another controversy of our times to which we may with great
propriety apply the maxim now before us. After the glory of
having first given a true view of the composition of water
had long rested tranquilly upon the names of Cavendish and
Lavoisier, a claim was made in favour of James Watt as the
real author of this discovery by his son, (Mr J. Watt,) and
his eulogist, (M. Arago[34\6]). It is not to our purpose
here to discuss the various questions which have arisen on
this subject respecting priority of publication, and
respecting the translation of opinions published at one time
into the language of another period. But if we look at
Watt's own statement of his views, given soon after those of
Cavendish had been published, we shall perceive that it is
marked by a violation of this maxim: we shall find that he
does admit imponderable fluids {45} as chemical elements;
and thus shows a vagueness and confusion in his idea of
chemical composition. With such imperfection in his views,
it is not surprising that Watt, not only did not anticipate,
but did not apprehend quite precisely the discovery of
Cavendish and Lavoisier. Watt's statement of his views is as
follows[35\6]:--'Are we not authorized to conclude that
water is composed of dephlogisticated air and phlogiston
deprived of part of their latent or elementary heat; that
dephlogisticated or pure air is composed of water deprived
of its phlogiston and united to elementary heat and light;
and that the latter are contained in it in a latent state,
so as not to be sensible to the thermometer or to the eye;
and if light be only a modification of heat, or a
circumstance attending it, or a component part of the
inflammable air, then pure or dephlogisticated air is
composed of water deprived of its phlogiston and united to
elementary heat?'
[Note 34\6: Éloge de James Watt, _Annuaire du Bur. des
Long._ 1839.]
[Note 35\6: _Phil. Trans._ 1784, p. 332.]
When we compare this doubtful and hypothetical statement,
involving so much that is extraneous and heterogeneous, with
the conclusion of Cavendish, in which there is nothing
hypothetical or superfluous, we may confidently assent to
the decision which has been pronounced by one[36\6] of our
own time in favour of Cavendish. And we may with pleasure
recognize, in this enlightened umpire, a due appreciation of
the value of the maxim on which we are now insisting.
'Cavendish,' says Mr. Vernon Harcourt, 'pared off {46} from
the hypotheses their theories of combustion, and _affinities
of imponderable for ponderable matter_, as complicating
chemical with physical considerations.'
[Note 36\6: The Rev. W. Vernon Harcourt, Address to the
British Association, 1839.--Since the first edition of this
work was published, and also since the second edition of the
_History of the Inductive Sciences_, Mr. Watt's
correspondence bearing upon the question of the Composition
of Water has been published by Mr. Muirhead. I do not find,
in this publication, any reason for withdrawing what I have
stated in the text above: but with reference to the
statement in the _History_, it appears that Mr. Cavendish's
claim to the discovery was not uncontested in his own time.
Mr. Watt had looked at the composition of water, as a
problem to be solved, perhaps more distinctly than Mr.
Cavendish had done; and he conceived himself wronged by Mr.
Cavendish's putting forwards his experiment as the first
solution of this problem.]
6. _Relation of Heat to Chemistry._--But while we thus
condemn the attempts to explain the thermotical phenomena of
chemical processes by means of chemical considerations, it
may be asked if we are altogether to renounce the hope of
understanding such phenomena? It is plain, it may be said,
that heat generated in chemical changes is always a very
important circumstance, and can sometimes be measured, and
perhaps reduced to laws; are we prohibited from speculating
concerning the causes of such circumstances and such laws?
And to this we reply, that we may properly attempt to
connect chemical with thermotical processes, _so far as_ we
have obtained a clear and probable view of the nature of the
thermotical processes. When our theory of Thermotics is
tolerably complete and certain, we may with propriety
undertake to connect it with our theory of Chemistry. But at
present we are not far enough advanced in our knowledge of
heat to make this attempt with any hope of success. We can
hardly expect to understand the part which heat plays in the
union of two bodies, when we cannot as yet comprehend in
what manner it produces the liquefaction or vaporization of
one body. We cannot look to account for Gay Lussac and
Dalton's Law, that all gases expand equally by heat, till we
learn how heat causes a gas to expand. We cannot hope to see
the grounds of Dulong and Petit's Law, that the specific
heat of all atoms is the same, till we know much more, not
only about atoms, but about specific heat. We have as yet no
thermotical theory which even professes to account for all
the prominent facts of the subject[37\6]: and the theories
which have been proposed are of the most diverse kind.
Laplace assumes particles of bodies surrounded by
atmospheres of caloric[38\6]; Cauchy makes heat consist in
longitudinal vibrations of the ether of which transverse
vibrations {47} produce light: in Ampère's theory[39\6],
heat consists in the vibrations of the particles of bodies.
And so long as we have nothing more certain in our
conceptions of heat than the alternative of these and other
precarious hypotheses, how can we expect to arrive at any
real knowledge, by connecting the results of such hypotheses
with the speculations of Chemistry, of which science the
theory is at least equally obscure?
[Note 37\6: _Hist. Ind. Sci._ b. x. c. 4.]
[Note 38\6: _Ib._]
[Note 39\6: _Hist. Ind. Sci._ b. x. c. 4.]
The largest attempts at chemical theory have been made in
the form of the Atomic Theory, to which I have just had
occasion to allude. I must, therefore, before quitting the
subject, say a few words respecting this theory.
{{48}}
CHAPTER V.
THE ATOMIC THEORY.
1. _The Atomic Theory considered on Chemical Grounds._--WE
have already seen that the combinations which result from
chemical affinity are definite, a certain quantity of one
ingredient uniting, not with an uncertain, but with a
certain quantity of another ingredient. But it was found, in
addition to this principle, that one ingredient would often
unite with another in different proportions, and that, in
such cases, these proportions are multiples one of another.
In the three salts formed by potassa with oxalic acid, the
quantities of acid which combine with the same quantity of
alkali are exactly in the proportion of the numbers 1, 2, 4.
And the same rule of the existence of multiple proportions
is found to obtain in other cases.
It is obvious that such results will be accounted for, if we
suppose that the base and the acid consist each of numerous
definite equal particles, and that the formation of the
salts above mentioned consists in the combination of one
particle of the base with one particle of acid, with two
particles of acid, and with four particles of acid,
respectively. But further; as we have already stated,
chemical affinity is not only definite, but reciprocal. The
proportions of potassa and soda which form neutral salts
being 590 and 391 in one case, they are so in all cases.
These numbers represent _proportions_ of weight in which the
two bases, potassa and soda, enter into analogous
combinations; 590 of potassa is _equivalent_ to 391 of soda.
These facts with regard to combination are still expressed
by the above supposition of equal particles, assuming that
the weights of a {49} particle of potassa and of soda are in
the proportion of 590 to 391.
But we pursue our analysis further. We find that potassa is
a compound of a metallic base, potassium, and of oxygen, in
the proportion of 490 to 100; we suppose, then, that the
particle of potassa consists of a particle of potassium and
a particle of oxygen; and these latter particles, since we
see no present need to suppose them divided, potassium and
oxygen being simple bodies, we may call _atoms_, and assume to
be indivisible. And by supposing all simple bodies to
consist of such atoms, and compounds to be formed by the
union of two, or three, or more of such atoms, we explain
the occurrence of definite and multiple proportions, and we
construct the Atomic Theory.
2. _Hypothesis of Atoms._--So far as the assumption of such
atoms as we have spoken of serves to express those laws of
chemical composition which we have referred to, it is a
clear and useful generalization. But if the Atomic Theory be
put forwards (and its author, Dr. Dalton, appears to have
put it forwards with such an intention,) as asserting that
chemical elements are really composed of _atoms_, that is,
of such particles not further divisible, we cannot avoid
remarking, that for such a conclusion, chemical research has
not afforded, nor can afford, any satisfactory evidence
whatever. The smallest observable quantities of ingredients,
as well as the largest, combine according to the laws of
proportions and equivalence which have been cited above. How
are we to deduce from such facts any inference with regard
to the existence of certain smallest possible particles? The
Theory, when dogmatically taught as a physical truth,
asserts that all observable quantities of elements _are_
composed of proportional numbers of particles which can no
further be subdivided; but all which observation teaches us
is, that if there be such particles, they are smaller than
the smallest observable quantities. In chemical experiment,
at least, there is not the slightest positive evidence for
the existence of such atoms. The assumption of _indivisible_
particles, smaller than the smallest {50} observable, which
combine, particle with particle, will explain the phenomena;
but the assumption of particles bearing this proportion, but
_not_ possessing the property of indivisibility, will explain
the phenomena at least equally well. The decision of the
question, therefore, whether the Atomic Hypothesis be the
proper way of conceiving the chemical combinations of
substances, must depend, not upon chemical facts, but upon
our conception of Substance. In this sense the question is
an ancient and curious controversy, and we shall hereafter
have to make some remarks upon it.
3. _Chemical Difficulties of the Hypothesis._--But before
doing this, we may observe that there is no small difficulty
in reconciling this hypothesis with the facts of chemistry.
According to the theory, all salts, compounded of an acid
and a base, are analogous in their atomic constitution; and
the number of atoms in one such compound being known or
assumed, the number of atoms in other salts may be
determined. But when we proceed in this course of reasoning
to other bodies, as metals, we find ourselves involved in
difficulties. The protoxide of iron is a base which,
according to all analogy, must consist of one atom of iron
and one of oxygen: but the peroxide of iron is also a base,
and it appears by the analysis of this substance that it
must consist of _two-thirds_ of an atom of iron and one atom
of oxygen. Here, then, our indivisible atoms must be
divisible, even upon chemical grounds. And if we attempt to
evade this difficulty by making the peroxide of iron consist
of two atoms of iron and three of oxygen, we have to make a
corresponding alteration in the theoretical constitution of
all bodies analogous to the protoxide; and thus we overturn
the very foundation of the theory. Chemical facts,
therefore, not only do not prove the Atomic Theory as a
physical truth, but they are not, according to any
modification yet devised of the theory, reconcileable with
its scheme.
Nearly the same conclusions result from the attempts to
employ the Atomic Hypothesis in expressing another important
chemical law;--the law of the {51} combinations of gases
according to definite proportions of their volumes,
experimentally established by Gay Lussac[40\6]. In order to
account for this law, it has been very plausibly suggested
that all gases, under the same pressure, contain an equal
number of atoms in the same space; and that when they
combine, they unite atom to atom. Thus one volume of
chlorine unites with one volume of hydrogen, and forms
hydrochloric acid[41\6]. But then this hydrochloric acid
occupies the space of the two volumes; and therefore the
proper number of particles cannot be supplied, and the
uniform distribution of atoms in all gases maintained,
without dividing into two each of the compound particles,
constituted of an atom of chlorine and an atom of hydrogen.
And thus in this case, also, the Atomic Theory becomes
untenable if it be understood to imply the indivisibility of
the atoms.
[Note 40\6: _Hist. Ind. Sc._ b. xiv. c. 8.]
[Note 41\6: Dumas, _Phil. Chim._ 263.]
In all these attempts to obtain distinct physical conception
of chemical union by the aid of the Atomic Hypothesis, the
atoms are conceived to be associated by certain forces of
the nature of mechanical attractions. But we have already
seen[42\6] that no such mode of conception can at all
explain or express the facts of chemical combination; and
therefore it is not wonderful that when the Atomic Theory
attempts to give an account of chemical relations by
contemplating them under such an aspect, the facts on which
it grounds itself should be found not to authorize its
positive doctrines; and that when these doctrines are tried
upon the general range of chemical observation, they should
prove incapable of even expressing, without
self-contradiction, the laws of phenomena.
[Note 42\6: See Chapter I. of this book.]
4. _Grounds of the Atomic Doctrine._--Yet the doctrine of
atoms, or of substance as composed of indivisible particles,
has in all ages had great hold upon the minds of physical
speculators; nor would this doctrine ever have suggested
itself so readily, or have been maintained so tenaciously,
as the true mode of {52} conceiving chemical combinations,
if it had not been already familiar to the minds of those
who endeavour to obtain a general view of the constitution
of nature. The grounds of the assumption of the atomic
structure of substance are to be found rather in the idea of
substance itself, than in the experimental laws of chemical
affinity. And the question of the existence of atoms, thus
depending upon an idea which has been the subject of
contemplation from the very infancy of philosophy, has been
discussed in all ages with interest and ingenuity. On this
very account it is unlikely that the question, so far as it
bears upon chemistry, should admit of any clear and final
solution. Still it will be instructive to look back at some
of the opinions which have been delivered respecting this
doctrine.
5. _Ancient Prevalence of the Atomic Doctrine._--The
doctrine that matter consists of minute, simple,
indivisible, indestructible particles as its ultimate
elements, has been current in all ages and countries,
whenever the tendency of man to wide and subtle speculations
has been active. I need not attempt to trace the history of
this opinion in the schools of Greece and Italy. It was the
leading feature in the physical tenets of the Epicureans,
and was adopted by their Roman disciples, as the poem of
Lucretius copiously shows us. The same tenet had been held
at still earlier periods, in forms more or less definite, by
other philosophers. It is ascribed to Democritus, and is
said to have been by him derived from Leucippus. But this
doctrine is found also, we are told[43\6], among the
speculations of another intellectual and acute race, the
Hindoos. According to some of their philosophical writers,
the ultimate elements of matter are atoms, of which it is
proved by certain reasonings, that they are each one-sixth
of one of the motes that float in the sunbeam.
[Note 43\6: By Mr. Colebrook. _Asiatic Res._ 1824.]
This early prevalence of controversies of the widest and
deepest kind, which even in our day remain undecided, has in
it nothing which need surprize us; or, at least, it has in
it nothing which is not in conformity {53} with the general
course of the history of philosophy. As soon as any ideas
are clearly possessed by the human mind, its activity and
acuteness in reasoning upon them are such, that the
fundamental antitheses and ultimate difficulties which
belong to them are soon brought into view. The Greek and
Indian philosophers had mastered completely the Idea of
Space, and possessed the Idea of Substance in tolerable
distinctness. They were, therefore, quite ready, with their
lively and subtle minds, to discuss the question of the
finite and infinite divisibility of matter, so far as it
involved only the ideas of space and of substance, and this
accordingly they did with great ingenuity and perseverance.
But the ideas of Space and of Substance are far from being
sufficient to enable men to form a complete general view of
the constitution of matter. We must add to these ideas, that
of mechanical Force with its antagonist Resistance, and that
of the Affinity of one kind of matter for another. Now the
former of these ideas the ancients possessed in a very
obscure and confused manner; and of the latter they had no
apprehension whatever. They made vague assumptions
respecting the impact and pressure of atoms on each other;
but of their mutual attraction and repulsion they never had
any conception, except of the most dim and wavering kind;
and of an affinity different from mere local union they did
not even dream. Their speculations concerning atoms,
therefore, can have no value for us, except as a part of the
history of science. If their doctrines appear to us to
approach near to the conclusions of our modern philosophy,
it must be because our modern philosophy is that philosophy
which has not fully profited by the additional light which
the experiments and meditations of later times have thrown
upon the constitution of matter.
6. _Bacon._--Still, when modern philosophers look upon the
Atomic Theory of the ancients in a general point of view
merely, without considering the special conditions which
such a theory must fulfil, in order to represent the
discoveries of modern times, they are {54} disposed to
regard it with admiration. Accordingly we find Francis Bacon
strongly expressing such a feeling. The Atomic Theory is
selected and dwelt upon by him as the chain which connects
the best parts of the physical philosophy of the ancient and
the modern world. Among his works is a remarkable
dissertation _On the Philosophy of Democritus, Parmenides,
and Telesius_: the last mentioned of whom was one of the
revivers of physical science in modern times. In this work
he speaks of the atomic doctrine of Democritus as a
favourable example of the exertions of the undisciplined
intellect. 'Hæc ipsa placita, quamvis paulo emendatiora,
talia sunt qualia esse possunt illa quæ ab intellectu sibi
permisso, nec continenter et gradatim sublevato, profecta
videntur.'--'These doctrines, thus [in an ancient fable]
presented in a better form, are such glimpses of truth as
can be obtained by the intellect left to its own natural
impulses, and not ascending by successive and connected
steps,' [as the Baconian philosophy directs]. 'Accordingly,'
he adds, 'the doctrine of Atoms, from its going a step
beyond the period in which it was advanced, was ridiculed by
the vulgar, and severely handled in the disputations of the
learned, notwithstanding the profound acquaintance with
physical science by which its author was allowed to be
distinguished, and from which he acquired the character of a
magician.'
'However,' he continues, 'neither the hostility of
Aristotle, with all his skill and vigour in disputation,
(though, like the Ottoman sultans, he laboured to destroy
all his brother philosophers that he might rest undisputed
master of the throne of science,) nor the majestic and lofty
authority of Plato, could effect the subversion of the
doctrine of Democritus. And while the opinions of Plato and
Aristotle were rehearsed with loud declamation and
professorial pomp in the schools, this of Democritus was
always held in high honour by those of a deeper wisdom, who
followed in silence a severer path of contemplation. In the
days of Roman speculation it kept its ground and its favour;
Cicero everywhere speaks of its author with the {55}
greatest praise; and Juvenal, who, like poets in general,
probably expressed the prevailing judgment of his time,
proclaims his merit as a noble exception to the general
stupidity of his countrymen.
. . . . Cujus prudentia monstrat
Magnos posse viros et magna exempla daturos
Vervecum in patriâ crassoque sub aere nasci.
'The destruction of this philosophy was not effected by
Aristotle and Plato, but by Genseric and Attila, and their
barbarians. For then, when human knowledge had suffered
shipwreck, those fragments of the Aristotelian and Platonic
philosophy floated on the surface like things of some
lighter and emptier sort, and so were preserved; while more
solid matters went to the bottom, and were almost lost in
oblivion.'
7. _Modern Prevalence of the Atomic Doctrine._--It is our
business here to consider the doctrine of Atoms only in its
bearing upon existing physical sciences, and I must
therefore abstain from tracing the various manifestations of
it in the schemes of hypothetical cosmologists;--its place
among the _vortices_ of Descartes, its exhibition in the
_monads_ of Leibnitz. I will, however, quote a passage from
Newton to show the hold it had upon his mind.
At the close of his _Opticks_ he says, 'All these things
being considered, it seems probable to me that God, in the
beginning, formed matter in solid, massy, hard,
impenetrable, moveable particles, of such sizes and figures,
and with such other properties, and in such proportions to
space, as most conduced to the end for which He formed them;
and that the primitive particles, being solids, are
incomparably harder than any porous bodies compounded of
them, even so very hard as never to wear or break in pieces;
no ordinary power being able to divide what God had made one
in the first creation. While the particles continue entire,
they may compose bodies of one and the same nature and
texture in all ages: but should they wear away or break in
pieces, the nature of things depending on them would be
changed. Water and earth composed {56} of old worn particles
and fragments of particles would not be of the same nature
and texture now with water and earth composed of entire
particles in the beginning. And therefore that nature may be
lasting, the changes of corporeal things are to be placed
only in the various separations and new associations and
motions of these permanent particles; compounded bodies
being apt to break, not in the midst of solid particles, but
where those particles are laid together and only touch in a
few points.'
We shall hereafter see how extensively the atomic doctrine
has prevailed among still more recent philosophers. Not only
have the chemists assumed it as the fittest form for
exhibiting the principles of multiple proportions; but the
physical mathematicians, as Laplace and Poisson, have made
it the basis of their theories of heat, electricity,
capillary action; and the crystallographers have been
supposed to have established both the existence and the
arrangement of such ultimate molecules.
In the way in which it has been employed by such writers,
the hypothesis of ultimate particles has been of great use,
and is undoubtedly permissible. But when we would assert
this theory, not as a convenient hypothesis for the
expression or calculation of the laws of nature, but as a
philosophical truth respecting the constitution of the
universe, we find ourselves checked by difficulties of
reasoning which we cannot overcome, as well as by
conflicting phenomena which we cannot reconcile. I will
attempt to state briefly the opposing arguments on this
question.
8. _Arguments for and against Atoms._--The leading arguments
on the two sides of the question, in their most general
form, may be stated as follows:
_For_ the Atomic Doctrine.--The appearances which nature
presents are compounded of many parts, but if we go on
resolving the larger parts into smaller, and so on
successively, we must at last come to something simple. For
that which is compound can be so no otherwise than by
composition of what is simple; and if we suppose all
composition to be removed, which {57} hypothetically we may
do, there can remain nothing but a number of simple
substances, capable of composition, but themselves not
compounded. That is, matter being dissolved, resolves itself
into atoms.
_Against_ the Atomic Doctrine.--Space is divisible without
limit, as may be proved by Geometry; and matter occupies
space, therefore matter is divisible without limit, and no
portion of matter is indivisible, or an _atom_.
And to the argument on the other side just stated, it is
replied that we cannot even hypothetically divest a body of
composition, if by composition we mean the relation of point
to point in space. However small be a particle, it is
compounded of parts having relation in space.
The Atomists urge again, that if matter be infinitely
divisible, a finite body consists of an infinite number of
parts, which is a contradiction. To this it is replied, that
the finite body consists of an infinite number of parts in
the same sense in which the parts are infinitely small,
which is no contradiction.
But the opponents of the Atomists not only rebut, but retort
this argument drawn from the notion of infinity. Your atoms,
they say, are indivisible by any finite force; therefore
they are infinitely hard; and thus your finite particles
possess infinite properties. To this the Atomists are wont
to reply, that they do not mean the hardness of their
particles to be infinite, but only so great as to resist all
usual natural forces. But here it is plain that their
position becomes untenable; for, in the first place, their
assumption of this precise degree of hardness in the
particles is altogether gratuitous; and in the next place,
if it were granted, such particles are not atoms, since in
the next moment the forces of nature may be augmented so as
to divide the particle, though hitherto undivided.
Such are the arguments for and against the Atomic Theory in
its original form. But when these atoms are conceived, as
they have been by Newton, and commonly by his followers, to
be solid, hard particles exerting attractive and repulsive
forces, a new set of {58} arguments come into play. Of
these, the principal one may be thus stated: According to
the Atomic Theory thus modified, the properties of bodies
depend upon the attractions and repulsions of the particles.
Therefore, among other properties of bodies, their hardness
depends upon such forces. But if the hardness _of the
bodies_ depends upon the forces, the repulsion, for
instance, of the particles, upon what does the hardness _of
the particles_ depend? what progress do we make in
explaining the properties of bodies, when we assume the same
properties in our explanation? and to what purpose do we
assume that the particles are hard?
9. _Transition to Boscovich's Theory._--To this difficulty
it does not appear easy to offer any reply. But if the
hardness and solidity of the particles be given up as an
incongruous and untenable appendage to the Newtonian view of
the Atomic Theory, we are led to the theory of Boscovich,
according to which matter consists not of solid particles,
but of mere mathematical centers of force. According to this
theory, each body is composed of a number of geometrical
points from which emanate forces, following certain
mathematical laws in virtue of which the forces become, at
certain small distances attractive, at certain other
distances repulsive, and at greater distances attractive
again. From these forces of the points arise the cohesion of
the parts of the same body, the resistance which it exerts
against the pressure of another body, and finally the
attraction of gravitation which it exerts upon bodies at a
distance.
This theory is at least a homogeneous and consistent theory,
and it is probable that it may be used as an instrument for
investigating and expressing true laws of nature; although,
as we have already said, the attempt to identify the forces
by which the particles of bodies are bound together with
mechanical attraction, appears to be a confusion of two
separate ideas[44\6].
[Note 44\6: 'Boscovich's Theory,' that all bodies may be
considered as consisting of a mere collection of centers of
forces, may be so conceived as possibly to involve an
explanation of all the powers which their parts exert, (such
powers, namely, as those which produce optical, thermotical
and chemical phenomena;) but this theory cannot supply an
explanation of the mechanical properties of a body as a
whole, especially of its _inertia_. A collection of mere
centers of force can have no inertia. If two bodies are
considered as two collections of centers of force, the one
attracting the other, there is in this view nothing to limit
or determine the velocity with which the one body will
approach the other. A world composed of such bodies is not a
_material_ world: for matter (as we have already seen in
book iii. chapter v.) implies not only force, but something
which resists the action of force.]
{59} 10. _Use of the Molecular Hypothesis._--In this form,
representing matter as a collection of molecules or centers
of force, the Atomic Theory has been abundantly employed in
modern times as an hypothesis on which calculations
respecting the elementary forces of bodies might be
conducted. When thus employed it is to be considered as
expressing the principle that the properties of bodies
depend upon forces emanating from immovable points of their
mass. This view of the way in which the properties of bodies
are to be treated by the mechanical philosopher was
introduced by Newton, and was a natural sequel to the
success which he had obtained by reasoning concerning
central forces on a large scale. I have already quoted his
Preface to the _Principia_, in which he says, 'Many things
induce me to believe that the rest of the phenomena of
nature, as well as those of astronomy, may depend upon
certain forces by which the particles of bodies, in virtue
of causes not yet known, are urged towards each other and
cohere in regular figures, or are mutually repelled and
recede; and philosophers, knowing nothing of these forces,
have hitherto failed in their examination of nature.' Since
the time of Newton, this line of speculation has been
followed with great assiduity, and by some mathematicians
with great success. In particular Laplace has shown that the
hypothesis may, in many instances, be made a much closer
representation of nature, if we suppose the forces exerted
by the particles to decrease so rapidly with the increasing
distance from them, that {60} the force is finite only at
distances imperceptible to our senses, and vanishes at all
remoter points. He has taught the method of expressing and
calculating such forces, and he and other mathematicians of
his school have applied this method to many of the most
important questions of physics; as capillary action, the
elasticity of solids, the conduction and radiation of heat.
The explanation of many apparently unconnected and curious
observed facts by these mathematical theories gives a strong
assurance that its essential principles are true. But it
must be observed that the actual constitution of bodies as
composed of distinct and separate particles is by no means
proved by these coincidences. The assumption, in the
reasoning, of certain centers of force acting at a distance,
is to be considered as nothing more than a method of
reducing to calculation that view of the constitution of
bodies which supposes that they exert force at _every_
point. It is a mathematical artifice of the same kind as the
hypothetical division of a body into infinitesimal parts, in
order to find its center of gravity; and no more implies a
physical reality than that hypothesis does.
11. _Poisson's Inference._--When, therefore, M. Poisson, in
his views of Capillary Action, treats this hypothetical
distribution of centers of force as if it were a physical
fact, and blames Laplace for not taking account of their
different distribution at the surface of the fluid and below
it[45\6], he appears to push the claims of the molecular
hypothesis too far. The only ground for the assumption of
separate centers, is that we can thus explain the action of
the whole mass. The intervals between the centers nowhere
enter into this explanation: and therefore we can have no
reason for assuming these intervals different in one part of
the fluid and in the other. M. Poisson asserts that the
density of the fluid diminishes when we approach very near
the surface; but he allows that this diminution is not
detected by experiment, and that the formulæ on {61} his
supposition, so far as the results go, are identical with
those of Laplace. It is clear, then, that his doctrine
consists merely in the assertion of the necessary truth of a
part of the hypothesis which cannot be put to the test of
experiment. It is true, that so long as we have before us
the hypothesis of separate centers, the particles very near
the surface are not in a condition symmetrical with that of
the others: but it is also true that this hypothesis is only
a step of calculation. There results, at one period of the
process of deduction, a stratum of smaller density at the
surface of the fluid; but at a succeeding point of the
reasoning the thickness of this stratum vanishes; it has no
physical existence.
[Note 45\6: Poisson, _Théorie de l'Action Capillaire_.]
Thus the _molecular_ hypothesis, as used in such cases, does
not differ from the doctrine of forces acting at _every
point_ of the mass; and this principle, which is common to
both the opposite views, is the true part of each.
12. _Wollaston's Argument._--An attempt has been made in
another case, but depending on nearly the same arguments, to
bring the doctrine of ultimate atoms to the test of
observation. In the case of the air, we know that there _is_
a diminution of density in approaching the upper surface of
the atmosphere, if it have a surface: but it is held by some
that except we allow the doctrine of ultimate molecules, it
will not be bounded by any surface, but will extend to an
infinite distance. This is the reasoning of Wollaston[46\6].
'If air consists of any ultimate particles no longer
divisible, then must the expansion of the medium composed of
them cease at that distance where the force of gravity
downwards is equal to the resistance arising from the
repulsive force of the medium.' But if there be no such
ultimate particles, every stratum will require a stratum
beyond it to prevent by its weight a further expansion, and
thus the atmosphere {62} must extend to an infinite
distance. And Wollaston conceived that he could learn from
observation whether the atmosphere was thus diffused through
all space; for if so, it must, he argued, be accumulated
about the larger bodies of the system, as Jupiter and the
Sun, by the law of universal gravitation; and the existence
of an atmosphere about these bodies, might, he remarked, be
detected by its effects in producing refraction. His result
is, that 'all the phenomena accord entirely with the
supposition that the earth's atmosphere is of finite extent,
limited by the weight of ultimate atoms of definite
magnitude, no longer divisible by repulsion of their parts.'
[Note 46\6: _Phil. Trans._ 1822, p. 89.]
A very little reflection will show us that such a line of
reasoning cannot lead to any result. For we know nothing of
the law which connects the density with the compressing
force, in air so extremely rare as we must suppose it to be
near the boundary of the atmosphere. Now there are possible
laws of dependence of the density upon the compressing force
such that the atmosphere would terminate in virtue of the
law without any assumption of atoms. This may be proved by
mathematical reasoning. If we suppose the density of air to
be as the square root of the compressing force, it will
follow that at the very limits of the atmosphere, the strata
of equal thickness may observe in their densities such a law
of proportion as is expressed by the numbers 7, 5, 3,
1[47\6].
[Note 47\6: For the compressing force on each being as the
whole weight beyond it, it will be for the four highest
strata, 16, 9, 4 and 1, of which the square roots are as 4,
3, 2, 1, or, as 8, 6, 4, 2; and though these numbers are not
exactly as the densities 7, 5, 3, 1, those who are a little
acquainted with mathematical reasoning, will see that the
difference arises from taking so small a number of strata.
If we were to make the strata indefinitely thin, as to avoid
error we ought to do, the coincidence would be exact; and
thus, according to this law, the series of strata terminates
as we ascend, without any consideration of atoms.]
If it be asked how, on this hypothesis, the density of the
highest stratum can be as 1, since there is {63} nothing to
compress it, we answer that the upper part of the highest
stratum compresses the lower, and that the density
diminishes continually to the surface, so that the need of
compression and the compressing weight vanish together.
The fallacy of concluding that because the height of the
atmosphere is finite, the weight of the highest stratum must
be finite, is just the same as the fallacy of those who
conclude that when we project a body vertically upwards,
because it occupies only a finite time in ascending to the
highest point, the velocity at the last instant of the
ascent must be finite. For it might be said, if the last
velocity of ascent be not finite, how can the body describe
the last particle of space in a finite time? and the answer
is, that there is no last finite particle of space, and
therefore no last finite velocity.
13. _Permanence of Properties of Bodies._--We have already
seen that, in explaining the properties of matter as we find
them in nature, the assumption of solid, hard,
indestructible particles is of no use or value. But we may
remark, before quitting the subject, that Newton appears to
have had another reason for assuming such particles, and one
well worthy of notice. He wished to express, by means of
this hypothesis, the doctrine that the laws of nature do not
alter with the course of time. This we have already seen in
the quotation from Newton. 'The ultimate particles of matter
are indestructible, unalterable, impenetrable; for if they
could break or wear, the structure of material bodies now
would be different from that which it was when the particles
were new.' No philosopher will deny the truth which is thus
conveyed by the assertion of atoms; but it is obviously
equally easy for a person who rejects the atomic view, to
state this truth by saying that the forces which matter
exerts do not vary with time, but however modified by the
new modifications of its form, are always unimpaired in
quantity, and capable of being restored to their former mode
of action. {64}
We now proceed to speculations in which the fundamental
conceptions may, perhaps, be expressed, at least in some
cases, by means of the arrangement of atoms; but in which
the philosophy of the subject appears to require a reference
to a new Fundamental Idea.
{{65}}
BOOK VII.
THE
PHILOSOPHY
OF
MORPHOLOGY,
INCLUDING
CRYSTALLOGRAPHY.
CRYSTALLIZATION exhibits to us the effects of the natural
arrangement of the ultimate particles of various compound
bodies; but we are scarcely yet sufficiently acquainted with
chemical synthesis and analysis to understand the rationale
of this process. The rhomboidal form may arise from the
proper position of 4, 6, 8 or 9 globular particles, the
cubic form from 8 particles, the triangular form from 3, 6
or 10 particles, the hexahedral prism from 7 particles, &c.
Perhaps, in due time we may be enabled to ascertain the
number and order of elementary particles, constituting any
given compound element, and from that determine the figure
which it will prefer on crystallization, and _vice versâ_.
JOHN DALTON, _Chemical Philosophy_ (1808), p. 210.
{{67}}
BOOK VII.
THE PHILOSOPHY OF MORPHOLOGY, INCLUDING CRYSTALLOGRAPHY.
CHAPTER I.
EXPLICATION OF THE IDEA OF SYMMETRY.
1. WE have seen in the History of the Sciences, that the
principle which I have there termed[1\7] the Principle of
Developed and Metamorphosed Symmetry, has been extensively
applied in botany and physiology, and has given rise to a
province of science termed Morphology. In order to
understand clearly this principle, it is necessary to obtain
a clear idea of the Symmetry of which we thus speak. But
this Idea of Symmetry is applicable in the inorganic, as
well as in the organic kingdoms of nature; it is presented
to our eyes in the forms of minerals, as well as of flowers
and animals; we must, therefore, take it under our
consideration here, in order that we may complete our view
of Mineralogy, which, as I have repeatedly said, is an
essential part of Chemical science. I shall accordingly
endeavour to unfold the Idea of Symmetry with which we here
have to do.
[Note 1\7: _Hist. Ind. Sc._ b. xvii. c. vi.]
It will of course be understood that by the term _Symmetry_
I here intend, not that more indefinite attribute of form
which belongs to the domain of the fine arts, as when we
speak of the 'symmetry' of an edifice {68} or of a
sculptured figure, but a certain definite relation or
property, no less rigorous and precise than other relations
of number and position, which is thus one of the sure guides
of the scientific faculty, and one of the bases of our exact
science.
2. In order to explain what Symmetry is in this sense, let
the reader recollect that the bodies of animals consist of
_two_ equal and similar sets of members, the right and the
left side;--that some flowers consist of three or of five
equal sets of organs, similarly and regularly disposed, as
the iris has _three_ straight petals, and three reflexed
ones, alternately disposed, the rose has _five_ equal and
similar sepals of the calyx, and alternate with these, as
many petals of the corolla. This orderly and exactly similar
distribution of two, or three, or five, or any other number
of parts, is Symmetry; and according to its various
modifications, the forms thus determined are said to be
_symmetrical_ with various numbers of members. The
classification of these different kinds of symmetry has been
most attended to in Crystallography, in which science it is
the highest and most general principle by which the classes
of forms are governed. Without entering far into the
technicalities of the subject, we may point out some of the
features of such classes.
[Illustration] The first of the figures (1) in the margin
may represent the summit of a crystal as it appears to an
eye looking directly down upon it; the center of the figure
represents the summit of a pyramid, and the spaces of
various forms which diverge from this point represent
sloping sides of the pyramid. Now it will be observed that
the figure consists of three portions exactly similar to one
another, and that each part or member is repeated in each of
these portions. The faces, or pairs of faces, are repeated
in _threes_, with exactly similar forms and angles. This
figure is said to be _three-membered_, or to have
_triangular_ symmetry. The same kind of {69} symmetry may
exist in a flower, as presented in the accompanying figure,
and does, in fact, occur in a large class of flowers, as for
example, all the lily tribe. The next pair of figures (2)
have four equal and similar portions, and have their members
or pairs of members four times repeated. Such figures are
termed _four-membered_, and are said to have _square_ or
_tetragonal_ symmetry. The _pentagonal_ symmetry, formed by
_five_ similar _members_, is represented in the next figures
(3). It occurs abundantly in the vegetable world, but never
among crystals; for the pentagonal figures which crystals
sometimes assume, are never exactly regular. But there is
still another kind of symmetry (4) in which the opposite
ends are exactly similar to each other and also the opposite
sides; this is _oblong_, or _two-and-two-membered_ symmetry.
And finally, we have the case of _simple_ symmetry (5) in
which the two sides of the object are exactly alike (in
opposite positions) without any further repetition.
[Illustration]
3. These different kinds of symmetry occur in various ways
in the animal, vegetable, and mineral kingdom. Vertebrate
animals have a right and a {70} left side exactly alike, and
thus possess _simple_ symmetry. The same kind of symmetry
(simple symmetry) occurs very largely in the forms of
vegetables, as in most leaves, in _papilionaceous_,
_personate_, and _labiate_ flowers. Among minerals, crystals
which possess this symmetry are called _oblique-prismatic_,
and are of very frequent occurrence. The _oblong_, or
_two-and-two-membered_ symmetry belongs to _right-prismatic_
crystals; and may be seen in _cruciferous_ flowers, for
though these are cross-shaped, the cross has two longer and
two shorter arms, or pairs of arms. The _square_ or
_tetragonal_ symmetry occurs in crystals abundantly; to the
vegetable world it appears to be less congenial; for though
there are flowers with four exactly similar and
regularly-disposed petals, as the herb Paris (_Paris
quadrifolia_), these flowers appear, from various
circumstances, to be deviations from the usual type of
vegetable forms. The _trigonal_, or _three-membered_
symmetry is found abundantly both in plants and in crystals,
while the _pentagonal_ symmetry, on the other hand, though
by far the most common among flowers, nowhere occurs in
minerals, and does not appear to be a possible form of
crystals. This pentagonal form further occurs in the animal
kingdom, which the oblong, triangular, and square forms do
not. Many of Cuvier's _radiate_ animals appear in this
pentagonal form, as _echini_ and _pentacrinites_, which
latter have hence their name.
4. The regular, or as they may be called, the _normal_ types
of the vegetable world appear to be the forms which possess
triangular and pentagonal symmetry; from these the others
may be conceived to be derived, by transformations resulting
from the expansion of one or more parts. Thus it is manifest
that if in a three-membered or five-membered flower, one of
the petals be expanded more than the other, it is
immediately reduced from pentagonal or trigonal, to simple
symmetry. And the oblong or two-and-two-membered symmetry of
the flowers of cruciferous plants, (in which the stamens are
four large and two small ones, arranged in regular
opposition,) is held by botanists to result {71} from a
normal form with ten stamens; Meinecke explaining this by
adhesion, and Sprengel by the metamorphosis of the stamens
into petals[2\7].
[Note 2\7: Sprengel, _Gesch. d. Bot._ ii. 304.]
It is easy to see that these various kinds of symmetry
include relations both of form and of number, but more
especially of the latter kind; and as this symmetry is often
an important character in various classes of natural
objects, such classes have often curious numerical
properties. One of the most remarkable and extensive of
these is the distinction which prevails between
monocotyledonous and dicotyledonous plants; the number
_three_ being the ground of the symmetry of the former, and
the number _five_, of the latter. Thus liliaceous and
bulbous plants, and the like, have flowers of three or six
petals, and the other organs follow the same numbers: while
the vast majority of plants are pentandrous, and with their
five stamens have also their other parts in fives. This
great numerical distinction corresponding to a leading
difference of physiological structure cannot but be
considered as a highly curious fact in phytology. Such
properties of numbers, thus connected in an incomprehensible
manner with fundamental and extensive laws of nature, give
to numbers an appearance of mysterious importance and
efficacy. We learn from history how strongly the study of
such properties, as they are exhibited by the phenomena of
the heavens, took possession of the mind of Kepler; perhaps
it was this which, at an earlier period, contributed in no
small degree to the numerical mysticism of the Pythagoreans
in antiquity, and of the Arabians and others in the middle
ages. In crystallography, numbers are the primary characters
in which the properties of substances are expressed;--they
appear, first, in that classification of forms which depends
on the degree of symmetry, that is, upon the number of
correspondencies; and next, in the laws of derivation,
which, for the most part, appear to be common in their
occurrence in proportion to the numerical simplicity of
their expression. But the manifestation {72} of a governing
numerical relation in the organic world strikes us as more
unexpected; and the selection of the number _five_ as the
index of the symmetry of dicotyledonous plants and radiated
animals, (a number which is nowhere symmetrically produced
in inorganic bodies,) makes this a new and remarkable
illustration of the constancy of numerical relations. We may
observe, however, that the moment one of these radiate
animals has one of its five members expanded, or in any way
peculiarly modified, (as happens among the echini), it is
reduced to the common type of animals simply symmetrical,
with a right and left side.
5. It is not necessary to attempt to enumerate all the kinds
of Symmetry, since our object is only to explain what
Symmetry is, and for this purpose enough has probably been
said already. It will be seen, as soon as the notion of
Symmetry in general is well apprehended, that it is or
includes a peculiar Fundamental Idea, not capable of being
resolved into any of the ideas hitherto examined. It may be
said, perhaps, that the Idea of Symmetry is a modification
or derivative of our ideas of space and number;--that a
symmetrical shape is one which consists of parts exactly
similar, repeated a certain number of times, and placed so
as to correspond with each other. But on further reflection
it will be seen that this repetition and correspondence of
parts in symmetrical figures are something peculiar; for it
is not _any_ repetition or any correspondence of parts to
which we should give the name of symmetry, in the manner in
which we are now using the term. Symmetrical arrangements
may, no doubt, be concerned with space and position, time
and number; but there appears to be implied in them a
Fundamental Idea of regularity, of completeness, of complex
simplicity, which is not a mere modification of other ideas.
6. It is, however, not necessary, in this and in similar
cases, to determine whether the idea which we have before us
be a peculiar and independent Fundamental Idea or a
modification of other ideas, provided we clearly perceive
the evidence of those Axioms by {73} means of which the Idea
is applied in scientific reasonings. Now in the application
of the Idea of Symmetry to crystallography, phytology and
zoology, we must have this idea embodied in some principle
which asserts more than a mere geometrical or numerical
accordance of members. We must have it involved in some
vital or productive action, in order that it may connect and
explain the facts of the organic world. Nor is it difficult
to enunciate such a principle. We may state it in this
manner. _All the symmetrical members of a natural product
are, under like circumstances, alike affected by the natural
formative power._ The parts which we have termed
_symmetrical_, resemble each other, not only in their form
and position, but also in the manner in which they are
produced and modified by natural causes. And this principle
we assume to be necessarily true, however unknown and
inconceivable may be the causes which determine the
phenomena. Thus it has not yet been found possible to
discover or represent to ourselves, in any intelligible
manner, the forces by which the various faces of a crystal
are consequent upon its primary form: for the hypothesis of
their being built up of integrant molecules, as Haüy held,
cannot be made satisfactory. But though the mechanism of
crystals is still obscure, there is no doubt as to the
principle which regulates their modifications. The whole of
crystallography rests upon this principle, that if one of
the primary planes or axes be modified in any manner, all
the symmetrical planes and axes must be modified in the same
manner. And though accidental mechanical or other causes may
interfere with the actual exhibition of such faces, we do
not the less assume their crystallographical reality, as
inevitably implied in the law of symmetry of the
crystal[3\7]. And we apply similar considerations to
organized beings. We assume that in a regular flower, each
of the similar {74} members has the same organization and
similar powers of developement; and hence if among these
similar parts some are much less developed than others, we
consider them as _abortive_; and if we wish to remove doubts
as to what are symmetrical members in such a case, we make
the inquiry by tracing the anatomy of these members, or by
following them in their earlier states of developement, or
in cases where their capabilities are magnified by
monstrosity or otherwise. The power of developement may be
modified by external causes, and thus we may pass from one
kind of symmetry to another; as we have already remarked.
Thus a regular flower with pentagonal symmetry, growing on a
lateral branch, has one petal nearest to the axis of the
plant: if this petal be more or less expanded than the
others, the pentagonal symmetry is interfered with, and the
flower may change to a symmetry of another kind. But it is
easy to see that all such conceptions of expansion,
abortion, and any other kind of metamorphosis, go upon the
supposition of identical faculties and tendencies in each
similar member, in so far as such tendencies have any
relation to the symmetry. And thus the principle we have
stated above is the basis of that which, in the History, we
termed the Principle of Developed and Metamorphosed
Symmetry.
[Note 3\7: Some crystalline forms, instead of being
_holohedral_ (provided with their whole number of faces),
are _hemihedral_ (provided with only half their number of
faces). But in these hemihedral forms the half of the faces
are still _symmetrically_ suppressed.]
We shall not at present pursue the other applications of
this Idea of Symmetry, but we shall consider some of the
results of its introduction into Crystallography.
{{75}}
CHAPTER II.
APPLICATION OF THE IDEA OF SYMMETRY TO CRYSTALS.
1. MINERALS and other bodies of definite chemical
composition often exhibit that marked regularity of form and
structure which we designate by terming them _Crystals_; and
in such crystals, when we duly study them, we perceive the
various kinds of symmetry of which we have spoken in the
previous chapter. And the different kinds of symmetry which
we have there described are now usually distinguished from
each other, by writers on crystallography. Indeed it is
mainly to such writers that we are indebted for a sound and
consistent classification of the kinds and degrees of
symmetry of which forms are capable. But this classification
was by no means invented as soon as mineralogists applied
themselves to the study of crystals. These first attempts to
arrange crystalline forms were very imperfect; those, for
example, of Linnæus, Werner, Romé de Lisle, and Haüy. The
essays of these writers implied a classification at once
defective and superfluous. They reduced all crystals to one
or other of certain _fundamental forms_; and this procedure
might have been a perfectly good method of dividing
crystalline forms into classes, if the fundamental forms had
been selected so as to exemplify the different kinds of
symmetry. But this was not the case. Haüy's fundamental or
'primitive' forms, were, for instance, the following: the
_parallelepiped_, the _octahedron_, the _tetrahedron_, the
_regular hexagonal prism_, the _rhombic dodecahedron_, and
the _double hexagonal pyramid_. Of these, the _octahedron_,
the _tetrahedron_, the _rhombic dodecahedron_, all belong to
the {76} same kind of symmetry (the TESSULAR systems); also
the _hexagonal prism_ and the _hexagonal pyramid_ both
belong to the RHOMBIC system; while the _parallelepiped_ is
so employed as to include all kinds of symmetry.
It is, however, to be recollected that Haüy, in his
selection of primitive forms, not only had an eye to the
external form of the crystal and to its degree and kind of
regularity, but also made his classification with an
especial reference to the _cleavage_ of the mineral, which
he considered as a primary element in crystalline analysis.
There can be no doubt that the cleavage of a crystal is one
of its most important characters: it is a relation of form
belonging to the interior, which is to be attended to no
less than the form of the exterior. But still, the cleavage
is to be regarded only as determining the degree of
geometrical symmetry of the body, and not as defining a
special geometrical figure to which the body _must_ be
referred. To have looked upon it in the latter light, was a
mistake of the earlier crystallographic speculators, on
which we shall shortly have to remark.
2. I have said that the reference of crystals to Primitive
Forms might have been well employed as a mode of expressing
a just classification of them. This follows as a consequence
from the application of the Principle stated in the last
chapter, that _all symmetrical members are alike affected_.
Thus we may take an upright triangular prism as the
representative of the rhombic system, and if we then suppose
one of the upper edges to be cut off, or truncated, we must,
by the Principle of Symmetry, suppose the other two upper
edges to be truncated in precisely the same manner. By this
truncation we may obtain the upper part of a rhombohedron;
and by truncations of the same kind, symmetrically affecting
all the analogous parts of the figure, we may obtain any
other form possessing three-membered symmetry. And the same
is true of any of the other kinds of symmetry, provided we
make a proper selection of a fundamental form. And this was
really the method employed by Demeste, Werner, and Romé de
Lisle. They {77} assumed a Primitive Form, and then
conceived other forms, such as they found in nature, to be
derived from the Primitive Form by truncation of the edges,
acumination of the corners, and the like processes. This
mode of conception was a perfectly just and legitimate
expression of the general Idea of Symmetry.
3. The true view of the degrees of symmetry was, as I have
already said, impeded by the attempts which Haüy and others
made to arrive at primitive forms by the light which
cleavage was supposed to throw upon the structure of
minerals. At last, however, in Germany, as I have narrated
in the History of Mineralogy[4\7], Weiss and Mohs introduced
a classification of forms implying a more philosophical
principle, dividing the forms into Systems; which, employing
the terms of the latter writer, we shall call the
_tessular_, the _pyramidal_ or _square pyramidal_, the
_prismatic_ or _oblong_, and the _rhombohedral_ systems.
[Note 4\7: _Hist. Ind. Sc._ b. xv. c. iv.]
Of these forms, the three latter may be at once referred to
those kinds of symmetry of which we have spoken in the last
chapter. The _rhombohedral_ system has _triangular_
symmetry, or is three-membered: the _pyramidal_ has _square_
symmetry, or is four-membered: the _prismatic_ has _oblong_
symmetry, and is two-and-two-membered. But the kinds of
symmetry which were spoken of in the former chapter, do not
exhaust the idea when applied to minerals. For the symmetry
which was there explained was such only as can be exhibited
on a surface, whereas the forms of crystals are solid. Not
only have the right and left parts of the upper surface of a
crystal relations to each other; but the upper surface and
the lateral faces of the crystal have also their relations;
they may be different, or they may be alike. If we take a
cube, and hold it so that four of its faces are vertical,
not only are all these four sides exactly similar, so as to
give square symmetry; but also we may turn the cube, so that
any one of these four sides shall become the top, and still
the four sides which are thus made vertical, though {78} not
the same which were vertical before, are still perfectly
symmetrical. Thus this cubical figure possesses more than
square symmetry. It possesses square symmetry in a vertical
as well as in a horizontal sense. It possesses a symmetry
which has the same relation to a _cube_ which four-membered
symmetry has to a _square_. And this kind of symmetry is
termed the _cubical_ or _tessular_ symmetry. All the other
kinds of symmetry have reference to an axis, about which the
corresponding parts are disposed; but in tessular symmetry
the horizontal and vertical axes are also symmetrical, or
interchangeable; and thus the figure may be said to have no
axis at all.
4. It has already been repeatedly stated that, by the very
idea of symmetry, all the incidents of form must affect
alike all the corresponding parts. Now in crystals we have,
among these incidents, not only external figure, but
_cleavage_, which may be considered as internal figure.
Cleavage, then, must conform to the degree of symmetry of
the figure. Accordingly cleavage, no less than form, is to
be attended to in determining to what system a mineral
belongs. If a crystal were to occur as a square prism or
pyramid, it would not on that account necessarily belong to
the square pyramidal system. If it were found that it was
cleavable parallel to one side of the prism, but not in the
transverse direction, it has only oblong symmetry; and the
equality of the sides which makes it square is only
accidental.
Thus no cleavage is admissible in any system of
crystallization which does not agree with the degree of
symmetry of the system. On the other hand, _any_ cleavage
which _is_ consistent with the symmetry of the system, is
(hypothetically at least) allowable. Thus in the oblong
prismatic system we may have a cleavage parallel to one side
only of the prism; or parallel to both, but of different
distinctness; or parallel to the two diagonals of the prism
but of the same distinctness; or we may have both these
cleavages together. In the rhombohedral system, the cleavage
may be parallel to the sides of the rhombohedron, as in Calc
{79} Spar: or, in the same system, the cleavage, instead of
being thus oblique to the axis, may be along the axis in
those directions which make equal angles with each other:
this cleavage easily gives either a triangular or a
hexagonal prism. Again, in the tessular system, the cleavage
may be parallel to the surface of the cube, which is thus
readily separable into other cubes, as in Galena; or the
cleavage may be such as to cut off the solid angle of the
cube, and since there are eight of these, such cleavage
gives us an octahedron, which, however, may be reduced to a
tetrahedron, by rejecting all parallel faces, as being mere
repetitions of the same cleavage; this is the case with
Fluor Spar: or the cube of the tessular system may be
cleavable in planes which truncate all the edges of the
cube; and as these are twelve, we thus obtain the
dodecahedron with rhombic faces: this occurs in Zinc Blende.
And thus we see the origin of Haüy's various primitive
forms, the tetrahedron, octahedron, and rhombic
dodecahedron, all belonging to the tessular system:--they
are, in fact, different cleavage forms of that system.
5. I do not dwell upon other incidents of crystals which
have reference to form, nor upon the lustre, smoothness, and
striation of the surfaces. To all such incidents the general
principle applies, that similar parts are similarly
affected; and hence, if any parts are found to be constantly
and definitely different from other parts of the same sort,
they are not similar parts; and the symmetry is to be
interpreted with reference to this difference.
We have now to consider the inferences which have been drawn
from these incidents of crystallization, with regard to the
intimate structure of bodies.
{{80}}
CHAPTER III.
SPECULATIONS FOUNDED UPON THE SYMMETRY OF CRYSTALS.
1. WHEN a crystal, as, for instance, a crystal of Galena,
(sulphuret of lead,) is readily divisible into smaller
cubes, and these into smaller ones, and so on without limit,
it is very natural to represent to ourselves the original
cube as really consisting of small cubical elements; and to
imagine that it is a philosophical account of the physical
structure of such a substance to say that it is made up of
cubical molecules. And when the Galena crystal has
externally the form of a cube, there is no difficulty in
such a conception; for the surface of the crystal is also
conceived as made up of the surfaces of its cubical
molecules. We conceive the crystal so constituted, as we
conceive a wall built of bricks.
But if, as often happens, the Galena crystal be an
octahedron, a further consideration is requisite in order to
understand its structure, pursuing still the same
hypothesis. The mineral is still, as in the other case,
readily cleavable into small cubes, having their corners
turned to the faces of the octahedron. Therefore these faces
can no longer be conceived as made up of the faces of
cubical elements of which the whole is constituted. If we
suppose a pile of such small cubes to be closely built
together, but with decreasing width above, so as to form a
pyramid, the face of such a pyramid will no longer be plane;
it will consist of a great number of the corners or edges of
the small elementary cubes. It would appear at first sight,
therefore, that such a face cannot represent the smooth
polished surface of a crystal. {81}
But when we come to look more closely, this difficulty
disappears. For how large are these elementary cubes? We
cannot tell, even supposing they really have any size. But
we know that they must be, at any rate, very small; so small
as to be inappreciable by our senses, for our senses find no
limit to the divisibility of minerals by cleavage. Hence the
surface of the pyramid above described would not consist of
visible corners or edges, but would be roughened by specks
of imperceptible size; or rather, by supposing these specks
to become still smaller, the roughness becomes smoothness.
And thus we may have a crystal with a smooth surface, made
up of small cubes in such a manner that their surfaces are
all oblique to the surface of the crystal.
Haüy, struck by some instances in which the supposition of
such a structure of crystals appeared to account happily for
several of their relations and properties, adopted and
propounded it as a general theory. The small elements, of
which he supposed crystals to be thus built up, he termed
_integrant molecules_. The form of these molecules might or
might not be the same as the _primitive form_ with which his
construction was supposed to begin; but there was, at any
rate, a close connexion between these forms, since both of
them were founded on the cleavage of the mineral. The tenet
that crystals are constituted in the manner which I have
been describing, I shall call the _Theory of Integrant
Molecules_, and I have now to make some remarks on the
grounds of this theory.
2. In the case of which I have spoken, the mineral used as
the example, Galena, readily splits into cubes, and cubes
are easily placed together so as to fit each other, and fill
the space which they occupy. The same is the case in the
mineral which suggested to Haüy his theory, namely, Calc
Spar. The crystals of this substance are readily divisible
into rhombohedrons, a form like a brick with oblique angles;
and such bricks can be built together so as to produce
crystals of all the immense varieties of form which Calc
Spar presents. This kind of masonry is equally possible in
many other {82} minerals; but as we go through the mineral
kingdom in our survey, we soon find cases which offer
difficulties. Some minerals cleave only in two directions,
some in one only; in such cases we cannot by cleavage obtain
an integrant molecule of definite form; one of its
dimensions, at least, must remain indeterminate and
arbitrary. Again, in some instances, we have more than three
different planes of cleavage, as in Fluor Spar, where we
have four. The solid, bounded by four planes, is a
tetrahedron; or if we take four _pairs_ of parallel faces,
an octahedron. But if we attempt to take either of these
forms for our integrant molecule, we are met by this
difficulty: that a collection of such forms will not fill
space. Perhaps this difficulty will be more readily
conceived by the general reader if it be contemplated with
reference to plane figures. It will readily be seen that a
number of equal squares may be put together so as to fill
the space which they occupy; but if we take a number of
equal regular octagons, we may easily convince ourselves
that no possible arrangement can make them cover a flat
space without leaving blank spots between. In like manner
octahedrons or tetrahedrons cannot be arranged in solid
space so as to fill it. They necessarily leave vacancies.
Hence the structure of Fluor Spar, and similar crystals, was
a serious obstacle in the way of the theory of integrant
molecules. That theory had been adopted in the first
instance because portions of the crystal, obtained by
cleavage, could be built up into a solid mass; but this
ground of the theory failed altogether in such instances as
I have described, and hence the theory, even upon the
representations of its adherents, had no longer any claim to
assent.
The doctrine of Integral Molecules, however, was by no means
given up at once, even in such instances. In this and in
other subjects, we may observe that a theory, once
constructed and carried into detail, has such a hold upon
the minds of those who have been in the habit of applying
it, that they will attempt to uphold it by introducing
suppositions inconsistent with {83} the original foundations
of the theory. Thus those who assert the Atomic Theory,
reconcile it with facts by taking the _halves of atoms_; and
thus the Theory of Integrant Molecules was maintained for
Fluor Spar, by representing the elementary octahedrons of
which crystals are built up, as touching each other only by
the _edges_. The contact of surface with surface amongst
integrant molecules had been the first basis of the theory;
but this supposition being here inapplicable, was replaced
by one which made the theory no longer a representation of
the facts (the cleavages), but a mere geometrical
construction. Although, however, the inapplicability of the
theory to such cases was thus, in some degree, disguised to
the disciples of Haüy, it was plain that, in the face of
such difficulties, the Theory of Integrant Molecules could
not hold its place as a philosophical truth. But it still
answered the purpose (a very valuable one, and one to which
crystallography is much indebted,) of an instrument for
calculating the geometrical relations of the parts of
crystals to each other: for the integrant molecules were
supposed to be placed layer above layer, each layer as we
ascend, _decreasing_ by a certain number of molecules and
rows of molecules; and the calculation of these _laws of
decrement_ was, in fact, the best mode then known of
determining the positions of the faces. The Theory of
Decrements served to express and to determine, in a great
number of the most obvious cases, _the laws of phenomena_ in
crystalline forms, though the Theory of Integrant Molecules
could not be maintained as a just view of the structure of
crystals.
3. The Theory of Integrant Molecules, however, involved this
just and important principle: that a true view of the
intimate structure of crystals must include and explain the
facts of crystallization, that is, crystalline form and
cleavage; and that it must take these into account,
according to their degree of _Symmetry_. So far all theories
concerning the elements of crystals must agree. And it was
soon seen that this was, in reality, all that had been
established by the investigations of Haüy and his school. I
have already, in the {84} _History_, quoted Weiss's
reflections on making this step. 'When in 1809,' he
says[5\7], 'I published my Dissertation, I shared the common
opinion as to the necessity of the assumption, and the
reality of the existence of a primitive form, at least in a
sense not very different from the usual sense of the
expression.' He then proceeds to relate that he sought a
ground for such an opinion, independent of the doctrine of
_Atoms_, which he, in common with a great number of
philosophers of that time in his own country, was disposed
to reject, inclining to believe that the properties of
bodies were determined by _Forces_ which acted in them, and
not by _Molecules_ of which they were composed. He adds,
that in pursuing this train of thought, he found, 'that out
of his Primitive Forms there was gradually unfolded to his
hands that which really governs them, and is not affected by
their casual fluctuations; namely, the Fundamental Relations
of their Dimensions,' or as we now may call them, _Axes of
Symmetry_. With reference to these Axes, he found, as he
goes on to say, that 'a multiplicity of internal
Oppositions, necessarily and mutually interdependent, are
developed in the crystalline mass, each Relation having its
own Polarity; so that the Crystalline Character is
co-extensive with these Polarities.' The character of these
polarities, whether manifested in crystalline faces,
cleavage, or any other incidents of crystallization, is
necessarily displayed in the degree and kind of Symmetry
which the crystal possesses: and thus this Symmetry, in all
our speculations concerning the structure of crystals,
necessarily takes the place of that enumeration of Primitive
Forms which were rejected as inconsistent with observed
facts, and destitute of sound scientific principle.
[Note 5\7: _Acad. Berlin._ 1816, p. 307.]
I may just notice here what I have stated in the History of
Mineralogy[6\7], that the distinction of systems of
crystallization, as introduced by Weiss and Mohs, was
strikingly confirmed by Sir David Brewster's discoveries
respecting the optical properties of minerals. {85} The
splendid phenomena which were produced by passing polarized
light through crystals, were found to vary according as the
crystals were of the Rhombohedral, Square Pyramidal, Oblong
Prismatic, or Tessular System. The Optical Symmetry exactly
corresponded with the Geometrical Symmetry. In the two
former Systems were crystals _uniaxal_ in respect of their
optical properties; the oblong prismatic, was _biaxal_;
while in the tessular, the want of a predominant axis
prevented the phenomena here spoken of from occurring at
all. The optical experiments must have led, and would have
led, to a classification of crystals into the above systems
or something nearly equivalent, even had they not been
already so arranged by attention to their forms.
[Note 6\7: _Hist. Ind. Sc._ b. xv. c. v.]
4. While in Germany Weiss and Mohs with their disciples,
were gradually rejecting what was superfluous in the
previous crystallographical hypotheses, philosophers in
England were also trying to represent to themselves the
constitution of crystals in a manner which should be free
from the obviously arbitrary and untenable fictions of the
Haüyian school. These attempts, however, were not crowned
with much success. One mode of representing the structure of
crystals which suggested itself, was to reject the
polyhedral forms which Haüy gave to his integrant molecules,
and to conceive the elements of crystals as _spheres_, the
properties of the crystal being determined not by the
_surfaces_, but by the _position_ of the elements. This was
done by Wollaston, in the _Philosophical Transactions_ for
1813. He applied this view to the tessular system, in which,
indeed, the application is not difficult; and he showed that
octahedral and tetrahedral figures may be deduced from
symmetrical arrangements of equal spherules. But though in
doing this, he manifested a perception of the conditions of
the problem, he appeared to lose his hold on the real
question when he tried to pass on to other systems of
crystallization. For he accounted for the rhombohedral
system by supposing the spheres changed into _spheroids_.
Such a procedure involved him in a gratuitous and useless
hypothesis: for to what purpose do we introduce the {86}
arrangement of atoms (instead of their figure,) as a mode of
explaining the symmetry of the crystallization, when at the
next step we ascribe to the atom, by an arbitrary fiction, a
symmetry of figure of the same kind as that which we have to
explain? It is just as easy, and as allowable, to assume an
elementary rhombohedron, as to assume elementary spheroids,
of which the rhombohedrons are constructed.
5. Many hypotheses of the same kind might be adduced,
devised both by mineralogists and chemists. But almost all
such speculations have been pursued with a most surprising
neglect of the principle which obviously is the only sound
basis on which they can proceed. The principle is
this:--that _All hypotheses concerning the arrangement of
the elementary atoms of bodies in space must be constructed
with reference to the general facts of crystallization_. The
truth and importance of this principle can admit of no
doubt. For if we make any hypothesis concerning the mode of
connexion of the elementary particles of bodies, this must
be done with the view of representing to ourselves the
forces which connect them, and the results of these forces
as manifested in the properties of the bodies. Now the
forces which connect the particles of bodies so as to make
them crystalline, are manifestly chemical forces. It is only
definite chemical compounds which crystallize; and in
crystals the force of cohesion by which the particles are
held together cannot in any way be distinguished or
separated from the chemical force by which their elements
are combined. The elements are understood to be combined,
precisely because the result is a definite, apparently
homogeneous substance. The properties of the compound bodies
depend upon the elements and their mode of combination; for,
in fact, these include everything on which they can depend.
There are no other circumstances than these which can affect
the properties of a body. Therefore all those properties
which have reference to space, namely, the crystalline
properties, cannot depend upon anything else than the
arrangement of the elementary molecules in space. These {87}
properties are the facts which any hypothesis of the
arrangement of molecules must explain, or at least render
conceivable; and all such hypotheses, all constructions of
bodies by supposed arrangements of molecules, can have no
other philosophical object than to account for facts of this
kind. If they do not do this, they are mere arbitrary
geometrical fictions, which cannot be in any degree
confirmed or authorised by an examination of nature, and are
therefore not deserving of any regard.
6. Those philosophers who have endeavoured to represent the
mode in which bodies are constructed by the combination of
their chemical atoms, have often undertaken to show, not
only that the atoms are combined, but also in what positions
and configurations they are combined. And it is truly
remarkable, as I have already said, that they have done
this, almost in every instance, without any consideration of
the crystalline character of the resulting combinations;
from which alone we receive any light as to the relation of
their elements in space. Thus Dr. Dalton, in his _Elements
of Chemistry_, in which he gave to the world the Atomic
Theory as a representation of the doctrine of definite and
multiple proportions, also published a large collection of
Diagrams, exhibiting what he conceived to be the
configuration of the atoms in a great number of the most
common combinations of chemical elements. Now these
hypothetical diagrams do not in any way correspond, as to
the nature of their symmetry, with the compounds, as we find
them displaying their symmetry when they occur crystallized.
Carbonate of lime has in reality a triangular symmetry,
since it belongs to the rhombohedral system; Dr. Dalton's
carbonate of lime would be an oblique rhombic prism or
pyramid. Sulphate of baryta is really two-and-two membered;
Dr. Dalton's diagram makes it two-and-one membered. Alum is
really octahedral or tessular; but according to the diagram
it could not be so, since the two ends of the atom are not
symmetrical. And the same want of correspondence between the
facts and the hypothesis runs through the whole {88} system.
It need not surprise us that the theoretical arrangement of
atoms does not explain the facts of _crystallization_; for
to produce such an explanation would be a second step in
science quite as great as the first, the discovery of the
atomic theory in its _chemical_ sense. But we may allow
ourselves to be surprised that an utter discrepance between
all the facts of crystallization and the figures assumed in
the theory, did not suggest any doubt as to the soundness of
the mode of philosophizing by which this part of the theory
was constructed.
7. Some little accordance between the hypothetical
arrangements of chemical atoms and the facts of
crystallization, does appear to have been arrived at by some
of the theorists to whom we here refer, although by no means
enough to show a due conviction of the importance of the
principle stated above. Thus Wollaston, in the Essay above
noticed, after showing that a symmetrical arrangement of
equal spherules would give rise to octahedral and other
tessular figures, remarks, very properly, that the metals,
which are simple bodies, crystallize in such forms. M.
Ampère[7\7] also, in 1814, published a brief account of an
hypothesis of a somewhat similar nature, and stated himself
to have developed this speculation in a Memoir which has not
yet, so far as I am aware, been published. In this notice he
conceives bodies to be compounded of _molecules_, which,
arranged in a polyhedral form, constitute _particles_. These
_representative forms_ of the particles depend on chemical
laws. Thus the particles of oxygen, of hydrogen, and of
azote, are composed each of four molecules. Hence it is
collected that the particles of nitrous gas are composed of
two molecules of oxygen and two of azote; and similar
conclusions are drawn respecting other substances. These
conclusions, though expressed by means of the polyhedrons
thus introduced, are supported by chemical, rather than by
crystallographical comparisons. The author does, indeed,
appeal to the crystallization of sal {89} ammoniac as an
argument[8\7]; but as _all_ the forms which he introduces
appear to belong to the _tessular_ system of
crystallization, there is, in his reasonings, nothing
distinctive; and therefore nothing, crystallographically
speaking, of any weight on the side of this theory.
[Note 7\7: _Ann. de Chimie_, tom. xc. p. 43.]
[Note 8\7: _Ann. de Chimie_, tom. xc. p. 83.]
8. Any hypothesis which should introduce any principle of
chemical order among the actual forms of minerals, would
well deserve attention. At first sight, nothing can appear
more anomalous than the forms which occur. We have, indeed,
one broad fact, which has an encouraging aspect, the
tessular forms in which the pure metals crystallize. The
highest degree of chemical and of geometrical simplicity
coincide: irregularity disappears precisely where it is
excluded by the consideration above stated, that the
symmetry of chemical composition must determine the symmetry
of crystalline form[9\7].
[Note 9\7: Inasmuch as this law, that the simple metals
crystallize in tessular forms, is the most signal example of
that connexion between the chemical nature of a body and its
crystalline form, I in the former Edition stated it with as
much generality as I could find any ground for, and I should
have been glad if I could have added confirmation of the
law, derived from later observations. But the most recent
investigations of crystallographers appear to have afforded
exceptions rather than examples of the rule. Arsenic and
Tellurium are said to be _rhombohedral_. Antimony, stated by
Haüy to be octahedral (and therefore tessular), has been
found by more modern observers to be _rhombohedral_. Tin has
been obtained by Professor Miller in beautiful crystals
belonging to the _pyramidal_ system. Professor Nöggerath has
observed in Zinc, after cooling from fusion, hexagonal
cleavage, rendering it probable that the mineral
crystallized in _rhombohedrons_ having their axes vertical,
like ice. G. Rose conceives it highly probable that Osmium
and Iridium are _rhombohedral_. (Poggendorf. Bd. liv.)
But all the more perfect metals are tessular; namely, Gold,
Silver, Mercury, Platinum, Iron, Copper; also Bismuth [?]
Perhaps the observation in which the crystallization of Zinc
is affected by its position is, on that very account, no
sufficient evidence of its free crystallization. We can
hardly conceive a collection of perfectly simple, similar
particles to crystallize so as to have one pre-eminent axis,
without some extraneous action affecting them.]
But if we go on to any other class of crystalline forms, we
soon find ourselves lost in our attempts to {90} follow any
thread of order. We have indeed many large groups connected
by obvious analogies; as the rhombohedral carbonates of
lime, magnesia, iron, manganese;--the prismatic carbonates
and sulphates of lime, baryta, strontia, lead. But even in
these, we cannot form any plausible hypothesis of the
arrangement of the elements; and in other cases to which we
naturally turn, we can find nothing but confusion. For
instance, if we examine the oxides of metals:--those of iron
are rhombohedral and tessular; those of copper, tessular;
those of tin, of titanium, of manganese, square pyramidal;
those of antimony, prismatic; and we have other forms for
other substances.
It may be added, that if we take account of the optical
properties which, as we have already stated, have constant
relations to the crystalline forms, the confusion is still
further increased; for the optical dimensions vary in
amount, though not in symmetry, where chemistry can trace no
difference of composition.
9. We will not quit the subject, however, without noticing
the much more promising aspect which it has assumed by the
detection of such groups as are referred to in the last
article; or in other words, by Mitscherlich's discovery of
_Isomorphism_. According to that discovery, there are
various elements which may take the place of each other in
crystalline bodies, either without any alteration of the
crystalline form, or at most with only a slight alteration
of its dimensions. Such a group of elements we have in the
earths lime and magnesia, the protoxides of iron and
manganese: for the carbonates of all these bases occur
crystallized in forms of the rhombohedral system, the
characteristic angle being nearly the same in all. Now lime
and magnesia, by the discoveries of modern chemistry, are
really oxides of metals; and therefore all these carbonates
have a similar chemical constitution, while they have also a
similar crystalline form. Whether or no we can devise any
arrangement of molecules by which this connexion of the
chemical and the geometrical property can be represented, we
cannot help {91} considering the connexion as an extremely
important fact in the constitution of bodies; and such facts
are more likely than any other to give us some intelligible
view of the relations of the ultimate parts of bodies. The
same may be said of all the other isomorphous or
plesiomorphous groups[10\7]. For instance, we have a number
of minerals which belong to the same system of
crystallization, but in which the chemical composition
appears at first sight to be very various: namely, spinelle,
pleonaste, gahnite, franklinite, chromic iron oxide,
magnetic iron oxide: but Abich has shown that all these may
be reduced to a common chemical formula;--they are bioxides
of one set of bases, combined with trioxides of another set.
Perhaps some mathematician may be able to devise some
geometrical arrangement of such a group of elements which
may possess the properties of the tessular system.
Hypothetical arrangements of atoms, thus expressing both the
chemical and the crystalline symmetry which we know to
belong to the substance, would be valuable steps in
analytical science; and when they had been duly verified,
the hypotheses might easily be divested of their atomic
character.
[Note 10\7: See _Hist. Ind. Sc._ b. xv. c. vi.]
Thus, as we have already said, mineralogy, understood in its
wider sense, as the counterpart of chemistry, has for one of
its main objects to discover those Relations of the Elements
of bodies which have reference to Space. In this research,
the foundation of all sound speculation is the kind and
degree of Symmetry of form which we find in definite
chemical compounds: and the problem at present before the
inquirer is, to devise such arrangements of molecules as
shall answer the conditions alike of Chemistry and of
Crystallography.
We now proceed to the Classificatory Sciences, of which
Mineralogy is one, though hitherto by far the least
successful.
{{93}}
BOOK VIII.
THE
PHILOSOPHY
OF THE
CLASSIFICATORY SCIENCES.
WHERE a certain apparent difference between things (although
perhaps in itself of little moment) answers to we know not
what number of other differences, pervading not only their
known properties but properties yet undiscovered, it is not
optional but imperative to recognise this difference as the
foundation of a specific distinction.
JOHN S. MILL, _System of Logic_, b. 1, ch. vii. § 4.
{{95}}
BOOK VIII.
THE PHILOSOPHY OF THE CLASSIFICATORY SCIENCES.
CHAPTER I.
THE IDEA OF LIKENESS AS GOVERNING THE USE OF COMMON NAMES.
1. _Object of the Chapter._--NOT only the Classificatory
Sciences, but the application of names to things in the
rudest and most unscientific manner, depends upon our
apprehending them as _like_ each other. We must therefore
endeavour to trace the influence and operation of the Idea
of Likeness in the common use of language, before we speak
of the conditions under which it acquires its utmost
exactness and efficacy.
It will be my object to show in this, as in previous cases,
that the impressions of sense are apprehended by acts of the
mind; and that these mental acts necessarily imply certain
relations which may be made the subjects of speculative
reasoning. We shall have, if we can, to seize and bring into
clear view the principles which the relation of _like_ and
_unlike_ involves, and the mode in which these principles
have been developed.
2. _Unity of the Individual._--But before we can attend to
several things as like or unlike, we must be able to
apprehend each of these by itself as _one thing_. {96} It
may at first sight perhaps appear that this apprehension
results immediately from the impressions on our senses,
without any act of our thoughts. A very little attention,
however, enables us to see that thus to single out special
objects requires a mental operation as well as a sensation.
How, for example, without an exertion of mental activity,
can we see one tree, in a forest where there are many? We
have, spread before us, a collection of colours and forms,
green and brown, dark and light, irregular and straight:
this is all that sensation gives or can give. But we
associate one brown trunk with one portion of the green
mass, excluding the rest, although the neighbouring leaves
are both nearer in contiguity and more similar in appearance
than is the stem. We thus have before us one tree; but this
unity is given by the mind itself. We see the green and the
brown, but we must _make_ the tree before we can see _it_.
That this composition of our sensations so as to form _one
thing_ implies an act of our own, will perhaps be more
readily allowed, if we once more turn our attention to the
manner in which we sometimes attempt to imitate and record
the objects of sight, by drawing. When we do this, as we
have already observed, we mark this unity of each object, by
drawing a line to separate the parts which we include from
those which we exclude;--an _Outline_. This line corresponds
to nothing which we see; the beginner in drawing has great
difficulty in discerning it; he has in fact to make it. It
is, as has been said by a painter of our own time[1\8], a
fiction: but it is a fiction employed to mark a real act of
the mind; to designate the singleness of the object in our
conception. As we have said elsewhere, we see lines, but
especially outlines, by mentally drawing them ourselves.
[Note 1\8: Phillips _On Painting_,--Design.]
The same act of conception which the outline thus represents
and commemorates in visible objects,--the same combination
of sensible impressions into a unit,--is exercised also with
regard to the objects of all {97} our senses: and the
singleness thus given to each object, is a necessary
preliminary to its being named or represented in any other
way.
But it may be said, Is it then by an arbitrary act of our
own that we put together the branches of the same tree, or
the limbs of the same animal? Have we equally the power and
the right to make the branch of the fir a part of the
neighbouring oak? Can we include in the outline of a man any
object with which he happens to be in contact?
Such suppositions are manifestly absurd. And the answer is,
that though we give unity to objects by an act of thought,
it is not by an _arbitrary_ act; but by a process subject to
certain conditions;--to conditions which exclude such
incongruous combinations as have just been spoken of.
What are these conditions which regulate our apprehension of
an object as one?--which determine what portion of our
impressions does, and what portion does not belong to the
same thing?
3. _Condition of Unity._--I reply, that the primary and
fundamental condition is, that we must be able to make
intelligible assertions respecting the object, and to
entertain that belief of which assertions are the
exposition. A tree _grows_, _sheds_ its leaves in autumn,
and _buds_ again in the spring, _waves_ in the wind, or
_falls_ before the storm. And to the tree belong all those
parts which must be included in order that such
declarations, and the thought which they convey, shall have
a coherent and permanent meaning. Those are _its_ branches
which wave and fall with _its_ trunk; those are _its_ leaves
which grow on _its_ branches. The permanent connexions which
we observe,--permanent, among unconnected changes which
affect the surrounding appearances,--are what we bind
together as belonging to one object. This permanence is the
condition of our conceiving the object _as_ one. The
connected changes may always be described by means of
assertions; and the connexion is seen in the identity of the
subject of successive predications; in the possibility of
applying many verbs to one substantive. We may {98}
therefore express the condition of the unity of an object to
be this: that _assertions concerning the object shall be
possible_: or rather we should say, that the acts of belief
which such assertions enunciate shall be possible.
It may seem to be superfluous to put in a form so abstract
and remote, the grounds of a process apparently so simple as
our conceiving an object to be one. But the same condition
to which we have thus been led, as the essential principle
of the unity of objects, namely, that propositions shall be
possible, will repeatedly occur in the present chapter; and
it may serve to illustrate our views, to show that this
condition pervades even the simplest cases.
4. _Kinds._--The mental synthesis of which we have thus
spoken, gives us our knowledge of _individual_ things; it
enables me to apprehend that particular tree or man which I
now see, or, by the help of memory, the tree or the man I
saw yesterday. But the knowledge with which we have mainly
here to do is not a knowledge of individuals but of kinds;
of such classes as are indicated by common names. We have to
make assertions concerning a tree or a man in general,
without regarding what is peculiar to this man or that tree.
Now it is clear that certain individual objects are all
called _man_, or all called _tree_, in virtue of some
resemblance which they have. If we had not the power of
perceiving in the appearances around us, likeness and
unlikeness, we could not consider objects as distributed
into kinds at all. The impressions of sense would throng
upon us, but being uncompared with each other, they would
flow away like the waves of the sea, and each vanish from
our contemplation when the sensation faded. That we do
apprehend surrounding objects as belonging to permanent
kinds, as being men and horses, oaks and roses, arises from
our having the idea of likeness, and from our applying it
habitually, and so far as such a classification requires.
Not only can we employ the idea of likeness in this manner,
but we apply it incessantly and universally to {99} the
whole mass and train of our sensations. For we have no
external sensations to which we cannot apply some language
or other; and all language necessarily implies recognition
of resemblances. We cannot call an object _green_ or _round_
without comparing in our thoughts its colour or its shape,
with a shape and a colour seen in other objects. All our
sensations, therefore, without any exception of kind or
time, are subject to this constant process of
classification; and the idea of likeness is perpetually
operating to distribute them into kinds, at least so far as
the use of language requires.
We come then again to the question, Upon what principle,
under what conditions, is the Idea of Likeness thus
operative? What are the limits of the classes thus formed?
Where does that similarity end, which induces and entitles
us to call a thing a _tree_? What universal rule is there
for the application of common names, so that we may not
apply them wrongly?
5. _Not made by Definitions._--Perhaps some one might expect
in answer to these inquiries a definition or a series of
definitions;--might imagine that some description of a tree
might be given which might show when the term was applicable
and when it was not; and that we might construct a body of
rules to which such descriptions must conform. But on
consideration it will be clear that the real solution of our
difficulty cannot be obtained in such a manner. For _first_;
such descriptions must be given in words, and must therefore
suppose that we have already satisfied ourselves how words
are to be used. If we define a tree to be 'a living thing
without the power of voluntary motion,' we shall be called
upon to define 'a living thing;' and it is manifest that
this renewal of the demand for definition might be repeated
indefinitely; and, therefore, we cannot in this way come to
a final principle. And in the _next_ place, most of those
who use language, even with great precision and consistency,
would find it difficult or impossible to give good
definitions even of a few of the general names which they
use; and therefore their practice cannot be regulated by any
{100} tacit reference to such definitions. That definitions
of terms are of great use and importance in their right
place, we shall soon see; but their place is not to regulate
the use of common language.
What then, once more, is this regulative principle? What
rules do men follow in the use of words, so as commonly to
avoid confusion and ambiguity? How do they come to
understand each other so well as they ordinarily do,
respecting the limits of classes never defined, and which
they cannot define? What is the common Convention, or
Condition to which they conform?
6. _Condition of the Use of Terms._--To this we reply, that
the Condition which regulates the use of language, is, that
it shall be capable of being used;--that is, that general
assertions shall be possible. The term _tree_ is applicable
as far as it is useful in expressing our knowledge
concerning trees:--thus we know that trees are fixed in the
ground, have a solid stem, branches, leaves, and many other
properties. With regard to all the objects which surround
us, we have an immense store of knowledge of such
properties, and we employ the names of the objects in such a
manner as enables us to express these properties.
But the connexion of such properties is variable and
indefinite. Some properties are constantly combined, others
occasionally only. The leaves of different oaks resemble
each other, the branches resemble far less, and may differ
very widely. The term _oak_ does not enable us to say that all
oaks have straight branches or all crooked. Terms can only
express properties as far as they are constant. Not only,
therefore, the accumulation of a vast mass of knowledge of
the properties and attributes of objects, but also an
observation of the habitual _connexion_ of such properties
is needed, to direct us to the consistent application of
terms:--to enable us to apply them so as to express truths.
But here again we are largely provided with the requisite
knowledge and observation by the common course of our
existence. The unintermitting stream of experience supplies
us with an incalculable {101} amount of such observed
connexions. All men have observed that the associations of
the same form of leaves are more constant than of the same
form of branches;--that though persons walk in different
attitudes, none go on all fours; and thus the term _oak_ is
so applied as to include those cases in which the leaves are
alike in form though the branches be unlike; and though we
should refuse to apply the term _man_ to a class of
creatures which habitually and without compulsion used four
legs, we make no scruple of affixing it to persons of very
different figures. The whole of human experience being
composed of such observed connexions, we have thus materials
even for the immense multiplicity of names which human
language contains; all which names are, as we have said,
regulated in their application by the condition of their
expressing such experience.
Thus amid the countless combinations of properties and
divisions of classes which the structure of language
implies, scarcely any are arbitrary or capricious. A word
which expressed a mere wanton collection of unconnected
attributes could hardly be called a _word_; for of such a
collection of properties no truth could be asserted, and the
word would disappear, for want of some occasion on which it
could be used. Though much of the fabric of language
appears, not unnaturally, fantastical and purely
conventional, it is in fact otherwise. The associations and
distinctions of phraseology are not more fanciful than is
requisite to make them correspond to the apparent caprices
of nature or of thought; and though much in language may be
called conventional, the conventions exist for the sake of
expressing some truth or opinion, and not for their own
sake. The principle, that _the condition of the use of terms
is the possibility of general, intelligible, consistent
assertions_, is true in the most complete and extensive sense.
7. _Terms may have different Uses._--The Terms with which we
are here most concerned are Names of Classes of natural
objects; and when we say that the principle and the limit of
such Names are their use in expressing propositions
concerning the classes, it is {102} clear that much will
depend on the kind of propositions which we mainly have to
express: and that the same name may have different limits,
according to the purpose we have in view. For example, is
the _whale_ properly included in the general term _fish_?
When men are concerned in catching marine animals, the main
features of the process are the same however the animals may
differ; hence whales are classed with fishes, and we speak
of the _whale-fishery_. But if we look at the analogies of
organization, we find that, according to these, the whale is
clearly not a fish, but a _beast_, (confining this term, for
the sake of distinctness, to suckling beasts or _mammals_).
In Natural History, therefore, the whale is not included
among fish. The indefinite and miscellaneous propositions
which language is employed to enunciate in the course of
common practical life, are replaced by a more coherent and
systematic collection of properties, when we come to aim at
scientific knowledge. But we shall hereafter consider the
principle of the classifications of Natural History; our
present subject is the application of the Idea of Likeness
in common practice and common language.
8. _Gradation of Kinds._--Common names, then, include many
individuals associated in virtue of resemblances, and of
permanently connected properties; and such names are
applicable as far as they serve to express such properties.
These collections of individuals are termed _Kinds_,
_Sorts_, _Classes_.
But this association of particulars is capable of degrees.
As individuals by their resemblances form Kinds, so kinds of
things, though different, may resemble each other so as to
be again associated in a higher Class; and there may be
several successive steps of such classification. _Man_,
_horse_, _tree_, _stone_, are each a name of a Kind; but
_animal_ includes the two first and excludes the others;
_living thing_ is a term which includes _animal_ and _tree_
but not _stone_; _body_ includes all the four. And such a
subordination of kinds may be traced very widely in the
arrangements of language. {103}
The condition of the use of the wider is the same as that of
the narrower Names of Classes;--they are good as far as they
serve to express true propositions. In common language,
though such an order of generality may in a variety of
instances be easily discerned, it is not systematically and
extensively referred to; but this subordination and
graduated comprehensiveness is the essence of the methods
and nomenclatures of Natural History, as we shall soon have
to show.
But such subordination is not without its use, even in
common cases, and when it is expressed in the terms of
common language. Thus _organized body_ is a term which
includes plants and animals; _animal_ includes beasts,
birds, fishes; _beast_ includes horses and dogs; _dogs_,
again, are greyhounds, spaniels, terriers.
9. _Characters of Kinds._--Now when we have such a Series of
Names and Classes, we find that we take for granted
irresistibly that each class has some _Character_ which
distinguishes it from other classes included in the superior
division. We ask what kind of beast a dog is; what kind of
animal a beast is; and we assume that such questions admit
of answer;--that each kind has some mark or marks by which
it may be described. And such descriptions may be given: an
animal is an organized body _having sensation and volition_;
man is a _reasonable_ animal. Whether or no we assent to the
exactness of these definitions, we allow the propriety of
their form. If we maintain these definitions to be wrong, we
must believe some others to be right, however difficult it
may be to hit upon them. We entertain a conviction that
there must be, among things so classed and named, a
possibility of defining each.
Now what is the foundation of this postulate? What is the
ground of this assumption, that there must exist a
definition which we have never seen, and which perhaps no
one has seen in a satisfactory form? The knowledge of this
definition is by no means necessary to our using the word
with propriety; for any one can make true assertions about
dogs, but who can define a {104} dog? And yet if the
definition be not necessary to enable us to use the word,
why is it necessary at all? I allow that we possess an
indestructible conviction that there must be such a
character of each kind as will supply a definition; but I
ask, on what this conviction rests.
I reply, that our persuasion that there must needs be
characteristic marks by which things can be defined in
words, is founded on the assumption of _the necessary
possibility of reasoning_.
The reference of any object or conception to its class
without definition, may give us a persuasion that it shares
the properties of its class, but such classing does not
enable us to reason upon those properties. When we consider
man as an animal, we ascribe to him in thought the
appetites, desires, affections, which we habitually include
in our notion of animal: but except we have expressed these
in some definition or acknowledged description of the term
_animal_, we can make no use of the persuasion in
ratiocination. But if we have described animals as 'being
impelled to action by appetites and passions,' we can not
only think, but say, 'man is an animal, and therefore he is
impelled to act by appetites and passions.' And if we add a
further definition, that 'man is a reasonable animal,' and
if it appear that 'reason implies conformity to a rule of
action,' we can then further infer that man's nature is to
conform the results of animal appetite and passion to a rule
of action.
The possibility of pursuing any such train of reasoning as
this, depends on the definitions, of _animal_ and of _man_,
which we have introduced; and the possibility of reasoning
concerning the objects around us being inevitably assumed by
us from the constitution of our nature, we assume
consequently the possibility of such definitions as may thus
form part of our deduction, and the existence of such
defining characters.
10. _Difficulty of Definitions._--But though men are, on
such grounds, led to make constant and importunate _demands_
for definitions of the terms which they employ in their
speculations, they are, in fact, far {105} from being able
to carry into complete effect the postulate on which they
proceed, that they must be able to find definitions which by
logical consequence shall lead to the truths they seek. The
postulate overlooks the process by which our classes of
things are formed and our names applied. This process
consisting, as we have already said, in observing permanent
connexions of properties, and in fixing them by the
attribution of names, is of the nature of the process of
Induction, of which we shall afterwards have to speak. And
the postulate is so far true, that this process of induction
being once performed, its result may usually be expressed by
means of a few definitions, and may thus lead by a deduction
to a train of real truths.