affect those near it, but the
primitive affection seizes only upon one. I have examined a great
number of bodies in which the peritoneum was inflamed either upon the
intestines, the stomach, the pelvis, or universally; now very often
when this affection is chronic, and almost always when it is acute,
the subjacent organs remain sound. I have never seen this membrane
exclusively diseased upon one organ, while that of neighboring ones
remain untouched; its affection is propagated more or less remotely.
I know not why authors have hardly ever spoken of its inflammation,
and have placed to the account of the subjacent viscera that which
most often belongs only to this. There are almost as many cases
of peritonitis as of pleurisy, and yet while these last have been
particularly noticed the others are almost entirely overlooked.
Oftentimes that part of the peritoneum corresponding to an organ,
is much inflamed; we see it in the case of the stomach; we observe
especially after the suppression of the lochia or the menses, that it
is the portion that lines the pelvis that is first affected. But soon
the affection becomes more or less general; at least examinations after
death prove it satisfactorily. 8th. Certainly the acute or chronic
catarrh of the bladder, or womb even, has nothing in common with the
inflammation of that portion of the peritoneum corresponding with
these organs. 9th. Every one knows that diseases of the periosteum
have oftentimes no connection with the bone, and _vice versa_,
that frequently the marrow is for a long time affected, while both the
others remain sound. There is no doubt that the osseous, medullary
and fibrous textures have their peculiar affections which we shall
not confound with the idea we may form of the diseases of the bones.
The same can be said of the intestines, of the stomach, etc., in
relation to their mucous, serous, muscular textures, etc. 10th. Though
the muscular and tendinous textures are combined in a muscle, their
diseases are very different. 11th. You must not think that the synovial
is subject to the same diseases as the ligaments that surround it, etc.
I think the more we observe diseases, and the more we examine bodies,
the more we shall be convinced of the necessity of considering local
diseases, not under the relations of the compound organs, which are
rarely ever affected as a whole, but under that of their different
textures, which are almost always attacked separately.
When the phenomena of disease are sympathetic, they follow the same
laws as when they arise from a direct affection. Much has been said
of the sympathies of the stomach, the intestines, the bladder, the
lungs, etc. But it is impossible to form an idea of them, if they
are referred to the organ as a whole, separate from the different
textures. 1st. When in the stomach, the fleshy fibres contract by the
influence of another organ and produce vomiting, they alone receive
the influence, which is not extended either to the serous or mucous
surfaces; if it were, they would be the seat, the one of exhalation,
the other of sympathetic exhalation and secretion. 2d. It is certain
that when the action of the liver is sympathetically increased, so
that it pours out more bile, the portion of peritoneum that covers it
does not throw out more serum, because it is not affected by it. It
is the same of the kidney, the pancreas, etc. 3d. For the same reason
the gastric organs upon which the peritoneum is spread do not partake
of the sympathetic influences that it experiences. I shall say as much
of the lungs in relation to the pleura, the brain in relation to the
_tunica arachnoides_, the heart to the pericardium, etc. 4th. It
is undeniable that in all sympathetic convulsions, the fleshy texture
alone is affected, and that the tendinous is not so at all. 5th. What
has the fibrous membrane of the testicles in common with the sympathies
of its peculiar texture? 6th. No doubt a number of sympathetic pains
that we refer to the bones, are seated exclusively in the marrow.
I could cite many other examples to prove, that it is not this or that
organ that sympathizes as a whole, but only this or that texture in
the organs; besides, this an immediate consequence of the nature of
sympathies. In fact the sympathies are but aberrations of the vital
properties; now these properties vary according to each texture; the
sympathies of these textures then would do the same.
FOOTNOTES:
[Footnote 26: Translated from _Traité sur les Membranes_ (1800).]
XXIV
AMADEO AVOGADRO
1776-1856
_Avogadro, who continued the researches of Dalton and Gay-Lussac,
was born in Turin, Italy, June 9, 1776. In 1796, after receiving the
doctor’s degree in law from the University of Turin, he was employed
by the government for the following ten years. He began his work in
science in 1806 and three years later was made professor of physics at
Vercelli. In 1811 he announced his famous law. According to Merz, since
the time of Boyle “it had been known that equal volumes of different
gases under equal pressure change their volumes equally if the
pressure is varied equally, and it was also known that equal volumes
of different gases under equal pressure change their volumes equally
with equal rise of temperature. These facts suggested to Avogadro, and
almost simultaneously to Ampère, the very simple assumption that this
is owing to the fact that equal volumes of different gases contain an
equal number of the smallest independent particles of matter. This is
Avogadro’s celebrated hypothesis. It was the first step in the direct
physical verification of the atomic view of matter.”_
_In 1820 Avogadro became professor of physics at Turin University,
where he remained for many years. He died July 9, 1856._
THE MOLECULES IN GASES PROPORTIONAL TO THE VOLUMES[27]
I.
M. Gay-Lussac has shown in an interesting Memoir (_Mémoires de la
Société d’Arcueil_, Tome II.) that gases always unite in a very
simple proportion by volume, and that when the result of the union is a
gas, its volume also is very simply related to those of its components.
But the quantitative proportions of substances in compounds seem only
to depend on the relative number of molecules which combine, and on the
number of composite molecules which result. It must then be admitted
that very simple relations also exist between the volumes of gaseous
substances and the numbers of simple or compound molecules which form
them. The first hypothesis to present itself in this connection, and
apparently even the only admissible one, is the supposition that the
number of integral molecules in any gases is always the same for equal
volumes, or always proportional to the volumes. Indeed, if we were
to suppose that the number of molecules contained in a given volume
were different for different gases, it would scarcely be possible
to conceive that the law regulating the distance of molecules could
give in all cases relations so simple as those which the facts just
detailed compel us to acknowledge between the volume and the number
of molecules. On the other hand, it is very well conceivable that
the molecules of gases being at such a distance that their mutual
attraction cannot be exercised, their varying attraction for caloric
may be limited to condensing a greater or smaller quantity around
them, without the atmosphere formed by this fluid having any greater
extent in the one case than in the other, and, consequently, without
the distance between the molecules varying; or, in other words, without
the number of molecules contained in a given volume being different.
Dalton, it is true, has proposed a hypothesis directly opposed to
this, namely, that the quantity of caloric is always the same for the
molecules of all bodies whatsoever in the gaseous state, and that the
greater or less attraction for caloric only results in producing a
greater or less condensation of this quantity around the molecules,
and thus varying the distance between the molecules themselves. But
in our present ignorance of the manner in which this attraction of
the molecules for caloric is exerted, there is nothing to decide
us _a priori_ in favour of the one of these hypotheses rather
than the other; and we should rather be inclined to adopt a neutral
hypothesis, which would make the distance between the molecules and
the quantities of caloric vary according to unknown laws, were it not
that the hypothesis we have just proposed is based on that simplicity
of relation between the volumes of gases on combination, which would
appear to be otherwise inexplicable.
Setting out from this hypothesis, it is apparent that we have the means
of determining very easily the relative masses of the molecules of
substances obtainable in the gaseous state, and the relative number
of these molecules in compounds; for the ratios of the masses of the
molecules are then the same as those of the densities of the different
gases at equal temperature and pressure, and the relative number of
molecules in a compound is given at once by the ratio of the volumes
of the gases that form it. For example, since the numbers 1.10359 and
0.07321 express the densities of the two gases oxygen and hydrogen
compared to that of atmospheric air as unity, and the ratio of the two
numbers consequently represents the ratio between the masses of equal
volumes of these two gases, it will also represent on our hypothesis
the ratio of the masses of their molecules. Thus the mass of the
molecule of oxygen will be about 15 times that of the molecule of
hydrogen, or, more exactly, as 15.074 to 1. In the same way the mass
of the molecule of nitrogen will be to that of hydrogen as 0.96913 to
0.07321, that is, as 13, or more exactly 13.238, to 1. On the other
hand, since we know that the ratio of the volumes of hydrogen and
oxygen in the formation of water is 2 to 1, it follows that water
results from the union of each molecule of oxygen with two molecules of
hydrogen. Similarly, according to the proportions by volume established
by M. Gay-Lussac for the elements of ammonia, nitrous oxide, nitrous
gas, and nitric acid, ammonia will result from the union of one
molecule of nitrogen with three of hydrogen, nitrous oxide from one
molecule of oxygen with two of nitrogen, nitrous gas from one molecule
of nitrogen with one of oxygen, and nitric acid from one of nitrogen
with two of oxygen.
II.
There is a consideration which appears at first sight to be opposed to
the admission of our hypothesis with respect to compound substances.
It seems that a molecule composed of two or more elementary molecules
should have its mass equal to the sum of the masses of these molecules;
and that in particular, if in a compound one molecule of one substance
unites with two or more molecules of another substance, the number
of compound molecules should remain the same as the number of
molecules of the first substance. Accordingly, on our hypothesis when
a gas combines with two or more times its volume of another gas, the
resulting compound, if gaseous, must have a volume equal to that of
the first of these gases. Now, in general, this is not actually the
case. For instance, the volume of water in the gaseous state is, as
M. Gay-Lussac has shown, twice as great as the volume of oxygen which
enters into it, or, what comes to the same thing, equal to that of the
hydrogen instead of being equal to that of the oxygen. But a means
of explaining facts of this type in conformity with our hypothesis
presents itself naturally enough: we suppose, namely, that the
constituent molecules of any simple gas whatever (i. e., the molecules
which are at such a distance from each other that they cannot exercise
their mutual action) are not formed of a solitary elementary molecule,
but are made up of a certain number of these molecules united by
attraction to form a single one; and further, that when molecules of
another substance unite with the former to form a compound molecule,
the integral molecule which should result splits up into two or more
parts (or integral molecules) composed of half, quarter, &c., the
number of elementary molecules going to form the constituent molecule
of the first substance, combined with half, quarter, &c., the number of
constituent molecules of the second substance that ought to enter into
combination with one constituent molecule of the first substance (or,
what comes to the same thing, combined with a number equal to this last
of half-molecules, quarter-molecules, &c., of the second substance);
so that the number of integral molecules of the compound becomes
double, quadruple, &c., what it would have been if there had been no
splitting-up, and exactly what is necessary to satisfy the volume of
the resulting gas.
On reviewing the various compound gases most generally known, I only
find examples of duplication of the volume relatively to the volume of
that one of the constituents which combines with one or more volumes
of the other. We have already seen this for water. In the same way,
we know that the volume of ammonia gas is twice that of the nitrogen
which enters into it. M. Gay-Lussac has also shown that the volume of
nitrous oxide is equal to that of the nitrogen which forms part of
it, and consequently is twice that of the oxygen. Finally, nitrous
gas, which contains equal volumes of nitrogen and oxygen, has a
volume equal to the sum of the two constituent gases, that is to say,
double that of each of them. Thus in all these cases there must be a
division of the molecule into two; but it is possible that in other
cases the division might be into four, eight, &c. The possibility of
this division of compound molecules might have been conjectured _a
priori_; for otherwise the integral molecules of bodies composed
of several substances with a relatively large number of molecules,
would come to have a mass excessive in comparison with the molecules
of simple substances. We might therefore imagine that nature had some
means of bringing them back to the order of the latter, and the facts
have pointed out to us the existence of such means. Besides, there
is another consideration which would seem to make us admit in some
cases the division in question; for how could one otherwise conceive
a real combination between two gaseous substances uniting in equal
volumes without condensation, such as takes place in the formation of
nitrous gas? Supposing the molecules to remain at such a distance that
the mutual attraction of those of each gas could not be exercised,
we cannot imagine that a new attraction could take place between the
molecules of one gas and those of the other. But on the hypothesis
of division of the molecule, it is easy to see that the combination
really reduces two different molecules to one, and that there would be
contraction by the whole volume of one of the gases if each compound
molecule did not split up into two molecules of the same nature. M.
Gay-Lussac clearly saw that, according to the facts, the diminution of
volume on the combination of gases cannot represent the approximation
of their elementary molecules. The division of molecules on combination
explains to us how these two things may be made independent of each
other.
III.
Dalton, on arbitrary suppositions as to the most likely relative number
of molecules in compounds, has endeavoured to fix ratios between the
masses of the molecules of simple substances. Our hypothesis, supposing
it well founded, puts us in a position to confirm or rectify his
results from precise data, and, above all, to assign the magnitude of
compound molecules according to the volumes of the gaseous compounds,
which depend partly on the division of molecules entirely unsuspected
by this physicist.
Thus Dalton supposes that water is formed by the union of hydrogen and
oxygen, molecule to molecule. From this, and from the ratio by weight
of the two components, it would follow that the mass of the molecule of
oxygen would be to that of hydrogen as 7-1/2 to 1 nearly, or, according
to Dalton’s evaluation, as 6 to 1. This ratio on our hypothesis is,
as we saw, twice as great, namely, as 15 to 1. As for the molecule of
water, its mass ought to be roughly expressed by 15 + 2 = 17 (taking
for unity that of hydrogen), if there were no division of the molecule
into two; but on account of this division it is reduced to half, 8-1/2,
or more exactly 8.537, as may also be found directly by dividing the
density of aqueous vapour 0.625 (Gay-Lussac) by the density of hydrogen
0.0732. This mass only differs from 7, that assigned to it by Dalton,
by the difference in the values for the composition of water; so that
in this respect Dalton’s result is approximately correct from the
combination of two compensating errors,--the error in the mass of the
molecule of oxygen, and his neglect of the division of the molecule.
FOOTNOTES:
[Footnote 27: Translated from _Essai d’une manière de déterminer
les masses relatives des molécules élémentaires des corps,
et les proportions selon lesquelles elles entrent dans les
combinaisons_--_Journal de Physique_, (1811).]
XXV
SIR HUMPHREY DAVY
1778-1829
_Born December 17, 1778, in Cornwall, Sir Humphrey Davy was
apprenticed in 1794 to a surgeon-apothecary at Penzance in whose
service he became interested in chemistry. Made superintendent of a
hospital in 1798, he had opportunities for gaining acquaintance with
influential men who in turn recommended him to Count Rumford. Through
the latter’s assistance he was appointed lecturer on chemistry at the
newly-founded Royal Institution where, in spite of his unattractive
appearance, he gained considerable reputation. In 1807 he advanced a
theory which partly explained electrolysis; in the following year he
discovered strontium and magnesium; and in 1809, chlorine. In 1812 he
was knighted; and shortly after his marriage, in the same year, he
injured an eye while experimenting and was compelled to interrupt his
work for a short time. In 1815 he invented the safety-lamp used by
miners. In 1818 he was created a baronet, and was elected President
of the Royal Society in 1820. He died May 29, 1829, at Geneva,
Switzerland, at the age of fifty-one._
ON SOME NEW PHENOMENA OF CHEMICAL CHANGES PRODUCED BY ELECTRICITY[28]
_Read November 19, 1807._
INTRODUCTION.
In the Bakerian Lecture which I had the honour of presenting to the
Royal Society last year, I described a number of decompositions
and chemical changes produced in substances of known composition by
electricity, and I ventured to conclude from the general principles
on which the phenomena were capable of being explained, that the new
methods of investigation promised to lead to a more intimate knowledge
than had hitherto been obtained, concerning the true elements of bodies.
This conjecture, then sanctioned only by strong analogies, I am now
happy to be able to support by some conclusive facts. In the course of
a laborious experimental application of the powers of electro-chemical
analysis, to bodies which have appeared simple when examined by common
chemical agents, or which at least have never been decomposed, it has
been my good fortune to obtain new and singular results.
Such of the series of experiments as are in a tolerably mature state,
and capable of being arranged in a connected order, I shall detail
in the following sections, particularly those which demonstrate the
decomposition and composition of the fixed alkalies, and the production
of the new and extraordinary bodies which constitute their bases.
In speaking of novel methods of investigation, I shall not fear to be
minute. When the common means of chemical research have been employed,
I shall mention only results. A historical detail of the progress
of the investigation, of all the difficulties that occurred, and of
the manner in which they were overcome, and of all the manipulations
employed, would far exceed the limits assigned to this Lecture. It is
proper to state, however, that when general facts are mentioned, they
are such only as have been deduced from processes carefully performed
and often repeated.
ON THE METHODS USED FOR THE DECOMPOSITION OF THE FIXED ALKALIES
The researches I had made on the decomposition of acids, and of
alkaline and earthy neutral compounds, proved that the powers of
electrical decomposition were proportional to the strength of the
opposite electricities in the circuit, and to the conducting power and
degree of concentration of the materials employed.
In the first attempts, that I made on the decomposition of the fixed
alkalies, I acted upon aqueous solutions of potash and soda, saturated
at common temperatures, by the highest electrical power I could
command, and which was produced by a combination of Voltaic batteries
belonging to the Royal Institution, containing 24 plates of copper and
zinc of 12 inches square, 100 plates of 6 inches, and 150 of 4 inches
square, charged with solutions of alum and nitrous acid; but in these
cases, though there was a high intensity of action, the water of the
solutions alone was affected, and hydrogen and oxygen disengaged with
the production of much heat and violent effervescence.
The presence of water appearing thus to prevent any decomposition, I
used potash in igneous fusion. By means of a stream of oxygen gas from
a gasometer applied to the flame of a spirit lamp, which was thrown
on a platina spoon containing potash, this alkali was kept for some
minutes in a strong red heat, and in a state of perfect fluidity.
The spoon was preserved in communication with the positive side of
the battery of the power of 100 of 6 inches, highly charged; and the
connection from the negative side was made by a platina wire.
By this arrangement some brilliant phenomena were produced. The potash
appeared a conductor in a high degree, and as long as the communication
was preserved, a most intense light was exhibited at the negative wire,
and a column of flame, which seemed to be owing to the development of
combustible matter, arose from the point of contact.
When the order was changed, so that the platina spoon was made
negative, a vivid and constant light appeared at the opposite point:
there was no effect of inflammation round it; but aeriform globules,
which inflamed in the atmosphere, rose through the potash.
The platina, as might have been expected, was considerably acted upon;
and in the cases when it had been negative, in the highest degree.
The alkali was apparently dry in this experiment; and it seemed
probable that the inflammable matter arose from its decomposition.
The residual potash was unaltered; it contained indeed a number of
dark grey metallic particles, but these proved to be derived from the
platina.
I tried several experiments on the electrization of potash rendered
fluid by heat, with the hopes of being able to collect the combustible
matter, but without success; and I only attained my object by employing
electricity as the common agent for fusion and decomposition.
Though potash, perfectly dried by ignition, is a non-conductor, yet it
is rendered a conductor by a very slight addition of moisture, which
does not perceptibly destroy its aggregation; and in this state it
readily fuses and decomposes by strong electrical powers.
A small piece of pure potash, which had been exposed for a few seconds
to the atmosphere, so as to give conducting power to the surface, was
placed upon an insulated disc of platina, connected with the negative
side of the battery of the power of 250 of 6 and 4, in a state of
intense activity; and a platina wire, communicating with the positive
side, was brought in contact with the upper surface of the alkali. The
whole apparatus was in the open atmosphere.
Under these circumstances a vivid action was soon observed to take
place. The potash began to fuse at both its points of electrization.
There was a violent effervescence at the upper surface; at the lower,
or negative surface, there was no liberation of elastic fluid; but
small globules having a high metallic lustre, and being precisely
similar in visible characters to quicksilver, appeared, some of which
burnt with explosion and bright flame, as soon as they were formed, and
others remained, and were merely tarnished, and finally covered by a
white film which formed on their surfaces.
These globules, numerous experiments soon showed to be the substance
I was in search of, and a peculiar inflammable principle the basis
of potash. I found that the platina was in no way connected with the
result, except as the medium for exhibiting the electrical powers of
decomposition; and a substance of the same kind was produced when
pieces of copper, silver, gold, plumbago, or even charcoal were
employed for completing the circuit.
The phenomenon was independent of the presence of air; I found that it
took place when the alkali was in the vacuum of an exhausted receiver.
The substance was likewise produced from potash fused by means of
a lamp, in glass tubes confined by mercury, and furnished with
hermetically inserted platina wires by which the electrical action
was transmitted. But this operation could not be carried on for any
considerable time; the glass was rapidly dissolved by the action of
the alkali, and this substance soon penetrated through the body of the
tube.
Soda, when acted upon in the same manner as potash, exhibited an
analogous result; but the decomposition demanded greater intensity
of action in the batteries, or the alkali was required to be in much
thinner and smaller pieces. With the battery of 100 of 6 inches in full
activity I obtained good results from pieces of potash weighing from
40 to 70 grains, and of a thickness which made the distance of the
electrified metallic surfaces nearly a quarter of an inch; but with a
similar power it was impossible to produce the effects of decomposition
on pieces of soda of more than 15 or 20 grains in weight, and that only
when the distance between the wires was about 1/8 or 1/10 of an inch.
The substance produced from potash remained fluid at the temperature of
the atmosphere at the time of its production; that from soda, which was
fluid in the degree of heat of the alkali during its formation, became
solid on cooling, and appeared having the lustre of silver.
When the power of 250 was used, with a very high charge for the
decomposition of soda, the globules often burnt at the moment of their
formation, and sometimes violently exploded and separated into smaller
globules, which flew with great velocity through the air in a state of
vivid combustion, producing a beautiful effect of continued jets of
fire.
THEORY OF THE DECOMPOSITION OF THE FIXED ALKALIES; THEIR COMPOSITION
AND PRODUCTION
As in all decompositions of compound substances which I had previously
examined, at the same time that combustible bases were developed at
the negative surface in the electrical circuit, oxygen was produced,
and evolved or carried into combination at the positive surface, it
was reasonable to conclude that this substance was generated in a
similar manner by the electrical action upon the alkalies; and a number
of experiments made above mercury, with the apparatus for excluding
external air, proved that this was the case.
When solid potash, or soda in its conducting state, was included
in glass tubes furnished with electrified platina wires, the new
substances were generated at the negative surfaces; the gas given out
at the other surface proved by the most delicate examination to be pure
oxygen; and unless an excess of water was present, no gas was evolved
from the negative surface.
In the synthetical experiments, a perfect coincidence likewise will be
found.
I mentioned that the metallic lustre of the substance from potash
immediately became destroyed in the atmosphere, and that a white crust
formed upon it. This crust I soon found to be pure potash, which
immediately deliquesced, and new quantities were formed, which in their
turn attracted moisture from the atmosphere till the whole globule
disappeared, and assumed the form of a saturated solution of potash.
When globules were placed in appropriate tubes containing common air
or oxygen gas confined by mercury, an absorption of oxygen took place;
a crust of alkali instantly formed upon the globule; but from the want
of moisture for its solution, the process stopped, the interior being
defended from the action of the gas.
With the substance from soda, the appearances and effects were
analogous.
When the substances were strongly heated, confined in given proportions
of oxygen, a rapid combustion with a brilliant white flame was
produced, and the metallic globules were found converted into a white
and solid mass, which in the case of the substance from potash was
found to be potash, and in the case of that from soda, soda.
Oxygen gas was absorbed in this operation, and nothing emitted which
affected the purity of the residual air.
The alkalies produced were apparently dry, or at least contained no
more moisture than might well be conceived to exist in the oxygen
gas absorbed; and their weights considerably exceeded those of the
combustible matters consumed.
The processes on which these conclusions are founded will be fully
described hereafter, when the minute details which are necessary will
be explained, and the proportions of oxygen, and of the respective
inflammable substances which enter into union to form the fixed
alkalies, will be given.
It appears, then, that in these facts there is the same evidence
for the decomposition of potash and soda into oxygen and two
peculiar substances, as there is for the decomposition of sulphuric
and phosphoric acids and the metallic oxides into oxygen and their
respective combustible bases.
In the analytical experiments, no substances capable of decomposition
are present but the alkalies and a minute portion of moisture; which
seems in no other way essential to the result, than in rendering them
conductors at the surface: for the new substances are not generated
till the interior, which is dry, begins to be fused; they explode when
in rising through the fused alkali they come in contact with the heated
moistened surface; they cannot be produced from crystallised alkalies,
which contain much water; and the effect produced by the electrization
of ignited potash, which contains no sensible quantity of water,
confirms the opinion of their formation independently of the presence
of this substance.
The combustible bases of the fixed alkalies seem to be repelled as
other combustible substances, by positively electrified surfaces, and
attracted by negatively electrified surfaces, and the oxygen follows
the contrary order; or the oxygen being naturally possessed of the
negative energy, and the bases of the positive, do not remain in
combination when either of them is brought into an electrical state
opposite to its natural one. In the synthesis, on the contrary, the
natural energies or attractions come in equilibrium with each other;
and when these are in a low state at common temperatures, a slow
combination is effected; but when they are exalted by heat, a rapid
motion is the result; and as in other like cases with the production of
fire.
FOOTNOTES:
[Footnote 28: From the _Transactions of the Royal Society of
London_.]
XXVI
MICHAEL FARADAY
1791-1867
_Born on September 22, 1791, at Newington, Surrey, England,
Michael Faraday was the son of a blacksmith. After an early and very
elementary education, he was apprenticed in 1805 to a book-binder in
whose service he read widely and thus educated himself. Developing an
interest in physics, he attended the evening lectures of Sir Humphrey
Davy who, in 1813, engaged him as an assistant. Seven years later he
wrote a history of electro-magnetism and succeeded, in the same year,
in getting a needle to rotate fully around a live wire. In 1823 he
liquefied chlorine, an experiment which destroyed the old notion of the
permanent distinction between gases and liquids. In 1831 he discovered
magneto-electric induction and advanced the conception of “lines of
magnetic force.” In 1845, in trying to send polarized rays of light
through heavy magnetized glass, he found that the magnet’s action
interrupted the passage of the light and that magnetization caused the
plane of polarization to rotate. He died August 25, 1867._
ON FLUID CHLORINE[29]
_Read March 13, 1823._
It is well known that before the year 1810, the solid substance
obtained by exposing chlorine, as usually procured, to a low
temperature, was considered as the gas itself reduced into that form;
and that Sir Humphrey Davy first showed it to be a hydrate, the pure
dry gas not being considerable even at a temperature of 40° F.
I took advantage of the late cold weather to procure crystals of this
substance for the purpose of analysis. The results are contained
in a short paper in the Quarterly Journal of Science, Vol. XV. Its
composition is very nearly 27.7 chlorine, 72.3 water, or 1 proportional
of chlorine, and 10 of water.
The President of the Royal Society having honoured me by looking at
these conclusions, suggested, that an exposure of the substance to
heat under pressure, would probably lead to interesting results; the
following experiments were commenced at his request. Some hydrate
of chlorine was prepared, and being dried as well as could be by
pressure in bibulous paper, was introduced into a sealed glass tube,
the upper end of which was then hermetically closed. Being placed
in water at 60°, it underwent no change; but when put into water
at 100°, the substance fused, the tube became filled with a bright
yellow atmosphere, and, on examination, was found to contain two
fluid substances: the one, about three-fourths of the whole, was of
a faint yellow colour, having very much the appearance of water; the
remaining fourth was a heavy bright yellow fluid, lying at the bottom
of the former, without any apparent tendency to mix with it. As the
tube cooled, the yellow atmosphere condensed into more of the yellow
fluid, which floated in a film on the pale fluid, looking very like
chloride of nitrogen; and at 70° the pale portion congealed, although
even at 32° the yellow portion did not solidify. Heated up to 100° the
yellow fluid appeared to boil, and again produced the bright coloured
atmosphere.
By putting the hydrate into a bent tube, afterwards hermetically
sealed, I found it easy, after decomposing it by a heat of 100°, to
distil the yellow fluid to one end of the tube, and so separate it from
the remaining portion. In this way a more complete decomposition of the
hydrate was effected, and, when the whole was allowed to cool, neither
of the fluids solidified at temperatures above 34°, and the yellow
portion not even at 0°. When the two were mixed together they gradually
combined at temperatures below 60°, and formed the same solid substance
as that first introduced. If, when the fluids were separated, the tube
was cut in the middle, the parts flew asunder as if with an explosion,
the whole of the yellow portion disappeared, and there was a powerful
atmosphere of chlorine produced; the pale portion on the contrary
remained, and when examined, proved to be a weak solution of chlorine
in water, with a little muriatic acid, probably from the impurity of
the hydrate used. When that end of the tube in which the yellow fluid
lay was broken under a jar of water, there was an immediate production
of chlorine gas.
I at first thought that muriatic acid and euchlorine had been formed;
then, that two new hydrates of chlorine had been produced; but at
last I suspected that the chlorine had been entirely separated from
the water by the heat and condensed into a dry fluid by the mere
pressure of its own abundant vapour. If that were true, it followed,
that chlorine gas, when compressed, should be condensed into the
same fluid, and, as the atmosphere in the tube in which the fluid
lay was not very yellow at 50° or 60°, it seemed probable that the
pressure required was not beyond what could readily be obtained by a
condensing syringe. A long tube was therefore furnished with a cap and
stop-cock, then exhausted of air and filled with chlorine, and being
held vertically with the syringe upwards, air was forced in, which
thrust the chlorine to the bottom of the tube, and gave a pressure of
about 4 atmospheres. Being now cooled, there was an immediate deposit
in films, which appeared to be hydrate, formed by water contained in
the gas and vessels, but some of the yellow fluid was also produced.
As this however might also contain a portion of the water present,
a perfectly dry tub and apparatus were taken, and the chlorine left
for some time over a bath of sulphuric acid before it was introduced.
Upon throwing in air and giving pressure, there was now no solid film
formed, but the clear yellow fluid was deposited, and more abundantly
still upon cooling. After remaining some time it disappeared, having
gradually mixed with the atmosphere above it, but every repetition of
the experiment produced the same results.
Presuming that I had now a right to consider the yellow fluid as pure
chlorine in the liquid state, I proceeded to examine its properties,
as well as I could when obtained by heat from the hydrate. However
obtained, it always appears very limpid and fluid, and excessively
volatile at common pressure. A portion was cooled in its tube to 0°;
it remained fluid. The tube was then opened, when a part immediately
flew off, leaving the rest so cooled by the evaporation as to remain a
fluid under the atmospheric pressure. The temperature could not have
been higher than 40° in this case; as Sir Humphrey Davy has shown
that dry chlorine does not condense at that temperature under common
pressure. Another tube was opened at a temperature of 50°; a part of
the chlorine volatilised, and cooled the tube so much as to condense
the atmospheric vapour on it as ice.
A tube having the water at one end and the chlorine at the other was
weighed, and then cut in two; the chlorine immediately flew off, and
the loss being ascertained was found to be 1.6 grains: the water
left was examined and found to contain some chlorine: its weight was
ascertained to be 5.4 grains. These proportions, however, must not
be considered as indicative of the true composition of hydrate of
chlorine; for, from the mildness of the weather during the time when
these experiments were made, it was impossible to collect the crystals
of hydrate, press, and transfer them, without losing much chlorine; and
it is also impossible to separate the chlorine and water in the tube
perfectly, or keep them separate, as the atmosphere within will combine
with the water, and gradually reform the hydrate.
Before cutting the tube, another tube had been prepared exactly like it
in form and size, and a portion of water introduced into it, as near as
the eye could judge, of the same bulk as the fluid chlorine: this water
was found to weigh 1.2 grains; a result, which, if it may be trusted,
would give the specific gravity of fluid chlorine as 1.33; and from its
appearance in, and on water, this cannot be far wrong.
ELECTRICITY FROM MAGNETISM
_Read November 24, 1831._
1. The power which electricity of tension possesses of causing an
opposite electrical state in its vicinity has been expressed by the
general term Induction; which, as it has been received into scientific
language, may also, with propriety, be used in the same general sense
to express the power which electrical currents may possess of inducing
any particular state upon matter in their immediate neighborhood,
otherwise indifferent. It is with this meaning that I purpose using it
in the present paper.
2. Certain effects of the induction of electrical currents have already
been recognized and described: as those of magnetization; Ampère’s
experiments of bringing a copper disc near to a flat spiral; his
repetition with electro-magnets of Arago’s extraordinary experiments,
and perhaps a few others. Still it appeared unlikely that these
could be all the effects which induction by currents could produce;
especially as, upon dispensing with iron, almost the whole of them
disappear, whilst yet an infinity of bodies, exhibiting definite
phenomena of induction with electricity of tension still remain to be
acted upon by the induction of electricity in motion.
3. Further: whether Ampère’s beautiful theory were adopted, or any
other, or whatever reservation were mentally made, still it appeared
very extraordinary, that, as every electric current was accompanied by
a corresponding intensity of magnetic action at right angles to the
current, good conductors of electricity, when placed within the sphere
of this action, should not have any current induced through them, or
some sensible effect produced equivalent in force to such a current.
4. These considerations, with their consequence, the hope of obtaining
electricity from ordinary magnetism, have stimulated me at various
times to investigate experimentally the inductive effect of electric
currents. I lately arrived at positive results; and not only had my
hopes fulfilled, but obtained a key which appeared to me to open out a
full explanation of Arago’s magnetic phenomena, and also to discover a
new state, which may probably have great influence in some of the most
important effects of electric currents.
5. These results I purpose describing, not as they were obtained, but
in such a manner as to give the most concise view of the whole.
EVOLUTION OF ELECTRICITY FROM MAGNETISM
27. A welded ring was made of soft round bar-iron, the metal being
seven-eighths of an inch in thickness, and the ring six inches in
external diameter. Three helices were put round one part of this ring,
each containing about twenty-four feet of copper wire one-twentieth
of an inch thick; they were insulated from the iron and each other,
and superposed in the manner before described (6), occupying about
nine inches in length upon the ring. They could be used separately or
conjointly; the group may be distinguished by the letter A. On the
other part of the ring about sixty feet of similar copper wire in two
pieces were applied in the same manner, forming a helix B, which had
the same common direction with the helices of A, but being separated
from it at each extremity by about half an inch of the uncovered iron.
28. The helix B, was connected by copper wires with a galvanometer
three feet from the ring. The helices of A were connected end to
end so as to form one common helix, the extremities of which were
connected with a battery of ten pairs of plates four inches square. The
galvanometer was immediately affected, and to a degree far beyond what
has been described when with a battery of tenfold power helices without
iron were used (10); but though the contact was continued, the effect
was not permanent, for the needle soon came to rest in its natural
position, as if quite indifferent to the attached electro-magnetic
arrangement. Upon breaking the contact with the battery, the needle
was again powerfully deflected, but in the contrary direction to that
induced in the first instance.
29. Upon arranging the apparatus so that B should be out of use, the
galvanometer be connected with one of the three wires of A (27), and
the other two made into a helix through which the current from the
trough (28) was passed, similar but rather more powerful effects were
produced.
30. When the battery contact was made in one direction, the
galvanometer-needle was deflected on the one side; if made in the other
direction, the deflection was on the other side. The deflection on
breaking the battery contact was always the reverse of that produced
by completing it. The deflection on making a battery contact always
indicated an induced current in the opposite direction to that from
the battery; but on breaking the contact the deflection indicated
an induced current in the same direction as that of the battery.
No making or breaking of the contact at B side, or in any part of
the galvanometer circuit, produced any effect at the galvanometer.
No continuance of the battery current caused any deflection of the
galvanometer-needle. As the above results are common to all these
experiments, and to similar ones with ordinary magnets to be hereafter
detailed, they need not be again particularly described.
31. Upon using the power of 100 pairs of plates (10) with this ring,
the impulse at the galvanometer, when contact was completed or broken,
was so great as to make the needle spin round rapidly four or five
times, before the air and terrestrial magnetism could reduce its motion
to mere oscillation.
39. But as might be supposed that in all the preceding experiments of
this section, it was by some peculiar effect taking place during the
formation of the magnet, and not by its mere virtual approximation,
that the momentary induced current was excited, the following
experiment was made. All the similar ends of the compound hollow
helix (34) were bound together by copper wire, forming two general
terminations, and these were connected with the galvanometer. The soft
iron cylinder (34) was removed, and a cylindrical magnet three-quarters
of an inch in diameter and eight inches and a half in length, used
instead. One end of this magnet was introduced into the axis of the
helix and then, the galvanometer-needle being stationary, the magnet
was suddenly thrust in; immediately the needle was deflected in the
same direction as if the magnet had been formed by either of the two
preceding processes (34, 36). Being left in, the needle resumed its
first position, and then the magnet being withdrawn the needle was
deflected in the opposite direction. These effects were not great; but
by introducing and withdrawing the magnet, so that the impulse each
time should be added to those previously communicated to the needle,
the latter could be made to vibrate through an arc of 180° or more.
40. In this experiment the magnet must not be passed entirely through
the helix, for then a second action occurs. When the magnet is
introduced the needle at the galvanometer is deflected in a certain
direction; but being in, whether it be pushed quite through or
withdrawn, the needle is deflected in a direction the reverse of that
previously produced. When the magnet is passed in and through at one
continuous motion, the needle moves one way, is then suddenly stopped,
and finally moves the other way.
41. If such a hollow helix as that described (34) be laid east and west
(or in any other constant position), and a magnet be retained east and
west, its marked pole always being one way; then whichever end of the
helix the magnet goes in at, and consequently whichever pole of the
magnet enters first, still the needle is deflected the same way: on the
other hand, whichever direction is followed in withdrawing the magnet,
the deflection is constant, but contrary to that due to its entrance.
57. The various experiments of this section prove, I think, most
completely the production of electricity from ordinary magnetism.
That its intensity should be very feeble and quantity small,
cannot be considered wonderful, when it is remembered that like
thermo-electricity it is evolved entirely within the substance of
metals retaining all their conducting power. But an agent which is
conducted along the metallic wires in the manner described; which,
whilst so passing possesses the peculiar magnetic actions and force
of a current of electricity; which can agitate and convulse the limbs
of a frog; and which, finally, can produce a spark by its discharge
through charcoal (32), can only be electricity. As all the effects can
be produced by ferruginous electro-magnets (34), there is no doubt that
arrangements like the magnets of Professors Moll, Henry, Ten Eyke, and
others, in which as many as two thousand pounds have been lifted, may
be used for these experiments; in which case not only a brighter spark
may be obtained, but wires also ignited, and, as the current can pass
liquids (23), chemical action be produced. These effects are still
more likely to be obtained when the magneto-electric arrangements to
be explained in the fourth section are excited by the powers of such
apparatus.
58. The similarity of action, almost amounting to identity, between
common magnets and either electro-magnets or volta-electric currents,
is strikingly in accordance with and confirmatory of M. Ampère’s
theory, and furnishes powerful reasons for believing that the action
is the same in both cases; but, as a distinction in language is still
necessary, I propose to call the agency thus exerted by ordinary
magnets, magneto-electric or magnelectric induction (26).
59. The only difference which powerfully strikes the attention as
existing between volta-electric and magneto-electric induction, is the
suddenness of the former, and the sensible time required by the latter:
but even in this early state of investigation there are circumstances
which seem to indicate, that upon further inquiry this difference will,
as a philosophical distinction, disappear (68).
FOOTNOTES:
[Footnote 29: This excerpt and the one following are from the
_Transactions of the Royal Society of London_.]
XXVII
JOSEPH HENRY
1797-1878
_Born at Albany, New York, December 17, 1797, Joseph Henry prepared
for the profession of medicine, but an appointment as an assistant
engineer on the state road diverted his interests toward mechanics.
In 1826 he was appointed instructor of physics at Albany Institute,
now the Albany Boys Academy, where he conducted his first experiments
in electricity. In 1828 he first produced a strong electro-magnet by
winding fine insulated wire around a piece of soft iron, and soon
succeeded in exciting his electro-magnet at a distance by the use of
high intensity batteries made up of many cells. Demonstrating that
the number of coils of fine wire about a magnet had as much influence
as the intensity of the current and that after winding many coils
around the soft iron magnet it could still be made magnetic, he
suggested the principle which Morse later used in the telegraph. In
1832 he discovered that in a long conductor the primary current, by an
induction upon itself, produced a number of secondary currents that
greatly increased the intensity of the discharge._
_He was appointed professor of natural philosophy at Princeton
University in 1832 and became secretary of the Smithsonian Institution
in 1846. He died in Washington, May 13, 1878._
ON THE PRODUCTION OF CURRENTS AND SPARKS OF ELECTRICITY FROM
MAGNETISM[30]
Although the discoveries of Oersted, Arago, Faraday, and others, have
placed the intimate connection of electricity and magnetism in a most
striking point of view, and although the theory of Ampère has referred
all the phenomena of both these departments of science to the same
general laws, yet until lately one thing remained to be proved by
experiment, in order more fully to establish their identity; namely,
the possibility of producing electrical effects from magnetism.
It is well known that surprising magnetic results can readily be
obtained from electricity, and at first sight it might be supposed
that electrical effects could with equal facility be produced from
magnetism; but such has not been found to be the case, for although the
experiment has often been attempted, it has nearly as often failed.
It early occurred to me that if galvanic magnets on my plan were
substituted for ordinary magnets, in researches of this kind, more
success might be expected. Besides their great powers these magnets
possess other properties, which render them important instruments in
the hands of the experimenter; their polarity can be instantaneously
reversed, and their magnetism suddenly destroyed or called into full
action, according as the occasion may require. With this view, I
commenced, last August, the construction of a much larger galvanic
magnet than, to my knowledge, had before been attempted, and also made
preparations for a series of experiments with it on a large scale,
in reference to the production of electricity from magnetism. I was,
however, at that time accidentally interrupted in the prosecution of
these experiments, and have not been able since to resume them until
within the last few weeks, and then on a much smaller scale than was
at first intended. In the meantime, it has been announced in the 117th
number of the _Library of Useful Knowledge_, that the result
so much sought after has at length been found by Mr. Faraday of the
Royal Institution. It states that he has established the general fact,
that when a piece of metal is moved in any direction, in front of a
magnetic pole, electrical currents are developed in the metal, which
pass in a direction at right angles to its own motion, and also that
the application of this principle affords a complete and satisfactory
explanation of the phenomena of magnetic rotation. No detail is given
of the experiments, and it is somewhat surprising that results so
interesting, and which certainly form a new era in the history of
electricity and magnetism, should not have been more fully described
before this time in some of the English publications; the only mention
I have found of them is the following short account from the _Annals
of Philosophy_ for April, under the head of Proceedings of the Royal
Institution:
“Feb. 17.--Mr. Faraday gave an account of the first two parts of
his researches in electricity; namely, Volta-electric induction and
magneto-electric induction. If two wires, A and B, be placed side by
side, but not in contact, and a Voltaic current be passed through
A, there is instantly a current produced by induction in B, in the
opposite direction. Although the principal current in A be continued,
still the secondary current in B is not found to accompany it, for
it ceases after the first moment, but when the principal current is
stopped, then there is a second current produced in B, in the opposite
direction to that of the first produced by the inductive action, or in
the same direction as that of the principal current.
“If a wire, connected at both extremities with a galvanometer,
be coiled in the form of a helix around a magnet, no current of
electricity takes place in it. This is an experiment which has been
made by various persons hundreds of times, in the hope of evolving
electricity from magnetism, and in other cases in which the wishes of
the experimenter and the facts are opposed to each other, has given
rise to very conflicting conclusions. But if the magnet be withdrawn
from or introduced into such a helix, a current of electricity is
produced whilst the magnet is in motion, and is rendered evident by
the deflection of the galvanometer. If a single wire be passed by a
magnetic pole, a current of electricity is induced through it which
can be rendered sensible.”
Before having any knowledge of the method given in the above account, I
had succeeded in producing electrical effects in the following manner,
which differs from that employed by Mr. Faraday, and which appears to
me to develop some new and interesting facts. A piece of copper wire,
about thirty feet long and covered with elastic varnish, was closely
coiled around the middle of the soft iron armature of the galvanic
magnet described in Vol. XIX of the _American Journal of Science_,
and which, when excited, will readily sustain between six hundred and
seven hundred pounds. The wire was wound upon itself so as to occupy
only about one inch of the length of the armature which is seven inches
in all. The armature, thus furnished with the wire, was placed in its
proper position across the ends of the galvanic magnet, and there
fastened so that no motion could take place. The two protecting ends
of the helix were dipped into two cups of mercury, and there connected
with a distant galvanometer by means of two copper wires, each about
forty feet long. This arrangement being completed, I stationed myself
near the galvanometer and directed an assistant at a given word to
immerse suddenly, in a vessel of dilute acid, the galvanic battery
attached to the magnet. At the instant of immersion, the north end
of the needle was deflected 30° to the west, indicating a current
of electricity from the helix surrounding the armature. The effect,
however, appeared only as a single impulse, for the needle, after a few
oscillations, resumed its former undisturbed position in the magnetic
meridian, although the galvanic action of the battery, and consequently
the magnetic power, was still continued. I was, however, much surprised
to see the needle suddenly deflected from a state of rest to about 20°
to the east, or in a contrary direction when the battery was withdrawn
from the acid, and again deflected to the west when it was re-immersed.
This operation was repeated many times in succession, and uniformly
with the same result, the armature the whole time remaining immovably
attached to the poles of the magnet, no motion being required to
produce the effect, as it appeared to take place only in consequence of
the instantaneous development of the magnetic action in one, and the
sudden cessation of it in the other.
This experiment illustrates most strikingly the reciprocal action of
the two principles of electricity and magnetism, if indeed it does not
establish their absolute identity. In the first place, magnetism is
developed in the soft iron of the galvanic magnet by the action of the
currents of electricity from the battery, and secondly, the armature,
rendered magnetic by contact with the poles of the magnet, induces in
its turn currents of electricity in the helix which surrounds it; we
have thus, as it were, electricity converted into magnetism and this
magnetism again into electricity.
Another fact was observed which is somewhat interesting, inasmuch as it
serves in some respects to generalize the phenomena. After the battery
had been withdrawn from the acid, and the needle of the galvanometer
suffered to come to a state of rest after the resulting deflection, it
was again deflected in the same direction by partially detaching the
armature from the poles of the magnet to which it continued to adhere
from the action of the residual magnetism, and in this way, a series of
deflections, all in the same direction, was produced by merely slipping
off the armature by degrees until the contact was entirely broken. The
following extract from the register of the experiments exhibits the
relative deflections observed in one experiment of this kind.
At the instant of immersion of the battery, deflection 40° west.
At the instant of emersion of the battery, deflection 18° east.
Armature partially detached, deflection 7° east.
Armature entirely detached, deflection 12° west.
The effect was reversed in another experiment, in which the needle was
turned to the west in a series of deflections by dipping the battery
but a small distance into the acid at first and afterwards immersing it
by degrees.
From the foregoing facts it appears that a current of electricity is
produced, for an instant, in a helix of copper wire surrounding a piece
of soft iron whenever magnetism is induced in the iron; and a current
in an opposite direction when the magnetic action ceases; also that an
instantaneous current in one or the other direction accompanies every
change in the magnetic intensity of the iron.
Since reading the account before given of Mr. Faraday’s method of
producing electrical currents I have attempted to combine the effects
of motion and induction; for this purpose a rod of soft iron ten inches
long and one inch and a quarter in diameter, was attached to a common
turning lathe, and surrounded with four helices of copper wire in such
a manner that it could be suddenly and powerfully magnetized, while
in rapid motion, by transmitting galvanic currents through three of
the helices; the fourth being connected with the distant galvanometer
was intended to transmit the current of induced electricity; all the
helices were stationary while the iron rod revolved on its axis within
them. From a number of trials in succession, first with the rod in one
direction, then in the opposite, and next in a state of rest, it was
concluded that no perceptible effect was produced on the intensity of
the magneto-electric current by a rotary motion of the iron combined
with its sudden magnetization.
The same apparatus, however, furnished the means of measuring
separately the relative power of motion and induction in producing
electrical currents. The iron rod was first magnetized by currents
through the helices attached to the battery and while in this state
one of its ends was quickly introduced into the helix connected with
the galvanometer; the deflection of the needle in this case was
seven degrees. The end of the rod was next introduced into the same
helix while in its natural state and then suddenly magnetized; the
deflection in this instance amounted to thirty degrees, showing a great
superiority in the method of induction.
The next attempt was to increase the magneto-electric effect while the
magnetic power remained the same, and in this I was more successful.
Two iron rods six inches long and one inch in diameter were each
surrounded by two helices and then placed perpendicularly on the
face of the armature, and between it and the poles of the magnet,
so that each rod formed, as it were, a prolongation of the poles,
and to these the armature adhered when the magnet was excited. With
this arrangement, a current from one helix produced a deflection of
thirty-seven degrees; from two helices both on the same rod, fifty-two
degrees, and from three fifty-nine degrees; but when four helices
were used, the deflection was only fifty-five degrees, and when to
these were added the helix of smaller wire around the armature, the
deflection was no more than thirty degrees. This result may perhaps
have been somewhat affected by the want of proper insulation in the
several spires of the helices; it, however, establishes the fact that
an increase in the electric current is produced by using at least
two or three helices instead of one. The same principle was applied
to another arrangement which seems to afford the maximum of electric
development from a given magnetic power; in place of the two pieces of
iron and the armature used in the last experiments, the poles of the
magnet were connected by a single rod of iron, bent into the form of a
horse-shoe, and its extremities filed perfectly flat so as to come in
perfect contact with the faces of the poles; around the middle of the
arch of this horse-shoe, two strands of copper wire were tightly coiled
one over the other. A current from one of these helices deflected the
needle one hundred degrees, and when both were used the needle was
deflected with such force as to make a complete circuit. But the most
surprising effect was produced when, instead of passing the current
through the long wires to the galvanometer, the opposite ends of the
helices were held nearly in contact with each other, and the magnet
suddenly excited; in this case a small but vivid spark was seen to pass
between the ends of the wires, and this effect was repeated as often as
the state of intensity of the magnet was changed.
In these experiments the connection of the battery with the wires from
the magnet was not formed by soldering, but by two cups of mercury,
which permitted the galvanic action on the magnet to be instantaneously
suspended and the polarity to be changed and rechanged without removing
the battery from the acid; a succession of vivid sparks was obtained
by rapidly interrupting and forming the communication by means of one
of these cups; but the greatest effect was produced when the magnetism
was entirely destroyed and instantaneously reproduced by a change of
polarity.
It appears from the May number of the _Annals of Philosophy_ that
I have been anticipated in this experiment of drawing sparks from the
magnet by Mr. James D. Forbes of Edinburgh, who obtained a spark on the
30th of March; my experiment being made during the last two weeks of
June. A simple notification of his result is given, without any account
of the experiment, which is reserved for a communication to the Royal
Society of Edinburgh; my result is therefore entirely independent of
his and was undoubtedly obtained by a different process.
ELECTRICAL SELF-INDUCTION IN A LONG HELICAL WIRE
I have made several other experiments in relation to the same subject,
but which more important duties will not permit me to verify in time
for this paper. I may, however, mention one fact which I have not seen
noticed in any work, and which appears to me to belong to the same
class of phenomena as those before described; it is this: when a small
battery is moderately excited by diluted acid, and its poles, which
should be terminated by cups of mercury, are connected by a copper
wire not more than a foot in length, no spark is perceived when the
connection is either formed or broken; but if a wire thirty or forty
feet long be used instead of the short wire, though no spark will be
perceptible when the connection is made, yet when it is broken by
drawing one end of the wire from its cup of mercury, a vivid spark
is produced. If the action of the battery be very intense, a spark
will be given by the short wire; in this case it is only necessary to
wait a few minutes until the action partially subsides, and until no
more sparks are given from the short wire; if the long wire be now
substituted a spark will again be obtained. The effect appears somewhat
increased by coiling the wire into a helix; it seems also to depend in
some measure on the length and thickness of the wire. I can account for
these phenomena only by supposing the long wire to become charged with
electricity, which by its reaction on itself projects a spark when the
connection is broken.
FOOTNOTES:
[Footnote 30: Silliman’s _American Journal of Science_, July,
1832, Vol. XXII, pp. 403-408; _Scientific Writings_, Vol. I., p.
73.]
XXVIII
SIR CHARLES LYELL
1797-1875
_Sir Charles Lyell, the son of a Scottish botanist of literary
tastes, was born at Kinnordy, Scotland, November 14, 1797. He went to
Oxford University, from which he graduated in 1819. He was admitted to
the bar in 1825. In 1827 he abandoned law for geology, and published
his “Principles of Geology” in 1830-1833. Lyell’s thesis was that
all the past changes of the earth were explainable by forces now
operative--an idea which underlies modern geology. He published his
“Antiquity of Man” in 1863, providing proofs of man’s long existence
on earth and thus contributing to the establishment of the Darwinian
theory. He died February 22, 1875._
UNIFORMITY IN THE SERIES OF PAST CHANGES IN THE ANIMATE AND INANIMATE
WORLD[31]
_Origin of the doctrine of alternate periods of repose and
disorder._--It has been truly observed that when we arrange the
fossiliferous formations in chronological order, they constitute
a broken and defective series of monuments; we pass without any
intermediate gradations from systems of strata which are horizontal, to
other systems which are highly inclined--from rocks of peculiar mineral
composition to others which have a character wholly distinct--from one
assemblage of organic remains to another, in which frequently nearly
all the species, and a large part of the genera, are different. These
violations of continuity are so common as to constitute in most regions
the rule rather than the exception, and they have been considered by
many geologists as conclusive in favour of sudden revolutions in the
inanimate and animate world. We have already seen that according to
the speculations of some writers, there have been in the past history
of the planet alternate periods of tranquility and convulsion, the
former enduring for ages, and resembling the state of things now
experienced by man; the other brief, transient, and paroxysmal, giving
rise to new mountains, seas, and valleys, annihilating one set of
organic beings and ushering in the creation of another.
It will be the object of the present chapter to demonstrate that
these theoretical views are not borne out by a fair interpretation of
geological monuments. It is true that in the solid framework of the
globe we have a chronological chain of natural records, many links of
which are wanting: but a careful consideration of all the phenomena
leads to the opinion that the series was originally defective--that
it has been rendered still more so by time--that a great part of what
remains is inaccessible to man, and even of that fraction which is
accessible nine-tenths or more are to this day unexplored.
The readiest way, perhaps, of persuading the reader that we may
dispense with great and sudden revolutions in the geological order
of events is by showing him how a regular and uninterrupted series
of changes in the animate and inanimate world must give rise to such
breaks in the sequence, and such unconformability of stratified rocks,
as are usually thought to imply convulsions and catastrophes. It is
scarcely necessary to state that the order of events thus assumed to
occur, for the sake of illustration, should be in harmony with all
the conclusions legitimately drawn by geologists from the structure
of the earth, and must be equally in accordance with the changes
observed by man to be now going on in the living as well as in the
inorganic creation. It may be necessary in the present state of science
to supply some part of the assumed course of nature hypothetically;
but if so, this must be done without any violation of probability,
and always consistently with the analogy of what is known both of the
past and present economy of our system. Although the discussion of so
comprehensive a subject must carry the beginner far beyond his depth,
it will also, it is hoped, stimulate his curiosity, and prepare him to
read some elementary treatises on geology with advantage, and teach
him the bearing on that science of the changes now in progress on the
earth. At the same time it may enable him the better to understand the
intimate connection between the Second and Third Books of this work,
one of which is occupied with the changes of the inorganic, the latter
with those of the organic creation.
In pursuance, then, of the plan above proposed, I will consider
in this chapter, first, the laws which regulate the denudation of
strata and the deposition of sediment; secondly, those which govern
the fluctuation in the animate world; and thirdly, the mode in which
subterranean movements affect the earth’s crust.
_Uniformity of change considered, first, in reference to denudation
and sedimentary deposition._--First, in regard to the laws governing
the deposition of new strata. If we survey the surface of the globe,
we immediately perceive that it is divisible into areas of deposition
and non-deposition; or, in other words, at any given time there are
spaces which are the recipients, others which are not the recipients,
of sedimentary matter. No new strata, for example, are thrown down on
dry land, which remains the same from year to year; whereas, in many
parts of the bottom of seas and lakes, mud, sand, and pebbles are
annually spread out by rivers and currents. There are also great masses
of limestone growing in some seas, chiefly composed of corals and
shells, or, as in the depths of the Atlantic, of chalky mud made up of
foraminifera and diatomaceæ.
As to the dry land, so far from being the receptacle of fresh
accessions of matter, it is exposed almost everywhere to waste away.
Forests may be as dense and lofty as those of Brazil, and may swarm
with quadrupeds, birds, and insects, yet at the end of thousands of
years one layer of black mould a few inches thick may be the sole
representative of those myriads of trees, leaves, flowers, and fruits,
those innumerable bones and skeletons of birds, quadrupeds, and
reptiles, which tenanted the fertile region. Should this land be at
length submerged, the waves of the sea may wash away in a few hours
the scanty covering of mould, and it may merely import a darker shade
of colour to the next stratum of marl, sand, or other matter newly
thrown down. So also at the bottom of the ocean where no sediment is
accumulating, seaweed, zoophytes, fish, and even shells, may multiply
for ages and decompose, leaving no vestige of their form or substance
behind. Their decay, in water, although more slow, is as certain and
eventually as complete as in the open air. Nor can they be perpetuated
for indefinite periods in a fossil state, unless imbedded in some
matrix which is impervious to water, or which at least does not allow
a free percolation of that fluid, impregnated as it usually is, with
a slight quantity of carbonic or other acid. Such a free percolation
may be prevented either by the mineral nature of the matrix itself,
or by the superposition of an impermeable stratum; but if unimpeded,
the fossil shell or bone will be dissolved and removed, particle after
particle, and thus entirely effaced, unless petrification or the
substitution of some mineral for the organic matter happen to take
place.
That there has been land as well as sea at all former geological
periods, we know from the fact that fossil trees and terrestrial plants
are imbedded in rocks of every age, except those which are so ancient
as to be very imperfectly known to us. Occasionally lacrustine and
fluviatile shells, or the bones of amphibious or land reptiles, point
to the same conclusion. The existence of dry land at all periods of the
past implies, as before mentioned, the partial deposition of sediment,
or its limitation to certain areas; and the next point to which I shall
call the reader’s attention is the shifting of these areas from one
region to another.
First, then, variations in the site of sedimentary deposition are
brought about independently of subterranean movements. There is always
a slight change from year to year, or from century to century. The
sediment of the Rhone, for example, thrown in the Lake of Geneva, is
now conveyed to a spot a mile and a half distant from that where it
accumulated in the tenth century, and six miles from the point where
the delta began originally to form. We may look forward to the period
when this lake will be filled up, and then the distribution of the
transported matter will be suddenly altered, for the mud and sand
brought down from the Alps will thenceforth, instead of being deposited
near Geneva, be carried nearly 200 miles southwards, where the Rhone
enters the Mediterranean.
In the deltas of large rivers, such as those of the Ganges and Indus,
the mud is first carried down for many centuries through one arm,
and on this being stopped up it is discharged by another, and may
then enter the sea at a point 50 or 100 miles distant from its first
receptacle. The direction of marine currents is also liable to be
changed by various accidents, as by the heaping up of new sandbanks, or
the wearing away of cliffs and promontories.
But, secondly, all these causes of fluctuation in the sedimentary areas
are entirely subordinate to those great upward or downward movements
of lands, which will be presently spoken of, as prevailing over large
tracts of the globe. By such elevation or subsidence certain spaces
are gradually submerged, or made gradually to emerge: in the one case
sedimentary deposition may be suddenly renewed after having been
suspended for one or more geological periods, in the other as suddenly
made to cease after having continued for ages.
If deposition be renewed after a long interval, the new strata will
usually differ greatly from the sedimentary rocks previously formed
in the same place, and especially if the older rocks have suffered
derangement, which implies a change in the physical geography of the
district since the previous conveyance of sediment to the same spot. It
may happen, however, that, even where the two groups, the superior and
the inferior, are horizontal and conformable to each other, they may
still differ entirely in mineral character, because, since the origin
of the older formation, the geography of some distant country has
been altered. In that country rocks before concealed may have become
exposed by denudation; volcanoes may have burst out and covered the
surface with scoriæ and lava; or new lakes, intercepting the sediment
previously conveyed from the upper country, may have been formed by
subsidence; and other fluctuations may have occurred, by which the
materials brought down from thence by rivers to the sea have acquired a
distinct mineral character.
It is well known that the stream of the Mississippi is charged with
sediment of a different colour from that of the Arkansas and Red
Rivers, which are tinged with red mud, derived from rocks of porphyry
and red gypseous clays in “the far west.” The waters of the Uruguay,
says Darwin, draining a granitic country, are clear and black, those
of the Parana, red. The mud with which the Indus is loaded, says
Burnes, is of a clayey hue, that of the Chenab, on the other hand, is
reddish, that of the Sutlej is more pale. The same causes which make
these several rivers, sometimes situated at no great distance the one
from the other, to differ greatly in the character of their sediment,
will make the waters draining the same country at different epochs,
especially before and after great revolutions in physical geography,
to be entirely dissimilar. It is scarcely necessary to add that marine
currents will be affected in an analogous manner in consequence of the
formation of new shoals, the emergence of new islands, the subsidence
of others, the gradual waste of neighbouring coasts, the growth of
new deltas, the increase of coral reefs, volcanic eruptions, and other
changes.
_Uniformity of change considered, secondly, in reference to the
living creation._--Secondly, in regard to the vicissitudes of
the living creation, all are agreed that the successive groups of
sedimentary strata found in the earth’s new crust are not only
dissimilar in mineral composition for reasons above alluded to, but are
likewise distinguishable from each other by their organic remains. The
general inference drawn from the study and comparison of the various
groups, arranged in chronological order, is this: that at successive
periods distinct tribes of animals and plants have inhabited the land
and waters, and that the organic types of the newer formations are more
analogous to species now existing than those of more ancient rocks. If
we then turn to the present state of the animate creation, and inquire
whether it has now become fixed and stationary, we discover that, on
the contrary, it is in a state of continual flux--that there are many
causes in action which tend to the extinction of species, and which are
conclusive against the doctrine of their unlimited durability.
There are also causes which give rise to new varieties and races in
plants and animals, and new forms are continually supplanting others
which had endured for ages. But natural history has been successfully
cultivated for so short a period, that a few examples only of local,
and perhaps but one or two of absolute, extirpation of species can as
yet be proved, and these only where the interference of man has been
conspicuous. It will nevertheless appear evident, from the facts and
arguments detailed in the chapters which treat of the geographical
distribution of species in the next volume, that man is not the only
exterminating agent; and that, independently of his intervention, the
annihilation of species is promoted by the multiplication and gradual
diffusion of every animal or plant. It will also appear that every
alteration in the physical geography and climate of the globe cannot
fail to have the same tendency. If we proceed still farther, and
inquire whether new species are substituted from time to time for those
which die out, we find that the successive introduction of new forms
appears to have been a constant part of the economy of the terrestrial
system, and if we have no direct proof of the fact it is because the
changes take place so slowly as not to come within the period of exact
scientific observation. To enable the reader to appreciate the gradual
manner in which a passage may have taken place from an extinct fauna to
that now living, I shall say a few words on the fossils of successive
Tertiary periods. When we trace the series of formations from the more
ancient to the more modern, it is in these Tertiary deposits that we
first meet with assemblages of organic remains having a near analogy to
the fauna of certain parts of the globe in our own time. In the Eocene,
or oldest subdivisions, some few of the testacea belong to existing
species, although almost all of them, and apparently all the associated
vertebrata, are now extinct. These Eocene strata are succeeded by a
great number of more modern deposits, which depart gradually in the
character of their fossils from the Eocene type, and approach more and
more to that of the living creation. In the present state of science,
it is chiefly by the aid of shells, that we are enabled to arrive at
these results, for of all classes the testacea are the most generally
diffused in a fossil state, and may be called the medals principally
employed by nature in recording the chronology of past events. In the
Upper Miocene rocks (No. 5 of the table, p. 135) we begin to find a
considerable number, although still a minority, of recent species,
intermixed with some fossils common to the preceding, or Eocene,
epoch. We then arrive at the Pliocene strata, in which species now
contemporary with man begin to preponderate, and in the newest of
which nine-tenths of the fossils agree with species still inhabiting
the neighbouring sea. It is in the Post-Tertiary strata, where all
the shells agree with species now living, that we have discovered the
first or earliest known remains of man associated with the bones of
quadrupeds, some of which are of extinct species.
In thus passing from the older to the newer members of the Tertiary
system, we meet with many chasms, but none which separate entirely,
by a broad line of demarcation, one state of the organic world from
another. There are no signs of an abrupt termination of one fauna and
flora, and the starting into life of new and wholly distinct forms.
Although we are far from being able to demonstrate geologically an
insensible transition from the Eocene to the Miocene, or even from the
latter to the recent fauna, yet the more we enlarge and perfect our
general survey, the more nearly do we approximate to such a continuous
series, and the more gradually are we conducted from times when many of
the genera and nearly all the species were extinct, to those in which
scarcely a single species flourished, which we do not know to exist
at present. Dr. A. Philippi, indeed, after an elaborate comparison
of the fossil tertiary shells of Sicily with those now living in the
Mediterranean, announced, as the result of his examination, that there
are strata in that island which attest a very gradual passage from a
period when only thirteen in a hundred of the shells were like the
species now living in the sea, to an era when the recent species had
attained a proportion of ninety-five in a hundred. There is, therefore,
evidence, he says, in Sicily of this revolution in the animate world
having been effected “without the intervention of any convulsion
or abrupt changes, certain species having from time died out, and
others having been introduced, until at length the existing fauna was
elaborated.”
In no part of Europe is the absence of all signs of man or his works,
in strata of comparatively modern date, more striking than in Sicily.
In the central parts of that island we observe a lofty table-land and
hills, sometimes rising to the height of 3,000 feet, capped with a
limestone, in which from 70 to 85 per cent of the fossil testacea are
specifically identical with those now inhabiting the Mediterranean.
These calcareous and other argillaceous strata of the same age are
intersected by deep valleys which appear to have been gradually formed
by denudation, but have not varied materially in width or depth since
Sicily was first colonized by the Greeks. The limestone, moreover,
which is of so late a date in geological chronology, was quarried for
building those ancient temples of Girgenti and Syracuse, of which the
ruins carry us back to a remote era in human history. If we are lost
in conjectures when speculating on the ages required to lift up these
formations to the height of several thousand feet above the sea, and
to excavate the valleys, how much more remote must be the era when the
same rocks were gradually formed beneath the waters!
The intense cold of the Glacial period was spoken of in the tenth
chapter. Although we have not yet succeeded in detecting proofs of the
origin of man antecedently to that epoch, we have yet found evidence
that most of the testacea, and not a few of the quadrupeds, which
preceded, were of the same species as those which followed the extreme
cold. To whatever local disturbances this cold may have given rise in
the distribution of species, it seems to have done little in effecting
their annihilation. We may conclude, therefore, from a survey of
the tertiary and modern strata, which constitute a more complete and
unbroken series than rocks of older date, that the extinction and
creation of species have been, and are, the result of a slow and
gradual change in the organic world.
_Uniformity of change considered, thirdly, in reference to
subterranean movements._--Thirdly, to pass on to the last of the
three topics before proposed for discussion, the reader will find, in
the account given in the Second Book, Vol. II., of the earthquakes
recorded in history, that certain countries have, from time immemorial,
been rudely shaken again and again; while others, comprising by
far the largest part of the globe, have remained to all appearance
motionless. In the regions of convulsion rocks have been rent asunder,
the surface has been forced up into ridges, chasms have opened, or the
ground throughout large spaces has been permanently lifted up above
or let down below its former level. In the regions of tranquillity
some areas have remained at rest, but others have been ascertained,
by a comparison of measurements made at different periods, to have
arisen by an insensible motion, as in Sweden, or to have subsided very
slowly, as in Greenland. That these same movements, whether ascending
or descending, have continued for ages in the same direction has been
established by historical or geological evidence. Thus we find on the
opposite coasts of Sweden that brackish water deposits, like those
now forming in the Baltic, occur on the eastern side, and upraised
strata filled with purely marine shells, now proper to the ocean, on
the western coast. Both of these have been lifted up to an elevation
of several hundred feet above high-water mark. The rise within the
historical period has not amounted to many yards, but the greater
extent of antecedent upheaval is proved by the occurrence in inland
spots, several hundred feet high, of deposits filled with fossil shells
of species now living either in the ocean or the Baltic.
It must in general be more difficult to detect proofs of slow and
gradual subsidence than of elevation, but the theory which accounts for
the form of circular coral reefs and lagoon islands, and which will
be explained in the concluding chapter of this work, will satisfy the
reader that there are spaces on the globe, several thousand miles in
circumference, throughout which the downward movement has predominated
for ages, and yet the land has never, in a single instance, gone down
suddenly for several hundred feet at once. Yet geology demonstrates
that the persistency of subterranean movements in one direction has
not been perpetual throughout all past time. There have been great
oscillations of level, by which a surface of dry land has been
submerged to a depth of several thousand feet, and then at a period
long subsequent raised again and made to emerge. Nor have the regions
now motionless been always at rest; and some of those which are at
present the theatres of reiterated earthquakes have formerly enjoyed
a long continuance of tranquillity. But, although disturbances have
ceased after having long prevailed, or have recommenced after a
suspension of ages, there has been no universal disruption of the
earth’s crust or desolation of the surface since times the most
remote. The non-occurrence of such a general convulsion is proved by
the perfect horizontality now retained by some of the most ancient
fossiliferous strata throughout wide areas.
That the subterranean forces have visited different parts of the globe
at successive periods is inferred chiefly from the unconformability of
strata belonging to groups of different ages. Thus, for example, on the
borders of Wales and Shropshire, we find the slaty beds of the ancient
Silurian system inclined and vertical, while the beds of the overlying
carboniferous shale and sandstone are horizontal. All are agreed that
in such a case the older set of strata had suffered great disturbance
before the deposition of the newer or carboniferous beds, and that
these last have never since been violently fractured, nor have ever
been bent into folds, whether by sudden or continuous lateral pressure.
On the other hand, the more ancient or Silurian group suffered only a
local derangement, and neither in Wales nor elsewhere are all the rocks
of that age found to be curved or vertical.
In various parts of Europe, for example, and particularly near Lake
Wener in the south of Sweden, and in many parts of Russia, the
Silurian strata maintain the most perfect horizontality; and a similar
observation may be made respecting limestones and shales of like
antiquity in the great lake district of Canada and the United States.
These older rocks are still as flat and horizontal as when first
formed; yet, since their origin, not only have most of the actual
mountain-chains been uplifted, but some of the very rocks of which
those mountains are composed have been formed, some of them by igneous
and others by aqueous action.
It would be easy to multiply instances of similar unconformability
in formations of other ages; but a few more will suffice. The
carboniferous rocks before alluded to as horizontal on the borders
of Wales are vertical in the Mendip hills in Somersetshire, where
the overlying beds of the New Red Sandstone are horizontal. Again,
in the Wolds of Yorkshire the last-mentioned sandstone supports on
its curved and inclined beds the horizontal Chalk. The Chalk again is
vertical on the flanks of the Pyrenees, and the tertiary strata repose
unconformably upon it.
As almost every country supplies illustrations of the same phenomena,
they who advocate the doctrine of alternate periods of disorder and
repose may appeal to the facts above described, as proving that every
district has been by turns convulsed by earthquakes and then respited
for ages from convulsions. But so it might with equal truth be affirmed
that every part of Europe has been visited alternately by winter and
summer, although it has always been winter and always summer in some
part of the planet, and neither of these seasons has ever reigned
simultaneously over the entire globe. They have been always shifting
from place to place; but the vicissitudes which recur thus annually
in a single spot are never allowed to interfere with the invariable
uniformity of seasons throughout the whole planet.
So, in regard to subterranean movements, the theory of the perpetual
uniformity of the force which they exert on the earth’s crust is quite
consistent with the admission of their alternate development and
suspension for long and indefinite periods within limited geographical
areas.
If, for reasons before stated, we assume a continual extinction of
species and appearance of others on the globe, it will then follow
that the fossils of strata formed at two distant periods on the same
spot will differ even more certainly than the mineral composition of
those strata. For rocks of the same kind have sometimes been reproduced
in the same district after a long interval of time; whereas all the
evidence derived from fossil remains is in favour of the opinion that
species which have once died out have never been reproduced. The
submergence, then, of land must be often attended by the commencement
of a new class of sedimentary deposits, characterized by a new set of
fossil animals and plants, while the reconversion of the bed of the sea
into land may arrest at once and for an indefinite time the formation
of geological monuments. Should the land again sink, strata will again
be formed; but one or many entire revolutions in animal or vegetable
life may have been completed in the interval.
As to the want of completeness in the fossiliferous series, which
may be said to be almost universal, we have only to reflect on what
has been already said of the laws governing sedimentary deposition,
and those which give rise to fluctuations in the animate world, to
be convinced that a very rare combination of circumstances can alone
give rise to such a superposition and preservation of strata as will
bear testimony to the gradual passage from one state of organic life
to another. To produce such strata nothing less will be requisite
than the fortunate coincidence of the following conditions: first, a
never-failing supply of sediment in the same region throughout a period
of vast duration; secondly, the fitness of the deposit in every part
for the permanent preservation of imbedded fossils; and, thirdly, a
gradual subsidence to prevent the sea or lake from being filled up and
converted into land.
It will appear in the chapter on coral reefs, that, in certain parts
of the Pacific and Indian Oceans, most of these conditions, if not
all, are complied with, and the constant growth of coral, keeping
pace with the sinking of the bottom of the sea, seems to have gone on
so slowly, for such indefinite periods, that the signs of a gradual
change in organic life might probably be detected in that quarter of
the globe if we could explore its submarine geology. Instead of the
growth of coralline limestone, let us suppose, in some other place,
the continuous deposition of fluviatile mud and sand, such as the
Ganges and Brahmapootra have poured for thousands of years into the
Bay of Bengal. Part of this bay, although of considerable depth,
might at length be filled up before an appreciable amount of change
was effected in the fish, mollusca, and other inhabitants of the sea
and neighbouring land. But if the bottom be lowered by sinking at
the same rate that it is raised by fluviatile mud, the bay can never
be turned into dry land. In that case one new layer of matter may be
superimposed upon another for a thickness of many thousand feet, and
the fossils of the inferior beds may differ greatly from those entombed
in the uppermost, yet every intermediate gradation may be indicated in
the passage from an older to a newer assemblage of species. Granting,
however, that such an unbroken sequence of monuments may thus be
elaborated in certain parts of the sea, and that the strata happen
to be all of them well adapted to preserve the included fossils from
decomposition, how many accidents must still concur before these
submarine formations will be laid open to our investigation! The whole
deposit must first be raised several thousand feet, in order to bring
into view the very foundation; and during the process of exposure the
superior beds must not be entirely swept away by denudation.
In the first place, the chances are nearly as three to one against
the mere emergence of the mass above the waters, because nearly
three-fourths of the globe are covered by the ocean. But if it be
upheaved and made to constitute part of the dry land, it must also,
before it can be available for our instruction, become part of that
area already surveyed by geologists. In this small fraction of land
already explored, and still very imperfectly known, we are required to
find a set of strata deposited under peculiar conditions, and which,
having been originally of limited extent, would have been probably much
lessened by subsequent denudation.
Yet it is precisely because we do not encounter at every step the
evidence of such gradations from one state of the organic world to
another, that so many geologists have embraced the doctrine of great
and sudden revolutions in the history of the animate world. Not content
with simply availing themselves, for the convenience of classification,
of those gaps and chasms which here and there interrupt the continuity
of the chronological series, as at present known, they deduce, from the
frequency of these breaks in the chain of records, an irregular mode of
succession in the events themselves, both in the organic and inorganic
world. But, besides that some links of the chain which once existed are
now entirely lost and others concealed from view, we have good reason
to suspect that it was never complete originally. It may undoubtedly be
said that strata have been always forming somewhere, and therefore at
every moment of past time Nature has added a page to her archives; but,
in reference to this subject, it should be remembered that we can never
hope to compile a consecutive history by gathering together monuments
which were originally detached and scattered over the globe. For, as
the species of organic beings contemporaneously inhabiting remote
regions are distinct, the fossils of the first of several periods which
may be preserved in any one country, as in America for example, will
have no connection with those of a second period found in India, and
will therefore no more enable us to trace the signs of a gradual change
in the living creation, than a fragment of Chinese history will fill up
a blank in the political annals of Europe.
The absence of any deposits of importance containing recent shells in
Chili, or anywhere on the western shore of South America, naturally led
Mr. Darwin to the conclusion that “where the bed of the sea is either
stationary or rising, circumstances are far less favourable than where
the level is sinking to the accumulation of conchiferous strata of
sufficient thickness and extension to resist the average vast amount
of denudation.” In like manner the beds of superficial sand, clay, and
gravel, with recent shells, on the coasts of Norway and Sweden, where
the land has risen in Post-tertiary times, are so thin and scanty as to
incline us to admit a similar proposition. We may in fact assume that
in all cases where the bottom of the sea has been undergoing continuous
elevation, the total thickness of sedimentary matter accumulating
at depths suited to the habitation of most of the species of shells
can never be great, nor can the deposits be thickly covered with
superincumbent matter, so as to be consolidated by pressure. When they
are upheaved, therefore, the waves on the beach will bear down and
disperse the loose materials; whereas, if the bed of the sea subsides
slowly, a mass of strata containing abundance of such species as live
at moderate depths, may be formed and may increase in thickness to any
amount. It may also extend horizontally over a broad area, as the water
gradually encroaches on the subsiding land.
Hence it will follow that great violations of continuity in the
chronological series of fossiliferous rocks will always exist, and the
imperfection of the record, though lessened, will never be removed by
future discoveries. For not only will no deposits originate on the
dry land, but those formed in the sea near land, which is undergoing
constant upheaval, will usually be too slight in thickness to endure
for ages.
In proportion as we become acquainted with larger geographical
areas, many of the gaps, by which a chronological table is rendered
defective, will be removed. We were enabled by aid of the labours of
Prof. Sedgwick and Sir Roderick Murchison, to intercalate, in 1838,
the marine strata of the Devonian period, with their fossil shells,
corals, and fish, between the Silurian and Carboniferous rocks.
Previously the marine fauna of these last-mentioned formations wanted
the connecting links which now render the passage from the one to
the other much less abrupt. In like manner the Upper Miocene has no
representative in England, but in France, Germany, and Switzerland it
constitutes a most instructive link between the living creation and the
middle of the great Tertiary period. Still we must expect, for reasons
before stated, that chasms will forever continue to occur, in some
parts of our sedimentary series.
_Concluding remarks on the consistency of the theory of gradual
change with the existence of great breaks in the series._--To
return to the general argument pursued in this chapter, it is assumed,
for reasons above explained, that a slow change of species is in
simultaneous operation everywhere throughout the habitable surface
of sea and land; whereas the fossilization of plants and animals is
confined to those areas where new strata are produced. These areas,
as we have seen, are always shifting their position, so that the
fossilizing process, by means of which the commemoration of the
particular state of the organic world, at any given time, is effected,
may be said to move about, visiting and revisiting different tracts in
succession.
To make still more clear the supposed working of this machinery, I
shall compare it to a somewhat analogous case that might be imagined
to occur in the history of human affairs. Let the mortality of the
population of a large country represent the successive extinction
of species, and the births of new individuals the introduction of
new species. While these fluctuations are gradually taking place
everywhere, suppose commissioners to be appointed to visit each
province of the country in succession, taking an exact account of the
number, names and individual peculiarities of all the inhabitants,
and leaving in each district a register containing a record of this
information. If, after the completion of one census, another is
immediately made on the same plan, and then another, there will at
last be a series of statistical documents in each province. When
those belonging to any one province are arranged in chronological
order, the contents of such as stand next to each other will differ
according to the length of the intervals of time between the taking of
each census. If, for example, there are sixty provinces, and all the
registers are made in a single year and renewed annually, the number
of births and deaths will be so small, in proportion to the whole
of the inhabitants, during the interval between the compiling of two
consecutive documents, that the individuals described in such documents
will be nearly identical; whereas, if the survey of each of the sixty
provinces occupies all the commissioners for a whole year, so that they
are unable to revisit the same place until the expiration of sixty
years, there will then be an almost entire discordance between the
persons enumerated in two consecutive registers in the same province.
There are, undoubtedly, other causes, besides the mere quantity of
time, which may augment or diminish the amount of discrepancy. Thus,
at some periods, a pestilential disease may have lessened the average
duration of human life; or a variety of circumstances may have caused
the births to be unusually numerous, and the population to multiply;
or a province may be suddenly colonized by persons migrating from
surrounding districts.
These exceptions may be compared to the accelerated rate of
fluctuations in the fauna and flora of a particular region, in which
the climate and physical geography may be undergoing an extraordinary
degree of alteration.
But I must remind the reader that the case above proposed has no
pretensions to be regarded as an exact parallel to the geological
phenomena which I desire to illustrate; for the commissioners are
supposed to visit the different provinces in rotation; whereas the
commemorating processes by which organic remains become fossilized,
although they are always shifting from one area to the other, are yet
very irregular in their movements. They may abandon and revisit many
spaces again and again, before they once approach another district;
and, besides this source of irregularity, it may often happen that,
while the depositing process is suspended, denudation may take place,
which may be compared to the occasional destruction by fire or other
causes of some of the statistical documents before mentioned. It is
evident that where such accidents occur the want of continuity in the
series may become indefinitely great, and that the monuments which
follow next in succession will by no means be equidistant from each
other in point of time.
If this train of reasoning be admitted, the occasional distinctness of
the fossil remains, in formations immediately in contact, would be a
necessary consequence of the existing laws of sedimentary deposition
and subterranean movement, accompanied by a constant dying-out and
renovation of species.
As all the conclusions above insisted on are directly opposed to
opinions still popular, I shall add another comparison, in the hope of
preventing any possible misapprehension of the argument. Suppose we
had discovered two buried cities at the foot of Vesuvius, immediately
superimposed upon each other, with a great mass of tuff and lava
intervening, just as Portici and Resina, if now covered with ashes,
would overlie Herculaneum. An antiquary might possibly be entitled to
infer, from the inscriptions on public edifices, that the inhabitants
of the inferior and older city were Greeks, and those of the modern
town Italians. But he would reason very hastily if he also concluded
from these data, that there had been a sudden change from the Greek
to the Italian language in Campania. But if he afterwards found three
buried cities, one above the other, the intermediate one being Roman,
while, as in the former example, the lowest was Greek and the uppermost
Italian, he would then perceive the fallacy of his former opinion and
would begin to suspect that the catastrophes, by which the cities
were inhumed, might have no relation whatever to the fluctuations in
the language of the inhabitants; and that, as the Roman tongue had
evidently intervened between the Greek and Italian, so many other
dialects may have been spoken in succession, and the passage from the
Greek to the Italian may have been very gradual, some terms growing
obsolete, while others were introduced from time to time.
If this antiquary could have shown that the volcanic paroxysms of
Vesuvius were so governed as that cities should be buried one above the
other, just as often as any variation occurred in the language of the
inhabitants, then, indeed, the abrupt passage from a Greek to a Roman,
and from a Roman to an Italian city, would afford proof of fluctuations
no less sudden in the language of the people.
So, in Geology, if we could assume that it is part of the plan of
Nature to preserve, in every region of the globe, an unbroken series
of monuments to commemorate the vicissitudes of the organic creation,
we might infer the sudden extirpation of species, and the simultaneous
introduction of others, as often as two formations in contact are found
to include dissimilar organic fossils. But we must shut our eyes to the
whole economy of the existing causes, aqueous, igneous, and organic,
if we fail to perceive that such is not the plan of Nature.
I shall now conclude the discussion of a question with which we have
been occupied since the beginning of the fifth chapter--namely, whether
there has been any interruption, from the remotest periods, of one
uniform and continuous system of change in the animate and inanimate
world. We were induced to enter into that inquiry by reflecting how
much the progress of opinion in Geology had been influenced by the
assumption that the analogy was slight in kind, and still more slight
in degree, between the causes which produced the former revolutions
of the globe, and those now in every-day operation. It appeared clear
that the earlier geologists had not only a scanty acquaintance with
existing changes, but were singularly unconscious of the amount of
their ignorance. With the presumption naturally inspired by this
unconsciousness, they had no hesitation in deciding at once that time
could never enable the existing powers of nature to work out changes
of great magnitude, still less such important revolutions as those
which are brought to light by Geology. They therefore felt themselves
at liberty to indulge their imaginations in guessing at what might be,
rather than inquiring what is; in other words, they employed themselves
in conjecturing what might have been the course of Nature at a remote
period, rather than in the investigation of what was the course of
Nature in their own times.
It appeared to them far more philosophical to speculate on the
possibilities of the past, than patiently to explore the realities of
the present; and having invented theories under the influences of such
maxims, they were consistently unwilling to test their validity by the
criterion of their accordance with the ordinary operations of Nature.
On the contrary, the claims of each new hypothesis to credibility
appeared enhanced by the great contrast, in kind or intensity, of the
causes referred to and those now in operation.
Never was there a dogma more calculated to foster indolence, and
to blunt the keen edge of curiosity, than this assumption of the
discordance between the ancient and existing causes of change. It
produced a state of mind unfavourable in the highest degree to the
candid reception of the evidence of those minute but incessant
alterations which every part of the earth’s surface is undergoing,
and by which the condition of its living inhabitants is continually
made to vary. The student, instead of being encouraged with the
hope of interpreting the enigmas presented to him in the earth’s
structure--instead of being prompted to undertake laborious inquiries
into the natural history of the organic world, and the complicated
effects of the igneous and aqueous causes now in operation--was taught
to despond from the first. Geology, it was affirmed, could never rise
to the rank of an exact science; the greater number of phenomena
must forever remain inexplicable, or only be partially elucidated by
ingenious conjectures. Even the mystery which invested the subject was
said to constitute one of its principal charms, affording, as it did,
full scope to the fancy to indulge in a boundless field of speculation.
The course directly opposed to this method of philosophizing consists
in an earnest and patient inquiry, how far geological appearances are
reconcilable with the effect of changes now in progress, or which
may be in progress in regions inaccessible to us, but of which the
reality is attested by volcanoes and subterranean movements. It also
endeavours to estimate the aggregate result of ordinary operations
multiplied by time, and cherishes a sanguine hope that the resources
to be derived from observation and experiment, or from the study of
Nature such as she now is, are very far from being exhausted. For this
reason all theories are rejected which involve the assumption of sudden
and violent catastrophes and revolutions of the whole earth, and its
inhabitants--theories which are restrained by no reference to existing
analogies, and in which a desire is manifested to cut, rather than
patiently to untie, the Gordian knot.
We have now, at least, the advantage of knowing, from experience, that
an opposite method has always put geologists on the road that leads
to truth--suggesting views which, although imperfect at first, have
been found capable of improvement, until at last adopted by universal
consent; while the method of speculating on a former distinct state of
things and causes has led invariably to a multitude of contradictory
systems, which have been overthrown one after the other--have been
found incapable of modification--and which have often required to be
precisely reversed.
The remainder of this work will be devoted to an investigation of the
changes now going on in the crust of the earth and its inhabitants.
The importance which the student will attach to such researches will
mainly depend on the degree of confidence which he feels in the
principles above expounded. If he firmly believes in the resemblance
or identity of the ancient and present system of terrestrial changes,
he will regard every fact collected respecting the causes in diurnal
action as affording him a key to the interpretation of some mystery in
the past. Events which have occurred at the most distant periods in
the animate and inanimate world will be acknowledged to throw light
on each other, and the deficiency of our information respecting some
of the most obscure parts of the present creation will be removed.
For as, by studying the external configuration of the existing land
and its inhabitants, we may restore in imagination the appearance of
the ancient continents which have passed away, so may we obtain from
the deposits of ancient seas and lakes an insight into the nature
of the subaqueous processes now in operation, and of many forms of
organic life which, though now existing, are veiled from sight. Rocks,
also, produced by subterranean fire in former ages, at great depths
in the bowels of the earth, present us, when upraised by gradual
movements, and exposed to the light of heaven, with an image of those
changes which the deep-seated volcano may now occasion in the nether
regions. Thus, although we are mere sojourners on the surface of the
planet, chained to a mere point in space, enduring but for a moment of
time, the human mind is not only enabled to number worlds beyond the
unassisted ken of mortal eye, but to trace the events of indefinite
ages before the creation of our race, and is not even withheld from
penetrating into the dark secrets of the ocean, or the interior of
the solid globe; free, like the spirit which the poet described as
animating the universe,
--_ire per omnes_
_Terrasque, tractusque maris, coelumque profundum_.
FOOTNOTES:
[Footnote 31: From the _Principles of Geology_, Bk. I, Ch. XIII.]
XXIX
CHARLES DARWIN
1809-1882
_Charles Robert Darwin, the grandson of Erasmus Darwin, was born at
Shrewsbury, England, February 12, 1809. He studied at both Edinburgh
and Cambridge, and graduated from the latter in 1831. From 1831 to 1836
he served as a naturalist on the “Beagle,” which made a trip around the
world in the interests of science. The voyage served as a post-graduate
course for Darwin, who then first adopted his evolutionary ideas and
developed as an original investigator. Reading Malthus, in 1838, on
the problem of population and the food supply, he integrated Malthus’
ideas into his own views of biology. In 1844 be began his “Origin of
Species,” which he completed in 1859. In 1858 he received a paper
from Alfred Russell Wallace, then in the Malay Archipelago, which
proposed the same theory of natural selection. Darwin believed that
when organisms increased much faster than the means of subsistence,
the ratios varied, and in the conditions produced by these natural
causes only those organisms survived which were best fitted to their
environment. He applied his concept to human evolution in his “Descent
of Man,” published in 1871. He died April 19, 1882, and was buried in
Westminster Abbey._
NATURAL SELECTION[32]
How will the struggle for existence, briefly discussed in the last
chapter, act in regard to variation? Can the principle of selection,
which we have seen is so potent in the hands of man, apply under
nature? I think we shall see that it can act most efficiently. Let
the endless number of slight variations and individual differences
occurring in our domestic productions, and, in a lesser degree, in
those under nature, be borne in mind; as well as the strength of the
hereditary tendency. Under domestication, it may be truly said that the
whole organization becomes in some degree plastic. But the variability,
which we almost universally meet with in our domestic production, is
not directly produced, as Hooker and Asa Gray have well remarked, by
man; he can neither originate varieties, nor prevent their occurrence;
he can only preserve and accumulate such as do occur. Unintentionally
he exposes organic beings to new and changing conditions of life, and
variability ensues; but similar changes of conditions might and do
occur under nature. Let it also be borne in mind how infinitely complex
and close-fitting are the mutual relations of all organic beings to
each other and to their physical conditions of life; and consequently
what infinitely varied diversities of structure might be of use to
each being under changing conditions of life. Can it then be thought
improbable, seeing that variations useful to man have undoubtedly
occurred, that other variations useful in some way to each being in the
great and complex battle of life, should occur in the course of many
successive generations? If such do occur, can we doubt (remembering
that many more individuals are born than can possibly survive) that
individuals having any advantage, however slight, over others, would
have the best chance of surviving and of procreating their kind? On the
other hand, we may feel sure that any variation in the least degree
injurious would be rigidly destroyed. This preservation of favourable
individual differences and variations, and the destruction of those
which are injurious, I have called Natural Selection, or the Survival
of the Fittest. Variations neither useful nor injurious would not be
affected by natural selection, and would be left either a fluctuating
element, as perhaps we see in certain polymorphic species, or would
ultimately become fixed, owing to the nature of the organism and the
nature of the conditions.